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21/08/2014

Cement

Raw Materials
 Chalk or Limestone
 Dug up at quarry face
 Quarried by blasting
 Stone crushed to approx 25mm
 Fed into washmills

Raw materials
 Clay
 Dug by scrapper type excavators
 Passed to washmills
 Made into slurry by addition of water
 Fed into tank

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Making Cement Slurry


 Chalk or Clay + Water
 Fed into washmillls
 From slurry storage tanks fed to Rotary Kiln
 Dries
 Produces Cement Clinker

Clinker
 Slurry fed in one end
 Pulverised coal blown in at firing end
 Dries
 Decarbonises ( removes carbon)
 Calcines slurry (subject to prolonged heat)
 Drive off CO2
 Heat at 1371oC
 Slurry transformed to clinker

Clinker
 Clinker conveyed to mills
 Ground to form Portland Cement
 5% gypsum added to prevent flash setting
 Gypsum = hydrated calcium sulphate CaSO4
 Cement

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Wet Process
 Wet Process

Cement
 Stored in silos
 Transported by road /rail
 Bulk
 Palletised Packs
 25kg bags

Process
 CaCO3 CaO + CO2
 Limestone Quicklime Carbon Dioxide

 Slaking = mixing with water


 CaO + H2O Ca(OH)2 + Heat (volume)

 Quicklime Slaked lime ( Calcium hydroxide)

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Manufacturing Process
 4 Key Variants
 1. Wet Process
 2. Semi Wet Process
 3. Semi Dry Process
 4. Dry Process

Manufacturing Process
Wet Process
 Clay mixed With Water = slurry
 Excess sand removed by settlement
 Chalk mixed with Water = slurry
 Slurries blended together
 Resultant Slurry fed into kiln and dried
 Resultant clinker ground and gypsum added

Manufacturing Process
Semi Wet
 Chalk broken down in water
 Blended with clay slurry
 Water content reduced from 40% to 19% by
filter press
 Resultant Filter Cake
 Extruded on grate
 Reduced to pellets
 Heated at 900 1100oC pecalcine
 Short kiln at 1450oC for clinkering

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Manufacturing Process
Semi Dry
 Dry Shale and limestone is blended
 12% water added
 Nodularised ( made into nodules extrusion)
 Precalcined
 Clinkered as semi wet process

Manufacturing Process
Dry Process
 Limestone 80%
 Shale 17%
 Sand 3%
 Milled to fine powders
 Blended to form Dry Meal

Manufacturing Process
Dry Process
 Meal passed through cyclones
 Preheated using recovered kiln gases
 750oC
 Added fuel precalcine at 900oC
 Fast roasting kiln to clinker 1450oC

 Clinker cooled ground and 5% gypsum added

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Types of Cement
 Ordinary Portland Cement BS EN 197-1 2000
 General use
 Grind to 2250 cm2/gm

 Rapid Hardening Cement


 High early strength required
 Grind to 3250 cm2/gm

Types of Cement
 Low Heat Portland Cement BS EN 14216:2004
 Large mass of concrete poured
 Reduce amount of lime in the constituents
 Sulphate Resisting Cement BRE Special Digest 1 :2005

 Chemical attack
 Sea water, Acid ground waters
 Mix blast furnace slag with portland cement
clinker

Types of Cement
 White Portland Cement
 Visual effect white or coloured finish
 Use china clay or high grade chalk free
 Free of colour forming impurities

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Types of Cement
 Masonry Cement BS EN 413-1: 2004
 Make mortars
 Additives
 Add air entrained agent
 Increases adhesiveness
 Fine inert mineral powder
 Assists water retention
 Limits strength development

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