Aiits 1719 Open Test Jeea Paper 1

FIITJEE JEE (Advanced)-2019
OPEN TEST
ALL INDIA INTEGRATED TEST SERIES
Paper 1
Time Allotted: 3 Hours Maximum Marks: 183

 Pl ea s e r ea d t h e i n s t r u c t i o n s c a r ef u ll y . Yo u a r e a l l o t t ed 5 m i n u t es
s p ec i f i c a ll y f o r t h i s p u r p o s e.
 Yo u a r e n o t a l l o wed t o l ea v e t h e E xa m i n at i o n Ha l l b ef o r e t h e en d o f
t h e t es t .
INSTRUCTIONS
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Parts.
3. Part-I is Physics, Part-II is Chemistry and Part-III is Mathematics.
4. Each part is further divided into Two sections: Section-A & Section-C
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers
on OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with black pen for each character of your
Enrolment No. and write your Name, Test Centre and other details at the designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.

1. Section-A (01– 07, 19 – 25, 37 - 43) contains 21 multiple choice questions which have one or
more than one correct answer. Each question carries +4 marks for correct answer and –2
marks for wrong answer
Partial Marks +1 for each correct option provided no incorrect options is selected.
Section-A (08 – 13, 26 – 31, 44 - 49) contains 18 questions. Each of 2 Tables with 3 Columns
and 4 Rows has three questions. Column 1 will be with 4 rows designated (I), (II), (III) and (IV).
Column 2 will be with 4 rows designated (i), (ii), (iii) and (iv). Column 3 will be with 4 rows
designated (P), (Q), (R) and (S).
Each question has only one correct answer and carries +3 marks for correct answer and –1
mark for wrong answer.
2. Section-C (14 – 18, 32 – 36, 50 - 54) contains 15 Numerical based questions with answer as
numerical value from 0 to 9 and each question carries +3 marks for correct answer. There is no
negative marking.
Name of the Candidate
Enrolment No.
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016, Ph 46106000, 26569493, Fax 26513942
website: www.fiitjee.com
AIITS-OT (Paper-1)-PCM-JEE(Advanced)/19 2
Useful Data
PHYSICS
Acceleration due to gravity g = 10 m/s2

Planck constant h = 6.6 1034 J-s
Charge of electron e = 1.6  1019 C
Mass of electron me = 9.1  1031 kg
2 2
Permittivity of free space 0 = 8.85  1012 C /N-m
3 3
Density of water water = 10 kg/m
Atmospheric pressure Pa = 105 N/m2
Gas constant R = 8.314 J K1 mol1
CHEMISTRY
Gas Constant R = 8.314 J K1 mol1

= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s constant h = 6.625  1034 Js
= 6.625  10–27 ergs
1 Faraday = 96500 coulomb
1 calorie = 4.2 joule
1 amu = 1.66  10–27 kg
1 eV = 1.6  10–19 J
Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,

N=9, Na=11, Mg=12, Si=14, Al=13, P=15, S=16,
Cl=17, Ar=18, K =19, Ca=20, Cr=24, Mn=25,
Fe=26, Co=27, Ni=28, Cu = 29, Zn=30, As=33,
Br=35, Ag=47, Sn=50, I=53, Xe=54, Ba=56,
Pb=82, U=92.
Atomic masses: H=1, He=4, Li=7, Be=9, B=11, C=12, N=14, O=16,
F=19, Na=23, Mg=24, Al = 27, Si=28, P=31, S=32,
Cl=35.5, K=39, Ca=40, Cr=52, Mn=55, Fe=56, Co=59,
Ni=58.7, Cu=63.5, Zn=65.4, As=75, Br=80, Ag=108,
Sn=118.7, I=127, Xe=131, Ba=137, Pb=207, U=238.
3 AIITS-OT (Paper-1)-PCM-JEE(Advanced)/19
Physics PART – I
SECTION – A
(One or More than one correct type)
This section contains 7 questions. Each question has FOUR options (A), (B), (C) and (D). ONE OR
MORE THAN ONE of these four options is(are) correct.
1. In the isothermal expansion of an ideal gas:

(A) there is no change in the temperature of the gas
(B) there is no change in the internal energy of the gas
(C) the work done by the gas is equal to the heat supplied to the gas
(D) the work done by the gas is equal to the change in its internal energy.
2. A particle of mass m is attached to one end of the light inextensible

string and other end of the string is fixed in vertical plane as shown.
5
Now particle is given horizontal velocity u  gl , then which of the l
2
following statement/s is/are correct.
u
(A) The string makes angle with the downward vertical is 600 when acceleration of the
particle is horizontal.
(B) The tension in string is 2 mg when acceleration of the particle is horizontal.
3
(C) The speed of the particle is gl when acceleration of the particle is horizontal
2
(D) The particle will not complete the circle.
Space for Rough work
3. A small block is connected to one end of a

massless spring of un-stretched length 4.9
m. The other end of the spring (see the
figure) is fixed. The system lies on a
horizontal frictionless surface. The block is
stretched by 0.2 m and released from rest at
t = 0. It then executes simple harmonic

motion with angular frequency   rad / s .
3
Simultaneously at t = 0, a small pebble is projected with speed  from point P at an
angle of 45° as shown in the figure. Point P is at a horizontal distance of 10 m fro O. If
the pebble hits the block at t = 1s, the value of  is (take g = 10 m/s2)
(A) 50 m / s (B) 51 m / s
(C) 52 m / s (D) 53 m / s
4. A cyclic process ABCA shown in V-T diagram is performed with a B C

constant mass on an ideal gas. The same process on a PV diagram V
A
is represented as
T
(A) A C (B) B C
P
P
B A
V V
(C) B C (D) B
P P
A A C
V V
5. A block of mass 1 kg moves under the influence of external forces on a rough horizontal
surface. At some instant, it has a speed of 1 m/s due east and an acceleration of 1 m/s2
due north. The force of friction acting on it is F
(A) F acts due west
(B) F acts due south
(C) F acts in the south west direction
(D) the magnitude of F cannot be found from the given data
6. A smooth massless wedge is pushed by a horizontal force m

F. When F
(A) F  0,N  mgcos ;N  normal reaction received by the
block

(B) F  0,N  mgcos 
(C) a  0,N  mgcos ;a  acceleration of the wedge
mg
(D) F  mg tan ,N 
cos 
7. Block A is placed on an inclined plane B making an angle of 30º with

horizontal. R2 is the reaction on A when B is stationary. R1 is the
reaction on A when B is moving with constant acceleration:
(A) If R1 / R2  4 / 3 , then block B moves with acceleration g / 3
(B) If R1 / R2  4 / 3 , then block B moves with acceleration g / 2
(C) If R1 / R2  4 / 3 , then block B remains stationary relative to block A
(D) If R1 / R2  4 / 3 , then block B will not be stationary relative to block A
(Matching type - Single Correct Option)

This section contains SIX questions of matching type. The section contains TWO tables (each having 3
columns and 4 rows). Based on each table, there are THREE questions. Each question has FOUR
options (A), (B), (C), and (D). ONLY ONE of these four options is correct.
Answer questions 8, 9 and 10 by appropriately matching the information given in the three
columns of the following table.
Consider a particle in space which is near Earth.

Column – 1 Column – 2 Column – 3
(I) A particle is thrown with velocity V (i) Path is parabola (P) Total energy is
which is less than V0. positive
(II) A particle is thrown with speed V which (ii) Path is circular (Q) Total energy is zero
is equal to V0
(III) A particle is thrown with speed V which (iii) Path is ellipse (R) Total energy is
is more than V0 but less than Ve negative
(IV) A particle is thrown with speed V = Ve (iv) Path is hyperbola (S) Total energy can be
positive or negative
V0 = orbital speed
Ve = escape speed
8. Combination that will match with bounded system will be

(A) (III) (iii) (R) (B) (I) (i) (P)
(C) (II) (iv) (P) (D) (IV) (ii) (R)
9. Combination that will match with unbounded system

(A) (IV) (i) (R) (B) (II) (iii) (R)
(C) (IV) (i) (Q) (D) (I) (i) (P)
10. For moon Earth system (assumed orbital velocity)

(A) (II) (iii) (S) (B) (II) (ii) (P)
(C) (II) (ii) (R) (D) (II) (iv) (P)
Answer questions 11, 12 and 13 by appropriately matching the information given in the
three columns of the following table.
A thin uniform rod of mass ‘m’ and length ‘’ is free to rotate about its upper end. When it is at
rest, it receives an impulse J at its lowest point, normal to its length. Immediately, after impact.
(I) Angular velocity of rod 3J2 (P) Linear momentum is conserved
(i)
2m
(II) Angular momentum of rod 3J (Q) Moment of inertia of Rod about COM
(ii)
2m m 2
is
3
(III) Kinetic energy of rod 3J (R) Angular momentum about COM is
(iii) conserved
m
(IV) Linear velocity of the mid (iv) J (S) Angular momentum about hinge is
point of rod conserved
11. Correct combination for angular velocity of the rod will be

(A) (I) (iii) (S) (B) (I) (ii) (Q)
(C) (I) (iii) (R) (D) (I) (ii) (P)
12. Correct combination for angular momentum of rod will be

(A) (II) (iv) (P) (B) (II) (ii) (Q)
(C) (II) (iii) (S) (D) (II) (i) (R)
13. Correct combination for linear velocity of mid point will be

(A) (IV) (ii) (S) (B) (IV) (ii) (Q)
(C) (IV) (iii) (P) (D) (IV) (ii) (R)
SECTION – C
(Single digit integer type)
This section contains FIVE questions. The answer to each question is a single Digit integer ranging from
0 to 9, both inclusive.
14. A piece of ice (heat capacity = 2100 J kg–1 0C–1 and latent heat = 3.36 x 105 J kg–1) of
mass m grams is at -50C at atmospheric pressure. It is given 420 J of heat so that the ice
starts melting. Finally when the ice-water mixture is in equilibrium, it is found that 1 gm of
ice has melted. Assuming there is no other heat exchange in the process, the value of m
is
15. There is a quarter cylindrical wall at one portion of a

container as shown in the diagram. A force F is applied to
avoid quarter cylindrical portion from rotating the value of F F
will be (In Newton)
h=1m R
h
R=1m Hinged
 = 103 kg m–3
depth = 1 m
6
16. Gravitational acceleration on the surface of a planet is g , where g is the gravitational
11
2
acceleration on the surface of the earth. The average mass density of the planet is
3
times that of the earth. If the escape speed on the surface of the earth is taken to be
11 kms-1, the escape speed on the surface of the planet in kms-1 will be
17. Find the mass of the hanging block in kg, which

will prevent the smaller block from slipping over
the triangular block. All the surfaces are friction
less and the strings and pulleys are light. (Given m m
= M = 1 kg, cot = 2)
M
18. A system of two identical rods (L shaped) of mass m, length L. P

System rest on a peg p as shown in the figure. Period of oscillations 0
90
n 2L
T  2 then n = ?
3g
Chemistry PART – II
SECTION – A
19. 10 g of Ne initially at a pressure of 506.625 KPa and temperature of 473 K expand

adiabatically against a constant external pressure of 202.65 KPa than
(A) Ssys = +ve (B) Stotal = Ssurr
(C) Stotal = +ve (D) Ssurr = 0
20. Which of the following reaction(s) is/are correctly representing enthalpy of formation?
1 1 1 1
(A) H2  g   I2  s  
 HI  g  (B) H2  g  CI2  g   HCI   
2 2 2 2
1 1 1 3
(C) H2  g  Br2      HBr  g  (D) P4  s   H2  g   PH3  g 
2 2 2 2
21 Which of the following is/are expected to form inner orbital octahedral complex.
(A) d8(strong field ligand) (B) d8(weak field ligand)
3
(C) d (weak field ligand) (D) d3(strong field ligand)
22. Two flasks A and B have equal volumes. A is maintained at 300 K and B at 600 K, while
A contains H2 gas, B has an equal mass of CH4 gas. Assuming ideal behaviour for both
the gases. Select the correct option.
(The collision diameter of CH4 is twice as that of H2)
Where uav – average speed
 – Mean free path
KE – Kinetic energy
(A) (uav)A = 2(uav)B (B) A = 2B
(C) K.EA = 2K.EB (D) Total K.EA = 4 total K.EB
23. Which of the following statements are correct for SNAr reaction?
(A) Follows second order kinetics (B) KH/KD > 1
(C) Involves carbanion-type intermediate (D) Involves two transition states
24. Select correct statement.

(A) Rate law may not bear a simple relationship to the stoichiometry equation.
(B) Rate law may not depend on the concentration of every reactant.
(C) Rate law may depend on the concentration of product.
(D) in some reaction concept or order of reaction has no meaning.
25. A system undergoes two cyclic processes 1 and 2. Process 1 is reversible and process
2 is irreversible. The correct statement/s relating to the two process is
(A) S(for process 1) = 0, while S(for process)  0.
(B) qcyclic = 0 for process 1 and qcyclic  0 for process 2.
(C) More heat can be converted to work in process 1 than in process 2.
(D) More heat can be converted to heat in process 1 than in process 2.


(I) Cl2 (i) KCN(aq) excess (P) Disproportionation
(II) CuSO4 (ii) NaOH (Q) Precipitation
(III) FeCl3 (iii) NH3(aq) excess (R) Redox
(IV) Hg(NO3)2 (iv) KI(aq) excess (S) Complex formation
26. For Cl2 molecule, the only correct combination is

(A) (I) (i) (Q) (B) (I) (ii) (P)
(C) (I) (i) (S) (D) (I) (iii) (S)
27. For FeCl3 the only correct combination is

(A) (III) (iii) (R) (B) (III) (iv) (R)
(C) (III) (iii) (S) (D) (III) (ii) (S)
28. For the formation of a soluble compound which combination is correct?

(A) (II) (iv) (S) (B) (II) (iv) (R)
(C) (III) (i) (S) (D) (IV) (iv) (R)

(I) Formaldehyde (i) CHCl3/NaOH (P) Substitution
(II) Glucose (ii) Br2(aq) (Q) Disproportionation
(III) Phenol (iii) KOBr (R) Degradation
(IV) Acetamide (iv) NaOH (S) Oxidation
29. The correct combination in which reaction proceeds with hydride transfer is
(A) (I) (iv) (R) (B) (II) (ii) (S)
(C) (IV) (i) (P) (D) (I) (iv) (Q)
30. The correct combination in which an aldehyde is formed

(A) (IV) (iii) (P) (B) (IV) (iii) (R)
(C) (III) (i) (P) (D) (II) (ii) (S)
31. The correct combination in which a produce is formed which can be identified by
reacting with CHCl3/KOH
(A) (I) (iv) (Q) (B) (II) (ii) (S)
(C) (IV) (iii) (R) (D) (III) (i) (P)
SECTION – C
32. The number of isomeric structure of di-substituted borazine (B3N3H4X2) is
33. The number of S-S bond(s) in tetrathionate ion is
34. The number of unpaired electron(s) in K2NiF6 is
35. The number of reducing sugars among the following is:

OMe OH OH
HO O HO O O
HO
OMe
OH OH
HO OH HO OMe HO OH
CH2OH
O OMe O OH O
HO HO
H OH
H OH
HO OH HO OH
H OH
HO HO
O CH2OH
H O
H
H H O OH O
HO HO
OH OH OH
36. The maximum number of dipeptides that could be obtained by reaction of phenylalanine
with leucine is
Mathematics PART – III
SECTION – A
37. If the equation x 4  ax 3  bx 2  32x  16  0 has all positive roots, then which of the
following is/are true?
(A) a  8 (B) sum of roots is 8
(C) b  8 (D) b = 24
38. Let a1,a2 ,a3 ......an are different numbers in A.P. and a3 ,a5 ,a8 .b1,b2 ,b3 ...... are in G.P.
and a9  40, then
9 
1 1
(A)  a2i  6144
i 1
(B) b
i 1

18
i
9 
2 1 1
(C) a
i 1
i  6278 (D) b
i 1

28
i
39. Ten persons numbered 1, 2, ….,10 play a chess tournament, each player playing
against every other player exactly one game. It is known that no game ends in a draw. If
w 1, w 2 ,.....w10 are the number of games won by players 1, 2, 3,…..,10, respectively, and
1,  2 ,......10 are the number of games lost by the players 1, 2,……..10, respectively,
then
(A)  w i    i  45 (B) w i   i  9
(C) w i
2
 81    i2 (D) w i
2
   i2
2! 2! 1! 8a
40. Let a, b, c be the sides of triangle ABC such that 2b  a  c . If    ,
1!9! 3!7! 5!5!  2c  !
then
(A) area of ABC is 6 (B) circumradius of ABC is 5
(C) inradius of ABC is 1 (D) ABC is right angled triangle
41. If all the roots of the equation z4  az3  bz 2  cz  d  0  a,b,c,d  R  are of unit
modulus, then
(A) a  4 (B) b  4
(C) c  4 (D) b  6

42. If x  X cos   Y sin , y  X sin   Y cos  and x 2  4xy  y 2  AX 2  BY 2 ; 0    ,
2
then which of the following option(s) is/are correct?
 
(A)   (B)  
6 4
(C) A  B  2 (D) A  B  4
43. In a triangle ABC, let BC = 1, AC = 2 and measure of angle C is 30o . Which of the
following statement(s) is (are) correct?
(A) 2 sin A  sinB
(B) Length of side AB equals 5  2 3
(C) Measure of angle A is less than 30o
(D) Circumradius of triangle ABC is equal to length of side AB

Columns 1, 2 and 3 contains expressions, values of p and related information, respectively.

Column 1 Column 2 Column 3
(I) , ,  are such that 3 q 1
(i) p  (P) 
  a 2 4 2
2
  a2
3
  a3
Then
3     a
4 4

p
, (p, q are
4
a q
coprime)
(II) If px 2  5x  2  0 and p 16 (Q) q = 1
(ii) 
2
3x  10x  q  0 have both roots 15 15
common then
(III) If  2p  q  x 2  p  1 x  5  0 has both (iii) 4 = p q 1
(R) 
roots  . Then 8 2
(IV) 15 (iv) p = 1 (S) Final answer is divisible by 2
If Tn  n.n!, then t
n 1
n  p! q
44. Which of the following represent correct combination?

(A) (I) (iv) (P) (B) (II) (i) (Q)
(C) (IV) (ii) (Q) (D) (IV) (ii) (S)
45. Which of the following represent incorrect combination?

(A) (I) (iii) (Q) (B) (I) (iii) (S)
(C) (III) (iii) (P) (D) (IV) (ii) (Q)

(A) (I) (ii) (Q) (B) (I) (iv) (S)
(C) (II) (i) (Q) (D) (I) (iii) (Q)
Columns 1contains curves and columns 2 and 3 has some information related to them.
Column 1 Column 2 Column 3
(I) xy  2x  4y  4  0 (i) Focus is (P) Conjugate hyperbola is

4  4 2, 4  4 2 
 x  3  y  4   12
(II) xy  4x  4y  32 (ii) Asymptote is x = 3 (Q)  x  4  y  4   16
(III) xy  4x  3y (iii) Eccentricity = 2 (R) 3x 2  y 2  1
(IV) Conic is given by (iv)  x  4  y  2   4 is the (S) Rectangular hyperbola
ea  e  a conjugate hyperbola
x
2 3
e  e a
a
y
2

(A) (I) (iv) (P) (B) (II) (i) (Q)
(C) (IV) (ii) (Q) (D) (IV) (ii) (S)
48. Which of the following represent incorrect combination?

(A) (I) (iv) (S) (B) (II) (i) (Q)
(C) (IV) (iii) (R) (D) (IV) (ii) (Q)

(A) (I) (ii) (Q) (B) (I) (iv) (S)
(C) (II) (i) (P) (D) (I) (iii) (Q)
SECTION – C
50. If a d c b and ad  bc, where a,b,c,d  R  then the family of lines

a x  b y  c   d x  0
2 2 2 2
passes through a fixed point M  x 0 , y 0  . Find the value of
x  y  .
1
0
1
0
51. The circle x 2  y 2  4x  4y  4  0 is inscribed in a triangle which has two of its sides
along the coordinate axes. The locus of the circumcenter of the triangle is
1/2

x  y  xy  k x 2  y 2   0 . Find k k  0  .
52. Let PQ be a variable normal chord of the parabola y 2  4x whose focus is S. If the locus
of the centroid of the triangle SPQ is the curve gy 2  3x  5   ky 4  w where g, k, w,  N ,
find the least value of

g  k  w 
49
53. If the area of the quadrilateral formed by the common tangents of the circle x 2  y 2  25
and the ellipse

x2 y2
  1 is A. Then the value of
3 11A  1
is
 
36 16 333
  2     2  
 4 tan 2 1  tan 2   4 tan 2 1  tan 2 
54. Consider, P   ,  and Q   ,  where , 
 1  tan2  1  tan2    1  tan2  1  tan2  
 2 2  2 2
varies, If the locus of mid point of PQ, which subtends right angle at the origin is
2
  
p x 2  16y 2  q x 2  4y 2  where p,q  N , then find the least value of  p  q  .

Aiits 1719 Open Test Jeea Paper 1

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FIITJEE JEE (Advanced)-2019

Time Allotted: 3 Hours Maximum Marks: 183

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts.

Name of the Candidate

Acceleration due to gravity g = 10 m/s2

Gas Constant R = 8.314 J K1 mol1

Atomic No: H=1, He = 2, Li=3, Be=4, B=5, C=6, N=7, O=8,

1. In the isothermal expansion of an ideal gas:

2. A particle of mass m is attached to one end of the light inextensible

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3. A small block is connected to one end of a

4. A cyclic process ABCA shown in V-T diagram is performed with a B C

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6. A smooth massless wedge is pushed by a horizontal force m

7. Block A is placed on an inclined plane B making an angle of 30º with

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(Matching type - Single Correct Option)

Consider a particle in space which is near Earth.

8. Combination that will match with bounded system will be

9. Combination that will match with unbounded system

10. For moon Earth system (assumed orbital velocity)

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11. Correct combination for angular velocity of the rod will be

12. Correct combination for angular momentum of rod will be

13. Correct combination for linear velocity of mid point will be

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15. There is a quarter cylindrical wall at one portion of a

17. Find the mass of the hanging block in kg, which

18. A system of two identical rods (L shaped) of mass m, length L. P

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19. 10 g of Ne initially at a pressure of 506.625 KPa and temperature of 473 K expand

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24. Select correct statement.

(Matching type - Single Correct Option)

Column – 1 Column – 2 Column – 3

26. For Cl2 molecule, the only correct combination is

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27. For FeCl3 the only correct combination is

28. For the formation of a soluble compound which combination is correct?

Column – 1 Column – 2 Column – 3

30. The correct combination in which an aldehyde is formed

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32. The number of isomeric structure of di-substituted borazine (B3N3H4X2) is

33. The number of S-S bond(s) in tetrathionate ion is

34. The number of unpaired electron(s) in K2NiF6 is

35. The number of reducing sugars among the following is:

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Mathematics PART – III

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(Matching type - Single Correct Option)

Columns 1, 2 and 3 contains expressions, values of p and related information, respectively.

44. Which of the following represent correct combination?

45. Which of the following represent incorrect combination?

46. Which of the following represent correct combination?

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47. Which of the following represent correct combination?

48. Which of the following represent incorrect combination?

49. Which of the following represent correct combination?

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50. If a d c b and ad  bc, where a,b,c,d  R  then the family of lines

find the least value of

and the ellipse