Zm_mH$ Roll No.

Tear Here
Sl.No. :

No. of Questions 30
SS41Chem.
No. of Printed Pages 11

C _m`{_H$ narjm, 2017

SENIOR SECONDARY EXAMINATION, 2017

TEAR HERE TO OPEN THE QUESTION PAPER

agm`Z {dkmZ

Z n H$mo ImobZo Ho$ {bE `hm \$mS>|

CHEMISTRY

g_` : 3 KQ>o
nyUmH$ : 56

ZmoQ> g_rH$aUm| H$mo Amd`H$ eVm] g{hV gVw{bV $n _| {b{IE&

narjm{W`m| Ho$ {bE gm_m` {ZX}e
GENERAL INSTRUCTIONS TO THE EXAMINEES :
1) narjmWu gdW_ AnZo Z n na Zm_mH$ A{Zdm`V {bI| &
Candidate must write first his/ her Roll No. on the question paper
compulsorily.
2) g^r Z hb H$aZo A{Zdm` h &
All the questions are compulsory.
3) `oH$ Z H$m Cma Xr JB Cma-nwpVH$m _| hr {bI| &
Write the answer to each question in the given answer-book only.
4) {OZ Zmo _| AmV[aH$ IS> h, CZ g^r Ho$ Cma EH$ gmW hr {bI|&
For questions having more than one part the answers to those parts are to
be written together in continuity.
`hm go H$m{Q>E

5) Z n Ho$ {hXr d AJoOr $nmVa _| {H$gr H$ma H$s w{Q> / AVa / {damoYm^mg hmoZo na {hXr
^mfm Ho$ Z H$mo ghr _mZ|&
If there is any error/ difference/ contradiction in Hindi & English versions of
the question paper, the question of Hindi version should be treated valid.
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6) Z g`m AH$ `oH$ Z

1 - 13 1

14 - 24 2

25 - 27 3

28 - 30 4

Q. Nos. Marks per question

1 - 13 1

14 - 24 2

25 - 27 3

28 - 30 4

7) Z H$_mH$ 21, 27, 28, 29 d 30 _| AmV[aH$ {dH$n h&

Question Nos. 21, 27, 28, 29 and 30 have internal choices.

IS> - A
SECTION - A

1) {ZVmj {H$Q>b Ho$ Ajr` X[a`m| VWm Ajr` H$moUmo H$m _mZ {b{IE&
Write the value of axial distances and axial angles of triclinic crystal. [1]

2) AmWZmo Ho$ dV A{^J_Z H$m H$mobaD$e {Z`_ H$s n[a^mfm {b{IE&

Write the defination of Kohlrausch law of independent migration of ions. [1]

3) S>o{Z`b gb _| H$ WmoS> _o hmoZo dmbr Agb A{^{H$`m Xr{OE&

Give half cell equation of doniell cell takes place at cathode. [1]

SS41Chem. 836
 3
4) {mr` H$mo{Q> H$s A{^{H$`m hoVw doJ {Z`VmoH$ H$s BH$mB {b{IE&
Write the unit of velocity constant for second order reaction. [1]

5) g_rH$aU 2N 2O5 2N 2O 4 + O 2 hoVw `{X AAm`wH$mg 6.93 gH$S> h Vmo Xa {Z`VmoH$ kmZ
H$s{OE&
For reaction 2N 2O5 2N 2O 4 + O 2 the Half life time is 6.93 sec, determine the
rate constant. [1]

6) gH$_U Vd AVamH$mer `m{JH$ ~ZmVo h EH$ H$maU Xr{OE&

Transition element form intertial compound. Give one reason. [1]

7) EopH$V EoH$mohb d ~opOb EoH$mohb `oH$ H$m EH$EH$ gy {b{IE&

Write the formula of each alkgl alcohal and benzyl alcohol. [1]

8) Eo{Zgmb H$s AZwZmXr gaMZmEo Xr{OE&

Give resonating structures of anisole. [1]

9) H${ZOmamo A{^{H$`m H$m agm`{ZH$ g_rH$aU {b{IE&

Write chemical equation of Cannizaro reaction. [1]

10) bmoamo Eogr{Q>H$Ab, Eogr{Q>H$Ab H$s VwbZm _| A{YH$ Abr` h& EH$ H$maU Xr{OE&
Chloroacetic acid is stronges acid than acetic acid give one reason. [1]

11) BZ `mo{JH$mo Ho$ Zm_ {b{IE

A) C6 H 5 N HSO 4
2
~)
Write the name of following compounds:- [1]
(A) C6 H 5 N HSO4
2
(B)

12) {ZZ{b{IV Amf{Y Ho$ H$ma H$mo nhMm{Z E Ama BgH$m H$ma H$ma {b{IE&
A) do{b`_ ~) {g_oQ>oS>rZ
Identified the type of following drugs and write its types. [1]
(A) Valium (B) Cimetidine

13) Q>obmZ VWm nr. dr. gr. Ho$ agm`{ZH$ gy Xr{OE&

Write the chemical formula of teflon and P.V.C. [1]

SS41Chem. 836 [ Turn Over

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IS> - ~
SECTION - B
14) A) R>mog Ho$ g_X{eH$ d {df_X{eH$ H${V _| H$moB EH$ gVa Xr{OE&
~) R>mog (H$) H$s {dYwV MmbH$Vm 104 107ohm1 m1 VWm R>mog (I) H$s {dYwV MmbH$Vm
1020 1010 ohm1 m1, h Vmo R>mog (H$) VWm R>mog (I) H$mo nhMm{ZE VWm BZH$m Zm_
{b{IE&
(A) Give any one difference between anisotropy and isotropy nature of solid.
(B) Electic conductivities of solid (X) is 104 107 ohm1 m1 and solid (Y) is
1020 1010 ohm1 m1, Indentified solid (X) and solid (Y) adn write their
name. 1 1
[1 + + ]
15) {ZZ{b{IV A{^{H$`mAm| Ho$ {bE Ho$db agm`{ZH$ g_rH$aU {b{IE& 2 2
A) O~ A_mo{Z`m H$s CoaH$ H$s CnpWVr _| dm`wS>br` AmgrOZ Ho$ gmW {H$`m hmoVr h&
~) O~ g`w[aH$ Ab H$s g\$a Q>mBAmgmBS> go {H$`m H$amVo h&
(A) When Ammonia react with atmospheric oxygen in the presence of catelyst.
(B) When sulphuric acid react with sulphur trioxide.
[1 + 1]
16) A) XeF2 VWm XeF4 _| CnpWV Ho$r` na_mUw _| gH$aU H$m Ho$db H$ma {b{IE&
~) Pcls H$s gaMZm _| CnpWV {Zajr` VWm Ajr` Am~Y H$s {^ {^ b~mBAm| H$m H$maU
g_PmB`o&
(A) Write only the types of hybridisation of central atompresent in XeF2 and
XeF 4
(B) Explain the reason of different length of equatorial and axial bond in the
structure of PCl5.
[1 + 1]
17) A) EoH$mohb H$m {dH$ VrH$aU H$mo g_PmB`o&
~) Jr`ma A{^H$_H$ go mW{_H$ EoH$mohb m H$aZo H$s agm`{ZH$ g_rH$aU Xr{OE&
(A) Explain denaturation of alcohol.
(B) Give chemical equation to obtain primary alcohol from grignard reagent.
[1 + 1]
18) A) Od {ZZZrH$aU ~hbH$ Ho$DH$ Xmo CXmhaU Xr{OE&
~) Q>o[aZbrZ Ho$ ~ZZo _| `w$ XmoZmo EH$bH$m| Ho$ gmYmaU Zm_ Xr{OE&
(A) Give two example of Bio degradaple polymers.
(B) Give the name of both monomers used in formation of terylene.
1 1
[ + + 1]
2 2

SS41Chem. 836
 5
19) A) gmdwZ VWm An_mOH$ _| H$moB Xmo AVa {b{IE&
~) gHo$arZ {H$g H$m` hoVw `w$ {H$`m OmVm h&
(A) Write any two difference between Soap and detergent.
(B) In which work saccharine is used.
1 1
[ + + 1]
2 2
20) A) {_eYmVw _| `w$ A{YH$V_ gKQ>Z dmbr Xmo YmVw Ho$ Zm_ {b{IE&
~) V+2 hoVw Mw~H$s` AmYwU H$m _mZ n[aH${bV H$s{OE&
(A) Write the name of two metal which used in maximum composition in
mischmetal.
(B) Calculate the value of magnetic moment of V+2
[1 + 1]
21) A) {ZH$V Ho$ n[aemoYZ _| `w$ "_mS> {d{Y' Ho$ XmoZmo agm`{ZH$ g_rH$aU Xr{OE&
~) _S>b n[aH$aU {d{Y H$m dN> d Zm_m{H$V {M ~ZmBE&
AWdm
A) MmXr Ho$ YmVwH$_ _| MmXr Ho$ {ZjmbZ _| `w$ gmo{S>`_ gmBZmBS> Ho$ `moJ na hmoZo dmbr XmoZmo
agm`{ZH$ g_rH$aU Xr{OE&
~) Eo`w{_{Z`_ Ho$ {ZH$fU Ho${bEo `w$ doYwV AnKQ>Zr gb H$m dN> Znm_m{$ {M ~ZmBE
(A) Give both chemical equation of 'Mond process' used in nickel refining.
(B) Draw a neat and labelled diagram of zone refining process.
OR
(A) Give both chemical equation of leaching of silver in silver metallargy by
using sodium cyanide.
(B) Draw a neat and lebelled diagram of electridytic cell for the extraction of
aluminum.
[1 + 1]
22) A) bmh YmVw Ho$ gjmaU H$mo amoH$Zo _| CgJ BboQ>moS> hoVw `w$ YmVw H$m Zm_ {b{IE& ~VmBE {H$
`h gjmaU H$mo {H$g H$ma amoH$Vm h&
~) Nacl, Hcl VWm CH3COOH hoVw m0 H$m _mZ H$_e 110, 100 VWm 390 Mole1 h& hoVw
H$m m0 _mZ kmV H$s{OE&
(A) Write the namo of metal used in sacrificial electrode for the preventation of
corrosion of iron metal how its prevent the corrosion.
(B) If m0 for Nacl, Hcl and CH3COOH are 110, 100 and 390 Mole1 respectively.
Determine the value of m0 for CH3COONa.
[1 + 1]

SS41Chem. 836 [ Turn Over

 6
23)

energy
Polential
(x)

(y)

R e a c t i o n
coordinate

A) Cnamo$ AmboI _| {MphV (H$) VWm (I) {H$go XemVo h& Cn`w$ Zm_ {b{IE&
~) AmboI _| {MphV Ho$db (H$) H$s n[a^mfm Xr{OE&
energy
Polential

(x)

(y)

R e a c t i o n
coordinate
(A) Write suitable name of (X) and (Y) denoted in above graph.
(B) Give defination of only (A) denoted in graph.
[1 + 1]
24) A) {dQ>m{_g 'A' VW {dQ>m{_g 'B' H$s H$_r g| hmoZo dmbo amoJm| Ho$ Zm_ {b{IE&
~) "eH$am' Ho$ AmYma na D.N.A. d R.N.A. _| AVa H$am|&
(A) Write the name of dieases due to desiciency of vitamines 'A' and vitamines
'B'
(B) On the basis of 'Sugar' differentiate D.N.A. and R.N.A.
[1 + 1]

SS41Chem. 836
 7
IS> - g
SECTION - C
25) A) ${Ya _| AmgrOZ H$s H$_ gmVm go ndVmamohr H$_Omoa hmo OmVo h VWm n> VWm gmoM Zhr
nmVo
i) Bg {d{e> Xem H$mo `m H$hVo h& Zm_ {b{IE&
ii) Bg pW{V Ho$ H$maU H$mo n> H$s{OE&
~) 30 Jm_ EWoZmoBH$ Ab 100 Jm_ Ob _| h& EWoZmohH$ Ab H$s _mobbVm Ob _| kmV H$s{OE&
(A) Due to low concentration of oxygen in blood, climber become weak and
unable to think clear-
(i) Write speitic name of above condition.
(ii) Explain the reason of such condition.
(B) 30 gm of ehanoic acid present in 100gm of water, determine molality of
ethonoic acid in water.
[1+1]
26) `mo{JH$ (A) EH$ Eoamo_{Q>H$ Eo_rZ h Omo 273 - 278 Vmn na NaNo2 + Hcl H$s {H$`m go `mo{JH$
(~) ~ZmVm h& `mo{JH$ (~) H$mo HBF4 g| {H$`m H$amZo na VWm m CnmX H$mo NaNo2 H$s CnpW{V
_| J_ H$aZo na `mo{JH$ (g) m hmoVm h& `mo{JH$ (g) H$m SntHcl H$s CnpW{V _| AnM`Z go
`m{JH$ (A) nwZ m hmoVm h&
Compound [A] is an aromatic amine which react with NaNo2 + Hcl at 273 - 278
km and form compound [B]. Compound [B] react with HBF4 and the obtained
product onfurther heating, in the presence of NaNo2 and cuform compound [C].
Compoun [C] reduced in the presence of SntHcl to re-formed compound [A].
Write general name of 'A', 'B' and 'C' and write equation of all reaction involved.
1 1 1 1 1 1
[ + + + + + = 3]
2 2 2 2 2 2
27) {ZZ{b{IV `m{JH$ agm`{ZH$ {H$`m H$m g_rH$aU VWm A) VWm ~) H$mo m H$aZo
A) `yQ>-2-BZb
~) bmoamo\$m_
AWdm
CH3-CHO go {ZZ{b{IV `m{JH$ A) VWm ~) H$mo m H$aZo H$s agm`{ZH$ A{^{H$`m H$m
_grH$aU VWm A{^{H$`m Ho$ Zm_ {b{IEo.
A) EWoZ
~) _moZmo bmoamo Eogr{Q>H$ Ab.

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 8
Write the equation of chemical reaction and main of reaction obtained following
compounds (A) and (B) from CH3CHO
(A) But - 2 - enal
(B) Chloroform
OR
Write the equation of chemical reaction and name of reaction to obtained
following compounds (A) and (B) from CH3COOH.
(A) Ethone
(B) Mono chloroacetic acid.
[1+1+1=3]
IS> - X
SECTION - D
28) 1) eha Ho$ EH$ \$Q>ar H$mo XfU ~moB {V~pYV H$aXoVm h& `mo{H$ \$Q>ar Ho$ dm_r Zo {M_{Z
na H$moT> Zhr bJm`m-
~) Bg H$mo> H$m Zm_ {b{IE {OgH$mo \$Q>ar ~m_r Zo Zhr bJm`m Wm&
g) Cnamo$ H$mo> H$m dN> Zm_m{H$V {V ~ZmBE&
2) A) gmb Ho$ Ho$XZ _mZ H$s n[a^mfm Xr{OEo&
~) {ZZ{b{IV Am`Zm| H$mo CZHo$ H$XZ _mZmo Ho$ AmYma na ~T>Vo H$_ Zo `dpWV H$s{OEo&
-PO43, Cl1, SO42
AWdm
1) A) 'doZrqeJ H$s_' {H$g H$ma H$m nm`_ ho& BgH$m C{MV Zm_ {b{IE&
~) Cnamo$ nm`g H$m dN> d Zm_m{H$V {M ~ZmBE&
2) A) AmH$ma daUm_H$ CoaU {H$go H$hVo h?
~) {ZZ{b{IV _o `w$ A{YemofH$ Ho$ Zm_ {b{IE&
i) {db`Z _o aJrZ XmWmo H$mo hQ>mZo _|
ii) Jg _mH$ _|

(1) One of the factory of city bained by pollution board because factory owner
not arrarge a chamber on chimney.
a) Write the name of chamber which not installed by factory owner.
b) Draw neat and labelled diagram of above chamber.
(2) a) Define coagulating value of sol
b) Arrange the following ions in increasing order on the basis of their
coagulating values.
[1+1+1+1=4]
OR

SS41Chem. 836
 9
(1) (a) Which types of emulsion is 'Vanishing cream'. Write its appropriate
name.
(b) Draw neat and labelled diagram of above emulsion.
(2) (a) What is shape selective catalysis?
(b) Write the name of adserbent used in following-
(i) To remove colouring matter from solution.
(ii) In gas mask.
[1+1+1+1/2+1/2=4]
29) (1) {ZZ{b{IV A{^{H$`m H$m agm`{ZH$ g_rH$aU {b{IE
A) dmQ>g A{^{H$`m
~) gS>_m`a A{^{H$`m
(2) A) i) CH3-Br+KOH CH3OH+KBr
CH 3 CH 3
ii)
CH3-C-Br+KOH CH3-C-OH+KBr
CH 3 CH 3
Cnamo$ g_rH$aU
i) VWm
ii) H$mZgo H$ma H$s Zm{_H$aZo hr A{^{H$`m h& `oH$ Ho$ Zm_ {b{IE&
~) XmoZmo A{^{H$`mAmo
i) VWm
ii) H$s {H$`m{dYr _o Xmo AVa {b{IE&
AWdm
1) {ZZ{b{IV A{^{H$`m H$m agm`{ZH$ {b{IE-
A) dwQ>g {\${Q>J A{^{H$`m
~) {\$Ho$Q>mBZ A{^{H$`m
2) A)

`m{JH$ 'J' `m{JH$ 'H$' `m{JH$ 'I'

Cnamo$ Zm{^H$aZo hr A{^{H$`mAmo
i) VWm
ii) _|
iii) go

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 10
{^-{^ {{dH$m` {d`mg dmbo CnmX (I) VWm (J) m hmoVo h&
BZXmoZmo H$_mo
i) VWm
ii) Ho$ Ho$db Zm_ {b{IE
~) `m{JH$
H$) _o `mo{JH$
J) {H$g H$ma H$s Zm{_H$aZohr {VWmnZ {H$`m{dYr go m hmoVm h& Zm_ {b{IE&
(1) Write the chemical equation of following reaction.
(a) Swarts reaction
(b) Sandmeyers reaction.
(2) (i) CH 3 -Br + KOH CH 3OH+KBr
CH 3 CH 3
(ii)
CH3-C-Br+KOH CH3-C-OH+KBr
CH 3 CH 3

Which types of nucelophillic substifution are in above reaction (i) and (ii).
(b) Write two differences between mechanisum of reaction (i) and (ii)
OR
(1) Write the chemical equation of following reaction
(a) Wurtz reaction
(b) Finkelstein reaction
[1+1+1+1=4]

(2)

Compound 'z' Compound 'x' Compound 'y'

Write the names of process to obtain compound (y) and compound (z)
from compound (x) in above unclophilin reaction (i) and (ii).
(b) Which type of nucelophillic substitution mechanisum involved to
obtained compound (z) from compound (x). Write the name of
mechanisum.
[1+1+1+1=4]

SS41Chem. 836
 11
30) A) {\$S>ob H$mQ> Egr{Q>bZ H$mo C{MV CXhmaU H$s ghm`Vm go g_PmB`o&
~) EgrQ>pS>hmBS> H${ZOmamo A{^{H$`m Zht XoVm h `m| g_PmB`o&
g) Q>r\$Z A{^{H$`m mam monoZb H$go m H$amooJo? monoZb Ho$ AmgrH$aU H$s A{^{H$`m
{b{IE&
X) \o$qbJ {db`Z H$s EpS>hmBS> Ho$ gmW {H$`m {b{IE?
AWdm
A) amoOoZ _wS> AnM`Z H$mo CXhmaU g{hV g_PmB`o&
~) H$m~m}pg{bH$ Abm| H$s AbVm na {VWm{n`mo Ho$ ^md H$mo g_PmB`o?
g) i) C6H5CH2OH A (B) C

ii)

Cnamo$ A{^{H$`mAm| _| CnmX A, B, C H$mo nhMm{ZE?

X) ImX n[aajU _| H$m~m}pg{bH$ Ab H$m H$mZgm `wn H$m_ _| {b`m OmVm h&

(i) Define primary and secondary valency of metal ionc proposed by werner
theory.
(ii) Write primary and secondary valency of co in [Co(Nn3)6] cl3.
(iii) Write structural formula of Ni(Co)4 and Cr(Co)6.
(iv) Draw the structure which shows Aynergic bonding interaction in a carbonyl
complex.
OR
(i) Define linkage and ionisation isomerisum
(ii) Which isomerisum show by [Co(NH3)6]. Write name.
(iii) Draw the diagram which show the transition of an electron in [Ti(H2o)6]3+
(iv) What impact takes place on metal comlex due to transition of an electron in
[Ti(H2o)6]3+

eee

SS41Chem. 836
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