Nama : Tsania Safitri

NIM : 4311414034

Prodi : Kimia

Makul : Dinamika Kimia

Diketahui

k1

Br2 Br. + Br.

k2

Br. + H2 HBr + H.

k3

H. + Br2 HBr + Br.

k*2

H. + HBr H2 + Br.

k*1

Br. + Br. Br2

Laju reaksi HBr

[]
= 2 [ . ][2 ] + 3 [ . ][2 ] 2 [ . ][]

Steady-state untuk [Br] [H]

[ . ]
= 21 [2 ] 2 [ . ][2 ] + 3 [ . ][2 ] + 2 [ . ][] 21 []2 = 0

[ . ]
= 2 [ . ][2 ] 3 [. ][2 ] 2 [ . ][] = 0

Kedua data steady-state diatas digabungkan :

[ . ] [ . ]
=

21 [2 ] 2 [ . ][2 ] + 3 [ . ][2 ] + 2 [ . ][] 21 []2 = 2 [ . ][2 ] 3 [ . ][2 ] 2 [ . ][]

Didapatkan hasil :

21 [2 ] 21 [ . ]2 = 0
Sehingga :

1 1 1
[ . ] = ( ) []
2 2
1

Steady-state untuk [H.]

2 [2 ][ . ]
[ . ] =
3 [2 ] + 2 []

Substitusi [Br.] ke [H.], menjadi :

1
2 ( 1 )2 [2 ] [2 ]1/2
1
[ . ] =
3 [2 ] + 2 []
[] [ . ]
Adisi
=

[] 22 [ . ][2 ] + 2 1 [ . ]2
=
22 [ . ][] + 21 [2 ]

1 1 1 1
22 ( 1 )2 [2 ] [2 ]2 + 21 {( 1 )2 [2 ]2 }2
1 1
= .
2 [2 ][ ]
22 ( ) [] + 21 [2 ]
3 [2 ] + 2 []

1 1
22 ( 1 )2 [2 ] [2 ]2 + 21 ( 1 )[2 ]
1 1
= .
2 [2 ][ ]
2 [] ( ) + 21 [2 ]
3 [2 ] + 2 []

1 1
22 ( 1 )2 [2 ] [2 ]2 + 21 [2 ]
1
=
2 [2 ][ . ]
2( ) + 21 [2 ]
3 [2 ] + 2 []

1 1
22 ( 1 )2 [2 ] [2 ]2 + 1
1
=
2 [2 ][ . ]
2( )+1
3 [2 ] + 2 []

1 1
22 ( 1 )2 [2 ] [2 ]2 + 1
1
=
2 [2 ][ . ]2 []
2( )+1
3 [2 ]

1 1
22 ( 1 )2 [2 ] [2 ]2 + 1
1
= 1 1

2 ( 1 )2 [2 ] [2 ]2 2 []
1
2( )+1
3 [2 ]
 21 [2 ] + 1
= []2 [ ]
2 1 2 + 1
( )
3 [2 ]

1 + 3 [2 ]
=
2 [] + 1