www.elsevier.com/locate/wasman
Department of Civil Engineering and Mechanics, College of Engineering and Applied Science, UWM Center for By-Products Utilization,
University of WisconsinMilwaukee, P.O. Box 784, Milwaukee, WI 53201, USA
Accepted 2 January 2004
Abstract
Solid waste management is one of the major environmental concerns in the United States. Over 5 billion tons of non-hazardous
solid waste materials are generated in USA each year. Of these, more than 270 million scrap-tires (approximately 3.6 million tons)
are generated each year. In addition to this, about 300 million scrap-tires have been stockpiled. Several studies have been carried out
to reuse scrap-tires in a variety of rubber and plastic products, incineration for production of electricity, or as fuel for cement kilns,
as well as in asphalt concrete.
Studies show that workable rubberized concrete mixtures can be made with scrap-tire rubber. This paper presents an overview of
some of the research published regarding the use of scrap-tires in portland cement concrete. The benets of using magnesium
oxychloride cement as a binder for rubberized concrete mixtures are also presented. The paper details the likely uses of rubberized
concrete.
2004 Published by Elsevier Ltd.
Table 1 Table 3
Some facts and gure concerning tires in USA (Rubber Manufac- Typical composition of manufactured tires by weight (Rubber Man-
turers Association, 2000) ufacturers Association, 2000)
Facts Figures Composition (wt%) Automobile Truck
tire tire
Number of scrap-tires generated annually 270 million
Approximate weight of scrap-tires 3.6 million tons Natural rubber 14 27
Number of scrap-tires in stock piles 300 million Synthetic rubber 27 14
Number of tires processing facilities 498 Carbon black 28 28
Scrap-tires used in civil engineering applications 30 million Steel 1415 1415
Scrap-tires processed into ground rubber 18 million Fabric, ller, accelerators and 1617 1617
Scrap-tires used for fuel 125 million antiozonants
Number of states with scrap-tires legislation/ 48
regulations
Number of states that ban whole tires from 33
landlls
2.3. Shredded/chipped tires
Number of states that ban all scrap-tires from 12
landlls Tire shreds or chips involve primary, secondary or
Number of states with no landll restrictions 5 both shredding operations. The size of the tire shreds
produced in the primary shredding process can vary
from as large as 300 to 460 mm (1218 in.) long by 100
Table 2 230 mm (49 in.) wide, down to as small as 100150 mm
Typical materials used in manufacturing tire (Rubber Manufacturers (46 in.) in length, depending on the manufacturers
Association, 2000) shredder model and the condition of the cutting edges.
1. Synthetic rubber Production of tire chips, normally sized from 76 (3 in.)
2. Natural rubber to 13 mm (0.5 in.), requires both primary and secondary
3. Sulfur and sulfur compounds shredding to achieve adequate volume (quantity) re-
4. Phenolic resin
5. Oil
duction (Read et al., 1991).
(i) Aromatic
(ii) Naphthenic 2.4. Ground rubber
(iii) Paranic
6. Fabric Ground rubber for commercial applications may be
(i) Polyester
(ii) Nylon
nominally sized as large as 19 mm (or 3/4 in.) to as small
7. Petroleum waxes as 0.15 mm (No. 100 sieve). It depends upon the type of
8. Pigments size reduction equipment and intended applications. The
(i) Zinc oxide processed used tires in ground rubber applications are
(ii) Titanium dioxide typically subjected to two stages of magnetic separation
9. Carbon black
10. Fatty acids
and to screening. Various size fractions of rubber are
11. Inert materials recovered (Heitzman, 1992). Some processes/markets
12. Steel wires term 30 mesh rubber as crumb rubber.
concrete lowered the compressive strength more than TALC (tire-added latex concrete) as a substitute for ne
the addition of ne crumb rubber. However, results re- aggregates or styrenebutadiene rubber (SBR) latex
ported by Ali et al. (1993) and Fattuhi and Clark (1996) while maintaining the same watercementitious materi-
indicate the opposite trend. als ratio. TALC showed higher exural and impact
Studies have indicated that if the rubber particles strengths than those of portland cement, latex modied
have rougher surface or given a pretreatment, then concrete and rubber-added concrete. Pictures taken us-
better and improved bonding may develop with the ing the SEM seem to support that there was better
surrounding matrix, and, therefore, that may result in bonding between crumb rubber and portland cement
higher compressive strength. Pretreatments may vary paste due to latex. TALC showed potential as a viable
from washing rubber particles with water to acid etch- construction material that is less brittle than other types
ing, plasma pretreatment and various coupling agents of concrete.
(Naik and Singh, 1991). In acid pretreatment, rubber Biel and Lee (1996) reported that the type of cement
particles are soaked in an alkaline solution (NaOH) for noticeably aects the compressive strength of rubcrete.
5 min and then rinsed with water. This treatment en- They used two types of cement, magnesium oxychloride
hances the strength of concrete containing rubber par- cement and portland cement, in making rubcrete. The
ticles through a microscopic (a very small) increase in percentage of ne aggregate substitution varied from 0%
the surface texture of the rubber particles. Eldin and to 90% by weight. It was observed that 90% loss in
Senouci (1993) soaked and thoroughly washed rubber compressive strength occurred for both portland cement
aggregates with water to remove contaminants, while rubber concrete (PCRC) and magnesium oxychloride
Rostami et al. (1993) used water, water and carbon cement rubber concrete (MOCRC) when aggregates
tetrachloride solvent, and water and a latex admixture (90% of ne aggregate and 25% of total aggregate) were
cleaner. Results showed that concrete containing water- replaced by untreated rubber. Magnesium oxychloride
washed rubber particles achieved about 16% higher cement concrete exhibited approximately 2.5 times the
compressive strength than concrete containing untreated compressive strength of portland cement concrete for
rubber aggregates, whereas this improvement in com- both inclusion of rubber and without inclusion of rub-
pressive strength was 57% when rubber aggregates ber in the concrete. In terms of splitting tensile strength,
treated with carbon tetrachloride were used. portland cement concrete specimens made with 25% of
Segre and Joekes (2000) have worked on the use of rubber by total aggregate volume retained 20% of their
tire rubber particles as addition to cement paste. In their splitting tensile strength after initial failure, whereas the
work, the surface of powdered tire rubber (particles of magnesium oxychloride cement concrete specimens with
maximum size 35 mesh, 500 lm) was modied to in- the same rubber content retained 34% of their splitting
crease its adhesion to cement paste. Low-cost proce- tensile strength. They further noted that use of magne-
dures and reagents were used in the surface treatment to sium oxychloride cement may provide high strength and
minimize the nal cost of the modied material. better bonding characteristics to rubber concrete, and
Among the surface treatments tested to enhance the rubber concrete made with magnesium oxychloride ce-
hydrophilicity of the rubber surface, a sodium hydroxide ment could possibly be used in structural applications if
(NaOH) solution gave the best result. The particles were rubber content is limited to 17% of the total volume of
surface-treated with NaOH saturated aqueous solutions the aggregate.
for 20 min before using them in concrete. Then, scan-
ning electron microscopy (SEM) and measurements of 4.2.2. Shrinkage
water absorption, density, exural strength, compressive A limited amount of literature is available concerning
strength, abrasion resistance, modulus of elasticity and the plastic shrinkage of concrete containing rubber
fracture energy were performed using test specimens (W/ particles. Preliminary results reported by Raghvan et al.
Cm, water-to-cementitious materials ratio as 0.36) con- (1998) suggest that incorporation of rubber shreds (two
taining 10% of powdered rubber or rubber treated with dierent shapes of rubber particles as constituents of
10% NaOH. The test results showed that the NaOH mortar: (i) granules about 2 mm in diameter and (ii)
treatment enhances the adhesion of tire rubber particles shreds having two sizes which were, nominally, 5.5
to cement paste, and mechanical properties such as mm 1.2 mm and 10.8 mm 1.8 mm (length diame-
exural strength and fracture energy were improved ter)) to mortar help in reducing plastic shrinkage
with the use of tire rubber particles as addition instead cracking in comparison to control mortar. They further
of substitution for aggregate. The reduction in the reported that control specimens developed cracks hav-
compressive strength (33%) was observed, which is ing an average width of about 0.9 mm, while the average
lower than that reported in the literature. crack width for specimens with a mass fraction of 5%
Lee et al. (1998) developed tire-added latex con- rubber shreds was about 0.40.6 mm. It was also re-
crete to incorporate recycled tire rubber as a part of ported that onset time of cracking was delayed by the
concrete. Crumb rubber from used tires was used in addition of 5% rubber shreds. Mortar without rubber
R. Siddique, T.R. Naik / Waste Management 24 (2004) 563569 567
shreds cracked within 30 min, while mortar with 15% in its body) seemed to decrease with an increase in
fraction by mass cracked after 1 h. It was further indi- rubber content. However, Topcu and Avcular (1997a,b)
cated that the higher the content of rubber shreds, the have recommended the use of rubberized concrete in
smaller the crack length and width, and the onset time of circumstances where vibration damping is required.
cracking was more delayed. Similar observations were also made by Fattuhi and
Clark (1996).
4.2.3. Toughness and impact resistance Topcu and Avcular (1997a,b) reported that the im-
Tantala et al. (1996) investigated the toughness pact resistance of concrete increased when rubber ag-
(toughness is also known as energy absorption capacity gregates were incorporated into the concrete mixtures.
and is generally dened as the area under loaddeec- The increase in resistance was derived from the en-
tion curve of a exural specimen) of a control concrete hanced ability of the material to absorb energy. Eldin
mixture and rubcrete mixtures with 5% and 10% bu and Senouci (1993) and Topcu (1995) also reported
rubber by volume of coarse aggregate. They reported similar results.
that toughness of both rubcrete mixtures was higher Hernandez-Olivares et al. (2002) have reported that
than the control concrete mixture. However, the addition of crumb tire rubber volume fractions up to 5%
toughness of rubcrete mixture with 10% bu rubber (26 in a cement matrix does not yield a signicant variation
mm) was lower than that of rubcrete with 5% bu of the concrete mechanical features, either maximum
rubber because of the decrease in compressive strength. stress or elastic modulus.
Based on their investigations on use of rubber shreds
(having two sizes which were, nominally, 5.5 mm 1.2 4.2.4. Freezing and thawing resistance
mm and 10.8 mm 1.8 mm) and granular (about 2 mm Savas et al. (1996) carried out investigations to study
in diameter) rubber in mortar, Raghvan et al. (1998) the rapid freezing and thawing (ASTM C 666, Proce-
reported that mortar specimens with rubber shreds were dure A) durability of rubber concrete. Various mixtures
able to withstand additional load after peak load. The were made by incorporating 10%, 15%, 20% and 30%
specimens were not separated into two pieces under the ground rubber by weight of cement used for the control
failure exural load because of bridging of cracks by mixture. Based on their studies, they concluded that:
rubber shreds, but specimens made with granular rubber (i) rubcrete mixtures with 10% and 15% ground rubber
particles broke into two pieces at the failure load. This (26 mm in size) exhibited durability factors higher than
indicates that post-crack strength seemed to be en- 60% after 300 freezing and thawing cycles, but mixtures
hanced when rubber shreds are used instead of granular with 20% and 30% ground rubber by weight of cement
rubber. could not meet the ASTM standards (durability factor);
Khatib and Bayomy (1999) reported that as the (ii) air-entrainment did not provide improvements in
rubber content is increased, rubcrete specimens tend to freezing and thawing durability for concrete mixtures
fail gradually and failure mode shape of the test speci- with 10%, 20% and 30% ground tire rubber and (iii)
men is either a conical or columnar (conical failure is increase in scaling (scaling gives an evaluation of the
gradual, whereas columnar is more of shreds having two surface exposed to freezing and thawing cycles as mea-
sizes which were, nominally, 5.5 mm 1.2 mm and 10.8 sured by the loss of weight) increased with the increase
mm 1.8 mm (length diameter) sudden failure). At a in freezing and thawing cycles.
rubber content of 60%, by total aggregate volume, the Benazzouk and Queneudec (2002) studied the freeze
specimens exhibited elastic deformations, which the thaw durability of cementrubber composites through
specimens retained after unloading. the use of two types of rubber aggregates. The types of
Eldin and Senouci (1993) demonstrated that the the aggregates were: compact rubber aggregate (CRA)
failure mode of specimens containing rubber particles and expanded rubber aggregates (ERA). Volume-ratio
was gradual as opposed to brittle. Biel and Lee (1996) of the aggregates ranged from 9% to 40%. The results
reported that failure of concrete specimens with 30%, showed improvements in the durability of the composite
45% and 60% replacement of ne aggregate with rubber containing 30% and 40% rubber by volume. Improve-
particles occurred as a gradual shear that resulted in a ment in the durability of the composite containing ERA
diagonal failure, whereas failure of plain (control) con- type aggregates is better than composite made with
crete specimens was explosive, leaving specimens in CRA aggregates. The nding is more distinct for ERA
several pieces. type.
Goulias and Ali (1997) found that the dynamic Paine et al. (2002) investigated the use of crumb
modulus of elasticity and rigidity decreased with an in- rubber as an alternative to air-entrainment for providing
crease in the rubber content, indicating a less sti and freezethaw resisting concrete. Three sizes of crumb
less brittle material. They further reported that damp- rubber, 0.51.5, 28 and 525 mm, were used. Test re-
ening capacity of concrete (a measure of the ability of sults showed that there is potential for using crumb
the material to decrease the amplitude of free vibrations rubber as a freezethaw resisting agent in concrete. The
568 R. Siddique, T.R. Naik / Waste Management 24 (2004) 563569
crumb rubber concrete performed signicantly better Also, the tensile and exural strengths of the TRA
under freezethaw conditions than plain concrete, and mortar specimens were higher than those of the control
the performance of crumb rubber concrete in terms of specimens.
scaling was similar to that of air-entrained concrete.