Investigation of droplet breakup in liquid-liquid dispersions by CFD - PBM
simulations: The influence of the surfactant type
PII: S1004-9541(16)30897-7
DOI: doi:10.1016/j.cjche.2017.01.014
Reference: CJCHE 821
To appear in:
Please cite this article as: Dongyue Li, Antonio Buo, Wioletta Podgorska, Daniele
L. Marchisio, Zhengming Gao, Investigation of droplet breakup in liquid-liquid dis-
persions by CFD - PBM simulations: The inuence of the surfactant type, (2017),
doi:10.1016/j.cjche.2017.01.014
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14000 800
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10000 600
g(d) (1/s)
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101
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100
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100
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PT
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Mean Sauter diameter (m)
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PT
200
150
CE
100
50
AC
0
0 700 1400 2100 2800 3500
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RI
150
SC
100
50
NU
0
0 700 1400 2100 2800 3500
Time (s)
MA
250
Mean Sauter diameter (m)
200
150
ED
100
50
PT
0
0 700 1400 2100 2800 3500
CE
Time (s)
250
Mean Sauter diameter (m)
200
AC
150
100
50
0
0 700 1400 2100 2800 3500
Time (s)
$ $- $ 0 0 0 0 0$ 0$ $0
$ $ - $- 0 $0 0 -- $ -
0 00
ACCEPTED MANUSCRIPT
&&
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"% ( " , % " % " "
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%"(( "% (" ( % " % (
SC
" (% ( "%" ( %"% " "
%( (" "%" %% ( %"
%"(( " < " %" ( ( ( ("
%"(( (" " (" %"% (%" (" "(
NU
"% % " " " " " "(
"( (" "% ( (% % ( " (" "
( ( %"% " " %%( "
MA
( (%"% % "" " <" ("( ( " ( (
" ( ( << %(%% ( (
( % " " %" ("( % " ("
( ("% % " %" ( "
ED
+ +.&+& +++
"(% ( "" " "% "(%" " "% (
ACCEPTED MANUSCRIPT
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C1 #$$ ' ' '
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SC
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NU
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d '$ #
MA
d32 $' $'
dc '$ '$ #
d $' '$ #
d #### $ 9'$' '$ 3
ED
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Md $' '
mk k $ $ ' #$ $ k3
CE
t $ #
Uc $ $# # #
Ud $ #'# # #
Ur # $ #
$'$ $
c '$ $# #
d '$ #'# #
min $'$ $
x ' $'$ $ ' '# #
$'$ ' ##$ '$ 2 #3
c ##$ $# # @#
d ##$ #'# # @#
ACCEPTED MANUSCRIPT
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t " )) .)
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c ) ) ) 3
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) " )
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SC
k " " " k
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NU
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ED
PT
CE
AC
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#&
P T
4 > A
RI
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>
SC
44 >A>
NU
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DD AD D\D A>A
4>A
MA
D D AD>A 4 A D
ED
PT
AD >A> \A>A
AC
>A> A >D
>D 4A
DA A> A AD A>D 4A
>D AD
ACCEPTED MANUSCRIPT
T
'+ 4 4 :4+ +
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4 '4 :'4' 4 4+ ' '+
RI
4 '4 :'4'
SC
4 4 ' 4 :4+ '
4 4 ' + 4
NU
4 :4 ' '4+ ' 4 '+
'4 4 :'4' 4
MA
4+ ' 4 :4+ ' '+
4
ED
PT
] 4 ''+44 + 4'+
4 :'4' 4 ' 4+ 4
'+ '
CE
] +4 ' 4
4 4 + 4 '4 :'4' 4 4+
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4 4 + 4 + '4 4 4
'+
'+ c 4 '++ + 4
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ACCEPTED MANUSCRIPT
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2 >?> ?A
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ED
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PT
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ACCEPTED MANUSCRIPT
T
()*0 )456 6(6 ) ( (
P
) ) )() H() (
(J ( 6
RI
6(6 6) ()*0 )456 (
SC
6))6) 6 ( ) ( 6
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)6
NU
( 6 )(6() J) ( ) )( ( 6)
)6 ( (66 (
)( (
MA
( 6 )(6() J) ( ) )( (
6) ) 6 (
ED
( 6 6 6)()6 6
6 (
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PT
)() ( ( ) () )(
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CE
AC
)()
( () )( 6 6)() ( ()
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6 6( 6 ( ) ) ( 6)( 6)(
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ACCEPTED MANUSCRIPT
T
+/01 177 0 0 1
P
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RI
+/01 0 0 1 7
SC
770 1011 7 11 10 7 01 +
0 10 1
NU
1 1 0 7 10771 0 0
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MA
1 1 1 0 7 7
7 1 0 ?? 1171 1700 7
+07 +070 77 7 1 7 7 0 1
1011 0
ED
+/01 01 7
07 0 707 ?? 1011 7
PT
+ 01 0 01 0
+/01 01 07 0
CE
1 ?? 1011 01 07
01 7 77 7 0
AC
+/01 01 707 0 1
7 01 70177 01 0 10
01
0 1 0 ?? 1011 007 07
01 7 70 01 0
011
01 771 1
0 0
ACCEPTED MANUSCRIPT
T
.2 5 < 2.2
P
<2 22<2 2 < 2 <
< 2 . 2. 2
RI
SC
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NU
. << <2
2
MA
. 522 . << 2
..
2 5<2 22 <2
ED
22 2 2.2
CE
AC
5<<< 2< .2
5 2 2<.< 2<.. 2R
.< 2
ACCEPTED MANUSCRIPT
( + (1 1( +
P
(+ ( ( 1(1 +1((1
RI
11(+ I(1 1 ++1 1( 1+
(
SC
T( ( I+ ( 1
(1 +1 (+1+ 1(+1 ( + +1(
1+ +1(( [[ +(++ (
NU
] I ( 1 +(+ + (1
MA
(1 (1 ( + +1(1+ (
1 +1(( ++1+ (
(+ I1 + ( 1+ 1 (
11 ++1+ ( (++
ED
(+ (1( 1 1+ (
(1( (+++ ( 1(
PT
(+ 11 + ( +(+ (11
1+ ++1+ ( (+1 I(++
CE
I 1 (+1 1( + ( +
+(+ (+ ( + + ( (+
1(1 +(++ (
+ 1(1( ( 1(1 + ( (
( 1(1 +(++ (
+ 11 1 (
+ ++ 1(+( + ( +[ +(+
11 ++ (
ACCEPTED MANUSCRIPT
T
*++ *++ 0 * *0+ 0*
P
0 + *
RI
K 0 * Q*0 * ++ *
SC
*+ * *
*+ 0 *+ * 0*+0
* *0 *0+ 00 RR +*
NU
++ *
+ Q0
RR +*++ + 0+ +0**
MA
0 +0* * +0* +*
K * 0*0 * *0+ + + *
ED
*0+ *
0* 0* + 0* *
*+0 *++
PT
*+ 0*0 0* 0*0
* ++0 * +
CE
++ + Q*0 *
+++ + 0 *+ ** 0 * *
AC
++ + 0+ 00 *++
* 00 Q++
+ *0*0 RR +*++ 0
* ++0 00 +
0 + *
ACCEPTED MANUSCRIPT
Highlights
T
l The multifractal kernel describes well when surfactants effect was included
P
RI
SC
NU
MA
ED
PT
CE
AC