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PERC G3 (GEAS: CHEM/THERMO) 16.

The pH concentration of a solution that has a


hydrogen ion concentration of 1x10^-6
1. Which of the following cannot separate a mole/Liter is 8.
homogeneous mixture? Filtration 17. What is the best conductor of heat? Diamond
2. The amount of energy needed to change a 18. The volume of a definite quantity of dry gas is
given mass of ice to water at constant inversely proportional to the pressure
temperature is called heat of FUSION.
provided the temperature remains constant.
3. Which of the following is a binary compound? Boyles law
Hydrochloric acid 19. Point at which titration is complete. Endpoint
4. What is the charge of a Hydrogen atom? ZERO 20. It is the enthalpy change associated with the
5. If the volume of 1 mole of gas is constant, condensation of gaseous positive and negative
lowering the temperature will make the ion into a crystal. Lattice energy
pressure increase. 21. Hunds rule indicates that electrons occupy all
6. When 200 mL of a gas at constant pressure is orbitals of given subshell singly before pairing.
heated from 0 degree Celsius to 100 degree 22. What are the particles that include proton and
Celsius, the volume must be multiplied by neutron? Baryons
373/273. 23. What is the quantum number which defines
7. How many moles of O2 are present in 44.8 L the direction of electrons angular momentum
of O2 at STP? 2 vector? Magnetic quantum number
8. At 5 atm and 70 degree Celsius, how many 24. What is the process in which hydrogen is
moles are present in 1.5 L of O2 gas? 0.267 changed to helium inside the sun and makes
9. If 40 g of ice melts at 0 degree Celsius, total
the sun shinier? Fusion
heat absorbed is ____. 25. What thermodynamic cycle describes
10. The properties of a solution include all of the functions of typical reciprocating piston
following except: dissolved particles will engines? Otto cycle
settle out upon stirring. 26. It is the mode of energy transfer between a
11. The transfer of energy from the more solid surface and the adjacent liquid or gas
energetic to the adjacent less energetic as a that is in motion, and it involves the combined
result of interaction between particles is effect of conduction and fluid motion.
called conduction. Convection
12. The molarity of a solution made by placing 98 27. What is the resulting compound when oxygen
gram of H2SO4 in sufficient water to make 500 combines with an element? oxide
mL of solution is 2. 28. According to the Bronsted-Lowry theory, an
13. It indicates the rate of heat conduction in the acid is proton donor.
direction proportional to the temperature 29. The second law of thermodynamics states that
gradient in that direction. Fouriers law of no engine can have a thermal efficiency of 100
heat conduction. % or as far as power plant to operate, the
14. If the change in enthalphy of a reaction is working fluid must exchange heat with the
negative, the reaction is definitely environment. Kelvin-planck statement
endothermic. 30. It is defined as the amount of light output in
15. The pH concentration of solution with lumens per watt of electricity. Light efficacy
hydrogen concentration of 1x10^-6 mole/liter 31. Lead in pencil is made up of graphite and
is 6. clay.
32. It states that the thermal efficiencies of all 45. In an engine, work is defined as the difference
reversible heat engines operating between between heat input and heat discharge.
two reservoirs are the same and that no heat 46. It is the customary to indicate accuracy by
engine is more efficient than a reversible one using a certain number of figure or digits.
operating between the same two reservoirs. Significant figures
Carnot principle. 47. It states that if a stress is placed on a system
33. The process where heat is absorbed from the on equilibrium whereby the equilibrium is
surroundings is called endothermic process. altered, the change will take palce which
34. It states that the change in the enthalpy of a tends to relieve or neutralize the effect of
reaction is the sum of the enthalpies of applied stress. Le Chateliers principle
reactions from which the reaction can be built. 48. Considered as derivatives of ammonia in
Hess law which one or more of the hydrogen have been
35. Constant of proportionality between energy of replaced by the alkyl or aryl group. It is
photon and frequency is called plancks characterized by unpleasant odor. Amine
constant. 49. a piston cylinder device contains a liquid-
36. States that every substance has finite position vapor mixture of water at 400 K. during
entropy except the entropy of pure, perfect constant pressure process, 700 kJ of heat is
crystalline structure which is zero at 0 K. Third transferred to the water. As a result, part of
law of thermodynamics. the liquid in the cylinder vaporizes. Determine
37. Number of intensive variables that can be the entropy change of the water during this
changed independently in system without process. 1.75 kJ/K
disturbing the number of phases in 50. Which of the following equation has two
equilibrium. Degree of freedom constants?
38. It states that the vapor pressure in a solution a. Van der waals equation (2)
is the sum of the vapor pressure at the pure b. Strobridge equation (16)
component multiplied by the mole fraction of c. Benedict-webb-rubin equation (8)
that component. Raoults law 51. Calculate the molar concentration of a
39. Temperature at which water density is solution that contains 15 grams of potassium
maximum. 4 degree celsius hydroxide in 225 mL of solution (K=39amu,
40. Isothermal process is a thermodynamic O=16amu, H=1amu). 1.2 M
process with constant temperature. It is 52. A piston cylinder device initially has 0.8 cubic
known as a hyperbolic process. meter of air at 110 kPa and at 80 degree
41. Thermodynamic measurement of strength of Celsius. The air is now compressed to 0.2 cubic
bonding between molecules. affinity meter in such a way that the temperature
42. A substance that increases the rate of reaction inside the cylinder remains constant.
without itself being consumed. Catalyst Determine the work done during the process.
43. A carnot engine receives 500 kJ per cycle from -122 kJ
a high temperature source at 600 degree Solution:
Celsius and rejects heat at temperature sink at
= ln
40 degree Celsius. Determine thermal
efficiency. 64.15% 53. It states that if two bodies are in thermal
44. What is added to a weak monoprotic acid to equilibrium with a third body, they are also in
produce a buffer solution? Its conjugate base
thermal equilibrium with each other. Zeroth 64. What is true about the polytropic exponent
law of thermodynamics n for a perfect gas undergoing an isobaric
54. It is the borosilicate glass with a very low process. n=0
coefficient of thermal expansion; hence it is 65. Sulfur hexafluoride is a colorless, odorless and
widely used as cooking and serving utensils. very unreactive gas. Calculate the pressure in
Pyrex atm exerted by 1.82 moles of gas in a steel
55. It is a colorless solid capable of being cut into vessel of volume 5.43 L at 45 degree Celsius.
brilliant crystals. It is the hardest and most 66. The ratio in absolute units of the actual gas
abrasive mineral known. Diamond temperature to the critical temperature of
56. It is the set of nuclide having equal mass gas. Specific gravity
number but of different atomic numbers.
Isobars 67. Ratio in absolute units of the actual gas
temperature to the critical temperature of
57. It is the first antimatter particle discovered,
gas. Reduced temperature
and it has the same mass as the positive 68. A bottle of ceramic tile cleanser which
particles but with opposite charge. It can essentially a solution of hydrochloric acid
survive by moving rapidly but once at rest, contains 130g of HCl and 750g of water. What
these are quickly annihilated and converted is the percent mass of hydrochloric acid in
totally and directly to energy. Positron cleanser? 14.88%
69. An enthalpy entropy chart is? Mollier
58. It is the calculation of both energy balances
diagram
and material balances in a chemical system. 70. Covalent bond between 2 atoms with
Stoichiometry different electronegativities so that the
59. It involves the replacement of one of the electron density is asymmetrically distributed.
atoms or groups of atoms attached to the Polar
carbon backbone of the organic material. 71. Rigid tank contains hot fluid that is cooled
60. Heat is transferred to a heat engine from a while being stirred by a paddle wheel. Initially
the internal energy of the fluid is 850kJ. During
furnace at a rate of 92 MW. If the rate of
the cooling process, the fluid losses 550kJ of
waste heat rejection to a nearby river is 45 heat and the paddle wheel does 200kJ of work
MW, determine the efficiency for the heat on the fluid. Neglect energy in the paddle
engine. 51.08% wheel. 500 kJ
61. Calculate the volume in liters occupied by 7.40 72. Lowest approximate temperature at which
gram of ammonia at STP (use N=14amu, water can be liquid? -18 degree celsius
H=1amu). 9.75 liters 73. Energy which a substance possesses because
of motion and configuration of its atoms,
62. Ten grams of sodium hydroxide is dissolved in
molecules and subatomic particles. Internal
enough water to make 1 L of solution. What is energy
the molarity of the solution? 0.25 M 74. Percent change in volume as liquid water
63. The food compartment of a refrigerator is freezes? 9.1 % increase
maintained at 4 degree Celsius by removing 75. Three moles of an ideal gas are compressed
heat from it at a rate of 300 kJ/min. if the slowly and isothermally from a volume of 5 to
1.5 ft^3 at a temperature of 320K. How much
required power input to the refrigerator is 3
work is done? -9.61 kJ
kW, determine the coefficient of performance. 76. How much heat is needed to raise the
1.67 temperature of 0.80 kg of ethyl alcohol from
59degF of its boiling point 172.94degF? (c =
0.6 cal/g degC) 30 kcal
77. Temperature at which the vapor will start to 91. Heat engine deriving its power from the
condense? Dew point energy liberated by the explosion of a mixture
78. Element with highest ionization potential of its of some hydrocarbon, in a gaseous or
atom? helium vaporized form. Internal combustion engine
79. Minimum amount of radioactive material 92. A steady-flow process at total constant
needed to sustain a nuclear chain reaction. pressure through a control volume for which
Critical mass there is no heat. Adiabatic saturation process
80. Which of the following is the weakest 93. The Pauli exclusion principle: limits the
attractive force? number of electron that can occupy an
a. Van der Waals force orbital to 2
b. b. Coordination covalent bond? 94. The Carnot cycle is composed of how many
c. Covalent bond reversible processes? 4
d. Polar Covalent bond 95. Assumes that the concentration of a reaction
81. What chemical bond is formed in binary intermediates is constant during the main part
compounds where the electronegativity of the reaction. Steady-state approximation
difference between atoms is greater than 0.2? 96. It is a thermodynamic cycle that converts heat
covalent bond into work. Water is usually the working fluid of
82. Compute the maximum possible efficiency of the cycle and heat is supplied externally in a
a heat engine operating between temperature closed system. Rankine cycle
limits, 100degC and 340degC. 39.15% 97. The impossibility of knowing both the precise
83. Efficiency of an Otto cycle with a compression location and the velocity of subatomic
ratio of 7:1? The gas used is air. 0.541 particles at the same time is known as:
84. Air in an automobile tire is initially at -10degC uncertainty principle
and 190kPa. After the automobile is driven 98. What pressure must be applied to 225mL of
awhile, the temperature rises to 10degC. gas at 1atm to reduce its volume to 100mL?
What is the new pressure? 204.448 kPa 2.25 atm
85. A 30-m vertical column of fluid (density = 1878 99. The property of a substance which remains
kg/m^3) is located where g=9.65mps^2. Find constant if no heat enters or leaves the system
the pressure at the base of the column. while it does work or alter its volume but
543.68 kPa which increases or diminishes should a small
86. A vertical column of water will be supported amount of heat enter or leave. entropy
to what height by standard atmospheric 100. Calculate the energy change
pressure? 33.9 ft associated with the third line of the Balmer
87. A substance which can act as an acid and a Series for Hydrogen gas, that is, the line that
base. Amphoteric results when an electron moves from n=6 to
88. How much water in L must be added to 0.5L of n=2 (Rhc = -1313kJ/mole). 301.45 kJ/mol
6M HCl to make it 2M? 1.5 L (?)
89. The First law of Thermodynamics maybe
expressed in the following equivalent:
a. net transfer is equal to the network
b. sum of total energy forms leaving the
system boundary is equal to the
energy input
c. c. energy can neither be created nor
destroyed, can be converted from one
form to another
d. d. all of the above
90. A unit of pressure used in high vacuum
technology and is equal to 1 mmHg. Torr

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