Stable Isotopes

Delta Deuterium - per mil

0
1; -10
-10 -10

-20 1; -20

-40

-60

-80

-100

-120

-140

-160
-22 -20 -18 -16 -14 -12 -10 -8 -6 -4 -2 0 2 4 6 8 10

Delta Oxygen 18 - per mil

371326787.xlsx 11/11/2017
Discharge Enthalpy - kj/kg

3000

2500

2000

1500

1000

500

0
0 500 1000 1500 2000 2500 3000 3500 4000
Chloride - ppm
Q u a r tz G e o th e r m o m e te r E n th a lp y - k j/k

3000

2500

2000

1500

1000

500

0
0 500 1000 1500 2000 2500 3000 3500 4000

Chloride - ppm
 1.0
10Mg/(10Mg+Ca)

0.9

0.8

0.7

0.6

0.5

0.4

0.3

0.2

0.1

0.0
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
10K/(10K+Na)
 log(K2/Mg)
0 1 2 3 4 5 6 7
-1 -4

Log(PCO2) bar
2; 0.2
0 -3
log(K2/Ca)

1 -2

2 -1

3 0

4 1

5 2
 log (K2/Mg)

0 1 2 3 4 5 6
0

100
SiO2 mg/kg

200 22
8

300
333
363

400

500

600
 18; 0.90

18
;0
.90
15; 0.80

15
;0
.80
14; 0.70

14
;0
.70
11; 0.60

11;
0.6
10; 0.50

0
10
;0
.50

7; 0.40
7;
0.4
0

6; 0.30
6;

Partial Equilibration
0.3
0

16; 0.189 3; 0.20

3;

17; 0.151
Immature Waters
0.2
0

2; 0.10
18; 0.080
2;
0.1

.00

.00

.00

.00
0

0
0

0.0
0.0

0.0

0.0

0.0

0.000 1; 0 ;0

;0

;0

;0
12

13

16

17
1;

4;

5;

8;

9;
 18; 0.90

18
;0
.90
15; 0.80

15
;0
.80
14; 0.70

14
;0
.70
11; 0.60

11;
0.6 10; 0.50
0
10
;0
.50

7; 0.40
7;
0.4
0

6; 0.30
6;
0.3
0

3; 0.20
3;
0.2
0

2; 0.10
2;
0.1

.00

.00

.00

.00
0

0
0

0.0

0.0

0.0

0.0

0.0

1; 0 ;0

;0

;0

;0
12

13

16

17
1;

4;

5;

8;

9;
 18; 0.90

18
;0
.90
15; 0.80

15
;0
.80
14; 0.70

14
;0
.70
11; 0.60

11;
0.6 10; 0.50
0
10
;0
.50

7; 0.40
7;
0.4
0

6; 0.30
6;
0.3
0

3; 0.20
3;
0.2
0

2; 0.10
2;
0.1

.00

.00

.00

.00
0

0
0

0.0
0.0

0.0

0.0

0.0

1; 0
;0

;0

;0

;0
12

13

16

17
1;

4;

5;

8;

9;
 Li - Rb - Cs Ternary

0.90

0.9
0
0.80

0.8
0
0.70

0.7
0
0.60

0.6
0 0.50
0.5
0

0.40
0.4
0

0.30
0.3
0

3; 0.20
3;
0.2
0

2; 0.10
2;
0.1

0
0

0.0
0.0

0
1; 0
0.0

0.0

0.0

0.0

0.0

0.0

0.0
1;

4;

371326787.xlsx 11/11/2017
 0.90

0.9
0
0.80

0.8
0
0.70

0.7
0
0.60

0.6
0 0.50
0.5
0

0.40
0.4
0

0.30
0.3
0

3; 0.20
3;
0.2
0

2; 0.10
2;
0.1

0
0

0.0
0.0

0
1; 0
0.0

0.0

0.0

0.0

0.0

0.0

0.0
1;

4;
 Li - Rb - Cs Ternary

0.90

0.9
0
0.80

0.8
0
0.70

0.7
0
0.60 2; 0.6003; 0.600

0.6
0
0.50
0.5
0

0.40
0.4
0

0.30
0.3
0

3; 0.20
3;
0.2
0

2; 0.10
2;
0.1

0
0

0.0

0.0

0
1; 0
0.0

0.0

0.0

0.0

0.0

0.0

0.0
1;

4;

371326787.xlsx 11/11/2017
 Trili
near
cati
ons
A
grid
cati
ons
B
grid
cati
ons
C
grid
Cati
ons
anio
ns A
grid

2;
7
anio

0.9

97
ns B

%
1;
80% grid

3;
7
80% anio

0.7

77
ns C

0
%

0.8
4; grid

2;
7
60% 60%
0.5
57
%

0
0.6
5;

3;
40% 40%
37

7
0.3
%

0
0.4
20% 20%
1; 0.1732

0
0.2
1; 0%
1; 0 4; 0% 5; 0% 0% 1; 0
 Prospect Map

659000
----
----
----
----
----
----
----
----
----
----
---
654000
UTM North

649000

644000

639000

634000
350000 355000 360000 365000 370000
UTM East
Geothermometers
Temperatures in degrees C

Amorphous Alpha Beta Chalcedony Quartz

Silica Cristobalite Cristobalite conductive conductive
Sample Name
C-02 -11 55 8 76 106
C-03 -11 55 8 76 106
C-04 -15 50 4 71 101
C-05 -53 6 -37 22 55
C-06 -78 -23 -64 -9 19
C-07 -47 14 -30 31 63
C-08 -48 12 -31 29 62
C-09 -39 22 -23 40 72
C-10 17 87 38 111 138
C-11 -11 55 8 76 106
C-12 55 129 79 157 179
C-13 71 146 96 176 196
C-14 66 141 91 171 191
C-15 66 141 91 171 191
C-16 59 133 83 162 184
C-17 77 153 103 184 202
C-18 -2 65 18 87 116
C-19 -37 25 -20 43 75
C-20 19 89 40 113 140
C-21 38 110 61 137 161
C-22 37 109 59 135 159
C-23 35 106 57 132 157
C-24 -11 55 8 76 106
C-25 33 105 56 131 155
C-26 46 119 69 146 169
C-27 43 116 66 143 166
C-28 42 115 65 142 166
C-29 44 117 68 144 168
C-30 40 112 63 139 163
C-31 41 114 64 141 164
 Na/K Na/K
Quartz Na-K-Ca Na/K Na/K Tonani
Na-K-Ca Truesdell Giggenbach
adiabatic Mg corr Fournier 1979 1980
1976 1988
106 10 10 12 -38 34 -25
106 38 38 297 293 305 343
102 31 31 382 422 381 492
61 27 27 328 339 334 396
33 1 1 252 233 265 274
68 28 28 325 335 331 391
67 #DIV/0! #DIV/0! #DIV/0! #DIV/0! Err:502 Err:502
76 -7 -7 238 214 251 252
133 99 99 196 161 213 194
106 74 74 203 170 219 204
167 169 169 194 159 211 191
180 179 179 192 157 209 189
177 170 170 185 148 202 178
177 177 177 188 152 205 183
171 175 175 195 160 212 192
185 184 184 195 161 212 193
115 63 63 209 178 225 212
78 11 11 270 257 281 301
135 87 87 543 715 517 846
152 86 86 148 104 167 130
151 87 87 144 100 164 126
149 81 81 146 102 165 128
106 52 52 188 152 206 184
148 83 83 153 110 172 136
159 91 91 143 99 163 125
157 93 93 145 101 164 127
156 92 92 144 100 163 126
158 90 90 147 103 166 129
154 91 91 145 101 164 127
155 84 84 144 100 163 126
 Na/K Na/K
K/Mg
Nieva & Nieva Arnorsson
Giggenbach 1986
1987 1983
4 -26 19
282 294 48
366 410 46
313 335 35
238 237 16
310 331 42
Err:502 Err:502 0
224 220 12
183 170 89
190 179 66
181 168 121
180 166 143
172 157 136
175 161 167
182 169 131
183 169 172
196 186 71
256 260 29
523 658 89
136 115 81
133 112 80
134 113 76
176 162 57
141 121 78
132 110 82
133 112 83
132 111 82
135 114 84
133 112 81
133 111 78
Liquid chemistry plotting spreadsheet version 3

Powell Geoscience Ltd. 3 September 2012

Copy water chemistry data into data field below. Use negative numbers to
plotted at detection. Cut & paste or move data but do not d

Sample UTM east UTM north

Sample Name Lab Number Date Label Elevation
C-01 C-01 C-01 660202.6 9236718.1
C-02 C-02 C-02 659581.1 9235494
C-03 C-03 C-03 658270.2 9237037.3
C-04 C-04 C-04 658321 9238080.4
C-05 C-05 C-05 658836 9238869
C-06 C-06 C-06 660268.9 9241224.8
C-07 C-07 C-07 661154.7 9238961.1
C-08 C-08 C-08 662462.7 9235833.3
C-09 C-09 C-09 664644.4 9237271.7
C-10 C-10 C-10 664620.9 9237281.7
C-11 C-11 C-11 664586.2 9237622.2
C-12 C-12 C-12 664537.3 9237637
C-13 C-13 C-13 664587.6 9237635.3
C-14 C-14 C-14 664572.5 9237654
C-15 C-15 C-15 664565.3 9237703.2
C-16 C-16 C-16 664550.2 9237931.4
C-17 C-17 C-17 664812.7 9238368.9
C-18 C-18 C-18 664455.1 9239580.5
C-19 C-19 C-19 664577.2 9237860.2
C-20 C-20 C-20 660562 9233320.3
C-21 C-21 C-21 660553.9 9233302.6
C-22 C-22 C-22 660534.9 9233301
C-23 C-23 C-23 660543.3 9233233.2
C-24 C-24 C-24 660525.8 9233253.8
C-25 C-25 C-25 660593.8 9233343.1
C-26 C-26 C-26 660585 9233351.7
C-27 C-27 C-27 660585 9233351.8
C-28 C-28 C-28 660592.6 9233360.6
C-29 C-29 C-29 660593 9233321.1
C-30 C-30 C-30 660562 9233320.3
C-31 C-31 C-31 660601.1 9233308.2
C-32 C-32 C-32 660593.9 9233377
C-33 C-33 C-33 660508.7 9233506.2
C-34 C-34 C-34 660550.9 9233456
C-35 C-35 C-35 660553.6 9233447.7
C-36 C-36 C-36 660575 9233444.2
C-37 C-37 C-37 660636.6 9233314.4
C-38 C-38 C-38 660620 9233306.3
C-39 C-39 C-39 660604.4 9233264
C-40 C-40 C-40 660696.7 9233316.9
C-41 C-41 C-41 660696.7 9233316.9
 CFB Ternary
factor
Cl 1
ld below. Use negative numbers to indicate detection limit. Data will be Ternary plot
& paste or move data but do not delete lines or columns. multiplier factors: F 25
B 25

Steam
Temp C Fraction pH Li Na K Ca Mg SiO2
35.9 8.84 0.033 73 0 2.9 0.21 54
25.4 7.51 0.005 9 2 10.3 2.13 54
23.8 6.76 0.005 3 1 6.4 1.62 49
25.8 6.66 0.005 2 1 1.8 0.80 16
24.9 6.33 0.005 1 0 0.6 0.30 6
25 7.26 0.005 2 1 2.0 0.52 20
26.1 5.66 0.005 3 0 1.6 0.41 19
24.9 6.92 0.005 1 0 2.6 1.07 25
54.2 6.92 0.578 132 10 24.7 1.75 100
33.4 8.04 0.212 51 4 12.6 2.00 54
99.4 7.71 1.314 320 24 46.2 0.98 196
97.7 8.13 1.724 397 29 21.4 0.39 248
98.7 8.15 1.459 392 26 30.0 0.46 233
99.6 8.09 1.685 439 31 21.5 0.11 233
98.9 8.2 1.519 350 27 29.8 0.67 209
99 8.08 1.917 437 34 18.8 0.10 270
53.6 6.83 0.292 83 8 62.1 4.14 67
24.9 7.12 0.005 4 1 8.9 2.07 26
98.7 7.02 0.005 8 8 6.7 1.01 104
96.6 8.08 0.238 267 10 62.4 3.54 149
87 7.57 0.26 292 11 64.5 3.89 145
87.2 7.79 0.212 252 10 65.2 4.20 139
34 7.44 0.036 45 3 22.7 2.63 54
75.5 6.84 0.22 249 11 71.1 4.41 136
95.8 7.97 0.305 309 11 60.4 3.70 169
97.4 8.03 0.262 310 12 57.5 3.71 162
100.1 7.92 0.279 307 11 57.0 3.80 160
104.2 8.15 0.283 297 11 64.3 3.32 165
99.2 8.31 0.273 294 11 56.6 3.71 153
100.7 8.35 0.241 236 9 48.3 3.16 157
72.3 8.02 0.238 249.8 9.27 65.7 3.52 144.3
99.9 8.26 0.27 287.9 10.6 58 3.33 156.5
28.2 8.13 0.005 25.5 0.96 14.7 2.6 33
86.7 8.08 0.229 194.2 7.11 49.5 2.82 139.7
80.6 7.47 0.238 202.2 7.65 51.7 2.09 131.6
69.3 7.8 0.193 260.9 9.69 59.2 3.27 119.4
97.4 7.43 0.229 210.9 8.45 52.2 3.99 144.1
76.4 7.38 0.189 174.6 7.62 51.1 4.95 120.3
78.9 7.35 0.182 203.9 7.65 44.9 2.33 105.1
82.9 7.12 0.257 291.7 10.9 64 10.89 132.9
31.7 7.05 0.005 0.2 0.05 0.24 0.05 0.5
CLB Ternary LRC Ternary CSH Ternary NKM Ternary XYZ Ternary
factor factor factor factor column element
Cl 1 Li 1 Cl 1 Na 1 K Li
Li 100 Rb 4 SO4 1 K 10 Y Rb
B 25 Cs 10 HCO3 1 Mg^.5 1000 Z Cs
mg/kg

B Cl F SO4 HCO3 CO3 NH4 As Rb Cs

0 1 0 8 188 0.1 0.034
0 2 0 1 65 0.1 0.016
0 1 0 0 40 0.2 0.016
0 2 0 1 14 0.4 0.005
0 1 0 1 5 0.1 0.005
0 1 0 1 15 0.1 0.007
0 1 0 1 10 0.2 0.008
0 1 0 0 12 0.1 0.008
8 158 1 56 101 0.1 0.979
3 61 0 24 59 0.3 0.351
20 408 2 123 185 0.1 1.59
28 532 2 157 112 0.2 2.712
26 519 2 153 137 0.1 2.378
29 596 2 172 102 0.1 2.158
24 460 2 137 125 0.1 2.108
30 590 2 170 108 0.1 2.611
4 87 0 81 188 0.1 0.72
0 1 0 5 46 0.1 0.148
0 1 0 32 20 0.2 0.234
3 251 3 227 183 0.6 0.252
3 286 3 261 189 0.7 0.205
3 237 3 230 203 0.7 0.175
1 38 1 52 67 0.1 0.075
3 230 3 240 211 1.2 0.126
3 311 3 264 189 0.7 0.181
3 315 3 267 169 0.7 0.146
3 312 3 268 166 1.2 0.13
3 309 3 249 186 1.1 0.146
3 299 3 265 164 0.7 0.113
3 227 3 206 167 0.4 0.109
2.64 250.2 2.89 225.7 196.2 0.76 0.121
2.9 296.3 3.22 251.5 171.8 0.5 0.113
0.1 24.45 0.3 24.28 51.9 0.06 0.025
2.48 180.8 2.41 175.3 199.3 0.64 0.091
2.38 201 2.4 196.9 198.3 0.6 0.093
2.09 258.4 2.92 232.6 167.8 0.27 0.09
2.67 200.7 2.44 185.3 191.1 0.21 0.09
2.29 162.7 2.18 168.4 210.5 0.91 0.052
1.99 193.4 2.43 195.6 206.4 1.02 0.045
2.49 291.1 3.32 269 180 0.32 0.092
0.06 0.13 0.05 0.1 0.05 0.005
YZ Ternary Isotopes Fixed address field for input data
factor
1 Position of fractionation cluster -10 -20 Copy of input columns using indirect cell ad
4 Position of meteoric trend line label -16 input field column:
10 D E F

Sample UTM
Cond UTM East
Sr Ba Fe Mn umhos/cm del 18O del D Label North
0.054 -6.63 -41.3 C-01 660202.6 9236718.1
0.012 -6.48 -39.6 C-02 659581.1 9235494
0.031 -6.24 -36.6 C-03 658270.2 9237037.3
0.013 -6.58 -38.3 C-04 658321 9238080.4
0.105 -6.73 -39.5 C-05 658836 9238869
0.056 -6.04 -33.7 C-06 660268.9 9241224.8
0.05 -5.91 -35.2 C-07 661154.7 9238961.1
0.019 -6.38 -36.9 C-08 662462.7 9235833.3
0.033 -5.79 -34.7 C-09 664644.4 9237271.7
0.018 -6.45 -37.7 C-10 664620.9 9237281.7
0.018 -6.34 -36.8 C-11 664586.2 9237622.2
0.005 -6.25 -36.3 C-12 664537.3 9237637
0.005 -5.46 -36.6 C-13 664587.6 9237635.3
0.005 -6.06 -36.8 C-14 664572.5 9237654
0.005 -5.9 -35.5 C-15 664565.3 9237703.2
0.005 -5.73 -36.9 C-16 664550.2 9237931.4
0.005 -6.06 -37.6 C-17 664812.7 9238368.9
0.015 -6.32 -36.4 C-18 664455.1 9239580.5
0.019 -4.07 -32.5 C-19 664577.2 9237860.2
0.005 -5.7 -35.8 C-20 660562 9233320.3
0.005 -5.8 -35.5 C-21 660553.9 9233302.6
0.005 -6.0 -37.8 C-22 660534.9 9233301
0.017 -6.0 -35.2 C-23 660543.3 9233233.2
0.023 -6.1 -37.1 C-24 660525.8 9233253.8
0.011 -5.6 -33.2 C-25 660593.8 9233343.1
0.005 -5.5 -34 C-26 660585 9233351.7
0.005 -5.4 -32.8 C-27 660585 9233351.8
0.005 -5.6 -34.1 C-28 660592.6 9233360.6
0.005 -5.6 -34.5 C-29 660593 9233321.1
0.005 -5.6 -34.9 C-30 660562 9233320.3
0.005 -5.62 -35 C-31 660601.1 9233308.2
0.005 -5.78 -36.2 C-32 660593.9 9233377
0.014 -6.03 -36.4 C-33 660508.7 9233506.2
0.005 -5.94 -35.6 C-34 660550.9 9233456
0.005 -5.94 -35 C-35 660553.6 9233447.7
0.01 -6.05 -35.9 C-36 660575 9233444.2
0.012 -5.77 -34.5 C-37 660636.6 9233314.4
0.005 -5.61 -33.9 C-38 660620 9233306.3
0.005 -5.76 -35.8 C-39 660604.4 9233264
0.005 -5.32 -34.7 C-40 660696.7 9233316.9
0.005 - -
 for input data

mns using indirect cell addresses to prevent changes to data addresses due to cut and move editing. Converts values to absolute

G H I J K L M N O P
mg/kg => meq/litre 0.14411 0.04350 0.02557 0.04990 0.08226
Steam
Elevation Temp C Fraction pH Li Na K Ca Mg SiO2
0 35.9 0 8.84 0.033 72.6 0.12 2.9 0.21 54
0 25.4 0 7.51 0.005 8.64 1.92 10.3 2.13 54.4
0 23.8 0 6.76 0.005 3.45 1.46 6.44 1.62 49
0 25.8 0 6.66 0.005 2.08 0.6 1.76 0.80 15.8
0 24.9 0 6.33 0.005 0.82 0.12 0.56 0.30 6
0 25 0 7.26 0.005 2.38 0.67 1.98 0.52 19.7
0 26.1 0 5.66 0.005 3.01 0 1.62 0.41 19
0 24.9 0 6.92 0.005 1.43 0.18 2.58 1.07 24.7
0 54.2 0 6.92 0.578 132 10.2 24.7 1.8 100.3
0 33.4 0 8.04 0.212 50.8 4.3 12.6 2.0 54.4
0 99.4 0 7.71 1.314 320.2 24.1 46.2 1.0 195.8
0 97.7 0 8.13 1.724 396.9 29.3 21.4 0.4 247.7
0 98.7 0 8.15 1.459 392.1 26.2 30 0.5 232.8
0 99.6 0 8.09 1.685 439.3 30.6 21.5 0.1 233.2
0 98.9 0 8.2 1.519 349.7 26.7 29.8 0.7 208.7
0 99 0 8.08 1.917 436.8 33.5 18.8 0.1 270
0 53.6 0 6.83 0.292 82.9 7.54 62.1 4.1 66.9
0 24.9 0 7.12 0.005 4 0.7 8.92 2.1 26.4
0 98.7 0 7.02 0.005 7.91 7.75 6.69 1.0 103.9
0 96.6 0 8.08 0.238 266.9 10.4 62.4 3.5 149
0 87 0 7.57 0.26 292.4 10.8 64.5 3.9 144.6
0 87.2 0 7.79 0.212 252.3 9.52 65.2 4.2 139.3
0 34 0 7.44 0.036 45 3.16 22.7 2.63 54.1
0 75.5 0 6.84 0.22 249.4 10.5 71.1 4.41 136.2
0 95.8 0 7.97 0.305 308.6 11.2 60.4 3.7 169.3
0 97.4 0 8.03 0.262 310.4 11.6 57.5 3.71 162.1
0 100.1 0 7.92 0.279 307.4 11.3 57 3.8 159.8
0 104.2 0 8.15 0.283 297.3 11.4 64.3 3.32 165.3
0 99.2 0 8.31 0.273 294.4 11 56.6 3.71 153
0 100.7 0 8.35 0.241 236.3 8.71 48.3 3.16 157.1
72.3 0 8.02 0.238 249.8 9.27 65.7 3.52 144.3
99.9 0 8.26 0.27 287.9 10.6 58 3.33 156.5
28.2 0 8.13 0.005 25.5 0.96 14.7 2.6 33
86.7 0 8.08 0.229 194.2 7.11 49.5 2.82 139.7
80.6 0 7.47 0.238 202.2 7.65 51.7 2.09 131.6
69.3 0 7.8 0.193 260.9 9.69 59.2 3.27 119.4
97.4 0 7.43 0.229 210.9 8.45 52.2 3.99 144.1
76.4 0 7.38 0.189 174.6 7.62 51.1 4.95 120.3
78.9 0 7.35 0.182 203.9 7.65 44.9 2.33 105.1
82.9 0 7.12 0.257 291.7 10.9 64 10.89 132.9
31.7 0 7.05 0.005 0.2 0.05 0.24 0.05 0.5
verts values to absolute to plot at detection limit. Values in Row 6 are factors to convert mg/kg to miliequivalents per litre for charg

Q R S T U V W X Y
0.02821 0.05264 0.02082 0.01639 0.03333 0.05544

B Cl F SO4 HCO3 CO3 NH4 As Rb

0.25 1.34 0.18 7.51 187.6 0 0.12 0.034 0
0.08 1.77 0 1.05 65.1 0 0.05 0.016 0
0.07 0.8 0 0.45 39.7 0 0.2 0.016 0
0.07 1.71 0 0.6 13.7 0 0.4 0.005 0
0.06 0.82 0 0.96 5.1 0 0.1 0.005 0
0.06 0.6 0 0.7 15.3 0 0.05 0.007 0
0.05 0.85 0 0.78 10.2 0 0.16 0.008 0
0.05 1.38 0 0.48 12.1 0 0.1 0.008 0
7.88 157.9 0.82 55.96 100.7 0 0.11 0.979 0
3.06 60.54 0.31 23.99 59 0 0.26 0.351 0
19.65 408.2 1.75 123.1 184.6 0 0.05 1.59 0
27.79 531.8 2.15 157.3 111.8 0 0.2 2.712 0
26.42 518.9 2.11 152.7 137.3 0 0.05 2.378 0
28.99 595.5 2.32 172.2 101.7 0 0.05 2.158 0
23.94 460 1.96 137.4 125.1 0 0.1 2.108 0
30.19 590.3 2.31 170 107.8 0 0.05 2.611 0
4.2 86.94 0.37 80.52 187.6 0 0.05 0.72 0
0.27 0.77 0.1 5.49 45.8 0 0.1 0.148 0
0.28 1.19 0.15 32.36 19.8 0 0.17 0.234 0
2.79 251 3.02 227.1 183.1 0 0.61 0.252 0
2.75 285.5 3.31 261.3 189.2 0 0.67 0.205 0
2.62 236.8 3.02 230.3 202.9 0 0.69 0.175 0
0.51 38.12 0.5 51.7 67.1 0 0.05 0.075 0
2.53 229.7 3.21 239.5 210.5 0 1.22 0.126 0
3.18 311 3.35 264.1 189.2 0 0.65 0.181 0
3.04 314.8 3.47 266.9 168.8 0 0.67 0.146 0
2.97 312 3.36 268.1 165.7 0 1.19 0.13 0
3.08 309.3 3.23 248.7 186.1 0 1.08 0.146 0
2.79 298.8 3.27 265.4 163.7 0 0.69 0.113 0
2.94 227.4 2.78 206.3 166.7 0 0.43 0.109 0
2.64 250.2 2.89 225.7 196.2 0 0.76 0.121 0
2.9 296.3 3.22 251.5 171.8 0 0.5 0.113 0
0.1 24.45 0.3 24.28 51.9 0 0.06 0.025 0
2.48 180.8 2.41 175.3 199.3 0 0.64 0.091 0
2.38 201 2.4 196.9 198.3 0 0.6 0.093 0
2.09 258.4 2.92 232.6 167.8 0 0.27 0.09 0
2.67 200.7 2.44 185.3 191.1 0 0.21 0.09 0
2.29 162.7 2.18 168.4 210.5 0 0.91 0.052 0
1.99 193.4 2.43 195.6 206.4 0 1.02 0.045 0
2.49 291.1 3.32 269 180 0 0.32 0.092 0
0.06 0.13 0.05 0.1 0 0 0.05 0.005 0
miliequivalents per litre for charge balance calculation.

Z AA AB AC AD AE AF AG D
0.03581
Cond isotope
Cs Sr Ba Fe Mn umohs/cm delO-18 delD labels
0 0 0 0.054 0 0 -6.63 -41.3 C-01
0 0 0 0.012 0 0 -6.48 -39.6 C-02
0 0 0 0.031 0 0 -6.24 -36.6 C-03
0 0 0 0.013 0 0 -6.58 -38.3 C-04
0 0 0 0.105 0 0 -6.73 -39.5 C-05
0 0 0 0.056 0 0 -6.04 -33.7 C-06
0 0 0 0.05 0 0 -5.91 -35.2 C-07
0 0 0 0.019 0 0 -6.38 -36.9 C-08
0 0 0 0.033 0 0 -5.79 -34.7 C-09
0 0 0 0.018 0 0 -6.45 -37.7 C-10
0 0 0 0.018 0 0 -6.34 -36.8 C-11
0 0 0 0.005 0 0 -6.25 -36.3 C-12
0 0 0 0.005 0 0 -5.46 -36.6 C-13
0 0 0 0.005 0 0 -6.06 -36.8 C-14
0 0 0 0.005 0 0 -5.9 -35.5 C-15
0 0 0 0.005 0 0 -5.73 -36.9 C-16
0 0 0 0.005 0 0 -6.06 -37.6 C-17
0 0 0 0.015 0 0 -6.32 -36.4 C-18
0 0 0 0.019 0 0 -4.07 -32.5 C-19
0 0 0 0.005 0 0 -5.7 -35.8 C-20
0 0 0 0.005 0 0 -5.82 -35.5 C-21
0 0 0 0.005 0 0 -6.04 -37.8 C-22
0 0 0 0.017 0 0 -5.96 -35.2 C-23
0 0 0 0.023 0 0 -6.09 -37.1 C-24
0 0 0 0.011 0 0 -5.59 -33.2 C-25
0 0 0 0.005 0 0 -5.5 -34 C-26
0 0 0 0.005 0 0 -5.39 -32.8 C-27
0 0 0 0.005 0 0 -5.6 -34.1 C-28
0 0 0 0.005 0 0 -5.58 -34.5 C-29
0 0 0 0.005 0 0 -5.6 -34.9 C-30
0 0 0 0.005 0 0 -5.62 -35 C-31
0 0 0 0.005 0 0 -5.78 -36.2 C-32
0 0 0 0.014 0 0 -6.03 -36.4 C-33
0 0 0 0.005 0 0 -5.94 -35.6 C-34
0 0 0 0.005 0 0 -5.94 -35 C-35
0 0 0 0.01 0 0 -6.05 -35.9 C-36
0 0 0 0.012 0 0 -5.77 -34.5 C-37
0 0 0 0.005 0 0 -5.61 -33.9 C-38
0 0 0 0.005 0 0 -5.76 -35.8 C-39
0 0 0 0.005 0 0 -5.32 -34.7 C-40
0 0 0 0.005 0 0- - C-41
Piper Plot
Separation of plot fields
0.2

sum sum Charge

cations anions Balance
3.34 3.28 1%
1.12 1.14 -1%
0.66 0.68 -2%
0.28 0.29 0%
0.10 0.13 -11%
0.27 0.28 -3%
0.26 0.21 11%
0.29 0.25 8%
7.47 7.31 1%
3.16 3.19 -1%
17.12 17.20 0%
19.37 20.22 -2%
19.47 20.18 -2%
21.22 22.17 -2%
17.66 17.99 -1%
21.08 22.08 -2%
7.28 7.22 0%
0.81 0.89 -5%
0.97 1.04 -3%
15.35 14.97 1%
16.61 16.77 0%
14.89 14.96 0%
3.40 3.28 2%
15.13 15.09 0%
17.11 17.55 -1%
17.05 17.39 -1%
16.92 17.28 -1%
16.81 17.12 -1%
16.30 16.81 -2%
13.23 13.59 -1%
14.75 15.13 -1%
16.03 16.58 -2%
2.09 2.06 1%
11.40 12.14 -3%
11.81 13.15 -5%
14.86 15.04 -1%
12.37 12.78 -2%
10.83 11.66 -4%
11.58 13.04 -6%
17.11 16.94 1%
0.03 0.01 56%
 Cl SO4 HCO3 Cl SO4 HCO3
C-01 1.34 7.51 187.6 196.45 1 4 95
C-02 1.77 1.05 65.1 67.92 3 2 96
C-03 0.8 0.45 39.7 40.95 2 1 97
C-04 1.71 0.6 13.7 16.01 11 4 86
C-05 0.82 0.96 5.1 6.88 12 14 74
C-06 0.6 0.7 15.3 16.6 4 4 92
C-07 0.85 0.78 10.2 11.83 7 7 86
C-08 1.38 0.48 12.1 13.96 10 3 87
C-18 0.77 5.49 45.8 52.06 1 11 88
C-09 157.9 55.96 100.7 314.56 50 18 32
C-10 60.54 23.99 59 143.53 42 17 41
C-11 408.2 123.1 184.6 715.9 57 17 26
C-12 531.8 157.3 111.8 800.9 66 20 14
C-13 518.9 152.7 137.3 808.9 64 19 17
C-14 595.5 172.2 101.7 869.4 68 20 12
C-15 460 137.4 125.1 722.5 64 19 17
C-16 590.3 170 107.8 868.1 68 20 12
C-19 1.19 32.36 19.8 53.35 2 61 37
C-17 86.94 80.52 187.6 355.06 24 23 53
C-20 251 227.1 183.1 661.2 38 34 28
C-21 285.5 261.3 189.2 736 39 36 26
C-22 236.8 230.3 202.9 670 35 34 30
C-23 38.12 51.7 67.1 156.92 24 33 43
C-24 229.7 239.5 210.5 679.7 34 35 31
C-25 311 264.1 189.2 764.3 41 35 25
C-26 314.8 266.9 168.8 750.5 42 36 22
C-27 312 268.1 165.7 745.8 42 36 22
C-28 309.3 248.7 186.1 744.1 42 33 25
C-29 298.8 265.4 163.7 727.9 41 36 22
C-30 227.4 206.3 166.7 600.4 38 34 28
C-31 250.2 225.7 196.2 672.1 37 34 29
C-32 296.3 251.5 171.8 719.6 41 35 24
C-33 24.45 24.28 51.9 100.63 24 24 52
C-34 180.8 175.3 199.3 555.4 33 32 36
C-35 201 196.9 198.3 596.2 34 33 33
C-36 258.4 232.6 167.8 658.8 39 35 25
C-37 200.7 185.3 191.1 577.1 35 32 33
C-38 162.7 168.4 210.5 541.6 30 31 39
C-39 193.4 195.6 206.4 595.4 32 33 35
C-40 291.1 269 180 740.1 39 36 24
C-41 0.13 0.1 0.23 57 43 0
 Bicarbonat

Chloride-bicarbonate-sulphate
Liquid_Analysis_v3_Powell&Cumming_2010_StanfordGW Geochemical Plotting

The charts and geothermometry report in this spreadsheet are described in an accompanying article b
Cumming delivered at the 35th Workshop on Geothermal Reservoir Engineering, Stanford University, S
California, February 1-3, 2010. References for the calculations and charts can be found in that docum
This spreadsheet accepts water chemistry and stable isotope data and plots them in standard ternary a
geothermometer grids. Data are pasted into the 'Input' sheet and appear on all the graphics applicable
type. Data may also be cut, pasted and moved within the data entry field without changing cell addres
calculations.
Graphics can be edited directly as EXCEL97 graphics and certain grid dimentions (e.g. multipliers on t
and evaporation cluster location on the stable isotope grid) can be changed on the 'input' sheet. Fields
these parameters are located above the data entry field.
Data entry field:
Rows 7 through 36 accept data for the plots (30 data points). The first 3 columns (Sample Name
1)
Date) are not referenced by the plots and are there for user reference.

Sample Label' in column D is a text field that will determine the label for points on the plots. The
2)
'X-Y chart labeler 97' can also be used to label the charts
Columns E, F, G & H are for UTM location, elevation and sample temperature. These will be us
locations on the "Map" sheet. Scales on the "Map" chart will need to be adjusted to accomodate t
3)
square-dimentioned empty text box is included in the upper left corner to assist in rectifying the N-
scales of the map

Enter or copy in laboratory analysis data (as mg/kg) in columns I through AD. Parts per million (pp
to mg/kg. Data in moles/liter can be converted to mg/kg by multipying by the appropriate molecula
analyte. Henley, Truesdell & Barton (1984) suggest that mg/litre can be converted directly to mg/k
noticable error below about 35,000 mg/kg total dissolved solids, which can be approximated by th
4)
analytes. At higher concentrations a correction for the density of the sample is needed. Data are s
in weight percent, which can be directly converted to mg/kg (1wt%=10,000 mg/kg). For a more co
discussion of units reported in analyses and their conversion to mg/kg, see Hem (1970). Negative
interpreted a "below detection" and are plotted at the detection limit.

Enter stable isotope data as "del" expressed in per mil (parts per thousand) in columns AE and AF
computed relative to the SMOW standard, such that del = (R - R SMOW) / RSMOW, where R is the isoto
5)
sample (18O/16O or D/H) and RSMOW is the isotope ratio of the standard. For most geothermal fluids
del D will be negative.

Columns BJ through BL present the sums of cations and anions charge (in meq/mg) and the char
percentage of the total ionic charge of the solution [cations-anions]/[cations+anions]. Charge in m
kg (meq/kg) is calculated using the conversion factors in Row 5 of hidden columns AG to BI. The c
6)
for iron assumes Fe+2. The sum of cations includes pH only if a pH value is entered. Charge balan
+-5% are highlighted in red font. An excess of anions or cations greater than this indicates an erro
of one of the major ionic species or a missing major ionic species
 Points plotted on the grids are accompanied by labels input in column D. Empty data rows (rows
chemical or isotope data) are plotted outside of the chart area (99, -99, 999, etc) and their data lab
Labels for incomplete data will sometimes be plotted to the left outside the chart area. These can
7)
presentation by adjusting the plot ranges of the charts. This may, however, permanently remove t
the data range beyond the plot range. It is recommended that graphs to be altered for presentatio
moved to a separate sheet (Menu:"Edit"/"Move or Copy Sheet"/"Create a Copy" checkbox)
Ternary vertex multipliers (the amounts multiplying the elements in the ternary plots) can be chang
above the data input field. It should be noted that in most cases the values in the box are those u
8)
originator (i.e, W Giggenbach). The location of the evaporation trend cluster in the isotope chart (
meteoric trend line label can be changed in the box on the upper right.
The "Report" sheet gives the results of standard geothermometer calculations for the chemical an
9)
sample name, source and date.
Notes:
Columns AG to BI are hidden. These cells copy the cells in the input field based upon fixed cell ad
1)
data can be cut/pasted and moved in the input data field without changing cell addresses in the ca
2) Columns BM to CT are hidden. These cells contain the geothermometer and ternary grid calculat
Two additional sheets used to generate the plots are hidden but available. Tgrid has the plot data
3)
grids. Ref has reference plot data for the ternaries and cross plots.
Input units are in mg/kg of the chemical species indicated. Data reported for a different variety of
4) NH3 rather than NH4) needs to be adjusted by the ratio of molecular weights (i.e. mg/kg NH4 = m
NH3*(18/17))
Some labs report total inorganic carbon (H2CO3+HCO3 -+CO3=) instead of bicarbonate and carbo
generally reported in units of bicarbonate ("as bicarbonate") and, confusingly, is often called bicarb
5) inorganic carbon is entered into the bicarbonate field it will result in an excess of anions over catio
H2CO3 does not have a charge in solution. Data should be requested as concentrations of these
carbonate specie (i.e., carbonic acid or dissolved CO2, bicarbonate and carbonate)

Versions:
- Added User defined XYZ ternary chart, so that User can define elements for the ternary, as well
factors. Elements are chosen by inputing row letter in left column of box
2 - Change to magnesium ion correction at R<5 to correct for error in equasion. Error caused tempe
to be 2 deg C too great
-Added row to top of input sheet to accommodate User Defined XYZ ternary
-Fixed cell address of Sample Name in Report page, due to added row at top of Input page

-Corrected R>5 equation for NaKCa Mg ion correction to equation in Fournier & Potter 1979 GCA
-Added column for steam fraction, so that well samples can be corrected for steam loss. This corr
to geothermometer values, geothermometer plots and chloride enthalpy plot. If steam fraction is l
value is assumed and no correction is applied. No correction is made to isotope data
-The steam fraction correction is made by multiplying the sample concentration by the liquid fractio
complement (1-X) of the steam fraction. Samples with an excess steam correction can be correct
3 the complement of the liquid correction factor for the value of steam fraction
3
-Added enthalpy-chloride plot for discharge enthalpy, sheet "XClHdisch"
-Added solubilities for alpha & beta cristobalite and amorphous silica to Xkms plot
-Added Piper (Trilinear) Plot in sheet "Piper". Data are plotted as milliequivalents/litre, not ppm. L
cropped by decreasing box size. Separation of plot fields can be increased by changing spacing i
above charge balance
-Added alpha & beta cristobalite and additional Na/K geothermometers to "Report" sheet.
 Geochemical Plotting Spreadsheet

n an accompanying article by T Powell & W

eering, Stanford University, Stanford,
can be found in that document
ts them in standard ternary and
on all the graphics applicable to that data
without changing cell addresses in the

entions (e.g. multipliers on ternary diagrams

d on the 'input' sheet. Fields for changing

t 3 columns (Sample Name, Lab Number &

.

for points on the plots. The Excel 97 add-in

mperature. These will be used to plot the

be adjusted to accomodate the locations. A
r to assist in rectifying the N-S and E-W grid

ugh AD. Parts per million (ppm) is equivalent

by the appropriate molecular weight of the
be converted directly to mg/kg without
h can be approximated by the sum of
sample is needed. Data are sometimes listed
0,000 mg/kg). For a more complete
g, see Hem (1970). Negative values are

sand) in columns AE and AF. Del values are

/ RSMOW, where R is the isotope ratio of the
. For most geothermal fluids both del 18O and

ge (in meq/mg) and the charge balance as a

ations+anions]. Charge in milliequivalents per
den columns AG to BI. The conversion factor
alue is entered. Charge balances greater than
er than this indicates an erroneous analysis
 D. Empty data rows (rows without input
9, 999, etc) and their data labels are blank.
e the chart area. These can be removed for
wever, permanently remove the labels from
to be altered for presentation should be
te a Copy" checkbox)
e ternary plots) can be changed in the boxes
alues in the box are those used by the plot
cluster in the isotope chart ("Iso") and the
.
culations for the chemical analysis, along with

field based upon fixed cell addresses, so that

ging cell addresses in the calculations.
eter and ternary grid calculations
able. Tgrid has the plot data for the ternary

rted for a different variety of that species (i.e.,

weights (i.e. mg/kg NH4 = mg/kg

ad of bicarbonate and carbonate. This is

usingly, is often called bicarbonate. If total
n excess of anions over cations because
d as concentrations of these separate
nd carbonate)

ments for the ternary, as well as multiplier

ox
quasion. Error caused temperature correction

ernary
w at top of Input page

Fournier & Potter 1979 GCA paper

ted for steam loss. This correction is applled
py plot. If steam fraction is left blank, a zero
to isotope data
centration by the liquid fraction, which is the
am correction can be corrected by entering
action
h"
o Xkms plot
equivalents/litre, not ppm. Legend can be
eased by changing spacing in Input field

s to "Report" sheet.