Cx is the concentration of X
• The minus sign indicates that X always moves from regions with
higher concentration to the regions where the concentration is lower.
Latent Heat + Sensible Heat
• Water vapour is transferred between the surface and the
air wherever there is difference in vapour pressure
between the surface and the overlying air.
• E α (es* - ea)…………………………………….(2)
LE = λv.E (6)
where : LE: rate of latent-heat transfer [ET-1]
λv : Latent heat of vaporization [EM-1]
E : rate of evaporation or condensation [MT-1]
LE = (λv + λf) E (7)
λf : latent heat of fusion
Evaporation is a diffusive process that follows Fick’s first law, which can be
E = KE.va.(es* -ea)……………………………………………….(1)
where, E : L/T
KE : LT2/M
where T is in oC
Sensible Heat Exchange:
H = KH.va.(Ts-Ta)…………………………..(9)
Ratio, B.
B = H/LE...........................................(11)
= γ (Ts-Ta )/(es-ea)
γ = 0.066 kPa/K
It is to be noted that γ is not actually a constant and it varies with pressure (which
is a function of elevation and time) and latent heat (varies slightly with
temperature)
Energy Balance Method
The general energy balance for an evapotranspiring body during a time period
Δt can be written as:
E = K + L - G - H + Aw- (ΔQ/ΔT)…………..(1)
E: Evaporation
K: Net short-wave radiation input
L: Net long-wave radiation input
G: Net output through conduction to the ground
H: Net output of sensible heat exchange
Aw : Net output associated with inflows and outflows of water ( water-advected
energy)
Q : the change in the amount of heat stored in the body per unit area between
beginning and end of t.
The water-atmosphere heat exchange is said to be in approximate local
air movement to or from the area above the region. If such an equilibrium
does not exist, horizontal airflows supply air-advected energy to the air
Dividing (1) by the latent heat of vaporization (v) and the density of water
(w),
E = (K + L – G – H + Aw - ∆Q/∆T) / (ρw.λv)…………………….(2)
Measurement of all these energy fluxes ( inputs and outputs) and the
change in the energy stored in the water body during the time interval (t)
H = B*LE = B* ρw.λv*E……………………………..(3)
α : albedo (reflectivity)
at is largely a function of humidity and cloud cover and can be estimated
Conduction to Ground:
sediments is negligible.
• Heat storage in lakes significantly influences the timing of evaporation
in deep lakes. The annual peak evaporation may be out of phase with
data for surface temperature, air temperature and relative humidity are
needed. So, the same considerations for time averaging apply as in the
mass-transfer approach.
Applicability of the Energy-Balance Method:
Same kind of measurement related difficulties as in case of water-balance
method.
The terms Aw and Q are small especially with longer time periods and
t
hence neglected often.
Penman (or Combination) Approach:
K LH
E ..............(1)
w .v
We know, H K H .va .(Ts Ta )..........(2)
Sensible Heat
Also the slope of the SVP vs temperature curve at the air temperature
can be approximated as:
* *
es ea
.........(3)
Ts Ta
* *
K H .v a .( e s ea )
H ..........(4)
Penman Combination Equation
Lake Evaporation:
• In an actual water body (such as lake), the free-water evaporation is
adjusted to include the effects of advection and heat storage effects.
Pan Evaporation:
• Direct approach to estimate free-water evaporation, exposing a
cylindrical pan of liquid water to the atmosphere and to solve the
water-balance equation for a convenient time period ∆t (one day),
E W [ 2 1 ]......... ....( 29 )
Here, W is the precipitation during ∆t. , ν1 and ν2 are the storages at the
beginning and the end of ∆t, respectively.
• Precipitation is measured in an adjacent non-recording
rain gage. The storage volumes are estimated by
measuring the water level in a small stilling well in the
pan with a high-precision hook gage.
• The water surface is maintained a few centimeters below
the pan rim by adding measured amounts of water as
necessary.
• For special studies on lake evaporation, pans are kept in
the centre of a floating platform with dimensions large
enough to ensure stability and prevent water splashing
in.
Pan Coefficient:
• An evaporation pan has far less heat-storage capacity;
lacks surface or ground-water inputs or outputs;
• sides of the pan are exposed to air and sun. This results
in elevating the warm-season average temperature and
vapour pressure of the water surface of a pan compared
to that of a nearby lake.
to:
• light intensity;
.( K L ) a .c a .C at .e a* .(1 w a )
ET .......... ......( 11 )
w . v .( .(1 C at / C can )
Penman-Monteith Equation.