Journal of Mineralogical
Osanai, N. and Petrological
Nakano, M. Owada, T.N. Nam, T.Sciences,
Miyamoto,Volume 103, page
N.T. Minh, N.V.226
Nam 241,
and 2008
T.V. Tri
**
Department of Earth Sciences, Yamaguchi University, Yamaguchi 753 8512, Japan -
***
Department of Geosciences, Hue University of Science, Hue, Vietnam
Department of Earth and Planetary Sciences, Kyushu University, Fukuoka 812 8581, Japan -
Research Institute of Geology and Mineral Resources, Hanoi, Vietnam
Department of Geology and Minerals of Vietnam, Hanoi, Vietnam
Recent geological and petrological investigations of the metamorphic rocks from Vietnam revealed the follow-
ing new evidences to understand the tectonic evolution of Southeast Asia; 1) findings of ultrahigh T (~ 1000 C)
-
pelitic granulites, high to ultrahigh P (~ 40 kbar) mafic metamorphic rocks and high P/medium T gneisses
- - - -
from the Kontum Massif, 2) eclogite and high P granulite from the Song Ma suture zone, and 3) ultrahigh T
- -
aluminous granulite from the Red River zone. These lines of evidence are strongly indicative of the highest -
metamorphic conditions in each metamorphic terrane. Estimated P T conditions and reaction textures from
-
these rocks delineate a characteristic clockwise pressure temperature time (P T t) path for each other.
- - - -
Based on the combination of P T paths from these complexes, two stages of metamorphic field gradient
- -
are identified. An earlier M0 stage of high P/T gradient is recognized, based on the peak P conditions from the
- - -
Kontum Massif and Song Ma suture zone. A later M1 stage of low P/T gradient is also identified by linking the
- -
peak metamorphic conditions from the Kontum Massif, the Song Ma suture zone and the Red River zone. The
former metamorphic field gradient could represent an early continental collision event and the latter would indi-
cate a peak metamorphic stage caused by very high T magmatic intrusion (asthenosphere upwelling) as a heat
-
source of ultrahigh T metamorphism. A simultaneous collision metamorphism throughout Vietnam should have
-
taken place during the continental collision between Indochina and South China cratons, which led to the for-
mation of Trans Vietnam Orogenic Belt.
2006a; Lan et al., 2003; Nakano et al., 2007a; Lepvrier et (Tran Quoc Hai, 1986) and metamorphosed Lower to
al., 2008). During the collision, several types of metamor- Middle Palaeozoic cover sequences (low grade rocks)
-
GEOLOGICAL OUTLINE
Kontum Massif
Figure 1. Distribution of metamorphic rocks in Vietnam and adja-
cent South-eastern Asia, modified after United Nations (1990).
The Kontum Massif in central Vietnam is classified into
three major metamorphic complexes, namely the Kannak
topics have revealed the following evidences that helped Complex in the south east, the Ngoc Linh Complex in the
-
to subdivide into three complexes. The Kham Duc Com- central and the Kham Duc Complex in the north and
plex consists of greenschist to blueschist facies (Trinh
- - south west (Fig. 2). The western extension of the Kontum
-
been considered to be derived from the Precambrian ophi- those from the Kham Duc Complex have been identified.
olite suit (e.g., Nguyen Xuan Tung et al., 1991). The Ngoc Many kinds of pelitic gneisses and granulites charac-
Linh Complex is composed mainly of amphibolite facies - teristically occur in the Kannak Complex, which are rep-
metamorphic rocks of Proterozoic age and has been re- resented by garnet orthopyroxene sillimanite cordierite
- - -
garded as Late Proterozoic fold belt (Tran Van Tri, 1992), granulite (Fig. 4a), garnet cordierite sillimanite biotite
- - -
while the Kannak Complex is composed of various types gneiss, garnet orthopyroxene biotite charnockitic gneiss
-
(Archean) age (e.g., Phan Cu Tien et al., 1991). The meta- pyroxene bearing S type tonalites (Plei Man Ko granitic
- -
morphic rocks from Red River zone, Song Ma suture complex) are also exposed in this complex (Owada et al.,
zone and Truong Son fold belt are still believed to be Pre- 2006), which show highly migmatized structures. Minor
cambrian to early Phanerozoic, although recent multi iso- - amounts of clinopyroxene and orthopyroxene bearing
- -
tope geochronological studies have shed light on the mafic granulite, orthopyroxene biotite enderbitic gneiss
-
ic gneisses. Characteristic large block of garnet amphibo- widely occur along the Tam Ky Phuoc Son shear zone. In
-
lite surrounded by pelitic gneisses crops out at the eastern eastern and western parts of the northern Kham Duc
part of the Kannak Complex. Complex, pelitic and psammitic schists are well devel-
The Ngoc Linh complex consists mainly of amphib- oped. Psammitic schist is intercalated with pelitic schist,
olite facies metamorphic rocks, namely garnet silliman-
- - and also mafic, ultramafic and felsic schists occur as thin
ite biotite gneiss, garnet biotite gneiss, amphibolite, gar-
- - or thick layers within the intercalations. In this complex,
net amphibolite and hornblende biotite gneiss. Other
- low grade schists are major lithologies, while some
-
Various metamorphic rocks of pelitic, psammitic, two formations, the Nam Co Formation and the Nam Su
mafic and calc silicate schists and gneisses are exposed in
- Lu Formation, based on the metamorphic grade (Fig. 3)
the northern and south western Kham Duc Complex (Fig.
- (Phan Son et al., 2005). The Nam Co Formation shows
2). The mylonites of mafic to intermediate compositions rather low grade conditions and consists mainly of mus-
-
Collision zone metamorphism in Trans Vietnam Orogenic Belt 229
amorphic rocks from the Song Ma suture zone as de- the left bank and the low grade Xuan Dai Group on the
-
Figure 4. Mode of occurrence and photomicrographs of ultrahigh-temperature granulite from the Kannak Complex (modified after Osanai et
al., 2004a; used with permission). Scale bar in all photos indicates 1 mm. (a) Knotty garnet-orthopyroxene-sillimanite-cordierite granulite.
Each knot contains multi-phase symplectite surrounding garnet. (b) Primary orthopyroxene porphyroblast including anhedral high-fluorine
phlogopite and quartz, surrounded by symplectite composed of later orthopyroxene and cordierite. (c) Coexisting orthopyroxene-sillimanite-
quartz, indicating ultrahigh-temperature metamorphism, replaced by retrograde cordierite and spinel. (d) Primary garnet and orthopyroxene
that are generally surrounded by later fine-grained multiple symplectites (corona) composed of orthopyroxene, spinel and cordierite. Ortho-
pyroxene moat is situated at the boundary between corona and surrounding quartz.
The Song Hong Group is subdivided into the Nui OVERVIEW OF METAMORPHIC
Con Voi and the Ngoi Chi Formations, where various EVOLUTION IN VIETNAM
high grade metamorphic rocks are observed, such as
-
east of Yen Bai town. The Xuan Dai Group is composed net orthopyroxene sillimanite cordierite) granulites from
- - -
Figure 5. Mode of occurrence and photomicrographs of ultrahigh-temperature/ultrahigh-pressure mafic granulite from the Ngoc Linh Complex
(modified after Nakano et al., 2004a; used with permission, 2007b) and the Kham Duc Complex (Nakano et al., 2007a). (a) Mafic granulite
included in mylonitized felsic gneiss. (b) Orthopyroxene + plagioclase + magnetite symplectite among garnet, clinopyroxene and quartz. Or-
thopyroxene moat is also formed around clinopyroxene and quartz. Scale bar indicates 1 mm. (c) Quartz rods within clinopyroxene indicates
that the texture was derived from original hyper-silicic clinopyroxene during decompression stage. (d) Characteristic rutile needles within
garnet. Scale bar in (c) and (d) show 0.5 mm. (e) Porphyroblastic garnet, gedrite and kyanite in garnet-gedrite-kyanite gneiss from the Kham
Duc Complex. Fibrolitic sillimanite is also observed. (f) Inclusions of staurolite and quartz within gedrite.
Kontum Massif (Figs. 5e and 5f; Nakano et al., 2004b, al., 2006a) from the Song Ma suture zone,
2005, 2007a), 5)finding of kyanite bearing aluminous garnet corun-
- -
6a and 6b; Nakano et al., 2008) and eclogite (garnet om- - (Figs. 6e and 6f; N. Nakano, unpublished data),
232 Y. Osanai, N. Nakano, M. Owada, T.N. Nam, T. Miyamoto, N.T. Minh, N.V. Nam and T.V. Tri
Figure 6. Photomicrographs of representative metamorphic rocks from the Song Ma suture zone and the Red River zone (modified after Na-
kano et al., 2006a and 2008). (a) High-P granulite from the Song Ma suture zone. Garnet porphyroblast coexists with orthopyroxene-pla-
gioclase symplectite and orthopyroxene-clinopyroxene-plagioclase hornblende quartz symplectite. (b) Back scattered SEM-image of
high-P granulite. (c) Hornblende-bearing eclogite from the Song Ma suture zone containing garnet. omphacite, quartz with minor hornblende
and rutile. (d) Back scattered SEM-image of eclogite, where characteristic clinopyroxene+plagioclase corona surrounds omphacite. (e) Co-
rundum-garnet- sillimanite-bearing aluminous granulite from the Red River zone. (f) Magnified mineral coexistence of garnet, corundum
and quartz.
6)understanding of a main metamorphic age for most The peak metamorphic conditions recognized in
metamorphic rocks in Vietnam to be Permo Triassic - each area, when combined with geochronological data set
(230 270 Ma), but part of them have older signatures
- are quite useful to retrieving the pressure temperature
- -
(Neoproterozoic: ca. 680 Ma and Ordovician Devonian:- time (P T t) path. Estimating P T path from individual
- - -
tectonic evolution of the regional metamorphic terrane, in Opx 1 (Opx 1) + Sil + Qtz = Crd 1 Grt 1 (1)
which metamorphic mineral parageneses, reaction tex- Opx 1 (Opx 1) + Sil = Crd 1 + Spl 1 (2)
tures and mineral chemistries would provide critical in- Grt 1 + Qtz = Opx 2 + Crd 2 (3)
sights into their metamorphic P T conditions. Following - Grt 1 + Crd 2 = Opx 3 + Spl 2 (4)
descriptions of metamorphic reactions, especially for the Grt 1 + Crd 2 = Grt 2 + Spl 3 (5)
Kontum Massif (Kannak, Ngoc Linh, and Kham Duc Crd 2 Qtz + melt = Opx 4 + Kfs + Pl (6).
Complexes), are revised from Osanai et al. (2005).
Reactions (1) to (5) suggest a sequential, nearly isother-
Representative reaction textures of the highest-grade mal decompression process under ultrahigh T conditions.
-
roxene, sillimanite, cordierite, spinel and quartz with sub- reaction at high P: -
ilmenite, apatite, corundum, zircon and monazite. The high F Phl + Sil + Qtz = Opx 1 Grt 1 + melt
- (7).
granulite shows various significant reaction textures indi-
cating multi phase/ multi stage symplectite formation
- - Interstitially existed melt, which might have been
during their metamorphic evolution started from ultra- produced by reaction (7) at the primary stage, was con-
high T conditions.
- sumed by the Opx 4 producing reaction (6) at the simi-
-
Anhedral to subhedral garnet porphyroblasts (Grt 1: lar T but relatively low P conditions.
- -
Alm43.050.2Sps00.1Prp48.455.1Grs1.42.8), including sillimanite Ngoc Linh Complex. The garnet orthopyroxene clino-
- -
needles, are generally surrounded by fine grained multi- - pyroxene granulite consists mainly of relatively large
ple symplectites composed of orthopyroxene (Opx 2: XMg: grains of garnet, clinopyroxene and quartz and fine -
feldspar and plagioclase, was identified along the bound- blende occur only as inclusions in garnet. Individual large
ary between these symplectites and adjacent quartz (Fig. grains of orthopyroxene, plagioclase and spinel are absent
4d). Part of Grt 1 is completely consumed and Opx 4 in the matrix, while they are present as symplectite phases
mantled Opx 2 Crd 2 symplectite is formed as a garnet
- around garnet, clinopyroxene and quartz.
pseudomorph (Fig. 4d). At the rim of Grt 1 (Alm57.660.2 Garnet (Grt 1: Alm3942Prp3336Grs2024Sps01) occurs
Sps00.2Prp34.538.0Grs3.95.4), fine symplectite composed of as relict anhedral grains and within the core of symplec-
rather Mg rich garnet (Grt 2: Alm55.156.7Sps00.3Prp39.240.6
- tite domains. The garnets are completely surrounded by
Grs4.04.3) and spinel (Spl 3: XMg = 0.57 0.60) was ob- - orthopyroxene, plagioclase, spinel and magnetite sym-
served. Coarse grained subhedral orthopyroxene porphy-
- plectite (Fig. 5b). Rutile, kyanite, clinozoisite, brown -
tions took place during the retrograde process: and Ca Tschermak (CaTs) components and sometimes
- -
234 Y. Osanai, N. Nakano, M. Owada, T.N. Nam, T. Miyamoto, N.T. Minh, N.V. Nam and T.V. Tri
supersilicic clinopyroxene (Cpx 0: Aug05CaEs514Jd814 gedrite (Fig. 5e). Kyanite is surrounded by plagioclase,
CaTs02) at high P condition. Clinopyroxene (Cpx 2:
- completely separated with quartz. Garnet has inclusions
Aug7590CaEs02Jd17CaTs29) and plagioclase (Pl 1: An2843) of quartz and gedrite includes staurolite (XMg = 0.20 0.24, -
symplectic intergrowth is observed in the core part of 0.2 1.0 wt% ZnO, 0.5 1.2 wt% TiO2) and quartz (Fig. 5f).
- -
clinopyroxene aggregates that indicates decompression Spinel (XMg = 0.17 0.18, 0.6 1.0 wt% ZnO) and cordierite
- -
breakdown texture of clinopyroxene (Cpx 4: Aug6788Ca fine grained prismatic sillimanite and gedrite. Spinel is
-
Es0Jd0CaTs411) is characterized by arrays composed of well developed in the sillimanite side of the symplectite,
orthopyroxene (Opx 3: XMg = 0.64 0.67, 0.4 1.1 wt% - - while a layer composed of single phase of cordierite is
Al2O3), plagioclase (Pl 4: An3747) and hornblende (XMg = present in the gedrite side. Fine grained prismatic silli-
-
out any garnet, clinopyroxene, quartz and rutile. These are St + Qtz = Ged + Ky (14)
divided into two types according to their mineral assem-
- Ky = Sil (15)
blages and chemistries. One is composed of Al poor or- - Ged + Sil = Spl + Crd (16).
thopyroxene (Opx 1: XMg = 0.61 0.68, 0.6 2.6 wt% Al2O3)
- -
0.48) and magnetite, which is formed around garnet or clinopyroxene, hornblende, ilmenite and rutile (Fig. 6a).
along the cracks of garnets. Above mentioned reaction - Minor amount of zircon, monazite and apatite are also
textures can be explained by following reactions: present in this rock. The coarse garnet porphyroblast
(Alm5862Prp1621Grs1924Sps02) is replaced with orthopy-
Grt 0 = Grt 1 + Ilm + Rt (8) roxene (XMg = 0.37 0.38) +plagioclase (An6085) symplec-
-
Cpx 0 = Cpx 1 + Qtz (9) tite. A multiple phase symplectite is composed of ortho-
-
Cpx 3 + H2O = Opx 3 + Hbl + Pl 4 (+ Cpx 4) (13). positions of minerals in the multiple phase symplectite -
Considering mineral parageneses and their chemis- roxene (Jd02CaTs05Aug9399), plagioclase (An3050) and
tries, the reactions (8) to (12) would take place during de- hornblende (XMg = 0.50 0.63). Nakano et al. (2008) made
-
biotite, kyanite, sillimanite, spinel, cordierite, plagioclase Rtzler, 2003). Hence Mg rich garnet, sodic augite and
-
and quartz. Minor amount of zircon, monazite and apatite quartz were equilibrated at high P/ T conditions, and - -
are also present in this rock type. subsequently these minerals broke down to form orthopy-
Coarse grained garnet (Alm6165Prp2933Grs12Sps24),
- roxene bearing assemblages during decompression stage
-
lite, phengite, epidote, plagioclase and rutile. Garnet in- consequently this aluminous granulite was considered to
cludes rutile needles similar to those found in the Ngoc have stabilized under kyanite field prior to the co
-
Linh Complex. Most of omphacite grains are surrounded rundum+quartz under ultrahigh T conditions.
-
analyses for pelitic, mafic and aluminous granulites were manite spinel granulite is also identified from the Red
-
Complex indicate the peak metamorphic conditions of existing corundum + quartz assemblage is still controver-
~ 11 12 kbar and 1000 1050 C (stage M1KN in Fig. 7).
- - sial, to be stable or metastable, using thermodynamic
Certain low grade assemblages from this complex show
- examinations (e.g., Guiraud et al. 1996; Shaw and Arima,
the metamorphic condition at around 8 9 kbar and - 1998; Harlov and Milke, 2002). However, on the basis of
800 900 C (stage M2KN in Fig. 7) as estimated by geo-
- worldwide natural occurrences of corundum+quartz,
thermobarometry using garnet rim and orthopyroxene which is reviewed by Mouri et al. (2004), the texturally
compositions in retrograde phases (e.g., Osanai et al., stable corundum + quartz assemblage is mainly ob-
2004a; Nakano et al., 2004a, 2004b). However, the served in the magnetite ilmenite spinel bearing high
- - - -
due to the lack of evidence of reaction textures and/or dry conditions. Therefore, it is assumed that garnet + co-
mineral inclusions. rundum + quartz coexistence from the Red River zone is
On the contrary, a series of changes in divariant min- stable under ultrahigh T conditions during the clockwise
-
ing the metamorphic evolution. Initial ultrahigh P assem- - not been found from the granulite as described above (Fig.
blage (stage M0NL in Fig. 7) indicates conditions of ~ 40 7).
kbar and ~ 900 C. The ultrahigh T metamorphosed - Based on the compilation of P T paths from the -
pelitic and mafic metamorphic rocks from the Kontum Kontum Massif, the Song Ma suture zone and the Red
Massif characteristically exposed along the Dac To Kan River zone, at least two stages of metamorphic field gra-
-
shear zone show the same isotopic age of 240 250 Ma - dient (progressive P T trend) can be identified. An earlier
-
(Osanai et al., 2004a; Tran Ngoc Nam et al., 2004). This high P/T gradient is recognized based on the peak P con-
- -
would indicate that the metamorphic evolution process of ditions from the Ngoc Linh (M0NL stage) Complex in the
these two types of very high grade metamorphic rocks
- Kontum Massif and the Song Ma suture zone (M0SM
from the Kannak and the Ngoc Linh Complexes would be stage) (Fig. 7). In addition, a later low P/T gradient is -
identical with a clockwise affinity. also identified by the connection of peak metamorphic
Metamorphic evolution deduced from the highest - conditions of the Kannak, Ngoc Linh (M1KN stage) and
grade metamorphic rock of garnet gedrite kyanite gneiss- - the Kham Duc (M1KD stage) Complexes (Fig. 7). As the
from the Kham Duc Complex yields peak P condition of - result, it is possible that the low grade Kham Duc Com-
-
around 12 kbar at 640 C (high P amphibolite facies). - - plex was situated at shallower depth than the high grade -
Reaction textures in this gneiss as described above indi- Ngoc Linh and the Kannak Complexes in the same conti-
cate clockwise P T path followed by low P amphibolite
- - - nental crust. The former metamorphic field gradient could
facies condition through the peak metamorphic condition- represent a continental collision event and the latter would
of 8 kbar and 740 C (stage M1KD in Fig. 7). indicate a very high T magmatic intrusion (e.g., Emeis-
-
kbar, at peak thermal conditions of 700 750 C (Nakano - Recently, many detailed geochronological works for the
et al., 2006a). Another high P garnet granulite, which in-
- metamorphic rocks from the Red River zone, Song Ma
dicates very high T peak metamorphic conditions (~ 20
- suture zone, Truong Son fold belt and Kontum Massif re-
kbar, 910 930 C), is also newly recognized from the
- vealed a Permo Triassic metamorphic episode throughout
-
Song Ma suture zone (Nakano et al., 2008) (Fig. 7). Vietnam as the main metamorphic stage (Fig. 8) (e.g.,
A kyanite bearing aluminous garnet corundum silli-
- - - Tran Ngoc Nam, 1998, 2000, 2001; Maluski et al., 1999,
Collision zone metamorphism in Trans Vietnam Orogenic Belt 237
2002, 2005; Nagy et al., 2001; Carter et al., 2001; Osanai regions. Nakano et al. (2006b, 2007a) reported a more de-
et al., 2001, 2003, 2004a; Nakano et al., 2003, 2004a, tailed metamorphic evolution process of UHP/UHT gran-
2004b, 2006a, 2006b, 2007a, 2008; Lan et al., 2003; Lep- ulites from Ngoc Linh Complex in the Kontum Massif.
vrier et al., 2004, 2008; Miyamoto et al., 2006; Owada et The UHP stage (M0NL) initiated at ca. 270Ma, which was
al., 2006; Roger et al., 2007). These works showed Per- followed by decompression and cooling stage (M2KN) of
mo Triassic metamorphic ages (230 270 Ma) that were
- - ca. 245 Ma passing through the peak metamorphic UHT
determined using SHRIMP, CHIME, Sm Nd and Rb Sr
- - stage (M1KN: 250 260 Ma) along a protracted clockwise
-
no distinct spatial or temporal relationship with metamor- for biotite (passing 300 C) indicates ca. 230 Ma (e.g.,
phic grade. It is therefore considered that Vietnam had ex- Tran Ngoc Nam, 1998) (Fig. 7). A similar cooling age
perienced extensive simultaneous crustal metamorphism (229 Ma) is also reported from the Song Ma suture zone
from north (Red River zone) to central (Kontum Massif) (Miyamoto et al., 2006).
238 Y. Osanai, N. Nakano, M. Owada, T.N. Nam, T. Miyamoto, N.T. Minh, N.V. Nam and T.V. Tri
However, older ages were also recognized from met- DISCUSSION AND CONCLUDING REMARKS
amorphic rocks in Vietnam. Recent results from the Kon-
tum Massif include, Sm Nd internal isochron (using gar-
- Various kinds of Permo Triassic metamorphic rocks, in-
-
net, hornblende, felsic fraction and whole rock) age of cluding UHT/UHP rocks, are exposed extensively from
678 23 Ma for the garnet amphibolite (Nakano et al., north (Red River zone) to central Vietnam (Kontum Mas-
2003; Osanai et al., 2003), monazite CHIME ages of ca.
- sif). These metamorphic rocks indicate typical clockwise
480 Ma as an inherited core age for garnet orthopyrox-
- P T evolution as described above, which correspond well
-
Kontum Massif. Therefore it would also indicate that the resulted from an orogeny during the continental collision
Kontum Massif had undergone an earlier Pan African - between Indochina and South China cratons. UHP/UHT
metamorphic event during Gondwana era. Ordovician - granulites are derived from basal portion of the continen-
Devonian ages are also reported from the Song Ma suture tal crust of the subducted Indochina craton beneath the
zone and the Red River zone (e.g., Lepvrier et al., 1997). South China craton. This collision/subduction system be-
tween Indochina and South China cratons is also pointed
out by Lepvrier et al. (2008). Hence we propose a Trans
Collision zone metamorphism in Trans Vietnam Orogenic Belt 239
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