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FEPERIKSAAN AKHTTE ST"F{L FEI{SX$gKAN MRSE{ 2{}1?

KIMIA

Kertas I

Satu jam lima belas minit

JA.NGAN BUKA KERTAS SOALAN INI SEHINGGA DIBERITAHU

1. Kevtas soalan ini adalch dalam dwibahasa

2. Calon dikehendaki membaca maklumat di halaman belakang kertas soalan ini.

Kertas soalan ini mengardungi 34 halaman bercetak dan 2 halaman tidak bercetak

[Lihat sebelah
TiULIT
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SULIT 4s4lt1

Which substance exists as an atom?

Balxan manakah wujud sebagai atom?

A Air
Udara
B Steam
Wap air
C Argon
Argon
D Ethane
Etana

Diagram 1 shows the set-up of apparatus for an experiment to determine the

empirical fonnula of magnesium oxide.
Rajah I menunjukkan susunan radas bagi satu eksperimen untuk menentukan.formula
empirik magnesium oks ida.

r.id
Penutup

Crucible
Magnesium Mangkuk pijar
Magnesium

Diagram 1
Raiah I

Why the crucibie lid is opened once in a while during the experiment?
Mengapakah penutup mangkuk piiar dibulm sekali sekala semasa eksperimen?

A To avoid explosion
Untuk me n ge I akkan I etup an

B To cool the magnesium

Untuk rne ny ej ukkan ma gnes ium

C To see what happen inside the crucible

Untuk melihat apa yang berlaht di dalam tnangluk piiar

D To allow oxygen gas to etrt€rthe crucible

Untuk membenarkan gas oksigm rnasuk ke dalam mangkuk pijar

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Which anion present in copper(Il) sulphate solution?

Anion manakah yang hadir dalam larutan kuprum(Il) sulfat?

A SO+2-

B Cu2* , Hu
C OH-, SO+2-

D Cr'* , so+2- , H*, oH-

Why are weather balloons filled with helium gas instead of hydrogen gas?
Mengapakah belon kaji cuaca diisi dengan gas helium berbanding gas hidrogen?

A Helium is unreactive
Helium tidak reaktif
B Helium is easily found in air
Helium mudah ditemui dalam udara
C Helium is lighter than hydrogen
Helium lebih ringan daripada hidrogen
D Helium is less dense than hydrogen
Helium kurang tumpct daripada hidrogen

Which compound is formed by sharing electrons?

Sebatian manakah yang terbentuk melalui perkongsian elektron?

A Methane, CH+
Metana, CHt
B Sodium oxide, NazO
Natrium oksida, NatO
C Lithium chloride, LiCl
Litium klorida, LiCl
D Calcium hydroxide, Ca(OH)z
Kals ium hidroksida, Ca(OH) z

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Diagram 2 shows the apparatus set-up of an electrolytic cell.

naiih 2 menunjukkan susunan radas suatu sel elektrolisis'

Bulb lights up
Mentol menyala

Substance P
Bahan P

Diagram 2
Raiah 2

Which ofthe following is substance P?

, ntdra yang berila*, yangmanakah bahan P?

A Ethyl ethanoate, CH:COOCzHs

Etil etanoat, CHsC O OC zI{s
B Glucose solution, CoHrzOe
Larutan glukosa, C cI{t zA a
C Chloromethane, CHtCl
Klorometana, CHsCI

D Ethanoic acid, CHTCOOH

Asid etanoik, CH{OOH

Why ammonia solution is a weak alkali?

Meigapakah larutan ammonia adqlah alknli lemah?

A Has high PH value

MemPunY ai nilai PH Yang tinggi

B Ionises PartiallY in water

Mengion sePara dalam air

C Contains a lot of ammonium ions

Mengandungi banY ak io n ammonium

D Produces high concentration of hydroxide ions in_tle water

Menghasilkin kepekatan ion hidroksida yang tinggi di dalam air

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SULIT 5 4$41lt

8 Which of the following substances are monoprotic acid?

Antara bahan-bahan berikut,yang manakah merupakan asid monoprotik?
I Hydrochloric acid
Asid hidroklorik
II Sulphuric acid
Asid sulfurik
m Phosphoric acid
Asidfosforik
fV Nitric acid
Asid nitrik

A I and tII
I dan III
B I and IV
I dan IV
C II and III
II dan III
D II and IV
II dan IY

Diagram 3 shows the apparatus set-up for the preparation of a salt.

Rajah j menunjukkan susunan radas bagi penyediaan suatu garqtn.

SolutionA q#r",,
Larutan'7
j
-> .,iHI- Garam

white \,, lffi . Ht

,JHS'""
Mendakan
s)utione
putih
Gl Larutan B
H
terhasil

Diagram 3
. Rajah 3
Which salt is prepared through this method?
Garam manakah yang disediakan melalui kaedah ini?

A Zinc sulphate
Zink sulfat
B Silver nitrate
Argentumnitrat
C Barium chloride
Barium klorida
D Lead(II) sulphate
Plumbum(Il) sulfat

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SULIT 4541/l

10 The following are the uses of substance Q in industries.

Maklumat berikut adalah kegunaan bahan Q dalam intlustri.

o To remove the surface oxide layer on metals in

electroplating.
Untuk menanggalkan lapisctn oksida pada logam
dalam penyaduran
. To produce detergents.
Un tuk menghas i lkan d eter gen.
o To make paints.
[] ntuk me ngh a s i I kan c at.
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What is substance Q?
Apakah bahan Q?

A Nitric acid
Asid nitrik

B Ammonia
Ammonia

C Sulphuric acid
Asid sulfurik

D Ammonium sulphate
Ammonium suffat

11 Diagram 4 shows a cookware which is coated with teflon or also known as

polyetrafl uoroethene, PTFE'

What is the monomer of teflon?
Rajah 4 meru.tnjukkan peralatan memasakyang disaluti dengaru teflon atau dikenali iuga
s eba gai p olitetraflor o e tena, PTF E.

Apakah monomer bagi teJlon?

Diagram 4
Rajah 4
A Ethene
Etena
Fluoroethene
Floroetena

C Tetrafluoroethane
Tetrafloroetuna
Tetrafluoroethene
Tetrafloroetena

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 7 454lll

t2 Which statement is true about both methanol and ethanol?

Antara pernyataan berikut yang man.akah benar mengenai metanol dan etanol?

A Both have different functional groups

Ke du a- duany a m e mp uny ai kumpu I an be rfun gs i b e r b ez a

B Both show similar physical properties

Ke dua- duany a m e nunj ukkan s ifat fi z i kal y an g s am ct

C Both show different chemical properties

Ke dua- duany a me nunj ukkan s ifat ki m i a y an g be r beza

D Both have same general formula

Kedua-duanya mempunyaiformula atn yang sama

13 Which of the following is not a correct unit for the rate of reaction?
Unit manakahyang tidak betul untuk kadar tindakbalas?

A gs-1

B g dm-3
C mol s-l

D cm3 min-l

14 Diagram 5 shows a fruit that contains compound R which gives its fruity smell.
Rajah 5 menunjukkan buah yang mengandungi sebatian R yang memberikannya bau
buah-buahan.

Diagram 5
Rajah 5

What is the homologous series of compound R?

Apakah siri homolog bagi sebatian R?

A Ester
Ester
B Alkene
Alkena
C Alcohol
Alkohol
D Carboxylic acid
Asid ksrboksilik

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 454111
SULIT

15 Which of the following is a reduction process?

Antara berikut yang manakah proses penurunan?

A A copper(Il) ion gains two electrons

Ion htprum(Il) menerima dua elektron
B Hydrogen sulphide loses its hydrogen
Hidr o gen s ulfi.da ke hilangan hidr ogen

C Iron(II) ion converted to iron(III) ion

Ion ferum(Il) b ertukar kepada ion ferum(Ill

D A magnesium atom loses two electrons

Atom magnesium kehilangan dua elektron

16 Aluminium atom undergoes oxidation to form ion by donating three electrons.

what is the oxidation number of aluminium in the ion formed?
Atom aluminium mengalami pengoksidaan membentuk ion dengan menderma tiga
elehron.
Apakah nombor pengoksidaan aluminium bagi ion yang terbentuk?

A-3
BO
c+2
D' +3

17 Which of the following process or reaction absorbs heat?

Antara proses atau tindak balas berikut, yang manakah meryerap haba?

A Boiling of water
Pendidihan air

B Freezing of liquid suiPhur

P emb ekuan cecair sulfur

C Reaction between hydrogen and nitrogen

Tindabalas dntara hidrogen dan nitrogen

D Reaction between zinc and hydrochioric acid

Tindak balas antara zink dan asid hidroklorik

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SI,ILIT 9 454u1

18 Diagram 6 shows the part of labelling on the food packaging.

Rajah 6 menunjukkan bahagian berlabel pada pembungkus makanan.

MFG: 060317
EXP : 060319

Diagram 6
Rajah 6

What is the type of food additive added to make sure that the food last longer until
the expiry date?
Apakah jenis bahan tambah makanan yang ditambah untuk memastikan makanan
tersebut dapat bertahan sehingga tarikh luput?

A Stabilizers
Penstabil
B Flavourings
Perisa
C Antioxidants
Antioksidan
D Preservatives
Pengawet

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 10 454111
SULIT

lg Diagram 7 shows the apparatus set-up to determine the heat of precipitation for
magnesium carbonate, MgCO:.
naiah 7 menuniukkan su.sunan radas bagi menentukan haba pemendakan bagi
magnesium karbonat, MgCO s.

Magnesium carbonate,
Magnesium nitrate, Sodium carbonate,
MgCOr solid
Mg(NOr)z solution NazCO: solution
Pepejal rnagnesium
Larutan magnesium Larutan natrium karbonat,
karbonat, MgCO:
nitrat, MCC'{O)z NazCOs

DtagramT
Raiah 7

Which of the following is correct about the reaction?

Antara yang berikut, yang manakah betul bagi tindak bslas tersebut?

A Heat is absorbed from the surroundings

Haba diseraP dari Persekitaran

B Heat is releas.ed and the container become hot

Haba dibebasknn dan bekas menjadi panas

C Total energy content ofthe reactant is higher than total energy content of
the product
Jumlah kandungan tenaga bahan tindak balos adalah lebih tinggi daripada
iumlah kandungan tenaga hasil tindak balas
D Heat absorbed during the broken of the bond is lower than heat released
during the formation of bond
Haba diserap semasa pemutusan ikatan adalah lebih rendah daripada
haba

dibebaskan semasa pembentukan ikatan

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 SULIT 11 454Ur

20 Which of the following is correct about properties of isotopes?

Antara berikti, yang manakah betul tentang ciri-ciri isotop?

A Have different chemical properties

Mempunyai sifat kimia yang berbeza
B Have different physical properties
Mempunyai sifat fizikal yang berbeza
C
IE Have the same number of neutrons in an atom
Memptmyai bilangan neutron yang sama di dalam atont

a D Have the same nucleon number

V Mempttnyai nombor nukleon yang sama

2l The melting point of substance W is -5 oC and its boiling point is 78 oC.

What is the physical state of substance W at -8 oC and 80 oC?
Takat lebur bahan W adalah -5 oC dan takat didih adalah 78 "C.
Apakah keadaanfizikal bahan W'pada -8 "C dan B0'C?

At -8 0C At 80 "C
Pada -8'C Padu 80 oC
A Solid Gas
Pepejal Gcts

Solid Liquid
Pepejal Cecair
C Liquid Gas
Cecair Gas

D Liquid Liquid
Cecatr Cecair

22 The following equation represents a chemical reaction involving gas J and L.

Persamaan berikut ntewakili tindak balas kimia melibatkan gas J dan L.

,*, + Lz(sl ) ZJLet

What is the ratio of volume of product to volume of reactants at the same

temperature and pressure?
Apakah nisbah isipadu hasil tindak balas kepada isipadu bahan tindak balas pada suhu
dan tekanan yang sama/

A1 2

B1 1

C2 1

D1 2

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 12 454lll
SULIT

to
23 Table I shows the result when three oxides of elements in period 3 are added
potassium hydroxide solution, KoH and hydrochloric acid, HCl.
dalam Kala 3
Jadual 1 menuniulikan keputusan apabila tiga ol<sida bagi unsur-unsur
hidroklorik, HCI'
ditambahkan dingan laritan kalium hidroksida, KOH dan asid

Oxide Added to KOH Added to HCI

Oksida Ditambah dengan KOH Ditambah dengan HCI

Oxide of P Reaction occurs Reaction occurs

Oksida P Tindak balas berlaku Tindak balas berlaku

Oxide of Q No reaction Reaction occurs

Olcsida Q Tiada tindak balas Tindak balas berlaku

Oxide of R Reaction occurs No reaction

Olrsida R Tindak balas berlaku Tiada tindak balas

Table 1

Jadual I

Arrange the elements P, Q, R in ascending order of their electronegativity'

Susunirnsur P, Q, R dalam tertib menaik keeletronegatifan'

A P,Q,R
B R,P,Q
C Q,P,R
D Q,R,P

24 Atom G has 6 electrons while atom L has 17 electrons.

What is the chemical formula of the compound formed betrveen G and L?
Atom G mempunyai 6 elektron manakala atom L mempunvai I7 elelrtron'
Apakahformula'kimia bagi sebatian yang terbentuk ottaro G dan L?

A GLz
B GL+

C GzL
D GtL

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SULIT 13 454u1

25 Diagram 8 shows an incomplete apparatus set-up of an electrolytic cell.

Rajah 8 menunjukkan sust$tan rodas yang tidak lengkap bagi suatu sel elektrolisis.

r1
{
IT
1l
i
I

0.5 mol dm-3

hydrochloric acid
0.5 mol dm-j
asid hidroklorik

Diagram 8
Rajah I
Which of the following shows the correct observation at T when the solution has
been electrolyzed for 10 minutes?
Antaraberilail, yang manakah merunjul*an pemerhatian yang betul pada T apabila
larutan dielektrolisiskrtru selarna 10 minit?

A B C D

sh i-;--il--
He

L"niliLflf, j

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SULIT l4 454lll

26 Diagram 9 shows the electron arrangement of magnesium ion with nuoleon

number 24.
Rajah 9 menunjukkan susundn elel#ron ion magnesium dengan nombor nukleon 24'

2+

Diagram 9
Raiah 9

Which of the following shows the electron arrangement and the number of
neutrons in magnesium atom?
Antara yang berikut, yang manakah menuniukkan sttsunan elektron dan bilangan
neutron dalam atom magnesium?

Electron arrangement Number of neutrons

Susunan elektron Bilangan neutron

A 2.8.2 t2
B 2.8.2 24

C 2.8 t2
D 2.8 24

27 The pH value of 0.1 mol dm-3 of acid U is 1.

Which statement is true about acid U?
Nilai pH bagi asid U 0.1 mol dm3 adalah I '
Pernyataan manakah adalah benar tentang asid L?

A SlightlY soluble in water

Larut sedikit dalam air
B Reacts only with a weak alkali
Hanya bertindak balas dengan alkali lemah

C The degree of ionization in water is high

Dariah pengionan dalam air adalah tinggi

D Has a low concentration of hydrogen ions

Mempunyai kepekatan ion hidrogen yang rendah

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28 Diagram 10 shows four processes involving chromium(Il) oxide, CrO.

Rajah 10 menunjukknn empat proses yang melibatkan kromium(Il) oksida, CrO.
CrO3

Process I{
Proses.K
Prccess L
Proses L
Cr CtO:
ftacess N,!
Pvoses M

->

Diagram 10
Rajah 10

Which of the following statements are correct about the processes undergoes by
chromium(Il) oxide?
Antara penyataan berikut, yang manakah betul mengenai proses-proses yang dilalui oleh
lcromium(Il) oksida?

I Chromium(Il) oxide undergoes reduction in process M

Kromium(Il) olrsida mengalami penurunan dalam proses M
II Chromium(Il) oxide undergoes oxidation in process K
Kromium(Il) oksida mengalami pengoksidaan dalam proses K
m Oxidation number of chromium increases from *2 to +6 in process N
Nombor pengoksidaan kromium meningkat dari +2 kepada +6 dalam
proses N
IV Oxidation number of chromium decreases from +2 to 0 in process L
Nombor pengoksidaan kromium menurun dari +2 kepada 0 dalam
proses L

A IandII
I dan II
B I and III
I dan III
C II and IV
II dan IV
D lll and IV
III dan IV

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Table 2 shows the pH value when ammonia is dissolved in

two different solvents'
29
dilarutkan dalam dua pelarut berbeza'
Jadual 2 menuniukkin nilai pH apabila ammonia

Solvent
Pelarut
Ammonia in solvent E
Arnmonia dalaru Pelarut E

Ammonia in solvent F
Arnmonia dalam Pelarut F
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Table2
Jadual 2

Which statement explains the difference in pH value?

Pernyataan manakah menerangkan perbezaan nilai pH?

A Ammonia molecules ionised in Set II

Molelatl-molelatl ammonia mengion dalam Set II
B Ammoniamolecules dissolved in solvent E
Molelat-mo lehtl ammoni a melarut dalam pelarut E

C Solvent E is water and solvent F is methylbenzene

Pelarut E ialah air dan pelarut F ialah metilberuena

D Concentration of hydroxide ion in Set I is higher

Kepekatanionhidrotrsidadalamsetladalahlebihtinggi

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 SULIT 17 454U1

30 Diagram 11 shows a device v made up of stainless steel and ceramics.

Raiak I I menunjukkan alat Y yang diperbuat claripada keluli tahan karat tlan ,seramik.

Diagram 1l
Rajah I I

wh{ are the important properties of the materials used in making device v?
Apakah ciri'ciri penting bahttn-bahan yang digwtalcan dalam pemhuatan alat v./

High heat resistant

Tahan habayang tinggi

Has shiny surface

Mempunyai permukaan b erkilat

m Resistant to rusting
Tahan karat
IV Strong and hard
Kuqt dan keras

A I and III
I dan III
B I and IV
I dan IV
C II and III
II dan III
II and IV
II dan IV

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SULIT l8 454u1

3l Diagram 12 shows the uses of calcium sulphate hemihydrate salt which has known
as plaster of Paris in medicinal fieid.
Rajah 12 ntenunjukkan kegunaan garam kalsium sulfat heruihidrat dtkenali sebagai
plaster Paris dalam bidang perubatan.

Diagram 12
Raiah 12

Which substances can be used to produce this sait?

Bahan manakah boleh digunakan untuk menghasilkan garctnt ini?

A Calcium + sulphuric acid

Kalsiurn + asid sulfurik
B Calcium oxide + sodium sulPhate
Kalsium oksida * natrium sulfat

C Calcium nitrate * potassium sulphate

Kalsium nitrat + kalium sttlfat
D Calcium carbonate + magnesium sulphate
Kalsium karbonat * magnesiuru sulfat

32 Substance U is produced in industrial process. It can react with barium hydroxide

solution to form a white pigment used in paint.
Which of the following is the equation involved in the manufacture of substance U?
Bahan U dihasilkan dalant proses industri. Ianya boleh bertindak balas dengan larutan barium
hidroksida untuk menghasilkan pigmen putihyang digunakan dalam cat.
Antara persamaan berikut, yang nwnakah terlibat dalam penghasilan bclhan U?

A Nz * 3Hz ) 2NHs
B 2NH: + HzSOq ) (NH+)zSO+
C HzSzOz + HzO )2HzSO+
D Ba(OH)z + HzSO+ ) BaSO+ +2HzO

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 SULIT 19 4541/t

33 Diagram 13 shows the apparatus set-up used to determine the rate of reaction.
Rajah 13 menunjukkan susunan rad*s bagi menentukan kadar tindak balas.

Reaction mixture
Campuran tindak
balas

Diagram 13
Rajah l3

Which of the following chemical reaction is not suitable to determine the rate of
reaction by using the apparatus set-up?
Antara tindak balas berikut, yang manakah tidak sesuai bagi penentuan kadar tindak
balas menggunakan susunan radas tersebut?

A CaCO: + 2HCl ) CaClz + HzO + COz

B NaHCO: + F{NO: ) NaNOr + HzO + COz
C Mg +2CH:COOH ) Mg(CH:COO)z +Hz
D ZnO + HzSO+ ) ZnSO+ + HzO

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SULIT 20 454U1

34 Diagram 14 shows two processes involving compound W.

Rajah 14 menunjukkan dua proses melibatkan sebatim W.

Compound V
Sebatian V
Decolourised Has carboxyl
brown colour of $oup
bromine water Mempunvai
Meluntwkan kumpulan korboksil
warna perang air Process II Tums blue litmus
bromin Proses II paper to red
Undergoes Compound W + Menukorkan kertas
combustion to Sebatian W litmus biru kepada
produce carbon merah
dioxide and Vinegar smell
water Menghasilkan bau
Mengalami cuka
pembalcaran bagi
menghasilkan
korbon diolcsida
dan air

Diagram 14
Rajah 14

Which structural formula represents compound W?

Formula struktur yang manakah yang mewakili sebatian W?

AHH
tt
H-C: C-H

BHH
lt
H-C C-OH
ll
HH
C H o
I ll
H
-C C -OH
I

D H HH
I tl
H _C C - C -OH
I tt
H HH

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SULIT 2t 454u1

Which of the following diagram shows an endothermic reaction?

Antara rajah berikut, yang manakah menunjukkan suatu tindak balas endotermik?

A Stearn
Wap air /)
\/
\,,/
*, ....,,:. { water
.".: *__ Aif

Calciumoxide
Kalsium oksida

B
n Flame
i\--'- Nj'alaan
i,,\]
11

n
H
I Natural gas
,- Gasasli
-

C
Carbonate salt
Garam karbonat

Lirae water
Air kapur

-Il ffi \
r*xiffi"i
Final teryeratrue

suhuaw,ai akali
Acid ffit v Atknti

Asid
-f=HI

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 SULIT 1','
4541/t

36 Diagram 15 shows a structural formula of ethyl butanoate which found in

pineapple.
Raiah l5 menunjukkan formula struktur etil butonoat yong terdapat di dalam nenas.

HHHOHH
ttlillr
H-C C-C-C-O-C C-H
tttlt
HHHHH
Diagram 15
Rajah l5

0.004 mol of ethyl butanoate has a mass of 0.464 g.

Which pair of information is correct about ethyl butanoate?
0.004 mol etil butanoat mempunyai jisim 0.464 g.
Antara pasangan maklumat berikut, yang manakah benar tentang etil butanoat?

Relative molecular mass Empirical formula

Jisim molekal relatif Formula empirik
A 86 CoHrzoz
B s8 C:HoO
C 116 C:HeO
D tt6 CoHrzOz

37 The equation represents the reduction reaction of acidified potassium

manganate(Vll) solution.
Persamaan mewakili tindak balas penurunan bagi larutan kalium manganatrTll) berasid.

MnO+- * xH* +ye- ) Mn2* * zHzO

What are the values of x, y and z?

Apakah nilai bagi x, y and z?

x v Z

A t6 10 8

B 16 5 4
C 8 5 4
a
D 8 J 2

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38 Table 3 shows the nucleon number and the number of neutrons for atoms of
elements S, T, U and V.
Jadual 3 menunjukkan nombor nukleon dan bilangan neutron bagi atom unsur S, T, U dan
T/.

Atom Nucleon number Number of neutrons

Atom Nombor nukleon Bilangan neutron

S 1 0

T 16 8

U 35 18

V 40 22

Table 3
Jadual 3

Which element will reacts with an alkali metal to produee a white solid that
dissolved in water to form a coloudess solution with pH 7.
Unsur manalrah yang bertindok balas dengan logam allcali untuk menghasillcan pepejal
putih))ang larut dalam air rnembentuk larutctn tidak berwarna dengan pH 7.

A V
B U
C T
D S

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the reaction
39 Diagram 16 shows a flow chart for the formation of compound Q from
between element P and element R.
nirn 16 menuniukpan carta alit pembentuyan sebatian Q daripada tindak balas arttara
unsur P dan unsur R.-

ElementP + ElementR
(Jnsur P Unsur R

* water
air

o Can conduct electicitY

Boleh mengalirkan elektrik
o Change the red litmus paper to blue
Menukmkan kertas litmus merah kepada biru

Diagram 16
Raiah 16

Which of the following is correct about element P, element R and compound Q?

Antarayang berihtt, yig manakah betul bagi ttgur P, unsur R dan sebatim Q?

Electron arrangement
Sustman elektron Type of bond in comPound Q
Jenis ikatan dalam sebatian Q
Element P Element R
Unsur P Unsur R
Covalent
1 2.8.7 Kovalen
Ionic
2.8.8.1 2.6 Ion
Ionic
2.8.1 2.8.7 Ion
Covalent
D 2.4 2.6 Kovalen

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ST]LIT ,q 4s4ut

40 Sulphuric acid is one of the important chemical used in tin mining. It is also a by-
product of the mine when mixed with water to form acidic waste. In a titration, the
chemist found that 25 cm3 of 0.2 mol dm-3 potassium hydroxide solution
neutralised 25 cm3 of acidic waste.
What is the concentration of the acidic waste?
Asid sulfurik adalah salah satu bahan kimia pentingyang digunakan dalam perlombongan
timah. Ia juga adalah bahan sampingan perlombongan apabila bercampur dengan air
membentuk air kumbahan berasid. Dqlam suatu pentitratan, seorang ahli kimia mendapati
25 cm3 larutan kalium hidroksida 0.2 mol dm-3 meneutralkan 25 cm3 air kumbahan
berasid,
Apakah kepekatan air kumbahan berasid tersebut?

A 0.1 mol dm-3

B 0.2 mol dm-3

C 1.0 mol dm-3

D 2.0 mol dm-3

4L Diagram 17 shows the apparatus set up to electroplate iron spoon with copper.
Raiah 17 menunjukkan susunan radas bagi penyaduran sudu besi dengan kuprum.

Copper
Kuprum
Iron spoon
Sudu besi
Copper (II) sulphate
solution
Larutan lruprum(I)
sulfat
DiagranlT
Rajah 17

After one hour, it is found that the iron spoon is not electroplated.
What should be done to ensure eleckoplating takes place?
Selepas satu jam, didapati sudu besi tidak disadurkan.
Apakah yang perlu dilakulcan untuk memastikan penyaduran berlaht?

A Use abigger iron sPoon

Gunalran sudu besi Yang besar

B Interctrange the terminal in the cell

Saling tukar terminal Pada sel
C Use coppedll) nitrate solution as electrolyte
Gunakan larutan kryram(Il) nitrat sebagai elektalit

D Increase the concentration of copper(Il) sulphate solution

Tambah kepekatan larutan kuprum(Il) sulfat

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SULIT 26 4541/t

42 Diagram 18 shows how Ali prepares a syrup solution during the actir.ity week at
his school.
Raiah l8 menunjukkan bagaimana Ali menyediakan larutan sirap semasa rninggu aktiviti
di sekolahnya.

i
i
2 iitre of water
2 kg ofsugar 2 liter air
2 kg gula

Diagram 18
Rajah lB

By using the prepared syrup solution, Ali has to make a new syrup solution to be
given to six groups of students. Each group must receive 0.5 litre of solution.
What is the concentration of the syrup solution received by each group?
[1 litre : 1 dm3, relative molecular mass of sugar : 3421

Dengan menggunakan larutan sirap yang disediakan. Ali perlu rnentediokan larutan
sirap yang baru untuk diedarkan kepada enam kuntptrlun pela_ittr'. .setiap kumpulan mesti
menerimc 0.5 liter larutan.
Apakah kepekatan larutqn sirap yang diterirna oleh setiap ktunpulan?
:
p liter I dm3, jisim molekul relarif guta : 3a2l

A 0.487 mol dm-3

B 1.949 mol dm-3
C 2.924 mol dm-3

D 11.696 mo ldm-3

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 SULIT 27 454llt

43 The following equation shows the displacement of metal Q from its salt solution.
Persamaan berikut menunjukkan penyesaran logam Q daripada larutan garamnya.

i
P+q(NO:)z ) P(NO:)z+a
What are metal P and metal Q?
Apaknh logam P dan logam Q?

P a
A Iron Zinc
l Ferum Zink
Iron Magnesium
Ferum Magnesium

C Zinc Magnesium
Zink Magnesium
I
I D Zinc Iron
I
i
I
Zink Ferum
i
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i

44 The following chemical equation shows the reaction between copper(Il) oxide and
nitric acid.
Persamaan kimia berikut rnenunjuklwn tindak balas antara kuprum(Il) oksida dan asid
nitrik.

CUO + 2HNO: ) CuQ.{Ot)z + 2HzO

If 10 g of copper(Il) oxide powder is added to 50 cm3 of 2 mol dm-3 nitric acid,
calculate the mass of unreacted copper(Il) oxide.
[Relative formula mass of CuO:80]
Sekiranya l0 g serbuk kuprum(Il) olcsida ditambahkan kepada 50 cm3 larutan asid nitrik
2 mol dm-3, hitung j is im kuprum (II) oks ida yang tidak b ertindak b alas.
{Jisimformula relatif CuO : 801

A 29
g B 49
c 59
D 69

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45 Table 4 shows two sets of reaction between metals and salt solutions.
Jadual 4 menunjukkan dua set tindak balas ontara logam dan larutan garatn.

Set Substances Observation

Set Bahan-bahan Pemerhatian
Excess magnesium and
copper(Il) sulphate solution Blue solution turns to colourless
1
Magne s ium b erl e bihan dan Larutan biru bertukar kepada tidak
I arutan kuprum(Il) s ulfat
berwarna

Excess copper and silver

nitrate solution Colourless solution turns to blue
2 Kuprum berlebihan dan Larutan tidak berwarna bertukar
larutan ar gentum nitr at kepada biru

Table 4
Jadual 4

Which of the following statements are true about the confirmatory test of the ions
present in solution formed in both set?
Antara penyataan-penyataan berikut yang manakah benar tentang kehadiran ion-ion
dalam larutan yang terbentuk dalam kedua-dua set?

I White precipitate is formed and insoluble when ammonia solution is added in

excess to the solution formed in Set I
Mendakan putih terbentuk dan tidak larut apabila larutan ammonia berlebihan
ditambah kepada larutan dalam Set I
il Blue precipitate is formed and insoluble when excess ammonia solution is
added to the soiution formed in Set II
Mendakan biru terbentuk dan tidak larut apabila larutan ammonia berlebihan
ditambah kepada larutan dalam Set II
ilI White precipitate is formed when lead(Il) nitrate solution is added ro the
solution formed in Set I
Mendakan putih terbentuk apabila larutan plumburnOll nitrat ditarnbah kepada
larutan dalam Set I
IV White precipitate is formed when sodium chioride soiution is added to the
solution formed in Set II
Mendakan putih terbentuk apabila larutan natrium klorida ditambah kepada larutan
dalam Set II

A I and III
I dan III
B Iand IV
I dan IY
C II and III
II and III
D II and IV
II dan IV

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 29 454u1

Diagram 19 shows the energy profile diagram for a reaction.

Rajah 19 menunjukknn gambar rajah profil tenaga bagi suatu tindak balas.

S+T)V+W

Energy
Tenaga

Diagram 19
Rajah 19

What is the value of the activation energy for this reaction?

Apakah nilai tenaga pengaktifan untuk tindak balas ini?

A 150kJ
B 95 KJ

C 55KJ
D 15KJ

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 30 4541/t

47 Table 5 shows the condition of reactants used in Experiment I, II and UL

Jadual 5 menunjukkan keadaan bahan tindak balas yang digunakan dalam
Elrsperimen I, II dan III.

Experiment Condition of reactants

Elxperimen Keadaan bahan tindak balas

Excess Mg powder + 50 cm3 of 2.0 mol dm-3 HCI solution

I Serbuk Mg birlebihan + 50 cm3 larutan HCI 2.0 mol drn':

E*cesrMg powder + 50 cm3 of 2.0 mol dm-3 HCI solution and

copper(Il) sulphate solution
II sr)6"k turg beiebihan + 50 cm3 larutan HCI 2.0 mol dm-3 dan
I ar ut an kuprum (II) s ulfat

Condition W
m Keadaan W

Table 5
Jaduol 5

Graph 1 shows the result of the experiments.

Graf 1 menunjukkan keputusan el<sperimen tersebut.

Ystrpme of ga*icm3
fsPar*"rge*tx' 3O

i,H:;
Graph 1
Graf I

What is condition W.used in Experiment III to obtain the curve III as shown in
Graph 1?
Apakah keadaan W yang digunakan dalam Eksperimen III bagi memperoleh lengkung
III seperti yang ditunjukkan dalam Graf 1?
A Excess Mg powder + 100 cm3 of 2.0 mol dm'3 HCI solution
Serbuk Mg berlebihan + 100 cms larutan HU 2'A mol dm-3

B Excess Mg powder + 25 cm3 of 4.0 mol dm-3 HCI solution

Serbuk Mg berlebihan + 25 cm3 ldrutan HCI 4,0 mol dm'3

C Excess Mg powder + 25 cm3 of 2.0 mol dm-3 HzSOa solution

Serbuk Mg berlebihan + 25 cm3 larutan HzSOt 2.0 mol dm-3

D Excess Mg powder + 50 cm3 of 2.0 mol dm-3 HzSO+ solution

Serbuk Mg berlebihan + 50 cm3 larutan HzSOt2.0 mol dm-3

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C:Ha'
48 The following chemical equation shows a combustion reaction of propane,
persamaan kimta berikut minunjukkan tindak balas pembakaran propana, CsHs.

gr1{s+5Oz )3COz+4HzO

what is the mass of propane needed to produce 550 cm3 of carbon dioxide gas at

room condition?
I Relative atomic mass: C: 12, H: 1]
:24 mol-l]
ilrtotu, volume of gas at room condition dm3

Apakah jisim propsna yong diperlukan bagi menghasilkan 550 cm3 gas karbon dioksida
pada keadaan bilik?
:
lJisimrelatif atomC 12, H: 1l
itsiprdu m-olar gas pada keadian bilik: 24 dm3 moll)

A 336.112 s
B 22.917 g
C 1.008 g
D 0.336 g

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SULIT a1 454lll

49 Diagram 20 shows a type of chemical cell.

Rajah 20 menunjukkan sejenis sel kimia.

MnOz cathode
Katod
Zn-KOH paste
(anode)
Steel case
Bekas keluli Pqsta Zry-KOH
(anode)

Brass current
collector
Loyang pengumpul
arus

Diagram 20
Rajah 20

Electricity is generated when the following reaction occurs:

Elehrik dihasilkan apabila tindak balas berikut berlaku:

Zn + 2MnOz )ZnO + MnzO:

Which of the following is the correct change in the oxidation number of zinc and
manganese?
Antara yang berikut, yang manakah betul tentang perubahan nombor pengolrsidaan zink
dan mangan?

Change in oxidation Change in oxidation

number of zinc number of manganese
Perubahan nombor Perubahan nombor
pengolaidaan zink pengolaidaan mangan

A +2to0 +Zto +6
B +2to0 +2to +3
C 0to+2 +4 to +3

D 0to+2 +4 to +6
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SL,ILIT 33 454u1

50 Diagram 21 shows the apparatus set-up for the reaction between 50 cm3
of 1.0 mol dm-3 copper(Il) sulphate solution with excess magnesium powder.
Rajah 2I menunjukkan susunan radas bagi tindakbalas antara 5A cm3 larutankuprum(Il)
sutfat 1.0 mol dm3 dengan serbuk magnesium berlebihan.

Magnesium powder
Serbuk magnesium
tl
la
al
t
I
.l-_
a
!-
50 cm3 of 1.0 mol dm-3 T-
'a
T--
copper(Il) sulphate solution t-
50 cm3 larutanh.prum(Il) sulfat
1.0 mol dm'3
Diagram2l
Rajah 21

105 kJ of heat is released when 1 mol of the metal is displaced.

What is the temperature change of the mixture?

[Specific heat capacity of a solution :4.2|g-toC-l, density of solution: 1g cmr]
1A5 kJ haba dibebaskan apabila I mol logam disesarkan.
Berapakah perubahan suhu bagi campuran itu?
lMuatan haba tentu larutan: 4.2 Jg't"Cl, ketumpatan larutan: lg cm'31

A 2.5 0C
B 5.0 0c
c 12.5 "C

D 25.0 0C

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KERTAS SOALAN TAMAT

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SUL[T 4541il.

INFGRMATION FOR CANDIDATES

MAKLUMAT {.]NTUK CALON
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i. This question paper consists of 50 questions.
Kertas soalan ini rnengandungi Sfi soalan.

2. Ansu'er all questions.

iav,ah semuu soal.an.
1
J. Ansr.ver each question by biaekening the correct space on the answff sheet.
ia,,*ab setiap soalan dengan menghitamkan rur;ngc*t. yailg betul Ttcda kertcis €
w
.f awupan.

4. Blacken only one spaoe for each question.

Hitamkan satu rttangan sahaja pada setiap soslan.

5. If you wish to ctrange your ansrver, erase the biackened mark that you have ma<tre.
Then blacken the new answer.
Sekiranya andc hendak ruenukar jatvcpctn, padarukan tanda yang teiah tJihuat.
Kernudi{tn kitantkan jawtzpatx y*rug bartt.

6. in the questicns provided are not drawn to scale unless srated.

Ti-re cliagrams
Raiah yqng ftxeftgiringi soalan tidak dilttitiskan mengikut sk*ls kecuali dinysso\uon.

7. You ma.v use a scientific caicuiator"

An d a di ls e n a r ka n m e n g gun akan kc lku I a t o r s aint ifi k.

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