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S c 44 RBS No. :
PAPER - 1 : PHYSICS, MATHEMATICS & CHEMISTRY
S - 1 : , U
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 PART A PHYSICS A
ALL THE GRAPHS/DIAGRAMS GIVEN ARE /U U
SCHEMATIC AND NOT DRAWN TO SCALE. U S U U

1. A particle is executing simple harmonic 1. , T U U U

motion with a time period T. At time t=0, t=0 U S S
it is at its position of equilibrium. The
kinetic energy - time graph of the particle ?
will look like :

(1) (1)

(2) (2)

(3) (3)

(4) (4)

2. The temperature of an open room of 2. U 30 m3

volume 30 m3 increases from 178C to 278C U 178C U 278C
due to the sunshine. The atmospheric U U U
pressure in the room remains 1105 Pa. 1105 Pa U U U
If ni and nf are the number of molecules in ni
the room before and after heating, then nf nfni
nfni will be :
(1) 2.510 25 (1) 2.510 25
(2) 2.510 25 (2) 2.510 25
(3) 1.6110 23 (3) 1.6110 23
(4) 1.3810 23 (4) 1.3810 23

B/Page 2 SPACE FOR ROUGH WORK / U

3. Which of the following statements is 3. ?
false ?

(1) A rheostat can be used as a potential (1) U

divider. U U
(2) Kirchhoffs second law represents (2) U m U
energy conservation.
(3) Wheatstone bridge is the most (3) USU
sensitive when all the four U U U
resistances are of the same order of
magnitude.

(4) In a balanced wheatstone bridge if (4) USU ,

the cell and the galvanometer are UU U
exchanged, the null point is
disturbed.

4. The following observations were taken for 4. cU

determining surface tension T of water by T
capillary method :

diameter of capillary, D=1.25102 m , D=1.25102 m

rise of water, h=1.45102 m. , h=1.45102 m

Using g=9.80 m/s 2 and the simplified g=9.80 m/s 2 U

rhg rhg
relation T= 103 N/m , the T= 103 N/m , U
2 2
possible error in surface tension is closest cU U U
to :

(1) 2.4% (1) 2.4%

(2) 10% (2) 10%

(3) 0.15% (3) 0.15%

(4) 1.5% (4) 1.5%

B/Page 3 SPACE FOR ROUGH WORK / U

5. In amplitude modulation, sinusoidal 5. U c
carrier frequency used is denoted by c m
and the signal frequency is denoted by m. U (m) U
The bandwidth (m) of the signal is such m<<c. U
that m<<c . Which of the following U ?
frequencies is not contained in the
modulated wave ?
(1) m+ c (1) m+ c
(2) c m (2) c m
(3) m (3) m
(4) c (4) c

6. A diverging lens with magnitude of focal 6. 25 cm U U U

length 25 cm is placed at a distance of 20 cm U
15 cm from a converging lens of magnitude U 15 cm U U U
of focal length 20 cm. A beam of parallel U U U
light falls on the diverging lens. The final U
image formed is :
(1) real and at a distance of 40 cm from (1) S U U 40 cm U
the divergent lens. U
(2) real and at a distance of 6 cm from (2) S U U 6 cm U
the convergent lens. U
(3) real and at a distance of 40 cm from (3) S U U 40 cm U
convergent lens. U
(4) virtual and at a distance of 40 cm (4) U U 40 cm U
from convergent lens. U
7. The moment of inertia of a uniform 7. R l
cylinder of length l and radius R about its m
perpendicular bisector is I. What is the I
ratio l/R such that the moment of inertia l/R ?
is minimum ?
(1) 1 (1) 1
3 3
(2) (2)
2 2
3 3
(3) (3)
2 2
3 3
(4) (4)
2 2
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8. An electron beam is accelerated by a 8. X-U U U U
potential difference V to hit a metallic U V U U U U
target to produce X-rays. It produces
continuous as well as characteristic X-rays. (characteristic) U (continuous)
If min is the smallest possible wavelength X-U X-U SU
of X-ray in the spectrum, the variation of U min log min
log min with log V is correctly represented log V
in : ?

(1) (1)

(2) (2)

(3) (3)

(4) (4)

B/Page 5 SPACE FOR ROUGH WORK / U

9. A radioactive nucleus A with a half life T, 9. UUU -A h- T
decays into a nucleus B. At t=0, there is , -B t=0
no nucleus B. At sometime t, the ratio of U -B t U
the number of B to that of A is 0.3. Then, B A 0.3 t
t is given by :
(1) t=T log (1.3) (1) t=T log (1.3)

T T
(2) t= (2) t=
log (1.3) log (1.3)

T log 2 T log 2
(3) t= (3) t=
2 log 1.3 2 log 1.3

log 1.3 log 1.3

(4) t=T (4) t=T
log 2 log 2

10. An electric dipole has a fixed dipole 10. l m SU m p

moment p , which makes angle with x- l E1= E i

respect to x-axis. When subjected to an U U T1= k

electric field E1= E i , it experiences a U l E 2= 3 E1 j U U

torque T1= k . When subjected to T2 = T1 U

another electric field E 2= 3 E1 j it

experiences a torque T2 = T1 . The angle
is :

(1) 608 (1) 608

(2) 908 (2) 908

(3) 308 (3) 308

(4) 458 (4) 458

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11. In a common emitter amplifier circuit 11. n-p-n U$SUU cU
using an n-p-n transistor, the phase U
difference between the input and the U
output voltages will be :
(1) 1358 (1) 1358
(2) 1808 (2) 1808
(3) 458 (3) 458
(4) 908 (4) 908

12. Cp and Cv are specific heats at constant 12. SU SU U cU c

pressure and constant volume respectively. Cp Cv
It is observed that
CpCv=a for hydrogen gas U , CpCv=a
CpCv=b for nitrogen gas U , CpCv=b
The correct relation between a and b is : a U b
(1) a=14 b (1) a=14 b
(2) a=28 b (2) a=28 b
1 1
(3) a= b (3) a= b
14 14
(4) a=b (4) a=b

13. A copper ball of mass 100 gm is at a 13. 100 gm

temperature T. It is dropped in a copper T 170 gm U 100 gm
calorimeter of mass 100 gm, filled with UUU, U U
170 gm of water at room temperature. , U
Subsequently, the temperature of the 758C T
system is found to be 758C. T is given by :
(Given : room temperature=308C, specific ( U =308C, C
heat of copper=0.1 cal/gm8C) c =0.1 cal/gm8C)
(1) 12508C (1) 12508C
(2) 8258C (2) 8258C
(3) 8008C (3) 8008C
(4) 8858C (4) 8858C

B/Page 7 SPACE FOR ROUGH WORK / U

14. A body of mass m=102 kg is moving in 14. m=102 kg U
a medium and experiences a frictional U U F=kv2
force F=kv 2 . Its initial speed is U U U
v0=10 ms1. If, after 10 s, its energy is v0=10 ms1 10 s
1 1
8
mv02, the value of k will be :
8
mv02 k

(1) 104 kg m1 (1) 104 kg m1

(2) 101 kg m1 s1 (2) 101 kg m1 s1

(3) 103 kg m1 (3) 103 kg m1

(4) 103 kg s1 (4) 103 kg s1

15. When a current of 5 mA is passed through 15. 15 U U UU

a galvanometer having a coil of resistance 5 mA U
15 , it shows full scale deflection. The S 010 V U
value of the resistance to be put in series U
with the galvanometer to convert it into a UU ?
voltmeter of range 010 V is :

(1) 2.535103 (1) 2.535103

(2) 4.005103 (2) 4.005103

(3) 1.985103 (3) 1.985103

(4) 2.04510 3 (4) 2.04510 3

B/Page 8 SPACE FOR ROUGH WORK / U

16. A slender uniform rod of mass M and 16. M l
length l is pivoted at one end so that it can U U US
rotate in a vertical plane (see figure). There U ( )
is negligible friction at the pivot. The free U U U U U
end is held vertically above the pivot and U U UU U
then released. The angular acceleration U
of the rod when it makes an angle with U
the vertical is :

3g 3g
(1) cos (1) cos
2l 2l

2g 2g
(2) cos (2) cos
3l 3l

3g 3g
(3) sin (3) sin
2l 2l

2g 2g
(4) sin (4) sin
3l 3l

B/Page 9 SPACE FOR ROUGH WORK / U

17. Some energy levels of a molecule are 17. U SU
shown in the figure. The ratio of the UZ r=1/2
wavelengths r=1/2, is given by :

3 3
(1) r= (1) r=
4 4

1 1
(2) r= (2) r=
3 3

4 4
(3) r= (3) r=
3 3

2 2
(4) r= (4) r=
3 3

18. A man grows into a giant such that his 18. c, U

linear dimensions increase by a factor U U 9
of 9. Assuming that his density remains U
same, the stress in the leg will change by a U ?
factor of :

(1) 81 (1) 81

1 1
(2) (2)
81 81

(3) 9 (3) 9

1 1
(4) (4)
9 9

B/Page 10 SPACE FOR ROUGH WORK / U

19. In a coil of resistance 100 , a current is 19. 100 U
induced by changing the magnetic flux U U U
through it as shown in the figure. The U U U
magnitude of change in flux through the
coil is :

(1) 250 Wb (1) 250 Wb

(2) 275 Wb (2) 275 Wb

(3) 200 Wb (3) 200 Wb

(4) 225 Wb (4) 225 Wb

20. In a Youngs double slit experiment, slits 20. mU , U U

are separated by 0.5 mm, and the screen 0.5 mm U U 150 cm
is placed 150 cm away. A beam of light , 650 nm U 520 nm
consisting of two wavelengths, 650 nm U , U U
and 520 nm, is used to obtain interference U cU cU
fringes on the screen. The least distance , UZ #
from the common central maximum to the , U
point where the bright fringes due to both
the wavelengths coincide is :

(1) 9.75 mm (1) 9.75 mm

(2) 15.6 mm (2) 15.6 mm

(3) 1.56 mm (3) 1.56 mm

(4) 7.8 mm (4) 7.8 mm

B/Page 11 SPACE FOR ROUGH WORK / U

21. A magnetic needle of magnetic moment 21. 6.7102 Am2
6.710 2 Am 2 and moment of inertia 7.5106 kg m2 Z,
7.510 6 kg m 2 is performing simple 0.01 T U
harmonic oscillations in a magnetic field U U 10 U
of 0.01 T. Time taken for 10 complete
oscillations is :

(1) 6.98 s (1) 6.98 s

(2) 8.76 s (2) 8.76 s

(3) 6.65 s (3) 6.65 s

(4) 8.89 s (4) 8.89 s

22. The variation of acceleration due to gravity 22. U d L U g

g with distance d from centre of the
earth is best represented by (R=Earths ? (R= )
radius) :

(1) (1)

(2) (2)

(3) (3)

(4) (4)

B/Page 12 SPACE FOR ROUGH WORK / U

23. 23.

In the above circuit the current in each U U U U

resistance is :

(1) 0.5 A (1) 0.5 A

(2) 0A (2) 0A

(3) 1A (3) 1A

(4) 0.25 A (4) 0.25 A

24. A particle A of mass m and initial velocity 24. m U v -A

m m
v collides with a particle B of mass UU SU -B
2 2
which is at rest. The collision is head on, UU S UU
and elastic. The ratio of the de-Broglie U- UZ A B
wavelengths A to B after the collision is :

A 2 A 2
(1) = (1) =
B 3 B 3

A 1 A 1
(2) = (2) =
B 2 B 2

A 1 A 1
(3) = (3) =
B 3 B 3

A A
(4) =2 (4) =2
B B

B/Page 13 SPACE FOR ROUGH WORK / U

25. An external pressure P is applied on a cube 25. 08C U U U P
at 08C so that it is equally compressed from U UU U
all sides. K is the bulk modulus of the S
material of the cube and is its coefficient K U U
of linear expansion. Suppose we want to U U
bring the cube to its original size by ?
heating. The temperature should be raised
by :
3 3
(1) PK (1) PK
(2) 3PK (2) 3PK
P P
(3) 3 K (3) 3 K

P P
(4) K (4) K

26. A time dependent force F=6t acts on a 26. 1 kg , U U

particle of mass 1 kg. If the particle starts (time dependent) F=6t U
from rest, the work done by the force US 1 s
during the first 1 sec. will be : mU
(1) 9J (1) 9J
(2) 18 J (2) 18 J
(3) 4.5 J (3) 4.5 J
(4) 22 J (4) 22 J

27. An observer is moving with half the speed 27. 10 GHz

of light towards a stationary microwave SU U (microwave)
source emitting waves at frequency d U U mU
10 GHz. What is the frequency of the U
microwave measured by the observer ? ( =3108 ms1)
(speed of light=3108 ms1)
(1) 17.3 GHz (1) 17.3 GHz
(2) 15.3 GHz (2) 15.3 GHz
(3) 10.1 GHz (3) 10.1 GHz
(4) 12.1 GHz (4) 12.1 GHz

B/Page 14 SPACE FOR ROUGH WORK / U

28. In the given circuit diagram when the 28. U U SUS
current reaches steady state in the circuit, U C U U
the charge on the capacitor of capacitance
C will be :

(1) r2 (1) r2
CE CE
(r+r2 ) (r+r2 )

r1 r1
(2) CE (2) CE
(r1+r) (r1+r)

(3) CE (3) CE

r1 r1
(4) CE (4) CE
( 2 +r )
r ( 2 +r )
r

29. A capacitance of 2 F is required in an 29. l U 2 F U U

electrical circuit across a potential 1.0 kV U
difference of 1.0 kV. A large number of 1 F U U U
1 F capacitors are available which can 300 V U U ,
withstand a potential difference of not
more than 300 V.

The minimum number of capacitors U U # U

required to achieve this is : U ?
(1) 24 (1) 24

(2) 32 (2) 32

(3) 2 (3) 2

(4) 16 (4) 16

B/Page 15 SPACE FOR ROUGH WORK / U

30. A body is thrown vertically upwards. 30. U U U U
Which one of the following graphs
correctly represent the velocity vs time ? ?

(1) (1)

(2) (2)

(3) (3)

(4) (4)

B/Page 16 SPACE FOR ROUGH WORK / U

 PART B MATHEMATICS B

31. Let k be an integer such that the triangle 31. k Z ,

with vertices (k, 3k), (5, k) and (k, 2) (k, 3k), (5, k) (k, 2) ,
has area 28 sq. units. Then the orthocentre 28 , -
of this triangle is at the point : U ,
1 1
(1) 2, (1) 2,
2 2

1 1
(2) 2, (2) 2,
2 2

3 3
(3) 1, (3) 1,
4 4

3 3
(4) 1, (4) 1,
4 4

32. If, for a positive integer n, the quadratic 32. Z n , m U

equation,
x(x+1)+(x+1)(x+2)+.... x(x+1)+(x+1)(x+2)+....
+ ( x + n 1) (x+n)=10n + ( x + n 1) (x+n)=10n
has two consecutive integral solutions, Z , n UU
then n is equal to :
(1) 11 (1) 11
(2) 12 (2) 12
(3) 9 (3) 9
(4) 10 (4) 10

The function f : R , defined f : R , ,

1 1 1 1
33.
2 2
33.
2 2
x x
as f ( x ) =
2
, is : f (x) = mU U
1+x 1 + x2
(1) neither injective nor surjective. (1) U U
(2) invertible. (2)
(3) injective but not surjective. (3) U U
(4) surjective but not injective. (4) U U
B/Page 17 SPACE FOR ROUGH WORK / U
34. The following statement 34.
(pq)[(~pq)q] is : (pq)[(~pq)q]
(1) a fallacy (1) (fallacy)
(2) a tautology (2) L (tautology)
(3) equivalent to ~pq (3) ~pq
(4) equivalent to p~q (4) p~q

35. If S is the set of distinct values of b for 35. S, b

which the following system of linear U U
equations
x+y+z=1 x+y+z=1
x+ay+z=1 x+ay+z=1
ax+by+z=0 ax+by+z=0
has no solution, then S is : , S
(1) a singleton (1)
(2) an empty set (2) U
(3) an infinite set (3) U
(4) a finite set containing two or more (4) U
elements

36. The area (in sq. units) of the region 36. {(x, y) : x/0, x+y3, x 2 4y
{(x, y) : x/0, x+y3, x 2 4y and y1+ x } ( )
y1+ x } is :

5 5
(1) (1)
2 2

59 59
(2) (2)
12 12

3 3
(3) (3)
2 2

7 7
(4) (4)
3 3

B/Page 18 SPACE FOR ROUGH WORK / U

37. For any three positive real numbers 37. S a, b c
a, b and c,
9(25a2+b2)+25(c 23ac)=15b(3a+c). 9(25a2+b2)+25(c23ac)=15b(3a+c)
Then : ,
(1) a, b and c are in G.P. (1) a, b c U
(2) b, c and a are in G.P. (2) b, c a U
(3) b, c and a are in A.P. (3) b, c a U
(4) a, b and c are in A.P. (4) a, b c U

38. A man X has 7 friends, 4 of them are ladies 38. X 7 , 4

and 3 are men. His wife Y also has 7 3 L , Y 7 ,
friends, 3 of them are ladies and 4 are men. 3 4 L X
Assume X and Y have no common friends. Y cU (common)
Then the total number of ways in which U X Y
X and Y together can throw a party 3 3 L U U
inviting 3 ladies and 3 men, so that 3 friends X Y - ,
of each of X and Y are in this party, is :
(1) 484 (1) 484
(2) 485 (2) 485
(3) 468 (3) 468
(4) 469 (4) 469

39. The normal to the curve 39. y(x2)(x3)=x+6 U,

y(x2)(x3)=x+6 at the point where y- U ,
the curve intersects the y-axis passes U ?
through the point :

1 1 1 1
(1) , (1) ,
2 3 2 3

1 1 1 1
(2) , (2) ,
2 2 2 2

1 1 1 1
(3) , (3) ,
2 2 2 2

1 1 1 1
(4) , (4) ,
2 3 2 3

B/Page 19 SPACE FOR ROUGH WORK / U

40. A hyperbola passes through the point 40. U P ( 2 , 3 ) U
P( 2, 3 ) and has foci at (2, 0). Then , (2, 0) U , U
the tangent to this hyperbola at P also P U S U U
passes through the point : ,
(1) ( 2, 3) (1) ( 2, 3)

(2) (3 2, 2 3) (2) (3 2, 2 3)
(3) (2 2, 3 3) (3) (2 2, 3 3)
(4) ( 3, 2) (4) ( 3, 2)

41. Let a, b, c e R. If f (x)=ax2+bx+c is such 41. a, b, c e R f (x)=ax2+bx+c

that a+b+c=3 and a+b+c=3 x, y e R
f (x+y)=f (x)+f (y)+xy, x, y e R, f (x+y)=f (x)+f (y)+xy
10 10
then f (n) is equal to : , f (n) UU
n=1 n=1

(1) 255 (1) 255

(2) 330 (2) 330
(3) 165 (3) 165
(4) 190 (4) 190

42. Let a = 2 i + j 2 k and b = i + j . 42. a =2 i + j 2k b=i + j

Let c be a vector such that c a = 3 , c c a =3 ,

( a b ) c = 3 and the angle between ( a b ) c = 3

c U

a b



c and a b be 308. Then a c is 308 , a c UU
equal to :
1 1
(1) (1)
8 8
25 25
(2) (2)
8 8
(3) 2 (3) 2
(4) 5 (4) 5

B/Page 20 SPACE FOR ROUGH WORK / U

43. Let a vertical tower AB have its end A on 43. U U AB
the level ground. Let C be the mid-point U A U AB C
of AB and P be a point on the ground such U S P AP=2AB
that AP=2AB. If BPC=, then tan is BPC= , tan UU
equal to :

4 4
(1) (1)
9 9

6 6
(2) (2)
7 7

1 1
(3) (3)
4 4

2 2
(4) (4)
9 9

44. Twenty meters of wire is available for 44. U, U

fencing off a flower-bed in the form of a M , U U UU U
circular sector. Then the maximum area U
(in sq. m) of the flower-bed, is : ( . ),
(1) 30 (1) 30

(2) 12.5 (2) 12.5

(3) 10 (3) 10

(4) 25 (4) 25

3 3
4 4
dx dx
45. The integral


1 + cos x
is equal to : 45.

1 + cos x
UU
4 4

(1) 1 (1) 1

(2) 2 (2) 2

(3) 2 (3) 2

(4) 4 (4) 4

B/Page 21 SPACE FOR ROUGH WORK / U

 dy dy
46. If (2 + sin x ) + (y + 1)cos x = 0 and 46. (2 + sin x ) + (y + 1)cos x = 0
dx dx
y

y(0)=1, then y is equal to : y(0)=1 , UU
2 2

4 4
(1) (1)
3 3

1 1
(2) (2)
3 3

2 2
(3) (3)
3 3

1 1
(4) (4)
3 3

47. Let I n = tan n x dx , (n > 1) . If 47. I n = tan n x dx , (n > 1)

I 4+I 6=a tan 5 x+bx 5+C, where C is a I 4+I 6 =a tan 5 x+bx 5+C , C
constant of integration, then the ordered U , (a, b) UU
pair (a, b) is equal to :

1 1
(1) , 0 (1) , 0
5 5

1 1
(2) , 1 (2) , 1
5 5

1 1
(3) , 0 (3) , 0
5 5

1 1
(4) , 1 (4) , 1
5 5

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48. Let be a complex number such that 48. 2+1=z
2+1=z where z = 3 . If z = 3

1 1 1 1 1 1
1 21 2 = 3k, 1 21 2 = 3k
2 7 2 7
1 1

then k is equal to : k UU

(1) 1 (1) 1

(2) z (2) z

(3) z (3) z

(4) 1 (4) 1

49. The value of 49. ( 21 C1 10C1 ) + ( 21 C2 10C2 ) +

( 21 C1 10C1 ) + ( 21 C2 10C2 ) +
( 21 C3 10C3 ) + ( 21 C 4 10C 4 ) + ..... +
( 21 C3 10C3 ) + ( 21 C 4 10C 4 ) + ..... +
( 21 C10 10C10 )
( 21 C10 10C10 ) is :

(1) 220210 (1) 220210

(2) 221211 (2) 221211

(3) 221210 (3) 221210

(4) 220 2 9 (4) 220 2 9

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50. lim cot x cos x equals : 50. lim cot x cos x UU
x
2 ( 2x ) 3 x
2 ( 2x ) 3

1 1
(1) (1)
4 4

1 1
(2) (2)
24 24

1 1
(3) (3)
16 16

1 1
(4) (4)
8 8

51. If 5(tan2 xcos2 x)=2cos 2x+9, then the 51. 5(tan 2 xcos 2 x)=2cos 2x+9,
value of cos 4x is : cos 4x

7 7
(1) (1)
9 9

3 3
(2) (2)
5 5

1 1
(3) (3)
3 3

2 2
(4) (4)
9 9

52. If the image of the point P(1, 2, 3) in the 52.

P(1, 2, 3)
plane, 2x+3y4z+22=0 measured 2x+3y4z+22=0 U
x y z x y z
parallel to the line, = = is Q, then = = U , Q , PQ UU
1 4 5 1 4 5
PQ is equal to :
(1) 6 5 (1) 6 5

(2) 3 5 (2) 3 5

(3) 2 42 (3) 2 42
(4) 42 (4) 42

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53. The distance of the point (1, 3, 7) from 53. (1, 1, 1) U
the plane passing through the point U
(1, 1, 1), having normal perpendicular x 1 y +2 z 4
= =
x 1 y +2 z 4 1 2 3
to both the lines = =
1 2 3 x 2 y +1 z +7
= = U ,
x 2 y +1 z +7 2 1 1
and = = , is :
2 1 1 (1, 3, 7) U

10 10
(1) (1)
74 74

20 20
(2) (2)
74 74

10 10
(3) (3)
83 83

5 5
(4) (4)
83 83

6x x
x 0,
1
If for x 0, , the derivative of tan1
1 54.
54.
4 4 1 9x 3

6x x
tan1 is x g(x ) , then g(x) x g(x ) , g(x) UU
1 9x 3
equals :

3 3
(1) 3 (1)
1 + 9x 1 + 9x 3

9 9
(2) 3
(2)
1 + 9x 1 + 9x 3

3x x 3x x
(3) 3 (3)
1 9x 1 9x 3

3x 3x
(4) 3 (4)
1 9x 1 9x 3

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55. The radius of a circle, having minimum 55. , y=4x2
area, which touches the curve y=4x2 U y=?x? S U ,
and the lines, y=?x? is :

(1) 4 ( 2 + 1) (1) 4 ( 2 + 1)

(2) 2 ( 2 + 1) (2) 2 ( 2 + 1)

(3) 2 ( 2 1) (3) 2 ( 2 1)

(4) 4 ( 2 1) (4) 4 ( 2 1)

56. A box contains 15 green and 10 yellow 56. 15 U 10

balls. If 10 balls are randomly drawn, - U U , S ,
one-by-one, with replacement, then the 10 , U
variance of the number of green balls U
drawn is :

6 6
(1) (1)
25 25

12 12
(2) (2)
5 5

(3) 6 (3) 6

(4) 4 (4) 4

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57. The eccentricity of an ellipse whose centre 57. , U ,
1 1
is at the origin is . If one of its directrices x=4 ,
2 2

3
U
is x=4, then the equation of the normal 1,
2

to it at 1, is :
3
2
U

(1) x+2y=4 (1) x+2y=4

(2) 2yx=2 (2) 2yx=2

(3) 4x2y=1 (3) 4x2y=1

(4) 4x+2y=7 (4) 4x+2y=7

58. If two different numbers are taken from 58. {0, 1, 2, 3, ......, 10}
the set {0, 1, 2, 3, ......, 10}; then the Z,
probability that their sum as well as U U , U
absolute difference are both multiple of 4,
is :

7 7
(1) (1)
55 55

6 6
(2) (2)
55 55

12 12
(3) (3)
55 55

14 14
(4) (4)
45 45

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59. For three events A, B and C, 59. U A, B C
P(Exactly one of A or B occurs) P(A B U )
=P(Exactly one of B or C occurs) =P(B C U )
1 1
=P(Exactly one of C or A occurs)= and =P(C A U )=
4 4
P(All the three events occur P( U U
1 1
simultaneously)= . )= ,
16 16
Then the probability that at least one of U U ,
the events occurs, is :

3 3
(1) (1)
16 16

7 7
(2) (2)
32 32

7 7
(3) (3)
16 16

7 7
(4) (4)
64 64

2 3 2 3
60. If A = , then adj (3A +12A) is
2 60. A= , adj (3A2+12A)
4 1 4 1
equal to : UU
72 63 72 63
(1) 84 (1)
51 84
51

72 84 72 84
(2) 63 (2)
51 63
51

51 63 51 63
(3) 84 72 (3) 84 72

51 84 51 84
(4) 63 72 (4) 63 72

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 PART C CHEMISTRY C U
61. Which of the following compounds will 61. U
form significant amount of meta product U U?
during mono-nitration reaction ?

(1) (1)

(2) (2)

(3) (3)

(4) (4)

62. U is equal to : 62. U UU ,

(1) Isochoric work (1) -
(2) Isobaric work (2)
(3) Adiabatic work (3) Lhc
(4) Isothermal work (4)

63. The increasing order of the reactivity of 63. S N1 U

the following halides for the SN1 reaction
is :
CH3CH2CH2Cl CH3CH2CH2Cl

(I) (II) (I) (II)

pH3COC6H4CH2Cl pH3COC6H4CH2Cl
(III) (III)
(1) (III) < (II) < (I) (1) (III) < (II) < (I)
(2) (II) < (I) < (III) (2) (II) < (I) < (III)
(3) (I) < (III) < (II) (3) (I) < (III) < (II)
(4) (II) < (III) < (I) (4) (II) < (III) < (I)

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64. The radius of the second Bohr orbit for 64. U U m U h
hydrogen atom is :
(Plancks Const. h=6.62621034 Js; ( SU h=6.62621034 Js;
mass of electron=9.10911031 kg; U =9.10911031 kg;
charge of electron e=1.602101019 C; U U e=1.602101019 C;
permittivity of vacuum Ul
e0=8.8541851012 kg1m3A2) e0=8.8541851012 kg1m3A2)
(1) 1.65 (1) 1.65
(2) 4.76 (2) 4.76
(3) 0.529 (3) 0.529
(4) 2.12 (4) 2.12

65. pKa of a weak acid (HA) and pKb of a weak 65. (HA) pKa
base (BOH) are 3.2 and 3.4, respectively. U (BOH) pKb 3.2 3.4
The pH of their salt (AB) solution is : (AB) pH
(1) 7.2 (1) 7.2
(2) 6.9 (2) 6.9
(3) 7.0 (3) 7.0
(4) 1.0 (4) 1.0

66. The formation of which of the following 66. U

polymers involves hydrolysis reaction ? ?
(1) Nylon 6 (1) 6
(2) Bakelite (2) U
(3) Nylon 6, 6 (3) 6, 6
(4) Terylene (4) UU

67. The most abundant elements by mass in 67. SS c UU cU

the body of a healthy human adult are : (61.4%);
Oxygen (61.4%); Carbon (22.9%), (22.9%), U (10.0%);
Hydrogen (10.0%); and Nitrogen (2.6%). U (2.6%) 75 kg
The weight which a 75 kg person would UU 1H U 2H U
gain if all 1H atoms are replaced by 2H U h ,
atoms is :
(1) 15 kg (1) 15 kg
(2) 37.5 kg (2) 37.5 kg
(3) 7.5 kg (3) 7.5 kg
(4) 10 kg (4) 10 kg

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68. Which of the following, upon treatment 68. , tert-BuONa
with tert-BuONa followed by addition of U U, U
bromine water, fails to decolourize the U U ?
colour of bromine ?

(1) (1)

(2) (2)

(3) (3)

(4) (4)

69. In the following reactions, ZnO is 69. , ZnO U

respectively acting as a/an :
(a) ZnO+Na2O Na2ZnO2 (a) ZnO+Na2O Na2ZnO2
(b) ZnO+CO2 ZnCO3 (b) ZnO+CO2 ZnCO3
(1) base and acid (1) U
(2) base and base (2) U U
(3) acid and acid (3)
(4) acid and base (4) U

70. Both lithium and magnesium display 70. U,

several similar properties due to the U U ,
diagonal relationship; however, the one ,
which is incorrect, is :
(1) both form basic carbonates (1) U U
(2) both form soluble bicarbonates (2) U
(3) both form nitrides (3) UU
(4) nitrates of both Li and Mg yield NO2 (4) , UU
and O2 on heating U U U NO2 O2

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71. 3-Methyl-pent-2-ene on reaction with HBr 71. UU S , 3--U-2-,
in presence of peroxide forms an addition HBr U U
product. The number of possible
stereoisomers for the product is :
(1) Six (1) U
(2) Zero (2)
(3) Two (3)
(4) Four (4) U

72. A metal crystallises in a face centred cubic 72. U SU

structure. If the edge length of its unit cell U a
is a, the closest approach between two , SU U
atoms in metallic crystal will be : U U
(1) 2a (1) 2a

(2) 2 2a (2) 2 2a

(3) 2a (3) 2a

a a
(4) (4)
2 2

73. Two reactions R1 and R2 have identical 73. , R1 R2 U

pre-exponential factors. Activation energy R1 R2
of R1 exceeds that of R2 by 10 kJ mol1. If 10 kJ mol1
k1 and k2 are rate constants for reactions R1 R2 300 K U U
R 1 and R 2 respectively at 300 K, then k1 k2 ln(k2/k1)
ln(k2/k1) is equal to : UU ?
(R=8.314 J mol1K1) (R=8.314 J mol1K1)

(1) 8 (1) 8

(2) 12 (2) 12

(3) 6 (3) 6

(4) 4 (4) 4

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74. The correct sequence of reagents for the 74. MU
following conversion will be :

(1) [Ag(NH3 )2 ]+OH, H+/CH 3OH, (1) [Ag(NH3 )2 ]+OH, H+/CH 3OH,
CH3 MgBr CH3 MgBr

(2) CH3 MgBr, H+/CH 3OH, (2) CH3 MgBr, H+/CH 3OH,
[Ag(NH3 )2 ]+OH [Ag(NH3 )2 ]+OH

(3) CH 3MgBr, [Ag(NH3 )2 ]+OH, (3) CH 3MgBr, [Ag(NH3 )2 ]+OH,

H+/CH3OH H+/CH3OH

(4) [Ag(NH3 )2 ]+OH, CH 3MgBr, (4) [Ag(NH3 )2 ]+OH, CH 3MgBr,

H+/CH3 OH H+/CH3 OH

75. The Tyndall effect is observed only when 75. UU

following conditions are satisfied : cU
(a) The diameter of the dispersed (a) U ,
particles is much smaller than the U UU
wavelength of the light used.
(b) The diameter of the dispersed (b) U ,
particle is not much smaller than the U UU
wavelength of the light used.
(c) The refractive indices of the (c) U S U
dispersed phase and dispersion U
medium are almost similar in
magnitude.
(d) The refractive indices of the (d) U S U
dispersed phase and dispersion U
medium differ greatly in magnitude.
(1) (a) and (d) (1) (a) (d)
(2) (b) and (d) (2) (b) (d)
(3) (a) and (c) (3) (a) (c)
(4) (b) and (c) (4) (b) (c)

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76. Which of the following compounds will 76. KOH
behave as a reducing sugar in an aqueous U M U
KOH solution ? U?
(1) (1)

(2) (2)

(3) (3)

(4) (4)

77. Given 77. ,

C(graphite)+O2(g) CO2(g) ; C(graphite)+O2(g) CO2(g) ;
rH8=393.5 kJ mol1 rH8=393.5 kJ mol1
H2(g)+ 21 O2(g) H2O(l) ; H2(g)+ 21 O2(g) H2O(l) ;
rH8=285.8 kJ mol1 rH8=285.8 kJ mol1
CO2(g)+2H2O(l) CH4(g)+2O2(g) ; CO2(g)+2H2O(l) CH4(g)+2O2(g) ;
rH8=+890.3 kJ mol1 rH8=+890.3 kJ mol1
Based on the above thermochemical U cU U U
equations, the value of rH8 at 298 K for U 298 K U
the reaction C(graphite)+2H2(g) CH4(g)
C(graphite)+2H2(g) CH4(g) will be : rH8
(1) +74.8 kJ mol1 (1) +74.8 kJ mol1
(2) +144.0 kJ mol1 (2) +144.0 kJ mol1
(3) 74.8 kJ mol1 (3) 74.8 kJ mol1
(4) 144.0 kJ mol1 (4) 144.0 kJ mol1

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78. Which of the following reactions is an 78.
example of a redox reaction ? (UU) U ?
(1) XeF4 + O2F2 XeF6 + O2 (1) XeF4 + O2F2 XeF6 + O2
(2) XeF2 + PF5 [XeF]+ PF6 (2) XeF2 + PF5 [XeF]+ PF6
(3) XeF6 + H2O XeOF4 + 2HF (3) XeF6 + H2O XeOF4 + 2HF
(4) XeF6 + 2H2O XeO2F2 + 4HF (4) XeF6 + 2H2O XeO2F2 + 4HF

79. The products obtained when chlorine gas 79. U UU NaOH

reacts with cold and dilute aqueous NaOH U
are :

(1) ClO and ClO 3 (1) ClO ClO 3

(2) 2 and ClO 3

ClO
(2) ClO
2 ClO
3

(3) Cl and ClO (3) Cl ClO

(4) Cl and ClO 2 (4) Cl ClO 2

80. The major product obtained in the 80.

following reaction is :

(1) ()C6H5CH(OtBu)CH2C6H5 (1) ()C6H5CH(OtBu)CH2C6H5

(2) C6H5CH=CHC6H5 (2) C6H5CH=CHC6H5
(3) (+)C6H5CH(OtBu)CH2C6H5 (3) (+)C6H5CH(OtBu)CH2C6H5
(4) ()C6H5CH(OtBu)CH2C6H5 (4) ()C6H5CH(OtBu)CH2C6H5

81. Sodium salt of an organic acid X produces 81. U X

effervescence with conc. H2SO4. X reacts H2SO4 U X
with the acidified aqueous CaCl2 solution CaCl2 U U
to give a white precipitate which KMnO4
decolourises acidic solution of KMnO4. U X
X is :
(1) C6H5COONa (1) C6H5COONa
(2) HCOONa (2) HCOONa
(3) CH 3COONa (3) CH 3COONa
(4) Na2C2O 4 (4) Na2C2O 4

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82. Which of the following species is not 82. S$ ?
paramagnetic ?

(1) NO (1) NO

(2) CO (2) CO

(3) O2 (3) O2

(4) B2 (4) B2

83. The freezing point of benzene decreases 83. U U 0.2 g 20 g

by 0.458C when 0.2 g of acetic acid is 0.458C
added to 20 g of benzene. If acetic acid U U
associates to form a dimer in benzene, U UU (m) U U
percentage association of acetic acid in
benzene will be :

(Kf for benzene=5.12 K kg mol1) ( Kf =5.12 K kg mol1)

(1) 64.6% (1) 64.6%

(2) 80.4% (2) 80.4%

(3) 74.6% (3) 74.6%

(4) 94.6% (4) 94.6%

84. Which of the following molecules is least 84. M

resonance stabilized ? SU ?

(1) (1)

(2) (2)

(3) (3)

(4) (4)

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85. On treatment of 100 mL of 0.1 M solution 85. CoCl3.6H2O 0.1 M 100 mL
of CoCl 3 .6H 2 O with excess AgNO 3 ; AgNO 3 U U
1.210 22 ions are precipitated. The 1.21022
complex is :

(1) [Co(H2O)4Cl2]Cl.2H2O (1) [Co(H2O)4Cl2]Cl.2H2O

(2) [Co(H2O)3Cl3].3H2O (2) [Co(H2O)3Cl3].3H2O

(3) [Co(H2O)6]Cl3 (3) [Co(H2O)6]Cl3

(4) [Co(H2O)5Cl]Cl2.H2O (4) [Co(H2O)5Cl]Cl2.H2O

86. The major product obtained in the 86.

following reaction is :

(1) (1)

(2) (2)

(3) (3)

(4) (4)

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87. A water sample has ppm level 87. ... (ppm) SU
concentration of following anions

F=10 ; SO 24=100 ; NO
3 =50 F=10 ; SO 24=100 ; NO
3 =50

The anion/anions that make/makes the /

water sample unsuitable for drinking is/ / , /
are :

(1) only NO
3 (1) NO
3

(2) both SO 24 and NO

3 (2) SO 24 NO
3

(3) only F (3) F

(4) only SO 24 (4) SO 24

88. 1 gram of a carbonate (M 2 CO 3 ) on 88. U (M2CO3) 1 HCl

treatment with excess HCl produces U
0.01186 mole of CO2. The molar mass of 0.01186 CO2 M2CO3
M2CO3 in g mol1 is : U g mol1

(1) 1186 (1) 1186

(2) 84.3 (2) 84.3

(3) 118.6 (3) 118.6

(4) 11.86 (4) 11.86

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89. Given 89. ,

ECl =1.36 V, E 3+ =0.74 V ECl /Cl=1.36 V, ECr 3+ =0.74 V
2 /Cl Cr /Cr 2 /Cr

ECr O 2/Cr 3+=1.33 V, EMnO

/Mn 2+
=1.51 V .
ECr O 2/Cr 3+

=1.33 V, EMnO
/Mn 2+
=1.51 V .
2 7 4 2 7 4

Among the following, the strongest

reducing agent is :

(1) Cr (1) Cr

(2) Mn2+ (2) Mn2+

(3) Cr3+ (3) Cr3+

(4) Cl (4) Cl

90. The group having isoelectronic species is : 90. U S ,

(1) O2, F, Na+, Mg2+ (1) O2, F, Na+, Mg2+

(2) O, F, Na, Mg+ (2) O, F, Na, Mg+

(3) O2, F, Na, Mg2+ (3) O2, F, Na, Mg2+

(4) O, F, Na+, Mg2+ (4) O, F, Na+, Mg2+

-o0o- -o0o-

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 Read the following instructions carefully :
1. The candidates should fill in the required particulars 1. U S U U (D -1) U U
on the Test Booklet and Answer Sheet (Side1) with U U U
Black Ball Point Pen.
2. U D-2 U U / U
2. For writing/marking particulars on Side2 of the
Answer Sheet, use Black Ball Point Pen only. U U
3. The candidates should not write their Roll Numbers 3. U S/U U U S
anywhere else (except in the specified space) on the
Test Booklet/Answer Sheet.
4. U
4. Out of the four options given for each question, only
one option is the correct answer.

5. For each incorrect response, (onefourth) marks of 5. U U
the total marks allotted to the question (i.e. 1 mark) (-) ( 1 )
will be deducted from the total score. No deduction U U U
from the total score, however, will be made if no
response is indicated for an item in the Answer Sheet.
, U
6. Handle the Test Booklet and Answer Sheet with care, 6. U S U U
as under no circumstances (except for discrepancy in US ( U S U
Test Booklet Code and Answer Sheet Code), another set S UU), U U S
will be provided. U
7. The candidates are not allowed to do any rough work
or writing work on the Answer Sheet. All calculations/ 7. U U U U
writing work are to be done in the space provided for , U S
this purpose in the Test Booklet itself, marked Space U U mU
for Rough Work. This space is given at the bottom of , U D U U U
each page and in four pages (Page 40-43) at the end of
the booklet. S U cU (cU 40-43) U
8. On completion of the test, the candidates must hand 8. U, / U U
over the Answer Sheet to the Invigilator on duty in the U U
Room/Hall. However, the candidates are allowed to S
take away this Test Booklet with them.
9. U U
9. Each candidate must show on demand his/her Admit
Card to the Invigilator.
10. No candidate, without special permission of the 10. U
Superintendent or Invigilator, should leave his/her S U
seat.
11. U U U S
11. The candidates should not leave the Examination Hall
without handing over their Answer Sheet to the
U U SU U U
Invigilator on duty and sign the Attendance Sheet U U S U SU
again. Cases where a candidate has not signed the U U
Attendance Sheet second time will be deemed not to
have handed over the Answer Sheet and dealt with as
an unfair means case. The candidates are also required U S S U
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Electronic device like mobile phone, pager etc. is
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