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Creating tomorrow’s solutions

SILANES I ORGANOFUNCTIONAL

For Powerful Connections


You’ve never worked like this
with silanes
OUR Geniosil ® TRADEMARK

WACKER organofunctional silanes, WACKER has been actively researching Contents


marketed under the trademark and developing organofunctional silanes
GENIOSIL®, include our established for decades. Chemically and technologi- The GENIOSIL® Trademark 3
standard silanes as well as numerous cally, they are closely related to silicones, Organofunctional Silanes 4
specialty silanes that will be of use which have always constituted one of Chemical Bonding to
in a variety of new application areas. our core businesses. Our experience in Organic Polymers 6
these fields, together with our expertise The “a Effect” 8
We encounter industrial products con- in organic fine chemicals, enables us GENIOSIL® für Adhesives and
taining organofunctional silanes every to continuously develop innovative Sealants 12
day, and without them, the world as processes and products in these key Product Overview GENIOSIL®
we know it would be hard to imagine. technologies. Organofunctional Silanes 16
As an important component of paints Product Overview
and varnishes, organofunctional silanes Today, WACKER produces a broad range Non-functional Silanes 18
ensure that they adhere to a variety of organofunctional silanes and markets WACKER at a Glance 19
of substrates and last for many years. them under the GENIOSIL® trademark.
Adhesives containing silanes can replace The product portfolio includes not only
rivets and bolts, while silane-modified the established, standard products, but
fillers and glass fibers reinforce plastics, also novel molecules with unrivaled prop-
thus making them suitable for a huge erties. These open up completely new
range of applications. fields of application.

This brochure provides an overview of


the organofunctional silanes produced
by WACKER. Special importance is given
to the a-silanes.

WACKER and GENIOSIL® are registered trademarks of


Wacker Chemie AG.

3
Organofunctional silanes –

Organofunctional silanes act as Fig. 1: Organofunctional silanes as molecular bridges


molecular bridges between organic
polymers and inorganic materials. Reactive Hydrolyzable
organofunctional alkoxy group
group

Organic X Si OR HO Inorganic
polymer substrate

X Si O

Organofunctional silanes are hybrid com- Bonding to the inorganic material is


pounds that combine the functionality effected by way of the hydrolyzable
of a reactive organic group and the inor- functional groups –OR. The most common
ganic functionality of an alkyl silicate in of these are the methoxy and ethoxy
a single molecule. This special property substituents. The silane’s alkoxy groups
means they can be used as molecular hydrolyze in the presence of moisture
bridges between organic polymers and to form reactive silanols. These either
inorganic materials react with themselves to form oligomeric
siloxanes, or else react with the inorganic
The choice of functional group X will substrate. Since hydroxyl groups are
depend ultimately on the nature of the present on almost all mineral and metallic
organic polymer. Commercially avail- surfaces, the silane will generally undergo
able silanes contain amino, epoxy and a condensation reaction and bond cova-
glycidoxy, mercapto and sulfido, isocya- lently to the inorganic substrate.
nate, methacryloxy and vinyl groups.
How these functional groups bind to The bridge-building property of organo-
the organic polymer is described in functional silanes is particularly important
detail on pages 6 and 7. in three application fields:
•• Adhesion promotion
•• Surface modification
•• Polymer crosslinking

4
MOLECULAR BRIDGES FORGE
STABLE BONDS
Fig. 2: Adhesion promotion Fig. 3: Surface modification Fig. 4: Crosslinking

Coating Filler Polymer Polymer

R X
X X X O O
O O
O O O Si
O X
Si O Si
HO Si O Si O Si OH O Si O O

O O O Si HO Si
OR
X
X
X
X
Substrate Polymer Polymer

Adhesion Promotion Surface Modification Crosslinking

Organofunctional silanes enhance adhe- Organofunctional silanes improve com- Organofunctional silanes function as
sion of coatings, adhesives and sealants patibility and enable inorganic fillers to crosslinkers for organic polymers, e. g. in
to a wide variety of substrates. bond chemically to organic resins. moisture-curing adhesives and sealants,
in paints and varnishes and in thermo-
plastics.

5
CHEMICAL BONDING TO
ORGANIC POLYMERS
The particular function and the nature Fig. 5: Endcapping
of the organic polymer will determine
the choice of silane as well as the way
in which it bonds chemically to the
polymer.

Functional silane Functional polymer

Fig. 6: Radical grafting


Polyolefin + peroxide

Vinyl- or methacryloxysilane

The mechanisms by which organofunc- Endcapping


tional silanes bond to organic polymers
are as varied as the polymers themselves. In this case, the silane’s organofunctional
The most important mechanisms are: group reacts with a terminal functional
•• Endcapping group of the precursor by forming a
•• Radical grafting covalent bond (Fig. 5).
•• Copolymerization
The choice of silane will depend on the
All three methods produce silane-modi- polymer. The following combinations are
fied polymers. These polymers can then common:
form stable siloxane bonds via the cross- •• Aminosilanes + NCO-terminated
linking of the remaining Si-alkoxy groups. polyurethanes
Likewise, they can also bond to fillers or •• Aminosilanes + acrylic/methacrylic
other inorganic surfaces. polymers
•• Isocyanatosilanes + OH-polymers
Table 1 is a guide showing which silanes (polyethers, polyesters, polyurethanes)
produce the best results in the various •• Amino- and epoxy/glycidoxysilanes
polymer systems. + epoxy resin precursors
•• Aminosilanes + phenol resin precursors

6
Fig. 7: Copolymerization Table 1: Compatibility of polymers and organofunctional silanes
Polymer Organofunctional group on silane
Polyacrylate Amino
C CH2 C CH2
Epoxy
Methacrylic
CO2R Vinyl
Si Butyl rubber, neoprene, phenolic resin, Amino
Vinyl- or
Acrylate/ methacryl- polyamide, polyether, epoxy resin, melamine Epoxy
methacrylate oxysilane Polyester Methacrylic
Polyolefin Amino
Vinyl
C CH2 C CH2 Polysulfide Epoxy
Vinyl
CO2R Polyurethane Amino
Epoxy
Si Isocyanate
EPR, EPDM, SBR Vinyl, Mercapto

Radical Grafting

Unsaturated silanes, such as vinyl-


or methacryloxysilanes, can be made
to bond to polymer chains via a radical
grafting reaction (Fig. 6):
•• Vinylsilanes + polyolefines
•• Methacryloxysilanes + polyolefines
•• Methacryloxysilanes + unsaturated
polyesters

Copolymerization

The polymerizable organofunctional


groups of a silane (e. g. methacryloxy-
or vinylsilane) are incorporated into
the chain during production of the
polymer (Fig. 7):
•• Methacryloxysilanes + monomeric
acrylates/methacrylates or styrene
•• Vinylsilanes + monomeric acrylates/
methacrylates or ethylene/
vinyl acetate

7
THE LENGTH OF THE BRIDGE DETERMINES
THE REACTIVITY – The “α EFFEcT“
The nature of the “bridge construction” Fig. 8 Fig. 10
determines the application proper-
ties. a-Silanes, that is, silanes with a OR OR
methylene bridge instead of the usual
propylene spacer between the silicon X (CH2)3 Si OR X CH2 Si OR
atom and the functional group, are
highly reactive and accordingly have OR OR
huge application potential.
Fig. 9 Fig. 11

CH3 CH3

X (CH2)3 Si OR X CH2 Si OR

OR OR

Most established organofunctional sila- WACKER’s strength is on specialty silanes.


nes are trialkoxysilanes with a propylene The name “specialty silane” implies first,
spacer between the silicon atom and the a special choice of highly reactive orga-
functional group X (Fig. 8). Dialkoxysila- nofunctional groups (e.g. isocyanate)
nes (Fig. 9) with a propylene spacer are and second, a relatively novel molecular
also available but are of little practical structure, as emphasized by the methyl-
importance compared with trialkoxy- ene spacer or bridge that replaces the
silanes. familiar propylene bridge.

The most important functional groups X These innovative silanes, referred to as


are the amino, glycidoxy, sulfur and meth- a-silanes (Figs. 10 and 11), display new
acryloxy groups. These standard silanes, properties. Their most important prop-
of which the GENIOSIL® product portfolio erty is without doubt the extremely high
includes a broad range, dominate today’s reactivity of the Si-alkoxy groups. This
market. results from electron interaction of the
functional group X with the Si atom, and
it can only be observed in the presence
of a spacer. The phenomenon is accord-
ingly referred to as the “a effect.”

8
Fig. 12: Schematic diagram of the “a effect” Practical Consequences of the
“a Effect”

The increased reactivity of the alkoxy


groups in a-silanes not only opens up
new fields of application for which stan-
dard g-silanes are insufficiently reactive
(e. g. for fast-curing adhesives), but
also renders them interesting building
blocks that offer many advantages in
established fields of application.

For example, the “a effect” reduces the


difference in reactivity between methoxy-
silyl and ethoxysilyl groups, thus making
it possible to replace methoxysilane by
ethoxysilane without impairing the appli-
Since highly reactive silanes are The “a Effect” cation properties. This is particularly im-
needed for a wide variety of applications, portant in applications where the release
WACKER has developed a specific An electronegative donor such as nitro- of methanol, which has a higher order of
portfolio of organofunctional a-silanes. gen or oxygen that is in the a position toxicity than ethanol, is problematic.
Besides aminosilanes, it includes relative to the silicon atom, i. e. is sepa-
silanes with methacryloxy, isocyanate rated only by a methylene bridge, acti- Another important advantage of a-silanes
and carbamate functional groups. vates the alkoxy groups on the silicon is that the bifunctional compounds are
atom. These groups demonstrate greater also highly reactive, whereas dialkoxy-
In contrast to established standard sila- reactivity towards nucleophiles, as seen silanes with a propylene spacer are not
nes with a propylene spacer (g-silanes), by their faster hydrolysis upon admission reactive enough for most applications.
both trialkoxy (Fig. 10) and dialkoxy of water. Especially in the field of flexible adhe-
a-silanes (Fig. 11) are extremely impor- sives and sealants, as well as coatings,
tant building blocks. The “a effect” can be described very bifunctional crosslinker silanes have
graphically using a-aminoalkylsilanes as great potential since they permit selective
The next chapter explains the “a effect” an example: back-bonding of the nitro- adjustment of the crosslinking density.
and the huge potential offered by gen’s free electron pair to the silicon atom
a-silanes. (Fig. 12) weakens the Si-O bonds. This
back-bonding becomes stronger with
increasing basicity of the nitrogen. The
latter, in turn, can be varied selectively via
the organic substituents on the nitrogen
atom. The “a effect” can be determined
quantitatively by investigating the hydroly-
sis kinetics of such silanes.

9
Hydrolysis of Unsaturated Silanes Fig. 13: Rate of hydrolysis of unsaturated silanes (acetone/water mixture, pH 4)

Unsaturated silanes – in particular vinyl-


and methacryloxysilanes – can be incor-
porated via copolymerization or grafting
reactions into polymer chains and are
therefore important crosslinkers for orga-
nic polymers (p. 6/7). In the presence of
water, the silane’s alkoxy groups hydro-
lyze to form silanol groups. Conden-
sation reactions between these silanol
groups produce a siloxane network.
Reaction rate
The speed of hydrolysis is influenced
strongly by ambient conditions, in par-
ticular pH and temperature, and also to
a considerable extent by the nature of
the silane. Fig. 13 shows the results of The result is impressive: the new a-meth- The “a Effect“ in Adhesives and
tests on the hydrolysis kinetics of three acryloxytrimethoxysilane reacts 20 times Sealants
different methacryloxysilanes and a faster than its g counterpart. The latter
vinyl-silane. The tests were conducted is widely used in paints and varnishes The “a effect” is just as pronounced in
in a water/acetone mixture at pH 4 at as a crosslinker. Even the bifunctional adhesives and sealants as it is in the
room temperature and demonstrate a-methacryloxysilane hydrolyzes 14 times hydrolysis of methacryloxysilanes. If, for
the speed at which the concentration faster than the standard methacryloxy- example, a polyether polyol is reacted
of a monomeric silane decreases under silane. Its reactivity thus corresponds with various alkoxy silanes bearing NCO
such conditions. approximately to that of vinyltrimethoxy- functional groups, thus forming silane-
silane, which is known for its high reactivity terminated polymers (cf. p. 14: STP tech-
and therefore commonly used as a water nology), the different reactivity of each
scavenger in adhesives and sealants. of the silanes becomes readily evident
when the polymers are used in standard
These experiments clearly demonstrate sealant formulations and the skin-forma-
the impact of the “a effect” on the tion times are determined.
reactivity of silanes. The objective now
is to capitalize on this effect in the form of
corresponding product characteristics.

10
Fig. 14: Skin-formation times of silane-terminated polyethers in adhesive formulations The key advantages of GENIOSIL®
a-silanes are:

• Faster hydrolysis and condensation


of the Si-alkoxy groups
• Faster production processes
• Better chemical and mechanical
product properties
• A wider range of applications for
organofunctional silanes

Skin-formation times

As Fig. 14 shows, skin-formation begins Another hugely important aspect of this


after just a few seconds when a-trimeth- application is that the dialkoxy a-silane
oxysilane is used, as compared to about grades, even the ethoxy variants, likewise
25 minutes in the case of g-trimethoxy- cure rapidly. Compared to this a corre-
silane. sponding g-dimethoxy system would be
far out of range (several hours) under the
A comparison of the ethoxysilanes is same conditions.
even more impressive: a-triethoxysilane
induces curing in a few minutes whereas These examples demonstrate the great
with g-triethoxysilane no skin-formation potential that di- and trialkoxy a-silanes
can be observed even after 2 hours. have as crosslinkers for moisture-curing
adhesives and sealants and for post-
curing coating systems. In addition, they
are interesting as adhesion promoters,
probably the most important field of appli-
cation for organofunctional silanes in
terms of quantities.

11
GENIOSIL ® FOR
ADHESIVES AND SEALANTS
Silane crosslinking is a key technology
for state-of-the-art adhesives and
sealants. GENIOSIL® a-silanes offer
unforeseen advantages.

Organofunctional silanes are essential The silanes fulfill various functions:


components in almost all adhesives and •• They act as crosslinkers in moisture-
sealants. curing reactive adhesives and sealants.
•• They improve the physical and
There are two basic methods of incor- mechanical properties of filled and
porating organofunctional silanes into reinforced formulations.
adhesives and sealants: either the silanes •• They enhance the resistance of the
are linked chemically to the base polymer cured products to chemicals.
by bonding the organofunctional groups •• They permit good adhesion to a variety
with the reactive ends of the polymer of different substrates.
(STP = Silane Terminated Polymers tech- •• They ensure good storage stability for
nology), or the silanes are mixed into the formulations and prevent premature
formulations in the form of additives. curing.

12
For highly reactive adhesive and sealant
systems, such as the a-silane-cross-
linking polymers described in the next
chapter, vinyltrimethoxysilane is only of
limited suitability as a water scavenger.
However, the carbamate- and methacryl-
oxy-functional a-silanes are an excellent
alternative for such systems.

GENIOSIL® as Crosslinker

Numerous polymers can be used in


moisture-curable systems by incorporat-
ing silanes. Silane crosslinking is espe-
cially important for acrylates, polyethers,
polyurethanes and polyesters as a means
of selectively optimizing and customizing
GENIOSIL® as Adhesion Promoter GENIOSIL® as Water Scavenger their properties. These include mechani-
cal properties, such as tensile strength at
In order to enhance adhesion, organo- The most commonly encountered water break, elongation at break, tear strength
functional silanes must bond chemically scavenger in adhesive and sealant for- and abrasion resistance but also storage
or physically to the organic polymer. mulations is vinyltrimethoxysilane. Due stability, chemical resistance and weath-
Since there is a wide variety of adhesive to the electron interactions of the vinyl ering resistance. In connection with
and sealant systems, a large number group, the Si-methoxy groups in this polyethers and polyurethanes, in par-
of organofunctional silanes are needed. silane hydrolyze substantially faster than ticular, silane crosslinking has attracted
The most commonly used adhesion pro- in saturated aliphatic alkylalkoxysilanes. much attention during the last few years,
moters are amino-, epoxy- and methacryl- Any moisture inherently present in the thereby opening up attractive fields of
oxysilanes. How much of which silane formulation is removed as the methoxy application for a-silanes. This technology
will ultimately be required will depend on groups hydrolyze (methanol is split off) is described in more detail in the next
the specific formulations in question. and the vinylsilane condenses. Only chapter.
when the latter reaction is essentially
complete will the remaining silane build-
ing blocks crosslink. The amount of
silane added will depend on the water
content of the formulation constituents;
usually about one percent by weight is
required.

13
Fig. 15: Synthesis of STP-U from NCO-prepolymers and aminosilanes

(catalyst)

2 ° Aminoalkyl-alkoxysilanes urea group

STP-U SILANE-TERMINATED POLYURETHANE

Fig. 16: Synthesis of STP-E from polyethers and NCO-silanes

(catalyst)

Isocyanatoalkyl-alkoxysilanes urethane group

STP-E SILANE-TERMINATED POLYETHER

STP Technology A disadvantage of STP-U sealants is the


high viscosity of the polymers, which
There are two principal reasons for mo- results from the urea units formed during
difying polyurethanes with GENIOSIL®: silane endcapping reactions. Urea is
first, to replace toxic and thus problem- known for its tendency to form hydro-
atic isocyanate groups and, second, to gen bridges resembling ladder rungs
improve such properties as adhesion, between the polymer strands. These high
chemical resistance and storage stability. viscosities must be taken into account
during the compounding and processing
Silane-terminated polyurethanes (subse- of such systems.
quently referred to as STP-U) are usually
produced by the reaction of NCO-con- Viscosity can be kept under control if
taining prepolymers with aminosilanes NCO-functional silanes are used instead
(Fig. 15). of aminosilanes, and are reacted with
hydroxyl-terminated polymers, such as
polyethers, polyurethanes or polyesters
(Fig. 16).

14
Advantages of GENIOSIL® a-STP-E
polymers in adhesives and sealants:

• Fast and complete curing


• Excellent mechanical properties
• Cost-efficient compounding
• Tin free formulations
• Tack-free surfaces
• Greater shelf life

Processing is particularly easy when pure The Unparalleled a-Silanes


polyethers are used (subsequently referred
to as STP-E), since the viscosity of these The new, highly reactive GENIOSIL®
systems is significantly lower than that a-silanes bring exceptional benefits for
of STP-U. Special polyethers are needed STP-E technology.
to achieve mechanical properties com-
parable to polyurethanes. Adhesives and sealants terminated with
these a-silanes cure completely and rap-
Greater detail on WACKER’s silane termi- idly, and display outstanding mechani-
nated polymers is available in a separate cal properties. This is currently the only
brochure “Another step ahead with technology available where formulations
GENIOSIL® STP-E binders”. are possible that do not require toxic tin
catalysts.

15
Product overview GENIOSIL ®
OrganofuncTional SILANEs
Product name Chemical name Structural formular Molecular Density Flash Boiling CAS-No
GENIOSIL® weight (25 °C) point point
Functional group [g/ml] [°C] [°C]

GF 9 N-(2-Aminoethyl)-3-amino- 222.4 1.03 >100 147/ [1760-24-3]


Amino propyltrimethoxysilane 16 hPa

GF 91 N-(2-Aminoethyl)-3-amino- 222.4 1.02 >100 147/ [1760-24-3]


Amino propyltrimethoxysilane, 16 hPa
high purity
GF 92 N-Cyclohexyl-3-amino- 261.4 0.99 >100 125/ [3068-78-8]
Amino propyltrimethoxysilane 2 hPa

XL 926 N-Cyclohexylamino- 275.5 0.95 119 236 [26495-91-0]


Amino methyltriethoxysilane

GF 93 3-Aminopropyltriethoxy- 221.4 0.94 93 217 [919-30-2]


Amino silane

GF 94 3-(2-Aminomethylamino) 264.4 0.97 > 100 > 110/ 5089-72-5


Amino propyltriethoxysilane 3 hPa

GF 95 N-(2-Aminoethyl)-3-amino- 206.4 0.97 >100 110/ [3069-29-2]


Amino propylmethyldimethoxy- 3 hPa
silane
GF 96 3-Aminopropyltrimethoxy- 179.3 1.01 79 210 [13822-56-5]
Amino silane

GF 98 3-Ureidopropyltrimethoxy- 222.3 1.15 99 >300 [23843-64-3]


Amino silane

XL 10 Vinyltrimethoxysilane 148.2 0.97 24 122 [2768-02-7]


Vinyl

XL 12 Vinyldimethoxymethylsilane 132.2 0.88 15 104 [16753-62-1]


Vinyl

GF 56 Vinyltriethoxysilane 190.3 0.91 43 158 [78-08-0]


Vinyl

GF 62 Vinyltriacetoxysilane 232.3 1.16 >93 112/ [4130-08-9]


Vinyl 13 hPa

16
Product name Chemical name Structural formular Molecular Density Flash Boiling CAS-No
GENIOSIL® weight (25 °C) point point
Functional group [g/ml] [°C] [°C]

GF 31 3-Methacryloxypropyl- 248.4 1.05 >100 125/ [2530-85-0]


Methacryl trimethoxysilane 15 hPa

XL 32 Methacryloxymethyl)- 204.3 1.02 82 205 [121177-93-3]


Methacryl methyldimethoxysilane

XL 33 Methacryloxymethyl- 220.3 1.07 92 217 [54586-78-6]


Methacryl trimethoxysilane

GF 39 3-Methacryloxypropyl- 332.4 1.16 >135 147/ [51772-85-1]


Methacryl triacetoxysilane 1 hPa

GF 60 N-Methyl[3-(Trimethoxysilyl) 237.3 1.11 141 102 [23432-62-4]


Carbamato propyl]carbamate

XL 63 N-Trimethoxysilylmethyl- 209.3 1.15 117 204 [23432-64-6]


Carbamato O-methylcarbamate

XL 65 N-Dimethoxy(methyl)silyl- 193.3 1.10 112 211 [23432-65-7]


Carbamato methyl-O-methylcarbamate

GF 69 Tris-[3-(trimethoxysilyl) 615.9 1.17 102 > 250/ 26115-70-8


Cyanurate propyl]-isocyanurate 0,13 hPa

GF 80 3-Glycidoxypropyltrimeth- 236.3 1.07 127 138/ [2530-83-8]


Glycidoxy oxysilane 13 hPa

GF 82 3-Glycidoxypropyltrieth- 278.4 1.01 >100 143/ [2602-34-8]


Glycidoxy oxysilane 13 hPa

17
Product overview
Non-funcTional SILANEs
Product name Chemical name Structural formular Molecular Density Flash Boiling CAS-No
Functional group weight (25 °C) point point
[g/ml] [°C] [°C]

Silan M1-Trimethoxy Methyltrimethoxysilane 136.2 0.95 11 102 [1185-55-3]


Methylalkoxy

Silan M1-Triethoxy Methyltriethoxysilane 178.3 0.89 33 143 [2031-67-6]


Methylalkoxy

Silan M2-Dimethoxy Dimethyldimethoxysilane 120.2 0.86 -11 78 [1112-39-6]


Methylalkoxy

Silan M2-Diethoxy Dimethyldiethoxysilane 148.3 0.83 13 113 [78-62-6]


Methylalkoxy

Silan M3-Ethoxy Trimethylethoxysilane 118.3 0.75 <-20 76 [1825-62-3]


Methylalkoxy

Silan IO-Trimethoxy Isooctyltrimethoxysilane 234.4 0.90 52 90/ [34396-03-7]


Alkylalkoxy 13 hPa

Silan IO-Triethoxy Isooctyltriethoxysilane 276.5 0.88 >40 236 [35435-21-3]


Alkylalkoxy

Silan 25013 VP Hexadecyltrimethoxysilane 346.6 0.89 122 159/ [16415-12-6]


Alkylalkoxy 2 hPa

Silan CHM-Dimethoxy (Cyclohexyl)methyl- 188.3 0.94 76 198 [17865-32-6]


Alkylalkoxy dimethoxysilane

Silan CP2-Dimethoxy Dicyclopentyldimethoxy- 228.4 0.98 >100 257 [126990-35-0]


Alkylalkoxy silane

Silan P-Triethoxy Phenyltriethoxysilane 240.4 0.99 >40 235 [780-69-8]


Phenyl

Crosslinker ES 23 Triacetoxyethylsilane 234.3 1.14 > 100 110/ 17689-77-9


Acetoxy 13 hPa

Crosslinker ET 13 1,2-Bis(triethoxysilyl) 354.6 0.96 > 100 118/ 16068-37-4


Acetoxy ethan 13 hPa

18
ExpErtisE and sErvicE nEtwork
on FivE continEnts

• sales and production sites, plus 20 technical


centers, ensure you a local presence worldwide.

WACKER is one of the world’s leading the globe with five business divisions, tailored to regional demands, supporting
and most research-intensive chemical operating 24 production sites, WACKER is them during every stage of their complex
companies, with total sales of €4.63 billion. currently active in over 100 countries. The production processes, if required.
Products range from silicones, binders Group maintains subsidiaries and sales WACKER e-solutions are online services
and polymer additives for diverse industrial offices in 29 countries across Europe, the provided via our customer portal and as
sectors to bio-engineered pharmaceutical Americas and Asia – including a solidly integrated process solutions. Our
actives and hyperpure silicon for established presence in China. With a customers and business partners thus
semiconductor and solar applications. As workforce of 16,300, WACKER sees itself benefit from comprehensive information
a technology leader focusing on sustain- as a reliable innovation partner that and reliable service to enable projects
ability, WACKER promotes products and develops trailblazing solutions for, and in and orders to be handled fast, reliably
ideas that offer a high value-added collaboration with, its customers. WACKER and highly efficiently. Visit us anywhere,
potential to ensure that current and future also helps them boost their own success. anytime around the world at:
generations enjoy a better quality of life Our technical centers employ local www.wacker.com
based on energy efficiency and protection specialists who assist customers world-
of the climate and environment. Spanning wide in the development of products

all figures are based on fiscal 2012.


Wacker Chemie AG
6085e/09.13 supersedes 6085e/12.12

Hanns-Seidel-Platz 4
81737 München, Germany
Tel. +49 89 6279-0

www.wacker.com

The data presented in this brochure are in accordance with the present state of our knowledge, but do not absolve the user from carefully checking all supplies immediately upon receipt.
We reserve the right to alter product constants with the scope of technical progress or new developments. The information given in this brochure should be checked by preliminary trials
because of conditions during processing over which we have no control, especially where other companies’ raw materials are also being used. The information provided by us does not
absolve the user from the obligation of investi-gating the possibility of infringement of third parties’ rights and, if necessary, clarifying the position. Recommendations for use do not constitute
a warranty, either express or implied, of the fitness or suitability of the product for a particular purpose.

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