http://www.scirp.org/journal/ojpchem
ISSN Online: 2165-6711
ISSN Print: 2165-6681
Department of Polymer and Surface Engineering, Institute of Chemical Technology (ICT), Mumbai, India
Keywords
Urea Formaldehyde Resins, Catalysts, Gel Time, Wood, pH,
Polyvinyl Acetate, Composite
1. Introduction
Urea-formaldehyde (UF) resin is one of the most important thermosetting ad-
hesive systems of interior class with the largest tonnage consumption (approx-
imately 1 million metric tons/annum) in wood processing industry and particu-
larly in wood-based panel (WBP) production [4]. The resin is used in the pro-
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R. V. Gadhave, P. T. Gadekar
requires changes in the processing conditions, including the resin system used.
The acidity of wood and the acid catalyst mixed in the adhesive play a very im-
portant role in providing (or generating) the optimum combined pH environ-
ment at the inter-phase during UF resin curing. To obtain optimum bond
strength, the press time and temperature must be adjusted for the pH environ-
ment. If this correction is not precise, the glue line will be uncured or over-cured
and will result in poor bond strength [12] [13] [14] [15] [16]. Gel time is a pa-
rameter which can correlate with process-ability of manufacturing of wood-
based composite panels.
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R. V. Gadhave, P. T. Gadekar
36
R. V. Gadhave, P. T. Gadekar
37
R. V. Gadhave, P. T. Gadekar
UF resin was reactively blended with various concentration of starch [32], es-
terified starch [33] [34] [35] and oxidized starch [36] as wood and wood compo-
site adhesive. It is found that new system with UF-starch blending has advantag-
es of low brittleness, low formaldehyde emission and water resistance characte-
ristics [32]. In esterified-starch blended UF adhesive strength found to be com-
parable with synthetic resin adhesive system and content of free formaldehyde
was lower than 0.3% [23] [24] [25]. Oxidized starch blended UF resin adhesive
has good chemical stability, insulating properties, temperature resistance, aging
resistance, oil resistance and mildew resistance and environmentally-friendly
starch adhesive has no harm to the human body and can be applied to wood ad-
hesion [37] [38] [39]. UF resin and modified starch mutual react and form a net
structure, water resistance of starch glue was improved, and drying time was
shortened [40] [41] [42]. So ultimately in above all systems few parts of UF were
replaced by starch, because of which formaldehyde emissions were reduced and
cost is maintained.
Addition of cross-linker in starch-urea formaldehyde blends system
UF-Starch blended adhesives were modified with different cross-linkers for
improvement in performance properties. Starch adhesives were modified by
isocyanate as cross-linker [43] [44] [45] [46] [47] [48] as well as starch adhesive
with polyvinyl alcohol, borax, and carboxy methyl cellulose (CMC) as system [4]
[49] [50] [51] [52] for wood composite can be prepared with isocyante as cross-
linker, influence factors on the bonding strength and water resistance of starch
adhesive were studied by different solid content, adding isocyanate and additives
like PVA, Acrylic emulsion. Bonding strength and water resistance were im-
proved significantly by adding additives and isocyanates to starch. An environ-
mentally friendly wood adhesive was developed by cross-linking cornstarch-UF
blend system with hexamethoxymethylmelamine (HMMM). It exhibited excel-
lent mechanical properties comparable to many of the commercially available
urea-formaldehyde plywood adhesives used for interior applications [53].
Blending of UF resin with polyvinyl acetate emulsion adhesive
The UF adhesive was modified with poly (vinyl acetate) to increase water re-
sistance.
Modification UF with the use of various natural derived materials like tannin,
lignin, cellulose, crude pyrolysis oil of wood, and soy have been carried out [54]
[55] [56] [57]. Also combination of UF and MF is used for plywood industries.
3. Conclusions
Process-ability/manufacturing of wood composite like medium density board,
particle board, plywood based on UF resin is a difficult task for manufactures
because various factors that can interfere with the curing process. From this re-
view paper, we concluded that gel time of urea formaldehyde resin is depended
on following factors:
1) Wood extractives
2) Wood pH values (Fiber acidity)
38
R. V. Gadhave, P. T. Gadekar
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