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XI (F.Sc.) Chemistry Ch # 6

18-12-2013 10 10 MINUTES
Q.1. Choose the correct option. 10
(i). Which pair has trigonal plannar structure?
(a) CO2, SO2 (b) NH3, PH3 (c) BF3,AlH3 (d) H2O, C2H2
(ii). Which of the following ion is smallest in size?
(a) Cl- (b) Mg2+ (c) Na+ (d)S2-
(iii). Which of the following elements will have lowest value of first ionization energy?
(a) Na (b) Li (c) Rb (d) Ca
(iv). Which of the following is polar?
(a) CCl4 (b) HCI (c) BF3 (d) CO2
(v). The paramagnetic property of oxygen is well explainect on the basis of
(a) VSEPR theory (b) VB theory (c) motheory (d) none of these
(vi). Bond angle between two H-S-H bond is
(a) 104.5o (b) 107.5o (c) 92o (d) 95o
(vii). Whih of the following species has un-paired electrons in anti-bonding molecular orbitals
(a) H2 (b) O22 (c) He2 (d) N 22
(viii). The bond order of O22 is
(a) 1 (b) 2 (c) 3 (d) 4
(ix). The octet rule is not followined in the formation of
(a) NF3 (b) CF4 (c) CCl4 (d) PCl5
(x). SI unit of dipole moment is
(a) pm (b) debye (c) mc (c) all

Q.No.2. Write short answers of the following questions. (10 x 2 = 20)

(i). Why dative bond cannot be formed between two similor atoms?
(ii). Why second electron affinity for all elements is pasitive?
(iii). Justify the energy of A.B.M.O is greater than B.M.O.
(iv). The di-pale moments of CO2 is zero but that of CO is 0.12 D. Why?
(v). What is the relationship between the bond energy, bond strength and bond length?
(vi). Why sigma bond is stronger than pi bond?
(vii). Lone pair of electrons on an atom occupy more space?
(viii). No bond in chemistry is 100% ionic. Justify it.
(ix). Define ionization energy.
(x). What is the sequence of molecular orbitals in nitrogen (N2) molecule?
Q.3 (a) Explain atomic orbital hybridization with refrence to Sp3, Sp2 and Sp mode of hybridization. 06
(b) Give the postulates of VSEPR theory. 04