2.34 Equilibrium constants for the complexes between cadmivm(ID) and chloride are Ky =
100, Ky ~ 4.0, Ka = 0.63, aud Xz ~ 0.20, Calculate the molar concentration of each
of the first four cadmium chloride complexes in a water sample if Cd* = 107" Mand
CI” = 107! M, Identify the most prevalent cadmium species,
3.3. A waste containing 1 percent sulfuric acid (10,000 mg/L} is neutralized by the
addition of a concentrated lime slurry (made by dissolving Ca(OH),(s) in water}. If
the water temperature is 15°C before neutralization, what is it after neutralization?
A sampie of groundwater with a teraperature of 16°C has 100 mg/L of Ca’* and
10 mg/L of CO}, Is this water in equilibrium with CaCO,(s)? If not, is
CaCO,(s) dissolving or precipitating?
3.13 The oxidation of ferrous iron (Fe**) to ferric iron (Fe**) by molecular oxygen can be
described by the following reaction;
AFe** (aq) + On(g) + 4H*(ag) = 4Fe** (aq) + 2H,0
(a) Using free energies of formation, calculate the equilibrium constant for this
reaction at 25°C.
(@) For a water in equilibrium with the atmosphere, a pH] of 2.0, and a total soluble
iron concentration of E mg/L, calculate the concentrations of Fe" (ag) and
te
3.23 What approximate osmotic pressure would be created across a semipermeable
membrane if water containing 0.01 M Na,SO,, 0.02 M MgCh, and 0.03 M CaCh
iz = on one side of the membrane and distilled water were on the other?3.33. On the basis of standard electrochemical potentials, which of the following metals
could act int a sacrificial manner to protect iron from corrosion: aluminum, copper,
eae, mean Wer, tin. and zinc’?437 Calculate the pHT of the equivalence point in the titration of solutions containing the
following concentrations of acetic acid with sodiam hydroxide: (a) 100 mg/L; ()
1000 mg/L; (c) 10,000 mg/L.
& Liter solution contains 100 mug of HCL, Calculate the following:
(a) Initial pH of the solution
(b) pH after addition of 1 mL of 1 N NaOH
(c) pH after addition of 2 mL of | N NaOH
(d@) pH after addition of 3 mL of 1 N NaOH
(e) mL of 1 N NaOH required to reach the equivalence point
as