con
volumen
constante 2015
y variable
INTEGRANTE:
CUBAS CASTILLO WAGNER SPENSER
1. PROBLEM 9 An Introduction to Chemical Engineering Kinetics & Reactor
Design
By Charles G. Hill
The reaction rate constant for the gas phase decomposition of ethylene oxide is
0.0212 min at 450 C.
SOLUCION
2. PROBLEM 28 An Introduction to Chemical Engineering Kinetics &
Reactor Design
By Charles G. Hill
The following addition reaction takes place in the gas phase at 400
1
A +B
A 0.40
B 0.40
C 0.11
Inerts 0.09
K1 K2
A B C
This network can represent a wide variety of important classes of reactions. For
example, oxidation reactions occurring in excess oxidant, where B is the desired
product. Calculate the time when production is high.
SOLUCION
4. Problem 6.9: Principles of Chemical Reactor Analysis and Design: New Tools
for Industrial Chemical Reactor Operations
Uzi Mann (Author), Ed. Wiley, 2 edition, Chap. 6, pag. 234 problem 6.9.
1
= 1 1 ( )
-rA=KCA2
INCOGNITA
xA=80% t= ?
1
= ( ) (1)
= 2 (2)
1
( ) = 2
1 2
( )= 2
2
= (3)
0 (1 + )
= 0 (1 ) (4)
12 1
= = (5)
2 2
(1 ) 20 (1 )2
0 =
0 (1 1/2 )
(1 ) (1 )2
= 0
0 (1 1/2 )
(1 )
(2 ) 2
= 2 0
(1 ) 0
Ahora integrando esto obtenemos
0 = 53.193
= 0 (1 + )
= 0 (1 1/2 )
= 300
Entonces tenemos:
= 0.8,
0 = 500,
1
= 11 (
)
0 = 53.193
Reemplazando en (6)
=26.364min
DATOS
2AB
-rA=KCA2
INCOGNITA
CA=10 M y t= 1h xA=?
1
= ( )
= ( ) (1)
= 2 (2)
( ) = 2
Despejando:
( ) =
2
e integrando:
2 =
Obtenemos:
1 1
( ) = (3)
Sabemos que:
= (1 ) (4)
1
( ) = (5)
1
1
( ) = (5)
1
Para: CA=1 M y t= 1h xA=0.5
1 0.5
( ) = (1)
1 / 1 0.5
El valor de K es:
= 1 .
CA=10 M y t= 1h xA=???
Utilizando la ecuacin 5:
1
( ) = 1 . (1)
10 / 1
Resolviendo:
= 0.909