(1) Who proposed the principle of uncertainty ?

(A) Heisenberg

(B) Rutherford

(C) Max Plank

(D) Einstein

Ans: Heisenberg

(2) What is the bond order H2 molecular?

(A) 1

(B) 0

(C) 1.5

(D) 2.5

Ans: 1

(3) The values

--------.
of Ψ at all equidistant points at a distance of r from the nucles is

(A) Opposite

(B) Equal

(C) Unequal

(D) Maximum

Ans: Equal

(4) The description of molecular orbitals of a molecule is similar to the description of

atomic orbitals of atoms. This statement is explained by --------.

(A) Mulliken and Hund

(B) Goudsmitt and Uhlenbeck
(C) Rutherford and Bohr
(D) Devison and Germer

Ans: Mulliken and Hund

(5) Total energy of an electron for an atom containing more than one electron is
decided by --------.

(A) n +1
(B) n -1
(C) 1 -n
(D) - (n + 1)

Ans: n +1

(6) SF6 possesses ------- type of geometry.

(A) Octahedral

(B) Trigonal bipyramidal

(C) Square planer

(D) Trig pyramidal

Ans: Octahedral

(7) What is constructed on the basis of wave nature of a moving electron ?

(A) Simple microscope

(B) Electron microscope
(C) Telescope

(D) Microscope

Ans: Electron microscope

 +
(8) Bond order of He2 is -------.

(A) 1/2

(B) 1

(C) 0

(D) 1.5

Ans: 1/2

(9) For l = 2, value of m is ------.

(A) m= +2, +1,0,-1,-2

(B) m= +1,0,-1
(C) m= +3,+2,+1,0,-1,-2,-3
(D) m =0

Ans: m= +2, +1,0,-1,-2

(10) In
PCl5 due to three P-Cl bonds remaining in the same plane angle between
them is --------.

0`
(A) 90

0
(B) 45

0
(C) 120

0
(D) 180

0
Ans: 120
(11) Who studied the effect of electrons released from a metal ?

(A) Bohr

(B) Albert Einstein

(C) Max Plank

(D) Rutherford

Ans: Albert Einstein

(12) From the following which does not form H-bond ?

(A) NH3

(B) CH4

(C) H2O

(D) HF

Ans: CH4

(13) All hybrid orbitals are similar in which respect ?

(A) Shape of orbitals

(B) Energy

(C) Number of neutrons

(D) Number of protons

Ans: Energy

(14) Models of structure of atom given by which scientists does not explain the
stability of atom ?

(A) Davisson and Gramer

(B) Hugenes and Max plank
(C) Rutherford and Bohr
(D) Heisenberg and William Hamilton

Ans: Rutherford and Bohr

(15) Who studied spectra of Hydrogen atom ?

(A) Bohr

(B) Max Plank

(C) Einstein

(D) Heisenberg

Ans: Bohr

(16) Collection of water in animal and plant cells is due to which bond ?

(A) Chemical bond

(B) Hydrogen bond
(C) Metallic bond
(D) Covalent bond

Ans: Hydrogen bond

(17) NH3,H2O and Hf in their liquid states possess strong ------- bond.

(A) Metallic bond

(B) Chemical bond
(C) Hydrogen bond
(D) Covalent bond

Ans: Hydrogen bond

 + .
(18) H2 has ------ bond length than H2

(A) More

(B) Less

(C) Equal

(D) Maximum

Ans: More

(19) From the following molecules whose bond order is 1 ?

(A) F2

(B) Ne2

(C) O2

+
(D) H2

Ans: F2

(20) Which scientists stated that electrons have quantised spin angular momentum ?

(A) Rutherford and Bohr

(B) William Hamilton
(C) Albert Einstein

(D) Goudsmit and Uhlenbeck

Ans: Goudsmit and Uhlenbeck

(21) Boiling point of H2O is greater than that of H2S because of -------.

(A) H-bond
(B) more molecular weight
(C) Covalent bond
+
(D) Covalent bond with n ion

Ans: H-bond

(22) σ
molecular orbitals possess --------
of symmetry.

(A) Curve

(B) Cylindrical

(C) Spherical

(D) Dumb bell shaped

Ans: Cylindrical

(23) Write the value of one Einstein.

NE = NC
(A) hλ

NE = Nhc
(B) λ

NE = λn
(C) C

NE = hc
(D) λ

NE = Nhc
Ans: λ
(24) Vander Waals force of attraction increasing on increasing which factor ?

(A) Number of electrons

(B) Distance

(C) Protons

(D) Neutrons

Ans: Number of electrons

(25) Probability of finding the electron in a nodal plane is --------.

(A) 1.0

(B) + 1/2

(C) Zero

(D) + 1/4

Ans: Zero

(26) What is decided by angular momentum quantum number ?

(A) Shape of orbitals

(B) Energy of an electron
(C) Value of magnetism
(D) number of orbitals

Ans: Shape of orbitals

(27) Aboutthe structure of atom, if an electron is seen as a particle and also as a

wave, a new horizon would be in view, who explained this ?

(A) Albert Einstein

(B) Max Plank
(C) Erwin Schrodinger
(D) Rutherford

Ans: Erwin Schrodinger

(28) What will be total probability of finding the electron in all the space around the
nucleus ?

(A) One

(B) Maximum

(C) Less

(D) Zero

Ans: One

2 2
(29) Which atom possesses 1s 2s 2px'2py'2pz' configuration ?

(A) N

(B) F1

(C) O

(D) Ne

Ans: N

3
(30) PCl5 due to its sp d hybridisation possesses --------- geometry.

(A) Square planar

(B) Trigonal bipyramidal
(C) Octahedral

(D) Rectangular planar

Ans: Trigonal bipyramidal

(31) Whichquantum number determines the total energy (En) of an electron of an
atom of and ions ?

(A) Principal quantum number

(B) Angular momentum quantum number
(C) Magnetic quantum number
(D) Spin quantum number

Ans: Principal quantum number

(32) Van der Waals force of attraction exists upto a distance of --------.

0
(A) 3.5 A
0
(B) 4.5 A
0`
(C) 2.5 A
0
(D) 1.5 A

0
Ans: 4.5 A

(33) In PCl5' P in its excited state has ------

number of half filled Sub shells.

(A) Four

(B) Three

(C) Six

(D) Five

Ans: Five
(34) Which scientists using a crystal of nickel showed that electrons in motion could
be diffracted like
x-rays ?

(A) Rutherford and Bohr

(B) De Broglit and Plank
(C) Davisson and Garmer
(D) Einstein and Plank

Ans: Davisson and Garmer

3+
(35) Mention the shapes of [CO(NH3)6] molecule ?

(A) Octahedral

(B) Trigonal bipyramidal

(C) Square planar

(D) triangular pyramidal

Ans: Octahedral

(36) Write
the equation showing the relation between photon of a light and its
frequency.

(A) E=hv

(B) E=NV

h
(C) E= v

v
(D) E= h
Ans: E=hv
(37) What is the electronic configuration of H2 molecule ?

(A)
(σ 15 )2
(B)
(σ15 )2(σ*15 )2
(C)
(σ15 )0(σ*15 )2
(D)
(σ15 )2(σ*15 )1

Ans:
(σ15 )2
(38) Which is the correct for the number of solutions Ψ in Schrodinger equation
for n = 2 ?

(A) 1

(B) 2

(C) 3

(D) 4

Ans: 4

(39) Values of bond angle in PCl5 are -----.

0 0
(A) 90 and 120
0
(B) 90

0
(C) 109 28'
0
(D) 180
 0 0
Ans: 90 and 120

(40) Bond order of which molecule is Zero ?

(A) Ne2

-
(B) F2

+
(C) O2

-
(D) N2

Ans: Ne2

(41) Evaporation of water is ------- at ordinary temperature because of H- bond.

(A) Fast

(B) Medium

(C) Slow

(D) Negligible

Ans: Slow

(42) According to MO theory number of electrons in antibonding molecular orbital

of O2 is ------.

(A) 2

(B) 4

(C) 6

(D) 0

Ans: 6
 3+
(43) What is the type of hybridisation in [Co(NH)3)6] ?

3
(A) sp d
2 3
(B) d sp
2
(C) sp

3 3
(D) sp d

2 3
Ans: d sp

(44) Which equation is correct from the following ?

∂2 Ψ+ ∂2 Ψ+ ∂2 Ψ+8π2m ( E −V ) Ψ=0
(A)
∂x 2 ∂y 2 ∂z 2 h2
∂2 Ψ+ ∂2 Ψ+ ∂2 Ψ+8πm2 ( E −V ) Ψ=0
(B)
∂x 2 ∂y 2 ∂z 2 h

∂2 Ψ+∂2 Ψ+∂2 Ψ+8πm ( E −V ) Ψ=0

(C)
∂x 2 ∂y 2 ∂z 2 h

∂2 Ψ+∂2 Ψ+∂2 Ψ+8πm ( E −V )Ψ=0

(D)
∂x 2 ∂y2 ∂z 2 h2

∂2 Ψ+ ∂2 Ψ+ ∂2 Ψ+8π2m ( E −V ) Ψ=0
Ans:
∂x 2 ∂y 2 ∂z 2 h2

(45) In N2 molecule number of electrons in bonding molecular orbitals is --------.

(A) 2
(B) 4

(C) 14

(D) 10

Ans: 2

(46) What is the type of hybridisation in PCl5 ?

3
(A) sp d
3 2
(B) sp d
3
(C) sp

2
(D) sp

3
Ans: sp d

(47) If frequency of radiations is different, then their --------- is different.

(A) Entropy

(B) Kinetic energy

(C) Energy

(D) Electric energy

Ans: Energy

(48) 4s orbital possesses --------- nodes.

(A) 4

(B) 3

(C) 0
(D) 2

Ans: 3

(49) What type of hybridisation takes place in SF6 ?

3
(A) sp

3 2
(B) sp d
3
(C) sp d
2
(D) sp

3 2
Ans: sp d

(50) From the following which is diamagnetic ?

+
(A) He2

+
(B) H2

(C) H2

-
(D) H2

Ans: H2

(51) Any attempt to reduce uncertainty of one kind increases the uncertainty of other
kind is indicated by which equation ?
 ∆x × ∆p ≥ h
(A) 4π

(B)
∆x × ∆p≤ 4hπ
(C)
∆x × ∆p= 4hπ
(D)
∆x × ∆p> 4hπ
∆x × ∆p ≥ h
Ans: 4π

(52) Write the formula to find out Bond order.

1 ( N − Na )
(A) 2 b
1 ( Na − N )
(B) 2 b

(C)
2( Nb − Na)
(D)
− 12( Nb − Na)
1 ( N − Na)
Ans: 2 b
(53) From the Schrodinger wave equation which quantum number does not evolve ?

(A) s

(B) n

(C) m

(D) l

Ans: s

(54) In
PCl5 two chlorine atoms arranged one above the other, the angle between
them is -------.

0
(A) 90

0
(B) 120

0
(C) 180

0
(D) 45

0
Ans: 180

(55) How many total orbitals are present if the value of 'n' is 3 for that energy level ?

(A) 3

(B) 6

(C) 9

(D) 27

Ans: 9

(56) Which symbol is used to indicate Bonding Molecular Orbitals (BMO) ?

(A) σ π and

(B) σ σ*and

(C) π π*and

(D) σ* π and

Ans: σ π and

(57) Magnitude ofVander Waals force of attraction being less than --------- it is
hidden under the effects of other attractive forces.

⋅ -1
(A) 10 k.calorie mole

⋅
-1
(B) 20 k.calorie mole

⋅
-1
(C) 25 k.calorie mole

⋅
-1
(D) 15 k.calorie mole

⋅
-1
Ans: 10 k.calorie mole

(58) Who proposed the principal of wave nature of light ?

(A) Hugenes

(B) Gramer

(C) Max Plank

(D) Rutherford

Ans: Hugenes
 -2
(59) What is the type of hybridisation in [Ni(CN)4] ?

2
(A) dsp

3
(B) sp d
3
(C) dsp

2
(D) d sp

2
Ans: dsp

0
(60) Because of hydrogen bond at 4 C temperature density of water is ------.

(A) Zero

(B) Less

(C) Maximum

(D) More

Ans: Maximum

(61) Which symbol is used to indicate Anti Bording Molecular Orbitals (ABMO) ?

(A) σ π and

(B) σ* π* and

(C) σ* π and

(D) σ π* and
Ans: σ* π* and

(62) Cotton fabrics do not dry faster than synthetic fabrics due to --------- ?

(A) Condensation

(B) Absorption

(C) H-bond

(D) Evaporation

Ans: H-bond

(63) From the following which orbitals are possible ?

(A) 1p, 3f
(B) 2s, 2p
(C) 1p, 2s
(D) 2p, 3f

Ans: 2s, 2p

(64) Weak attraction existing between molecule - molecule is described by which

scientist ?

(A) Einstein

(B) Max Plank

(C) Heisenberg

(D) Vander Waals

Ans: Vander Waals

(65) Spin quantum number bears which two values ?

(A)
+ 12 and 1

(B)
− 1
2 and 0

(C)
− 12 and + 12

3 and − 2
2 1
(D)

Ans:
− 12 and + 12

(66) Write the relation between energy of a photon and its momentum according to
Einstein's theory of relativity.

(A)
E = PC
E = Pλ
(B)

(C) E=C.p

(D)
E = Pcλ
Ans: E=C.p

(67) Write the matter wave equation.

λ= h
(A) mv
E = hc
(B) λ
(C)
λ = hc
E
λ = Eh
(D)

λ= h
Ans: mv
(68) Hydrogen bonds are formed in protein molecules of living animals due to which
group present in proteins ?

(A) -COOH

(B) -CO-NH-

(C) COOR

(D) -CO-

Ans: -CO-NH-

(69) Which orbital is obtained for quantum numbers n = 2, l = 1, and

m = -1 ?

(A) 2pz

(B) 3dxy

(C) 2s

(D) 3py

Ans: 2pz

(70) Total number of electrons in H2 molecule is ----------.

(A) 1
(B) 0

(C) 2

(D) 4

Ans: 2

(71) If n=3 then what is the value of quantum number 1 ?

(A) 0

(B) 0,1

(C) 0,1,2

(D) 1,2

Ans: 0,1,2

(72) He2 molecule does not exist because its bond order is --------.

(A) 1

(B) 0

(C) -1

(D) 0.5

Ans: 0

(73) Write the value of E for the hydrogen atom and ions containing only one
electron.

En = −2πn22mZe
h2
4
(A)

En = −2πm2 Z 2e4
n2 h2
(B)
 En = −2πn22mZ
h2
2e 4
(C)

En = −2πnmZe
2h
2
(D)

En = −2πn22mZ
h2
2e 4
Ans:

(74) If l = 3 and n = 5 then which orbital is obtained ?

(A) 3f orbital
(B) 4f orbital
(C) 6f orbital
(D) 5f orbital

Ans: 5f orbital

(75) Which scientist imagined matter waves ?

(A) De Broglie

(B) Rutherford

(C) Bohr

(D) Einstein

Ans: De Broglie

(76)The values of principal quantum number are positive integers except

________.

(A) One
(B) Two

(C) Zero

(D) Three

Ans: Zero

(77) From the following which molecules have bond order zero ?

(A) H2

(B) He2

(C) O2

(D) N2

Ans: He2

(78) Which orbital possesses maximum energy ?

(A) 3d

(B) 4f

(C) 3p

(D) 2s

Ans: 4f

(79) Bond energy of hydrogen bond is

--------.

(A) 30 k.joule/mole
(B) 44 k.joule/mole
(C) 40 k.joule/mole
(D) 45 k.joule/mole
Ans: 40 k.joule/mole

(80) Whatis the attraction resulting between covalently bonded positively charged
hydrogen and electronegative elements having non-bonding electron-pair called ?

(A) Hydrogen bond

(B) Chemical bond
(C) Covalent bond
(D) Double bond

Ans: Hydrogen bond

(81) What is the bond order of N2 ?

(A) 2

(B) 3

(C) Zero

(D) 4

Ans: 3

(82) Among the groups 15, 16 and 17 the hydrides of their first elements show high
melting and boiling points supporting the presence of -------.

(A) H-bond

(B) Vander Waals bond

(C) Metallic bond
(D) Covalent bond

Ans: H-bond