ae 13 marks} 19 The following reaction scheme shows the formation of different amines starting from benzene. le le | f Op-eomens HICH,), D CH.NH, Or by H(CH,), Nu, (2) State the reagents A to G in the above reaction scheme. [7 marks} (b) Suggest a chemical test which can be used to differentiate the above two amines, [3 marks} (©) Give the IUPAC names for both amines, [2 marks} (4) Compare the basicity of the two amines, Explain your answer, 13 marks]49 (a) Describe and explain the variation in thé melting point and electrical conductivity of the Group 14 elements (C to Pb). [7 marks] (b) The group valency of the Group 14 elements is +4. However, for lead, there is a higher tendency to form lead (II) compounds rather than lead (IV) compounds due to the ‘inert- pair effect’. Explain in detail the italicised term. [4 marks] (©) 3.20 g of an impure sample of lead (IV) oxide is heated with excess of acidified potassium iodide solution. The iodine liberated requires 90.0 cm? of 0.20 mol dm” sodium thiosulphate for complete reaction. Calculate the percentage of purity of the sample of lead (IV) oxide. [Pb = 207, O = 16, 1 mol of I, reacts with 2 moles of Na,$,0,] [4 marks} 20 Explain the following in detail: (a) There is little variation in the first ionisation energy of the transition elements from titanium to copper. [3 marks] (b) The third ionisation energy for iron is lower than expected. [3 marks] (c) Titanium (IV) chloride is a colourless liquid with a boiling point of 136°C. [3 marks] (a) When excess concentrated hydrochloric acid is added to aqueous copper (II) sulphate, the solution turns yellow-green. [3 marks] (e) The melting point of iron is higher than that of calcium. Explain why. [3 marks]