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Shiksha Plus IIT and Medical Academy n l m

(a) 2 1 0
Test Code: C 17/01
(b) 2 1 1
Topic: Atomic Structure (c) 3 1 1
(d) 3 0 0
30 Questions
8. The orbital diagram in which the Aufbau's
principle is violated is [IIT 1988; AMU 1999]

2s 2px 2 py 2 pz
Question Paper:
(a)
1. For an electron of Cu atom, the ratio of
(b)
orbit angular momentum to orbital angular
momentum is 9 : 2. It may not be for (c)
(1) 13th e & 16th e (d)
(2) 14th e & 17th e 9. The mass of neutron is nearly
(3) 15th e & 18th e [MNR 1988; UPSEAT 1999, 2000, 02]
(4) 11th e and 12th e (a) 10 23
kg (b) 10 24 kg
2. The ionisation energy of a hydrogen like
atom is 9 times of hydrogen atom. The (c) 10 26 kg (d) 10 27 kg
radius of 2nd Bohr orbit of this atom: 10. Which electronic level would allow the
(1) 0.529 (2) 0.7053 hydrogen atom to absorb a photon but not to
(3) 1.158 (4) 2.116 emit a photon
3. rd
No. of waves for 3 electron of lithium atom [IIT 1984; CPMT 1997]
is
(a) 3s (b) 2p
(1) 1 (2) 2
(3) 3 (4) 4 (c) 2s (d) 1s
4. If the velocity of an electron moving in first 11. Which of the following is not correct for
Bohrs orbit of hydrogen has to be reduced electron distribution in the ground state [AIIMS 1982]
to 7.27 105 m, it should be shifted by
4s 3d
(1) 4.23 away from nucleus
(a) Co (Ar )
(2) 4.23 towards nucleus
(3) 4.76 away from nucleus (b) Ni(Ar )

(4) 4.76 towards nucleus (c) Cu (Ar )


5. A photon of radiation of wavelength 4000 (d) Zn(Ar )
has an energy E. The wavelength of
photon of radiation having energy 0.5E will 12. If electron, hydrogen, helium and neon
be nuclei are all moving with the velocity of light,
(1) 2000 (2) 4000 then the wavelengths associated with these
(3) 8000 (4) 16000 particles are in the order [MP PET 1993]

(a) Electron > hydrogen > helium > neon


6. Which of the following pair have same
number of nucleon? (b) Electron > helium > hydrogen > neon
(1) 6C13, 7N14 (2) 6C12, 6C13 (c) Electron < hydrogen < helium < neon
(3) 20C
40,
18Ar
40 (4) 8O16, 7N15 (d) Neon < hydrogen < helium < electron
7. The correct set of quantum numbers for
the unpaired electron of chlorine atom is [IIT 1989; MP PET 2004]
13. From the given sets of quantum numbers can be placed in order of increasing
the one that is inconsistent with the theory energy from the lowest to highest, as
is [IIT Screening 1994] (a) (iv) < (ii) < (iii) <(i)
(a) n 3;l 2;m 3; s 1 / 2 (b) (ii) < (iv) < (i) < (iii)
(b) n 4; l 3; m 3; s 1 / 2 (c) (i) < (iii) < (ii) < (iv)
(c) n 2; l 1; m 0l s 1 / 2 (d) (iii) < (i) < (iv) < (ii)

(d) n 4; l 3; m 2; s 1 / 2 19. Ground state electronic configuration of


nitrogen atom can be represented by
14. The uncertainty in the position of an
(a)
electron ( mass = 9 .1 10 28 g) moving with
a velocity of 3 .0 10 4 cm s 1 accurate upto
(b)
0.001% will be
(Use
h
in the uncertainty expression, (c)
4
where h 6.626 10 27 erg s ) (d) 1995]
[CBSE PMT
(a) 1.92 cm (b) 7.68 cm
(c) 5.76 cm (d) 3.84 cm 20. Which of the following statements (s) is
(are) correct
15. The orbital angular momentum of an
[IIT 1998]
electron in s orbital is
[IIT 1996; AIEEE 2003; MP PET 2004]
(a) The electronic configuration of Cr is
[ Ar ] 3 d 5 4 s 1 (Atomic no. of Cr 24 )
1 h
(a) . (b) Zero
2 2 (b) The magnetic quantum number may
(c)
h
(d) 2.
h have a negative value
2 2
(c) In silver atom, 23 electrons have a
16. Values of the four quantum numbers for spin of one type and 24 of the
the last electron in the atom are opposite type (Atomic no. of Ag 47 )
n 4, l 1, m 1 and s 1 / 2 . Atomic
(d) The oxidation state of nitrogen in HN 3
number of the atom will be
is 3
(a) 22 (b) 32
21. The position of both an electron and a
(c) 33 (d) 36
helium atom is known within 1.0nm and
17. The atomic weight of an element is 39. the momentum of the electron is known
The number of neutrons in its nucleus is within 50 10 26 kg ms 1 . The minimum
one more than the number of protons.
uncertainty in the measurement of the
The number of protons, neutrons and
momentum of the helium atom is
electrons respectively in its atom would
[CBSE PMT 1998; AIIMS 2001]
be [MP PMT 1997] 1
(a) 50 kg ms (b) 60 kg ms 1
(a) 19, 20, 19 (b) 19, 19, 20
(c) 80 10 26 kg ms 1 (d)
(c) 20, 19, 19 (d) 20, 19, 20
26 1
50 10 kg ms
18. The electrons identified by quantum
numbers n and l (i) n 4, l 1 (ii)
n 4, l 0 (iii) n 3, l 2 (iv) n 3, l 1
22. Which of the following pair of orbitals (a) 8, 26, 10 (b) 10, 24, 20
posses two nodal planes [RPMT 2000] (c) 8, 22, 24 (d) 12, 20, 22
(a) p xy , d x 2 y 2 (b) d xy , d zx

(c) p xy , d zx (d) d z 2 , d x 2 y 2 29. In the simultaneous measurement of


position and momentum of a macroscopic
23. The number of atoms in 0.004 g of particle, it was found that x (uncertainty in
position) is zero then uncertainty in
magnesium are
momentum is
[AFMC 2000]
(1) Zero
(a) 4 10 20
(b) 8 10 20
(2) Infinite
(c) 10 20 (d) 6 .02 10 20 (3) h/
24. Which of the following have the same (4) Cannot be calculated from above data
number of unpaired electrons in d 30. Which one of the following pair have same
orbitals [Roorkee 2000] number of angular node?
(a) Cr (b) Mn (1) 4p, 3s (2) 5p, 6d
(c) Fe3+ (d) Co3+ (3) 5p, 7p (4) 3s, 4p

25. The quantum numbers + 1/2 and 1/2 for


the electron spin represent [IIT Screening 2001]

(a) Rotation of the electron in clockwise


and anticlockwise direction
respectively
(b) Rotation of the electron in
anticlockwise and clockwise direction
respectively
(c) Magnetic moment of the electron
pointing up and down respectively
(d) Two quantum mechanical spin states
which have no classical analogue
26. The de-Broglie wavelength of a tennis ball
of mass 60 g moving with a velocity of 10
metres per second is approximately [AIEEE 2003]
33 31
(a) 10 metres (b) 10 metres

(c) 10 16 metres (d) 10 25 metres

27. Which of the following are isoelectronic


and isostructural NO 3 , CO 32 , ClO 3 , SO 3 [IIT Screening 2003]
(a) NO 3 , CO 32 (b) SO 3 , NO 3

(c) ClO 3 , CO 32 (d) CO 32 , SO 3

28. The total number of electrons present in


all the s-orbitals, all the p-orbitals and all
the d-orbitals of cesium ion are
respectively [EAMCET 2003]