1. Quick Revision
1.2 Cement
Concrete sets to a rock-like mass due to a chemical reaction (hydration) which
takes places between cement and water, resulting in a paste of matrix (Calcium
Silicate Hydrate (C-S-H)) which binds the other constituents together.
2(2CaO.SiO2) + 4H2O 3CaO.2SiO2.3H2O + Ca(OH)2
There are several different types of cement, among which Ordinary Portland
Cement is most commonly used in Hong Kong.
Setting – This is the term used to describe the stiffening of the cement paste.
Broadly speaking, setting refers to the change from a fluid to a rigid state.
1.3 Aggregate
Aggregates are inert, inexpensive materials dispersed throughout the cement
paste so as to produce a large volume of concrete.
Coarse aggregate – aggregate mainly retained on a 5 mm test sieve.
Fine aggregate – aggregate mainly passing a 5 mm test sieve.
2. Strength of Concrete
Concrete is naturally strong in compression, i.e. it can resist quite high crushing loads.
On the other hand, it is relatively weak in tension, i.e. it cracks fairly readily if
stretched or bent.
.
The effect of extent of air voids
on potential concrete strength
(source: C&CAA T41)
Influence of porosity on relative strength
of various materials (Source: Neville)
For fully compacted concrete, the strength of concrete decreases with the
water/cement ratio increases, since excessive water results in voids and
capillaries.
Therefore, the water-cement ratio of a concrete mix is one of the most
important influences on concrete strength. It is calculated by
Water cement ratio = mass of free water ÷ mass of cement
For a given concrete mix, the maximum potential strength will be achieved
only with full compaction, i.e. if all voids or spaces between the particles of
aggregate are filled with cement paste and all air is expelled from the system.
Otherwise, the strength of concrete decreases with the air void content
increases.
2.3 Age
The hydration of reaction, and therefore strength development, will continue
for long periods of time.
The reaction is most vigorous in the first week, but then slows progressively to
an almost imperceptible rate which may continue for many years.
Since the hydration of reaction will continue for long periods of time, it is
essential that moisture is present for a sufficient time to allow the reaction to
proceed.
Substantial reduction in potential strength will result from inadequate curing
(as shown in the figure below).
The influence of moist curing on the strength of concrete with a water/cement ratio 0.5
(source: Neville & Brooks)
The rate of strength development will depend also on the type of cement.
The shape and texture of aggregate particles has an important influence on the
workability of fresh concrete, and hence may affect both the water demand and
the water-cement ratio.
Flat, flaky or elongated particles not only reduce workability but may also affect
adversely the strength of concrete by their tendency to selective orientation and
bridging (thus forming pockets or honeycombs),
On the other hand, the strength of concrete is affected by the bond between
coarse aggregate particles and the cement paste, and by the interlocking
characteristics of the aggregate.
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2.1.1 Natural aggregate
4. Shear Strength
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5. Deformation of concrete independent of load
Besides deformation due to applied load, volume changes due to shrinkage and
temperature variation are also of importance.
Most concrete, after it is placed, bleeds, i.e. water rises to the surface as the solid
particles settle.
The bleed water evaporates and there is a loss of total volume - the concrete has
'settled'. This contraction is known as plastic shrinkage.
If there is no restrain, the net result is simply a very slight lowering of the
surface level.
However, if there is something near the surface, such as reinforcing bar, which
restrains part of the concrete from settling while the concrete on either side
continues to drop, there is potential for a crack to form over the restraining
element.
Differential amounts of settlement may also occur where there is a change in the
depth of a section, such as at a beam/slab junction.
Generally, the cracks are not deep but, because they tend to follow and penetrate
down to the reinforcement, they may reduce the durability of a structure.
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5.2 Drying Shrinkage and Moisture Movement
a. Water/cement ratio
The higher the w/c ratio, the larger the shrinkage.
b. Aggregate
Aggregates restrain the amount of shrinkage.
Use of larger aggregate permits the use of leaner mix at a constant w/c ratio,
thus reduces shrinkage.
c. Relative humidity
The lower the relative humidity, the larger the drying shrinkage.
d. Curing
Adequate curing can also reduce formation of drying shrinkage cracks as it
will increase the tensile strength of concrete.
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5.3 Carbonation
Carbonation is the process where Carbon Dioxide in the air reacts with Calcium
Hydroxide of the concrete to form Calcium carbonate.
Ca(HO)2 + CO2 CaCO3 + H2O
In association with the process, concrete experiences a contraction known as
Carbonation Shrinkage.
Concrete with a high water/cement ratio and inadequately cured will be more
prone to carbonation.
Carbonation results in increase in strength and decrease in permeability. (This
is possible due to water released by carbonation aids the process of hydration
and the CaCO3 formed deposits in the voids within the cement paste.)
Carbonation proceeds slowly from the surface inwards, and the rate of
carbonation decreases with time because of the decrease of permeability on the
outer surface due to carbonation.
The bad effect of carbonation is that it neutralises the alkaline nature of the
concrete, thus the protection of steel from corrosion is vitiated.
The extent of carbonation can be detected by treating a freshly broken surface
with phenolphthalein. The free Ca(OH)2 is coloured pink while the carbonated
portion is uncoloured.
Concrete has a positive coefficient of thermal expansion and about 0.00001 per
C.
Thermal expansion or contraction, if restrained, may induce stresses in
structures and cause cracking.
The remedy is to provide movement joints at suitable locations for large
structures.
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6. Deformation of concrete under load
stress
Every material deforms when under load, E = , or
strain
strain = stress / E.
That is, to estimate the deformation of concrete when under load, its Young’s
modulus must be known.
However, the elastic property of concrete is non-linear.
Theoretically, the tangent to the curve at the origin can be measured, and this is
known as the initial tangent modulus.
unloading
Secant modulus
Strain
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6.2 Creep
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A sustained load removed results in the decrease in elastic strain immediately.
This strain is generally smaller than the initial elastic strain because of the
increase in modulus of elasticity with age.
The instantaneous recovery is followed by a gradual decrease in strain, called
creep recovery.
Creep recovery is always smaller than the preceding creep, thus there is a
residual deformation.
a. Strength
Increase in strength usually leads to a reduction in creep.
b. Mix proportion
Creep decreases as the w/c ratio and the volume of cement paste decreases.
c. Aggregate
Creep increases as the aggregates become finer;
it is generally greater when porous aggregates are used.
d. Curing
Creep decreases as cement hydration proceeds;
Concrete kept continuously wet will have creeps less than cured in air.
e. age
Rate of creep decreases as the concrete ages.
Reference
A.M. Nevelle & J.J. Brooks (1990), Concrete Technology, Longman
Cement and Concrete Association of Australia, Standard Australia (1994), Guide to Concrete
Construction.
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