Displacement Method
Jc Malenab Ancheta between particles within the bulk sample. While the
Department of Mining, Metallurgical, and Materials second type is the bulk density where the volume
Engineering, College of Engineering includes total volume of the closed pore, open pore,
University of the Philippines Diliman and solid material. The third type, which was
Quezon City, Philippines determined in the experiment, is the apparent density
where the volume of the solid material and closed
Abstract- The main objective of the experiment is to pore are measured (Totten,G., Funatani, K., Xie,L,
determine the density of a 10% v/v acetic acid and an ore 2004).
sample using displacement method and pycnometry. The
density of the solid was determined first using the Density Determination is important in many
displacement volume of water in the graduated cylinder
industries. In agriculture, the density of grains, feeds,
and its preweighed mass. The other method was using the
fertilizer and soil samples are measured. In the
pycnometer where it uses water as working liquid and
displaced volume water when poured in apparatus will be pharmaceutical industry, density measurements are
used to calculate for its density. The calibrated volume is correlated with solubility rates of powders and
24.94 1.23 ml and the measured density acetic acid is tablets. In powder metallurgy, it permits distinction
1.0103 0.00001 with a 3.78 % error. While the density of between different materials as well as determination
the solid using the analytical balance and using the of inaccessible porosity of powder or a finished P/M
pycnometer was 4.98 6.10 g/ml and 3.22541.6940 g/ml part (Angelo; Subramanian,2008). Density can
respective. These data cant be compared and Its accuracy
influence mechanical strength, hardness,
cant be validated because of the unknown theoretical
density of the solid. The experiment is said to be a success electrical conductivity and magnetic and gas
since the densities were determined. permeability of PM compacts.
Page 1 of 8
capillary hole through it so that air bubbles may pycnometer with the sample. Water will be added and
escape from the apparatus. This enables given the its mass can be obtained.
volume of working liquid to be measured precisely.
(Kucerka, 2006). The density of the solid is given by:
= V (6)
Vl = (3) The first part of the experiment was the
determination of the density of a 5-gram Baguio ore
sample using the analytical balance. A 50ml
Equation 3 shows the volume of the liquid with
graduated cylinder was first filled with distilled water
unknown density and this volume obtained is just
up to the 30 ml mark before pouring the ore sample.
equal to the volume of water in eq. 2.
The sample was carefully transferred to avoid spilling
outside the cylinder. The final volume of the pulp
Combining Equations 2 and 3
was then recorded and the density of the material was
2 calculated using equation 1. Three trials were
(4)
2 =
performed.
Isolating the density of liquid gives The second part is the density measurement of a
liquid in the pycnometer. The pycnometer was first
= x 2 (5) preheated to 105 C in the oven for one hour and was
2
cooled in a dessicator before weighing in the
The pycnometer will also be used in determining the analytical balance. To calibrate, distilled water was
density of an ore sample by measuring the weight of used to fill the pycnometer up to the neck. The
capillary tube was then inserted and was made sure
Page 2 of 8
that no air bubble is trapped inside. Subsequently, the Table 3.Calibration Volume of Pycnometer
exterior of the was washed with ethanol and wiped Trial Mass of Density of Calibration
with lint-free tissue. The pycnometer was weighed water (g) water at 29 volume (ml)
when it was completely dry. The calibration volume C (g/ml)
1 24.8678 0.995943 24.9690.710
was computed using eq. 2.
2 24.8186 0.995943 24.9200.710
The steps were repeated but 10% v/v acetic acid was
3 24.8293 0.995943 24.9300.710
used to fill the pycnometer. The density of liquid was
calculated using eq. 5.
The average calibration volume is 24.94 1.23 ml
The last part was the density determination of the ore and has 0.24% error from the theoretical volume of
sample. The dry pycnometer was weighed before the 25 ml. The calibration step is important because this
non-soluble particulate sample was poured to fill value can be used to determine the density of the
about 1/3 of its volume. It was weighed again before liquid and solid. The occupied volume of the tested
filling it up with distilled water up to the neck. The liquid in the pycnometer is just the same as the
capillary tube was inserted and bubbles trapped calibration volume, therefore we can manipulate the
inside was avoided. The exterior was washed with formula to calculate for its density. And the distilled
ethanol and the final weight was recorded. Equation 8 water was used as the working liquid because it is
will be used to calculated for the density of the solid. accessible and its density at different temperature
values is well-known.
III. Results and Discussion
Table 4. Density of Acetic Acid
The calculated density of solid using the
Trial Temp Mass of Mass of Density of
displacement method on three trials are shown on (C) water CH3COOH CH3COOH
Table 2. (g) (g) (g/ml)
0.000006
Table 2. Density of Solid using Displacement Method 1 29 24.8678 25.2308 1.0081
Trial Mass of Initial Final
Solid (g) volume Volume Density 2 29 24.8186 25.2641 1.0115
0.1 mg 0.5 ml 0.5ml g/ml
1 4.933 30 31 4.93.49 3 29 24.8293 25.2662 1.0111
2 4.9982 30 31 5.03.53
3 4.9996 30 31 5.03.54 Table 4 shows the experimental density of the acetic
acid. It has a mean density of 1.0103 0.00001 g/ml
and a standard deviation of 0.001831. The mean
The density values have an average of 4.98 6.10
experimental density has a 3.78 % error from the
g/ml and standard deviation of 0.03805.
theoretical density of 1.05 g/ml.
The mean value has a high uncertainty. The error can On the determination of the density of solid
be attributed to the mass of sample poured in the using pynometer, the following data was tabulated in
graduated cylinder, since the amount was small, the Table 5.
change in volume or the displacement was also small
Table 5. Density Measurement of Solid using
which cant be measured by the scaling of the Pycnometer
graduated cylinder accurately. Another error maybe Temp Mass of Mass of Density of
in the reading of the measurement. Trial (C) solid water (g) solid (g/ml)
0.1 mg 0.1 mg
The next part was the calibration and the volume of 1 29 8.2049 22.30508 3.22541.6940
pycnometer as shown on Table 3.
We cannot compare which of the two methods is
more accurate since the theoretical density of the
solid is unkown.
Page 3 of 8
The data from the other groups was compared as IV. Conclusions and Recommendations
shown in Tables 6-8.
Page 4 of 8
V. References
Boljanovic, Vukota. (2007). Applied Mathematical and Physical Formulas - Pocket Reference. Industrial Press.
http://app.knovel.com/hotlink/toc/id:kpAMPFPR01/applied-mathematical/applied-mathematical accessed
(accesed October 10,2015).
Totten, George, Kiyoshi Funatani, Lin Xie. (2004) Handbook of Metallurgical Process Design. (CRC Press). pp.373-
734
https://books.google.com.ph/books?id=3zjfgq8pUvcC&printsec=frontcover&source=gbs_atb#v=onepag
e&q&f=false (accessed October 4, 2015).
Angelo P., and R.Subramanian. (2008) POWDER METALLURGY: SCIENCE, TECHNOLOGY AND APPLICATIONS.
PHI Learning Pvt. Ltd., pp. 79-81
D854-92e1 Standard Test Method for Specific Gravity of Soils, AMERICAN SOCIETY FOR TESTING AND
MATERIALS (1997)
Bateni,A; N. Parvin and M. Ahmadi. (2011)Density evaluation of powder metallurgy compacts using in situ X-ray
radiography.http://www.researchgate.net/publication/233545357_Density_evaluation_of_powder_metall
urgy_compacts_using_in_situ_X-ray_radiography. (accessed October 10, 2015).
Page 5 of 8
VI. Appendix
B. Calibration of Volume
Page 6 of 8
Uncertainty of volume = ( 2 ) = 0.709987
Uncertainty Budget
Trial 1
Source value ci ui ciui fraction ciui^2
mass of pyc 21.1965 0.000583 0.0001 5.83266E-08 0.719358879 3.40199E-15
Mass of pyc + water 46.0643 -0.04054 0.0001 4.05407E-06 50 1.64354E-11
(W)
Mass of pyc + 46.4273 0.039957 0.0001 3.99574E-06 49.28064112 1.59659E-11
CH3COOH(S)
density of water at T 0.995943 1.012264 0 0 0
calibration factor 0.9977 1.010481 0 0 0 0
Summation 8.10813E-06 3.24048E-11
Uncertainty of density = ( 2 ) = 0.709987
Page 7 of 8
Summation 8.15105E-06 3.26444E-11
Uncertainty of density = ( 2 ) = 0.709987
Page 8 of 8