In the past, soap was made by mixing animal fats with alkaline and wood
ashes
Large-scale commercial soapmaking occurred in 1791 when a French
Chemist, Nicholas Leblanc patented a process for making soda ash or
sodium carbonate from common salt. The process yielded large quantities of
quality soda ash.
Soap can be prepared through saponification. Use a flow chart to show soap
preparation process in the laboratory, starting with the raw materials. Include
any relevant chemical equation.
Oils and fats are esters formed from glycerol and fatty acids.
The oil or fat molecules are “broken up” or hydrolyzed to glyce ro l and fatty
acids.
The fatty acids formed then react with sodium hydroxide, NaOH to form a salt
(soap)
Fats and oils are hydrolyzed (split) with a high-pressure steam to yield crude fatty
acids and glycerol.
The fatty acids are then purified by distillation and neutralized with an alkali to
produce soap and water (neat soap-soap in liquid form).
Fatty acid + NaOH → Glycerol + Sodium soap
Potassium soaps are softer and are found in some liquid hand soaps
and shaving creams.
Give the definition of detergent and some examples of detergents.
Salt that are formed by neutralizing an alkyl hydrogen sulphate with an alkali.
Dodecylsulfate sodium
dodecylsulfate
Both soap and detergent clean so much better than water alone. Use a flow
chart and colourful diagram to summarize the cleansing action of soap and
detergent.
One part of the soap and detergent anion is negatively charged (polar end).
- It dissolves in water. It is hydrophilic or “likes water”.
When soap or detergent is added to the dirty surface of a piece of cloth covered with
a layer of oil or grease
(a) The negatively charged ‘heads’ (hydrophilic) of soap ions or detergents ions
dissolves
in water
(b)The hydrocarbon ‘tails’ (hydrophobic) of soap or detergent ions dissolves in the layer
of grease
If the water is agitated slightly, the grease begins to lifted off the surface.
When the cloth is rinsed with water, the droplets will be carried away
Heating and stirring may help to loosen the dirt particles from the material being
washed
Compare and contrast the effectiveness of cleansing action of soap and
detergent in hard water by using mind maps or table.
Hard water contains a great amount of calcium and magnesium ions. These ions react with
the soap to form an insoluble precipitate known as soap scum.