Hydrogen Sulfide
Section 1. Identification
GHS product identifier : Hydrogen Sulfide
Chemical name : hydrogen sulfide
Other means of : Hydrogen sulfide; Hydrogen sulfide (H2S); Sulfuretted hydrogen; Sewer gas;
identification Hydrosulfuric acid; dihydrogen sulfide
Product use : Synthetic/Analytical chemistry.
Synonym : Hydrogen sulfide; Hydrogen sulfide (H2S); Sulfuretted hydrogen; Sewer gas;
Hydrosulfuric acid; dihydrogen sulfide
SDS # : 001029
Supplier's details : Airgas USA, LLC and its affiliates
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 1/12
Hydrogen Sulfide
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 2/12
Hydrogen Sulfide
Specific hazards arising : Contains gas under pressure. Extremely flammable gas. In a fire or if heated, a
from the chemical pressure increase will occur and the container may burst, with the risk of a subsequent
explosion. This material is very toxic to aquatic life with long lasting effects. Fire water
contaminated with this material must be contained and prevented from being discharged
to any waterway, sewer or drain.
Hazardous thermal : Decomposition products may include the following materials:
decomposition products sulfur oxides
Special protective actions : Promptly isolate the scene by removing all persons from the vicinity of the incident if
for fire-fighters there is a fire. No action shall be taken involving any personal risk or without suitable
training. Contact supplier immediately for specialist advice. Move containers from fire
area if this can be done without risk. Use water spray to keep fire-exposed containers
cool. If involved in fire, shut off flow immediately if it can be done without risk. If this is
impossible, withdraw from area and allow fire to burn. Fight fire from protected location
or maximum possible distance. Eliminate all ignition sources if safe to do so.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
equipment for fire-fighters apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 3/12
Hydrogen Sulfide
Advice on general : Eating, drinking and smoking should be prohibited in areas where this material is
occupational hygiene handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment before
entering eating areas. See also Section 8 for additional information on hygiene
measures.
Conditions for safe storage, : Store in accordance with local regulations. Store in a segregated and approved area.
including any Store away from direct sunlight in a dry, cool and well-ventilated area, away from
incompatibilities incompatible materials (see Section 10). Store locked up. Eliminate all ignition sources.
Keep container tightly closed and sealed until ready for use. Cylinders should be stored
upright, with valve protection cap in place, and firmly secured to prevent falling or being
knocked over. Cylinder temperatures should not exceed 52 C (125 F).
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 4/12
Hydrogen Sulfide
Appropriate engineering : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
controls other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapor or dust concentrations below any lower explosive limits. Use explosion-proof
ventilation equipment.
Environmental exposure : Emissions from ventilation or work process equipment should be checked to ensure
controls they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process equipment
will be necessary to reduce emissions to acceptable levels.
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 5/12
Hydrogen Sulfide
Possibility of hazardous : Under normal conditions of storage and use, hazardous reactions will not occur.
reactions
Conditions to avoid : Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
products not be produced.
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 6/12
Hydrogen Sulfide
Delayed and immediate effects and also chronic effects from short and long term exposure
Short term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Long term exposure
Potential immediate : Not available.
effects
Potential delayed effects : Not available.
Potential chronic health effects
Not available.
General : No known significant effects or critical hazards.
Carcinogenicity : No known significant effects or critical hazards.
Mutagenicity : No known significant effects or critical hazards.
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 7/12
Hydrogen Sulfide
Bioaccumulative potential
Not available.
Mobility in soil
Soil/water partition : Not available.
coefficient (KOC)
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 8/12
Hydrogen Sulfide
Transport 2.3 (2.1) 2.3 (2.1) 2.3 (2.1) 2.3 (2.1) 2.3 (2.1)
hazard class(es)
Packing group - - - - -
Environment No. No. No. Yes. No.
Additional Toxic - Inhalation Product classified as - The marine pollutant The environmentally
hazard Zone B per the following mark is not required hazardous substance
information sections of the when transported in mark may appear if
Reportable quantity Transportation of sizes of 5 L or 5 kg. required by other
100 lbs / 45.4 kg Dangerous Goods transportation
Package sizes shipped Regulations: 2.13-2.17 regulations.
in quantities less than (Class 2), 2.13-2.17 Passenger and Cargo
the product reportable (Class 2), 2.7 (Marine AircraftQuantity
quantity are not subject pollutant mark). limitation: 0 Forbidden
to the RQ (reportable Cargo Aircraft Only
quantity) transportation The marine pollutant Quantity limitation: 0
requirements. mark is not required Forbidden
when transported by
Limited quantity road or rail.
Yes.
Explosive Limit and
Packaging instruction Limited Quantity Index
Passenger aircraft 0
Quantity limitation:
Forbidden. ERAP Index
0
Cargo aircraft
Quantity limitation: Passenger Carrying
Forbidden. Ship Index
Forbidden
Special provisions
2, B9, B14 Passenger Carrying
Road or Rail Index
Forbidden
Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product.
Special precautions for user : Transport within users premises: always transport in closed containers that are
upright and secure. Ensure that persons transporting the product know what to do in the
event of an accident or spillage.
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 9/12
Hydrogen Sulfide
Clean Air Act (CAA) 112 regulated toxic substances: hydrogen sulfide
Clean Air Act Section 112 : Listed
(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602 : Not listed
Class I Substances
Clean Air Act Section 602 : Not listed
Class II Substances
DEA List I Chemicals : Not listed
(Precursor Chemicals)
DEA List II Chemicals : Not listed
(Essential Chemicals)
SARA 302/304
Composition/information on ingredients
SARA 302 TPQ SARA 304 RQ
Name % EHS (lbs) (gallons) (lbs) (gallons)
hydrogen sulfide 100 Yes. 500 - 100 -
SARA 304 RQ : 100 lbs / 45.4 kg
SARA 311/312
Classification : Fire hazard
Sudden release of pressure
Immediate (acute) health hazard
Composition/information on ingredients
Name % Fire Sudden Reactive Immediate Delayed
hazard release of (acute) (chronic)
pressure health health
hazard hazard
hydrogen sulfide 100 Yes. Yes. No. Yes. No.
SARA 313
Product name CAS number %
Form R - Reporting hydrogen sulfide 7783-06-4 100
requirements
Supplier notification hydrogen sulfide 7783-06-4 100
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include
copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
State regulations
Massachusetts : This material is listed.
New York : This material is listed.
New Jersey : This material is listed.
Pennsylvania : This material is listed.
International regulations
International lists
National inventory
Australia : This material is listed or exempted.
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 10/12
Hydrogen Sulfide
Flammability 4
Physical hazards 2
Caution: HMIS ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4
representing significant hazards or risks Although HMIS ratings are not required on SDSs under 29 CFR 1910.
1200, the preparer may choose to provide them. HMIS ratings are to be used with a fully implemented HMIS
program. HMIS is a registered mark of the National Paint & Coatings Association (NPCA). HMIS materials
may be purchased exclusively from J. J. Keller (800) 327-6868.
The customer is responsible for determining the PPE code for this material.
National Fire Protection Association (U.S.A.)
4 Flammability
Health 4 0 Instability/Reactivity
Special
Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency
Response Copyright 1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is
not the complete and official position of the National Fire Protection Association, on the referenced subject
which is represented only by the standard in its entirety.
Copyright 2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to
be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of
chemicals. The user is referred to certain limited number of chemicals with recommended classifications in
NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA
or not, anyone using the 704 systems to classify chemicals does so at their own risk.
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 11/12
Hydrogen Sulfide
Date of issue/Date of revision : 3/23/2017 Date of previous issue : No previous validation Version : 0.01 12/12