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One major change since the third edition has been our response to concerns
about the mathematical complexity of the material. We have not sacrificed
the mathematical rigour of the previous edition but we have tried in
numerous ways to make the mathematics more accessible. We have introduced
short commentaries into the text to remind the reader of the mathematical
fundamentals useful in derivations. We have included more worked
examples to provide the reader with further opportunities to see formulae in
action. We have added new problems for each chapter. We have expanded the
discussion on numerous occasions within the body of the text to provide
further clarification for or insight into mathematical results. We have set aside
Proofs and Illustrations (brief examples) from the main body of the text so
that readers may find key results more readily. Where the depth of presentation
started to seem too great in our judgement, we have sent material to
the back of the chapter in the form of an Appendix or to the back of the book
as a Further information section. Numerous equations are tabbed with www
to signify that on the Website to accompany the text [www.oup.com/uk/
booksites/chemistry/] there are opportunities to explore the equations by
substituting numerical values for variables.
One major change since the third edition has been our response to concerns
about the mathematical complexity of the material. We have not sacrificed
the mathematical rigour of the previous edition but we have tried in
numerous ways to make the mathematics more accessible. We have introduced
short commentaries into the text to remind the reader of the mathematical
fundamentals useful in derivations. We have included more worked
examples to provide the reader with further opportunities to see formulae in
action. We have added new problems for each chapter. We have expanded the
discussion on numerous occasions within the body of the text to provide
further clarification for or insight into mathematical results. We have set aside
Proofs and Illustrations (brief examples) from the main body of the text so
that readers may find key results more readily. Where the depth of presentation
started to seem too great in our judgement, we have sent material to
the back of the chapter in the form of an Appendix or to the back of the book
as a Further information section. Numerous equations are tabbed with www
to signify that on the Website to accompany the text [www.oup.com/uk/
booksites/chemistry/] there are opportunities to explore the equations by
substituting numerical values for variables.
One major change since the third edition has been our response to concerns
about the mathematical complexity of the material. We have not sacrificed
the mathematical rigour of the previous edition but we have tried in
numerous ways to make the mathematics more accessible. We have introduced
short commentaries into the text to remind the reader of the mathematical
fundamentals useful in derivations. We have included more worked
examples to provide the reader with further opportunities to see formulae in
action. We have added new problems for each chapter. We have expanded the
discussion on numerous occasions within the body of the text to provide
further clarification for or insight into mathematical results. We have set aside
Proofs and Illustrations (brief examples) from the main body of the text so
that readers may find key results more readily. Where the depth of presentation
started to seem too great in our judgement, we have sent material to
the back of the chapter in the form of an Appendix or to the back of the book
as a Further information section. Numerous equations are tabbed with www
to signify that on the Website to accompany the text [www.oup.com/uk/
booksites/chemistry/] there are opportunities to explore the equations by
substituting numerical values for variables.
i
i
CHAPTER 5
Complex Numbers
Complex numbers are usually introduced by considering a quadratic equation of
the type x? — x +1 = 0, where the quacratic formula gives
where i = /=Tis the imaginary unit. A number of the form a + ib, where @ and
are real numbers, is called a complex number. Ifa = 0, then x = ib is called an
imaginary number. The message here is that we must introduce imaginary numbers
in order to be able to solve quadratic equations in general. It shouldn't be surprising
that initially there was a great resistance to the introduction of complex numbers
it took many years for them to be accepted as legitimate members of our
jinary number” seems to convey a certain
and tha
‘number system, The very na
numbers.
ee of mysticism to 1
If complex numbers had arisen only with quadratic equations, then it might
have been easy to reject them by asserting that the equation x? — x + 1 = 0 has
no solutions. After all, we're probably comfortable saying that sin x = 2 has no
solution for real values of x. Historically, imaginary numbers were most puzzling
in the study of the solutions to cubic equations, Consider the cubic equation x? +
2x! x2 = 0. You can verify by inspection that this equation has three real roots,
1 and —2. Yet when you solve this equation using the standard (fairly messy)
formula for calculating the three Toots, square roots of negative numbers occur at
several intermediate steps. The final results are the three real roots, so itis apparent
that the occurrence of imaginary numbers doesn’t invalidate any of the formulas.
Eventually, mathematicians came not only Yo tolerate innaginary wmlbers WAG
cembrace them fully.You might wonder if more complicated polynomial equations (such as 17th
e equations) require the introduction of types of numbers “beyond” complex
jed nothing less than the fundamental theorem of algebra, which says that ever
degree polynomial equation, ayx" + ay-ix"-! +--+ ax + ay
0,
Complex Numbers and the Complex Plane
said in the introduction, a number ofthe form a +ib, where a and b are real
and i? = —1, is called a complex number. Usually, we write a complex
x +iy 6.)
is the real part of z and y isthe imaginary part, which we express as
x = Re(e) y = Im(z) (5.2)
add or subtract complex numbers by adding or subtracting their real and
parts separately. For example, if z) = 2+ 3i and 2» = 1 — 4i, then
2-1) +(3-(-4li
+n
3i) +30 ~ 41) = 4 4 6143 — 120 = 7-61
@ multiply complex numbers together, we simply multiply the two quantities
ls and use the fact that i? = —1, For example,
(2-3 +21) = 6 431-441 — 27?
=-44+71
ide complex numbers, it is convenient to introduce the complex con
2, which we denote by :* and form by replacing / by ~i. For example,
+ iy, then z* =x ~ iy. Note that a complex number multiplied by its
B conjugate is a real quantity
(r+ iy) =
pei
oot of z2* is called the magnitude or the absolute value of
|e}. Consider now the quotient of two complex numbers:chapter 5: Complex Numbers,
“This ratio can be written in the form x +iy if we multiply both the numerator and
the denominator by 1 — 2i, the complex conjugate of the denominator:
241 ( =) 4-31 43
142i \T=2 3
EXAMPLE 5-1
‘Show that
SOLUTION:
(2) -558
x+iy \x-ty, w+y
|
}
Because complex numbers consist of two pars, areal part and an imaginary
part, we ean representa complex number bya pointin two-dimensional coordinate
{stem where the real partis plotted along the horizontal (x) axisand the imaginary
partis plotted along the vertical (») axis, as shown in Figure 51. The pane of such
a figure is called the complex plane, If we draw a vector from the origin of this
Figure 5.1. Representation of figure tothe point: = (x.y), then the length of the vector, = («7 + 917i
companies = IVS eager able ale of: The angle a eves maker wih
the x axis is the argument of z.
‘The plane of this figure is called the
complex plane
EXAMPLE 5-2
Determine the curve in the complex plane that is described by [=~ 1
SOLUTION
Je Male D+ il alee IP +?
and so [z~ I| = 2 corresponds to
(-1pty=4
which is a crete of radius 2 centered at x = 1, y = 0 Figure 5.2), :
—
| “The addition of two numbers in the complex plane has a nice geometrical in-
terprettion. Figure 5.3 illustrates the addition ofz) = x1 +iy1 and zn =a +32
fees, Te peetn hae Dana tn anlar peda ees and 22, We say
(en ip +9? = 4hinthe complex plane. that the addition of z) and zp satisfies the, parallelogram law.to Figure 5.1, we see that we can represent a complex number < is
eos sin? 64)
cos +ir sind (55)
ye
1 from the origin to the point (x, y) and
tnd = 3.7)
id above, the angle 6 is called the argument of z and r is its magnitude,
denote these two quantities by @ = argz and r = ||. Equation 5.5 is
the polar form of |
+4 in polar form,
ESSOLUTION: ‘The magnitude of z is V2 and tané =
tre 5.4 shows, the angle 6 lies in
‘Thus, the polar form of < is
As Fig-
second quadrant, so 9 = 37/4.
VA (eos +isin®)
The Example above illustrates the fact that you must be aware in which quadrant
Bie angle lies. Ifyou use ahand calculator to evaluate tan~(—1), you'll get —7/4
Phe reason for ths is that tan~! 6 is a multivalued function (Problem S-3)
“Another way to express z = x +iy in terms of rand 0 is by using Euler’ formula,
elf = 050 +i sind 68
which is derived in Problem 5-14, Using Equation 5.8, we can express 2 as
r(cosd + i sin8) = re” 69)
complex numbers, 2) and
Figure 5.4
Figure 5.3. A geometrical
interpretation ofthe addition of two
‘The complex number
in polar form.Chapter 5: Complex Numbers
EXAMPLE 5-4
Show that e°* = cos# — i sin@ and use this result and the polar repre-
sentation of z to show that |e!| = 1
SOLUTION: To prove that e°! = cos ~ i sind, we use Equation 5.8
and the fact that cos is an even function of 6 [cos(—#) = cos] and that
sin is an odd function of @ (sin(~#) = — sin 6]. Therefore,
e-"9 = cos(—6) + i sin(—#) = cos 6 — i sind E
Furthermore,
(cos @ +1 sin8\(cos ~ i siné))
(cos? 8 + sin* 8)!
EXAMPLE 5-5 bes
Bypess y= 1-0 and zy = 1 ~1 in terms of Euler formula ES
Ss
SOLUTION: In both cases, r = v2. The point z = I + / lies in the first ee
tan'(L
n/4,and 3
a= vier" :
have the same value of y/x. Once again, we see
that you must be aware in which quadrant the angle 6 lies.
Multiplying and dividing complex numbers is easy in polar form:
nize = (rie! yrne
For example, the product of z) and z2 in Example 5-5 is ziz2 = 2e%*
2¢'/2 = —2i and their ratio is 21/22
‘We can use the polar form of complex numbers to derive many trigonometric
identities, For example, start with
eaeb = gitar‘Unapter 5: Complex Numbers
and write
(cose + i sina) (cos B +i sin) = cos(a +A) +isin(a + 6)
Expand the left side and equate the real and imaginary parts of both sides to get
cos. cos B — sina sin = cos(a +B)
sina cos B + cosa sin = sin(a +A)
‘The expression e!® occurs frequently in physical applications. Because =
cos wt +i sinat, this expression has the physical interpretation of a unit vector (a
vector whose length is one) that rotates about the origin in the complex plane in @
counterclockwise direction with a frequency of w radians per second (Figure 5.5).
Given this interpretation, e~' canbe viewed asa unit vector rotating ina clockwise
direction.
‘We can also use Euler's formula to derive the formulas (Problem 5-10)
(5.10)
oaee
sind = SF and co ?
‘These two formulas have anice geometrical interpretation. Consider cos ot =
(€% + e-lst)/2, As we said above, 0/2 may be viewed as a vector rotating in
the complex plane in a counterclockwise direction and e~'™'/2 may be viewed
as one rotating in a clockwise direction, as shown in Figure 5.6. At ¢ = 0, the
sum of the two vectors points @ unit length along the positive real axis. AS f
evolves, the two vectors rotate in opposite directions in such @ way that their
‘vertical components cancel and the sum of their horizontal components oscillates
back and forth between +1 and —1 with a frequency of w radians per second,
according to cost
We can use Equations 5.10 to derive trigonometric identities. For example,
sina cos 8 =
1 1
5 sind +B) + 5 singe — B)
‘We can also use Equations 5.10 to evaluate integrals involving sin.x or cos x
i
EXAMPLE 5-6
Evaluate
tm [Cetsnea e>o
by using Equation 5.10.
589
Figure 5.5, The expression e* has the
physical interpretation of a unit veetor
that is rotating about the origin in a
counterclockwise direction at a
frequency of w radians per second,
Figure 6.6. Geometrical
{interpretation ofthe expression
concor = (et 4 2/2,Chapter 5: Complex Numbers
SOLUTION:
I=
~4(4--4)-2
i ati) ~ date =
‘We can evaluate / in Example $6 another way. Because e!"
econo
[Ce sneas=im [eng
= cost +i sint,
=im(—)
This procedure gives us
as a by-product.
“oosrdt = Re [ ee—ay =Re(
EXAMPLE 5-7
Summations such as
50) = cosnd
‘occur in group theory, crystallography, and optics. Derive a closed ex-
pression for S()
SOLUTION: We express cos nd as (e+ e~!)/2 and use Equation 3.2
with x =e, Therefore, we have
2( — cos)
where in getting to the last line we combined the two terms and used
Equation 5.10 several times (see Problem 5-24),
" I‘Chapter 5: Complex Numbers 4
Problems.
5-1, Find the real and imaginary parts of the following qua
A-P Her Ere — g) (VI+AEM?
$2, rmx + Diy, then find
(@) Re(et) (6) Re(e!)—() Im?) (A) Re(ez*)_—_(@) Imbez*)
5-3. Determine the value of tan“! @ for te folowing complex numbers:
@-1-i W-14#i WI-i =i
‘5-4. Express the following numbers in the form re
6 )4- VBI 1-2 AHF
5-5, Express the following complex numbers inthe form x + iy
Gee) GED Ge) eH (4) eit 4 nl
5-6, Discuss the statement that multiplying @ complex number by has a geometric
inuerpretation of rotating the number by 90° counterclockwise inthe complex
plane,
5-7. Prove that
5-8. Show that Re
5-9, Determine the region inthe complex plane described by |<
5-10. Show that cos = (e!¥ + e~!#)/2 and that sind = (e” ~ e°i8)/2i
—1. Comment on the nature ofthe numbers in tis relation.
(e+ 2")/2 and that km (2) =
+13
5-11, Use Equation 5.8 1 derive the formula of de Moivre,
cosnd +i sind = (cos0 + i sind
Use the formula of de Moivee to derive the trigonometric identities
£0828 = cos? @ ~ sin’ @
sin26 = 2sind cose
£0830 = cos! — 3c0s0 sin? A = 40s! — 30s
sin30 = 3cos?@ sing — sin'@ = 3sine — 4sin’
5-12, Evaluate (a) (1-47)! and (b) (1 =".
5-13, Consider the set of functions
1
(6) =
i v2;
First show that
~ for all values of m #0
[voun{ go ea
Now show that
O30)8(0)d6
ieee62 ‘Chapter 5: Complex Numbers
5-14. This problem offers a derivation of Bulers formula. Start with
110) = In(cos0 + isiné) Oy
Show that
af
: ei 2
fa @
[Now integrate both sides of equation 2 to obtain
{(@) =In(e0s0 + isin®) = 18 +6 @
‘where ¢ i a constant of integration, Show that ¢ = 0 and then exponentate
equation 3 to obtain Euler's formula
5-15. Wecan use Euler’ formula and the formulas of de Moivre (Problem 5-11) to
evaluate @ host of integrals, First show that
[eedeno nasa,
Use this result to show that
[Now use the same method to show that
[ coseae = [ satoao=
(See the following problem.)
5-16. Here is another way to evaluate cos d9 and sin #d@ (ae the previous
oblem). First write cos@ as
"Now use the binomial theorem inthe form
2 en)! nee
: Ct aaa
to show that
ee ent
cos" 40 = 7 OO
[ Bae
Use a similar approach to show that
: ae en!
sin 69 m= 0,1,2,
i mF
O14
S17. Use Euler's formula to show that
cosix = coshx and sinix =/sinhx
"Now show that
sinhix = isinx and coshix = cosplex Numbers.
Buler’s formula to show that
cosacos 8 = B)
L
sinarsinl = 5 cos(a ~ 9) ~ 5 costar 6)
1. The equation x" = 1 has
is problem shows how to find the
Wedistnct roots, called the N roots of unity,
EN roots of unity. We shall see that some of the roots turn out to be complex, so
Tets write the equation as 2" = 1. Now let z = e and obtain e'
= lor
cos NO +i sin NO = 1
[Now argue that N@ = 2m, where m has the W distinct values D,1,2..... N= 1
or thatthe N roots of unity ate given by
a Neat
‘Show that we obtain z = J and z= 1 for N= and N= 2, respectively, Now
show that
- and =
3 279
for N = 3. Show that each of these roots is of unit magnitude, Plot these three
‘roots inthe complex plane. Now show that z = 1, i, ~1,and ~i for N = 4 and
that
for N = 6, Plot the four roots for N= 4 and the six roots for N= 6 in the
complex plane. Compare the plots for WV = 3, N = 4, and W’ = 6, Do you seea
pattern?
5-21. Using the results ofthe previous problem, ind the
2 distinct roots of
5-22, The Schwarz inequality says that if) = x, + iy, and zy = #2 + iy then
|. To prove tis inequality, start with its square
aunt yin S lel Le
(mst yo? < + yDad +9)
Now use the fact that (x;y aay)? > Oto prove
5-23, Starting with O° e-#* dx = J
‘nto real and imaginary parts to show that
creer:
(1 = fy-VZand separate the result
5-24. Show that