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Question1.

Amixtureofcarbonmonoxideandcarbondioxideisfoundtohaveadensityof1.7g/litatSTP.Themolefractionofcarbon
monoxideis:
[A] 0.37
[B] 0.40
[C] 0.30
[D] 0.50

Question2.
Considerthereaction,

WheregasesXandYareinsolubleandinerttowaterandZformabasicsolution.Inanexperiment3moleeachofXandYare
allowedtoreactin15litflaskat500K.Whenthereactioniscomplete,5Lofwaterisaddedtotheflaskandtemperatureisreduced
to300K.Thepressureintheflaskis:(neglectaqueoustension)
[A] 1.64atm
[B] 2.46atm
[C] 4.92atm
[D] 3.28atm

Question3.
Aprotonacceleratedfromrestthroughapotentialdifferenceof'V'voltshasawavelength associatedwithit.Analphaparticlein
ordertohavethesamewavelengthmustbeacceleratedfromrestthroughapotentialdifferenceof:
[A] Vvolt
[B] 4Vvolt
[C] 2Vvolt

[D] volt

Question4.
At1400K, forthereaction .A10.0Lreactionvessel
at1400Kcontains2.00moleofCH4,3.0molofCS2,3.0moleofH2and4.0moleofH2S.Then:
[A] Thisreactionisatequilibriumwithaboveconcentrations
[B] Thereactionwillproceedinforwarddirectiontoreachequilibrium
[C] Thereactionwillproceedinbackwarddirectiontoreachequilibrium
[D] Theinformationisinsufficienttodecidethedirectionofprogressofreaction

Question5.
Thevalueofk pforthereactionat

is'1atm'.AtequilibriuminaclosedcontainerpartialpressureofBrClgasis0.1atmandatthistemperaturethevapourpressureof
Br 2 isalso0.1atm.ThenwhatwillbeminimummolesofBr 2 tobeaddedto1moleofCl2,initially,togetaboveequilibrium
situation:

[A] moles

[B] moles

[C] moles

[D] 2moles

Question6.
AnacidbaseindicatorwhichisaweakacidhasapKavalue=5.45.Atwhatconcentrationratioofsodiumacetatetoaceticacid
wouldbeindicatorshowacolourhalfwaybetweenthoseofitsacidandconjugatebaseforms?pKaofaceticacid=4.75.[log2=
0.3]
[A] 4:1
[B] 7:1
[C] 5:1
[D] 2:1
Question7.
EqualvolumeoftwosolutionhavingpH=2andpH=10aremixedtogetherat .ThenpHofresultingsolutionis:(TakeKw at
)
[A] 2+log2
[B]
[C] 7
[D] 6

Question8.
Whichofthefollowinghasbeenarrangedincorrectorderofdecreasingfreezingpoint?
[A] 0.05MKNO 3>0.04MCaCl2>0.140Msugar>0.075MCuSO 4
[B] 0.04MBaCl2>0.140Msucrose>0.075MCuSO 4>0.05MKNO 3
[C] 0.075MCuSO 4>0.140Msucrose>0.04MBaCl2>0.05MKNO 3
[D] 0.075MCuSO 4>0.05MNaNO 3>0.140Msucrose>0.04MBaCl2

Question9.
AnidealmixtureofliquidsAandBwith2molesofAand2molesofBhasatotalvapourpressureof1atmatacertaintemperature.
Anothermixturewith1moleofAand3molesofBhasavapourpressuregreaterthan1atm.Butif4molesofCareaddedtothe
secondmixture,thevapourpressurecomesdownto1atm.VapourpressureofC, .Calculatethevapour
pressuresofpureAandpureB.
[A]
[B]
[C]
[D]

Question10.
Identifythetrueandfalsestatementandansweringivenoptions:

I.Duringelectrolysisof1MNaClsolutionCl2doesnotformattheanode.
II.Foraconcentrationcellwithitsreactionatequilibriumboth and arezero.
III.InasolutionofHCNtheconcentrationof ionsisgivenby .
[A] FTF
[B] TTT
[C] FFF
[D] FTT

Question11.
AceticacidistitratedwithNaOHsolution.Whichofthefollowingstatementiscorrectforthistitration?
[A] Conductanceincreasesuptoequivalencepoint,thenitdecreases
[B] Conductancedecreasesuptoequivalencepoint,thenitincreases
[C] Firstconductanceincreasesslowlyuptoequivalencepointandthenincreasesrapidly
[D] Firstconductanceincreasesslowlyuptoequivalencepointandthendropsrapidly

Question12.
Whatisthevalueof if and for0.04ofaCH3COOHat :
[A] 10.3
[B] 9.2
[C] 4.7
[D] 4.8

Question13.
Statement1:Inelectrochemicalcell,wecannotuseKClinthesaltbridgeifanodicorcathodiccompartmentconsistsofAg+or
Pb2+ion.

Statement2:Saltbridgeisemployedtomaintaintheelectricalneutralityandtominimizetheliquidliquidjunctionpotential.
[A] Statement1isTrue,Statement2isTrueandStatement2isacorrectexplanationforStatement1
[B] Statement1isTrue,Statement2isTrueandStatement2isNOTacorrectexplanationforStatement1
[C] Statement1isTrue,Statement2isFalse
[D] Statement1isFalse,Statement2isTrue

Question14.
Considerthereactionat300K

If3moleofH2completelyreactwith3moleofCl2toformHCl, ofthereactionwillbe:
[A] Zero
[B]
[C] 555kJ
[D] Noneofthese

Question15.
Statement1:Theamountofworkdoneintheisothermalexpansionisgreaterthanworkdoneintheadiabaticprocessforsame
finalvolume.

Statement2:Intheadiabaticexpansionofagastemperatureandpressurebothdecreaseduetoincreaseininternalenergyof
thesystem.
[A] Statement1isTrue,Statement2isTrueandStatement2isacorrectexplanationforStatement1
[B] Statement1isTrue,Statement2isTrueandStatement2isNOTacorrectexplanationforStatement1
[C] Statement1isTrue,Statement2isFalse
[D] Statement1isFalse,Statement2isTrue

Question16.
Forwhichprocesswill and beexpectedtobemostsimilar.
[A]
[B]
[C]
[D]

Question17.
AcrystalismadeofparticleX,YandZ.XformsFCCpacking,YoccupiesalloctahedralvoidsofXandZoccupiesalltetrahedral
voidsofX,ifalltheparticlesalongonebodydiagonalareremovedthentheformulaofthecrystalwouldbe:
[A]
[B]
[C]
[D]

Question18.
Statement1:TheratioofZn2+and perunitcellofZnSandCaF2is1:2.

Statement2:InZnS,Zn2+ionsoccupyalternatetetrahedralvoidsandinCaF2, ionsoccupyallthetehrahedralvoidsofFCC
unitcell.
[A] Statement1isTrue,Statement2isTrueandStatement2isacorrectexplanationforStatement1
[B] Statement1isTrue,Statement2isTrueandStatement2isNOTacorrectexplanationforStatement1
[C] Statement1isTrue,Statement2isFalse
[D] Statement1isFalse,Statement2isTrue

Question19.
Atacertaintemperature,thefirstorderrateconstantk 1isfoundtobesmallerthanthesecondorderrateconstantk 2.Iftheenergy
ofactivationE1ofthefirstorderreactionisgreaterthanenergyofactivationE2ofthesecondorderreaction,thenwithincreasein
temperature.
[A] k 1willincreasefasterthank 2,butalwayswillremainlessthank 2
[B] k 2willincreasefasterthank 1
[C] k 1willincreasefasterthank 2,andbecomesequaltok 2
[D] k 1willincreasefasterk 2andbecomesgreaterthank 2

Question20.
Theactivitypermlofasolutionofradioactivesubstanceisx.Howmuchwaterbeaddedto200mlofthissolutionsothattheactivity
fallstox/20permlafter4halflives?
[A] 100ml
[B] 150ml
[C] 80ml
[D] 50ml

Question21.
Whattypeofcrystaldefectisindicatedinthediagrambelow?

[A] Frenkeldefect
[B] Schottkydefect
[C] Interstitialdefect
[D] FrenkelandSchottkydefects

Question22.
At ,thevapourpressureofpureliquid'A'is520mmHgandthatofpureliquid'B'is1000mmHg.Ifamixturesolutionof'A'
and'B'boilsat and1atmpressure,theamountof'A'inthemixtureis:(1atm=760mmHg)
[A] 52molepercent
[B] 34molepercent
[C] 48molepercent
[D] 50molepercent

Question23.
If isthedegreeofdissociationofNa2SO 4,thevan'tHofffactor(i)usedforcalculatingthemolecularmassis:
[A]
[B]
[C]
[D]

Question24.
t1/4canbetakenasthetimetakenfortheconcentrationofareactanttodropto3/4ofitsinitialvalue.Iftherateconstantforafirst
orderreactionisk,thet1/4canbewrittenas:
[A] 0.75/k
[B] 0.69/k
[C] 0.29/k
[D] 0.10/k

Question25.
AschematicplotoflnKeqversusinverseoftemperatureforareactionisshownbelow:

Thereactionmustbe:
[A] Highlyspontaneousatordinarytemperature
[B] Onewithnegligibleenthalpychange
[C] Endothermic
[D] Exothermic

Question26.
Forthebalancedequation ,thevalueofp,q,rands
respectively:
[A] 2,1,2,1
[B] 1,2,1,2
[C] 1,2,2,1
[D] 2,1,1,2

Question27.
MixtureX=0.02moleof[Co(NH3) 5SO 4]Brand0.02moleof[Co(NH3) 5Br]SO 4waspreparedin2Lofsolution.

1LofmixtureX+excessAgNO 3 Y.

1LofmixtureX+excessBaCl2 Z.

NumberofmolesofYandare:
[A] 0.01,0.01
[B] 0.02,0.01
[C] 0.01,0.02
[D] 0.02,0.02

Question28.

Themaximumnumberofelectronsthatcanhaveprincipalquantumnumber,n=3andspinquantumnumber, ,is:

[A] 3
[B] 5
[C] 7
[D] 9

Question29.
At ,500mLofheliumdiffusesin30min.Whatisthetime(inhours)takenfor1000mLofSO 2todiffuseundersame
experimentalconditions?
[A] 240
[B] 3
[C] 2
[D] 4

Question30.
Whichisdecreasingorderofstrengthofbases?

and

[A]
[B]
[C]
[D]

Question31.
Consideraneutralconductingsphere.Apositivepointchargeisplacedoutsidethesphere.Thenetchargeonthesphereisthen
[A] Negativeanddistributeduniformlyoverthesurfaceofthesphere
[B] Negativeandappearsonlyatthepointonsphereclosesttothepointcharge
[C] Negativeanddistributednonuniformlyovertheentiresurfaceofthesphere
[D] Zero

Question32.
Pressureversustemperaturegraphsofanidealgasareasshowninfigure.Choosethewrongstatement.
[A] DensityofgasisincreasingingraphI
[B] DensityofgasisdecreasingingraphII
[C] DensityofgasisconstantingraphIII
[D] Noneofthese

Question33.
Aringofradiusrissuspendedfromapointonitscircumference.Thenitsangularfrequencyofsmalloscillationsis:

[A]

[B]

[C]

[D]

Question34.
Thedensityoficeis917kg/m3andthatofwateris1024kg/m3.Thenthefractionofthetotalvolumeofanicebergthatexposedis:
[A]
[B]
[C]
[D]

Question35.
AthinsphericalconductingshellofradiusRhasachargeq.AnotherchargeQisplacedatthecentreoftheshell.Theelectrostatic
potentialatapointPatdistance fromthecentreoftheshellis:

[A] Zero

[B]

[C]

[D]

Question36.
TwoidenticalcapacitorshavethesamecapacitanceC.Oneofthemischargedtopotential andtheotherof .Thenegative
endsofthecapacitorareconnectedtogether.Whenthepositiveendsarealsoconnected,thedecreaseinenergyofthecombined
systemis:
[A]

[B]

[C]

[D]

Question37.
Asteadycurrentflowsinametallicconductorofnonuniformcrosssection.Whichofthefollowingquantitiesisconstantalongthe
conductor:
[A] Current
[B] Currentdensity
[C] Electricfield
[D] Driftspeed

Question38.
AlargenumberofliquiddropseachofradiusrcoalescetoformasingledropofradiusR.Theenergyreleasedintheprocessis
convertedintothekineticenergyofthebigdropsoformed.Thespeedofthebigdropis(givensurfacetensionofliquidisT.density
ofliquidis )

[A]

[B]

[C]

[D]

Question39.
Foraparticleundergoingsimpleharmonicmotion,thevelocityisplottedagainstdisplacement.Thecurvewillbe:
[A] astraightline
[B] aparabola
[C] anellipse
[D] acircle

Question40.
Aparallelplatecapacitorischarged.Iftheplatesarepulledapart
[A] thecapacitanceincreases
[B] thepotentialdifferenceincreases
[C] thetotalchargeincreases
[D] thechargeandpotentialdifferenceremainthesame

Question41.
Athinglassrodisbentintoasemicircleofradiusr.Acharge isuniformlydistributedalongtheupperhalfandacharge is
uniformlydistributedalongthelowerhalfasshowninthefigure.TheelectricfieldEatpointP,thecentreofthesemicircle,is:
[A]

[B]

[C]

[D]

Question42.
Abulletofmassof20gmmovingwithaspeedof25m/shitsaniceblockofmass980gmkeptonfrictionlessfloorandgetsstuckin
it.Thenamountoficethatmeltif ofthelostkineticenergygoesintoiceis:
[A]
[B]
[C]
[D]

Question43.

2moleofagaswith ismixedwith3moleofagaswith ,thenthevalueof fortheresultingmixtureis:

[A]

[B]

[C]

[D] Noneofthese

Question44.
AtubeoflengthLisfilledcompletelywithanincompressibleliquidofmassMandthetubeisclosedatbothends.Thetubeisthen
rotatedinahorizontalplaneaboutoneofitsendswithuniformangularvelocity .Theforceexertedbytheliquidattheotherendis
:

[A]

[B]

[C]

[D]

Question45.
Intheshownarrangementoftheexperimentofameterbridge,ifACcorrespondingtonulldeflectionofgalvanometerisx,thenits
valueiftheradiusofthewireABisdoubled:
[A]
[B]
[C]
[D]

Question46.
AparallelplatecondenserwithadielectricofdielectricconstantKbetweentheplateshasacapacityCandischargedtoapotentialV
volt.Thedielectricslabisslowlyremovedfrombetweentheplatesandthenreinserted.Thenetworkdonebythesysteminthis
processis:

[A]

[B]
[C]
[D] zero

Question47.
IntheMillikan'soildropexperiment,anoildropof20additionalelectronsiskeptstationaryinaconstantelectricfieldof
(densityofoil=2.2g ).Theradiusofthedropis:

[A]

[B]

[C]

[D]

Question48.
ThreeidenticalrodsA,BandCofequaldiametersarejoinedinseriesasshowninfigure.Theirthermalconductivitiesare2K,Kand
K/2respectively.Thenthetemperatureattwojunctionpointis:

[A]
[B]
[C]
[D]

Question49.
Alargetankisfilledwithwater .Asmallholeismadeinthesidewallofthetankatdepth10mbelowwater
surface.Awaterjetemergeshorizontallyfromthehole,andfallsatahorizontaldistanceRfromit,asshowninfigure.Whatextra
pressuremustbeappliedonthewatersurfacesothattherangebecomes2Ronground.(Takeareaofholdnegligibleascompared
toareaoftank)(Given1atm=105Paandg=10m/s 2)
[A] 9atm
[B] 4atm
[C] 5atm
[D] 3atm

Question50.
Amovingcoilgalvanometerofresistance isusedasanammeterusingaresistanceof .Themaximumdeflection
currentinthegalvanometeris .Thevalueofminimumcurrentinthecircuitsothattheammetershowsmaximum
deflectionis:
[A] 10.01mA
[B] 1000.1mA
[C] 100.1mA
[D] 1.01mA

Question51.

Anequimolarmixtureofamonatomicandadiatomicidealgasissuddenlycompressedto thofitsoriginalvolume.Theratioof

finaltemperaturetotheinitialtemperatureis:
[A]
[B]
[C]
[D]

Question52.
Inthecapacitorshowninthecircuitischargedto5Vandleftinthecircuitin12sthechargeonthecapacitorwillbecome:

[A]

[B]

[C]

[D]

Question53.
AsolidsphereofradiusR,madeupofamaterialofbulkmodulusKissurroundedbyaliquidinacylindricalcontainer.Apistonof
areaAfloatsonthesurfaceoftheliquid.WhenamassMisplacedonthepistontocompresstheliquid,thefractionalchangeinthe
radiusofthesphereis:

[A]

[B]

[C]
[D]

Question54.
Auniformelectricfieldof12500 existsbetweenthetwoplatesofaparallelplatecapacitor.Ifanelectronatrestis
introducedinthisregion,thetimetakenbytheelectrontotraveladistanceof2cminadirectionoppositetotheelectricfieldandthe
correspondinggaininitsKEarerespectively.
[A]
[B]
[C]
[D]

Question55.
1moleofH2and1moleofHeatapressureof respectivelyandatemperatureT0arekeptintwodifferentcontainers.
Theratiooftheirrmsvelocitiesis

[A]
[B]
[C]
[D]

Question56.
AcircuitisconnectedasshowninthefigurewiththeswitchSopen.Whentheswitchisclosed,thetotalamountofchargethatflows
fromYtoXis:

[A] 0
[B]
[C]
[D]

Question57.
Auniformrodofdensity isplacedinawidetankcontainingaliquidofdensity .Thedepthofliquidinthetankishalf
thelengthoftherod.Therodisinequilibrium,withitslowerendrestingonthebottomofthetank.Inthisposition,therodmakesan
angle withthehorizontal.Then isequalto:

[A]

[B]

[C]

[D]

Question58.
Aspringmasssystemexecutesdampedharmonicoscillationsgivenbytheequation
(wherethesymbolshavetheirusualmeanings)

Ifa2kgmass(m)isattachedtoaspringofforceconstant(K)1250N/m,theperiodoftheoscillationis .Thedamping
constant'b'hasthevalue.
[A]
[B] 2.8kg/s
[C] 98kg/s
[D] 28kg/s

Question59.
Twosimplependulumoflength arereleasedfromthesamephasetogether.Theywillbeatthesamephaseaftera
minimumtime.

[A]

[B]

[C] 2s
[D] Noneofthese

Question60.
Asshowninfigure,ifthepointCisearthedandthepointAisgivenapotentialof2000V,thenthepotentialatpointBwillbe:

[A] 400V
[B] 500V
[C] 1000V
[D] 1300V

Question61.
IfAandBareacutepositiveanglessatisfyingtheequations

3sin2A+2sin2B=1and ,then(A+2B)is:
[A] 0
[B]

[C]

[D]

Question62.

Theseries isequalto:

[A]

[B]

[C]
[D]

Question63.
Astudentappearsinanobjectivetestwhichcontains10multiplechoicequestionswhereeachquestionhasfourchoices.The
maximumnumberofdifferentanswerscanthestudentgiveifeachquestionmayhavemorethanonecorrectanswersis:
[A]
[B]
[C]
[D]

Question64.
Letasequence ofcomplexnumbersbedefinedby , for ,where .
Thendistanceof from intheargandplaneis:
[A] 1
[B]
[C]
[D]

Question65.

Thesumoftheseries is:

[A] 0

[B]

[C]

[D]

Question66.
Theunitdigitintheproduct is:

[A] 6
[B] 2
[C] 4
[D] 1

Question67.

Thepointofintersectionofcurves is:

[A]

[B]

[C] Nosolution
[D] 2i

Question68.

Aquadraticequationwhoseproductofrootsx 1andx 2isequalto4andsatisfyingtherelation is:

[A]
[B]
[C]
[D]
Question69.
If aretherootsof ,then:

[A]
[B]
[C]
[D] Noneofthese

Question70.
Astudentwalksfromhishome(atX)toVMC(atY)onaroadwaynetwork(asshownintheadjacentfigure).Thenumberofwaysin
whichastudentcanreachVMCwhileavoidingpointsMandNonthewayis:

[A] 1225
[B] 2025
[C] 5005
[D] 1680

Question71.

If upto , upto and upto ,then

is:

[A]

[B]

[C]

[D]

Question72.
If denotesrespectively then
thevalueofthetriplet(u,v,w)is:
[A] (1,0,0)
[B] (0,1,0)
[C] (1,1,0)
[D] (1,0,1)

Question73.
If betherootsoftheequation ,thentherootsoftheequation
are:

[A]
[B]
[C]
[D]

Question74.
If ,thenlocusofthepoints1+2zisacirclewithcentre:
[A]
[B]
[C]
[D]

Question75.
Giventhattheequation (wherep,q,r,sarenonzero)hasarealroot.Then:

Question76.
Thecoefficientof in is:

Question77.
Thenumberofpermutationsofnelementstakenallatatimeinwhichtwogivenelementsaandbarenotadjacentis:

Question78.
Thenumberoffourdigitnumbersthatcanbeformedcontainingnotmorethantwodistinctdigitsis:

Question79.
Numberofincreasingpermutationsofmsymbolsaretherefromthesetofnnumbers wheretheorderamong
thenumbersisgivenby is:

Question80.
If where thenpossibleargumentofzis:

Question81.
If aresuchthat is:

Question82.

Let If areinA.P.,thenthevalueofnis:

Question83.

Thevalueof ,thenthevalueofnisequalto:

Question84.
Thenumberofintegralvaluesofaforwhichthequadraticequation(x+a)(x+1991)+1=0hasintegralrootsare:

Question85.
Letr,sandtbetherootsoftheequation,8x 3+1001x+2008=0.Thevalueof(r+s) 3+(s+t) 3+(t+r) 3is:

Question86.

If ,thentnisequalto:

Question87.
If iseliminatedfromtheequations ,

then isequalto:

Question88.

Thesumoftheseries is:

Question89.
Ifx,2y,3zareinA.P.wherethedistinctnumbersx,y,zareinG.P.,thenthecommonratiooftheG.P.is:

Question90.

If ,thenthevalueoftanxtanytanztantisequalto:

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