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Duplex America 2000 Conference

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Practical aspects for production welding and control of duplex


stainless steel pressure and process plants
Authors: C. Baxter (Avesta Sheffield Ltd, Sheffield, UK) and M. Young (Whiteley Read Ltd, Rotherham, UK)

Keywords: duplex, welding procedures, production, properties, training

1 Summary rules are the basis. However, the emphasis,


balance and detail must be appreciated in
Good stainless steel practice is the basis for terms of duplex stainless steel.
welding duplex and superduplex grades. This paper describes some of the more
However, some issues from the generalized important aspects of good practice for
‘good practice’ rules must be emphasized duplex stainless steel so that welding pro-
where as other issues need only the same cedures may be designed to be technically
attention as when welding 300 series stain- and practically correct and relevant.
less steels.
This paper discusses good ‘duplex and
superduplex‘ stainless steel practice. 3 Duplex good practice: the basis
Issues around, for example, welding proce-
dure design, heat input and interpass tem- The guidance given here is considered in
perature are discussed. relation to pipe welding where the penetra-
The practical application of the rules is all tion bead is the corrosion ‘active’ surface;
important. The first step is to educate the other configurations are variations on this
work force into thinking ‘duplex’, i.e. not theme. It is assumed that the weld is to be
just another grade of stainless steel. Speci- put into service with no post-weld heat
fication and practical fabrication issues, as treatment.
applied to reactor and pressure vessel fab-
rication, are described. Welding procedures 3.1 Joint configuration
are given, together with the results of proce- The bevel design is determined by the nor-
dure qualification tests and production test mal criteria of welding access in relation to
plates. joint volume. Bevel angles of 30–35º are
standard for vee butts.
It is very important to consider the root zone
2 Introduction configuration. The welding consumable’s
nickel content is boosted by ~2% in order
Although duplex stainless steels are to stabilize the weld bead ferrite/austenite
increasingly used for pressure and process phase balance. Care must be taken to
plants in a wide range of industries and ensure that the increased nickel content is
applications, it is still important to remem- not diluted by parent material. This is prima-
ber and appreciate the ‘how to weld’ issues
associated with these steels.
When welding the generic C-Mn steel fam-
ily, the detailed grade characteristics deter-
mine the emphasis that must be placed on,
e.g., techniques to avoid hydrogen crack-
ing, heat input control etc. A similar concept
of balanced emphases exists for stainless
steel.
General Good Practice ‘rules’ exist in vari-
ous codes, e.g. EN 1011 Part 3, but the
emphasis of these rules must be balanced
and detailed for different generic grades of
stainless steel
Duplex stainless steel is in the stainless
steel family and therefore the good practice Figure 1. Optimum root pass heat input (hi root).

Stainless Steel World – ©2000 KCI Publishing BV


Practical aspects for production welding and control of duplex stainless steel pressure and process plants
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Figure 2. WPS design based on root run heat input.

rily achieved by controlling the root gap. zero gap but a heavier face (~5mm) (~0.2")
The root gap should be set and maintained on which to build the weld passes.
at nominally 2mm (80 thow) although
slightly larger root gaps can be tolerated for 3.2 Heat input and welding procedure design
22 and 23 chromium duplexes. It is well The most important elements of WPS
known that some welders weld ‘hotter’ or design are heat input level and balance.
‘colder’ than others. The root face would The root pass heat input is dependent on
generally be around 2mm (80 thow) the thickness and grade being welded. The
although feather edges are acceptable to ‘S’ curve shown in figure 1 illustrates this
welder preference. If too large a root gap or and identifies the potential implications of
root face is used, the heat input to complete welding too hot or too cold for a given thick-
the pass may be too high or the pass would ness.
be impractically thin or incomplete penetra- The heat input balance for a given joint is
tion will occur. based on the root pass heat input (HIroot).
Single- or double-sided welding etc. can be The cold, fill and capping pass heat inputs
used as dictated by the normal consider- are taken as a percentage of HIroot as illus-
ations of component being welded, thick- trated in figure 2. For example, if the appro-
ness and shop fabrication practices. priate heat input for a thicker joint is
Double-sided welding, for example, does 1.2kJ/mm (30.5kJ/in), the cold pass would
not require the same level of root configura- be deposited at between ~0.9 and
tion control provided 2 or more passes are 1.3kJ/mm (22.9 and 33kJ/in), i.e. ~75%
deposited on each side. The root gap and < HIroot < ~110%.
face would generally be determined by The balance of heat inputs is an important
more classic welding process requirements factor in maximizing the metal deposition
rather than alloy and metallurgical require- rate whilst minimizing the possibility of met-
ments. Thicker joints that can be sub- allurgical damage through unacceptable
merged arc welded would tend to have a intermetallic formation.

Stainless Steel World – ©2000 KCI Publishing BV


Duplex America 2000 Conference
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The heat input may need to be adjusted Given that interpass temperature is one of
slightly if the cap is the active surface or if the factors determining ∆t, there is a bal-
double-sided welding is used. In practice, ance between heat input and interpass. In
changing from one welding position to practical terms, the interpass temperature
another has very little influence on the root will be in the range 100 to 150ºC (210 to
pass heat input. 300ºF) dependent on the alloy and thick-
ness being welded.
3.3 Preheat and interpass temperature Various cooling techniques can be used to
Welding heat input is an important parame- maintain productivity in relation to interpass
ter that fabricators relate to. The issue is, in temperature control: equally the welder can
fact, cooling time (∆t) or cooling rate, which work on several joints at a time, one cooling
include heat input, thickness and ‘start’ while another is being welded.
temperature.
Preheating duplex stainless steel is 3.4 Balanced welding
extremely rare; to all intents and purposes Stainless steels have a higher coefficient of
assume that it is unnecessary. expansion than carbon steels and therefore
Interpass temperature must, however, be they tend to ‘move’ more during welding.
controlled. This must be taken into account.
Interpass temperature is the maximum tem- Production and economic factors require a
perature of the metal immediately prior to maximum joint completion rate.
starting any welding. It should be measured Metallurgical factors require control of root
in and around the area where the welding is gaps, interpass temperature etc.
about to start and where it is anticipated fin- These two seemingly conflicting aspects
ishing. The locations to check most care- can be resolved by using a balanced weld-
fully are along the underlying weld bead or ing technique.
on the bevel face, not 2" away on the plate We are all familiar with the conventional
or pipe surface. approaches including double-sided weld-

Figure 3. Balanced welding sequences.

Stainless Steel World – ©2000 KCI Publishing BV


Practical aspects for production welding and control of duplex stainless steel pressure and process plants
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ing, back-step welding, centre-out welding, In reality, plasma or laser cutting is used.
welding from stiff sections towards flimsy The cut edge should be mechanically
sections etc. They should be used. dressed to remove the cutting oxides and
The requirement for root configuration con- cutting HAZ.
trol can be significantly helped by adopting The joint must be fitted and tacked correctly
a ‘segmented’ approach (skip welding as to allow welding to be completed according
appropriate for plate welding). Segmented to the WPS. Bridge pieces and strong
welding should be used in conjunction with backs can be used as temporary attach-
adequate tacks and/or stiff line-up clamps. ments. Root, bridge and bullet tacks can all
Weld from 6 o’clock towards 3 then from 9 be used but the tack weld needs to be
o’clock towards 12, balancing the weld larger than that for C-Mn, maybe by 25–
bead around the joint in comfortable, con- 50%.
venient segments. This will help to keep the As with any welding which demands integ-
root gap open, allow the welder to maintain rity, the weld zone must be properly clean
the correct heat input and, importantly, and dry before starting to weld. The bevel
allow the welder to have increased continu- area should be solvent cleaned
ity of welding.
4.2 Production control and monitoring
Heat input control is very important, as pre-
4 Practical application of duplex good viously discussed. It is obviously rather
practice easy to set mechanized or automated weld-
ing equipment, e.g. submerged arc welding,
4.1 Joint preparation and fit-up to give the correct heat input. However,
Although machined joint preparations are manual welding can also be controlled by
preferred, it is not practical to use them all using the run-out length approach.
the time. Any thermal cutting technique Electrodes are characterized by their typical
results in a thermal history being retained at current, voltage and burn time. The heat
the cut edge. Consequently a similar input can therefore be controlled by moni-
thought pattern to that associated with toring the length over which the electrode is
welding heat input is appropriate, although ‘run-out’, figure 4. A requirement to weld
not to the same level and extent. with (e.g.) a heat input of 1.5kJ/mm (38kJ/

Steel grade AS 2205 Welding consumable: 2205


Wall thickness 5.5mm
Root gap 1.5mm
Root face 1.5mm
Welding position 1G
Interpass temp. 120˚C
PWHT None 2" NB pipe weld

Pass & Consum. Heat input Properties achieved (To contract require-
process diam. (mm) (kJ/mm) ments)
Phase balance Pass
Root GTA 2.4 0.75–1.2 Bends (R&F) 180º 4t Pass
Cold GTA 2.4 0.65–1.0 G48A @ 22ºC Pass
Cap GTA 2.4 0.65–1.0 CVN: Weld Metal >74 J @ –50ºC
CVN: weld metal >78 J @ –50ºC
(CVNs: 10×4.5mm)
Table 1. Welding procedure qualification data for GTA welded AS 2205 duplex stainless steel pipe.

Stainless Steel World – ©2000 KCI Publishing BV


Duplex America 2000 Conference
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Figure 4. Heat input control by electrode run-out length.

in) off a 3.25mm (1/8") diam. electrode these data help the welder to gauge travel
would result in a run out length of approxi- speed in relation to WPS requirements.
mately 110mm (4.3"). Shorter or longer run- The extent of monitoring is clearly depen-
out lengths corresponds to higher or lower dent on many factors. It would not normally
heat inputs, respectively. be appropriate to monitor any individual
Good working practice for welders is to welder for more than a few passes, say,
chalk the run-out length on the joint where once a week. This is a supportive activity,
they can see it during welding as a bench- not policing.
mark for self-monitoring. Other aspects of production that should be
Confidence to fabricate duplex correctly considered for monitoring include the avail-
and economically grows with experience ability and use of the equipment for check-
and being able to demonstrate a good level ing purge gas oxygen content, cleanliness
of production control. Production monitor- of plate and rolls, fit-up of joints
ing is the key.
Monitoring the welding operations, and 4.3 Welding process issues
having records to correlate with the WPS, is Welding process selection relates in the
a very powerful and effective method of: normal way to process characteristics and
economics. However, there are several spe-
a helping the welder to stay within param- cific aspects that should be considered in
eter ranges and relation to the duplex family.
b building the corporate confidence that The most common process for single-sided
duplex can be effectively fabricated root (and cold) passes is gas tungsten arc
welding (GTAW).
Such records might typically include job The fluxing processes result in a flux cover-
and welder identification, WPS number, ing on the cap and, where single-sided, on
pass number and heat input. Feedback of the root pass. Flux is a very effective crevice

Stainless Steel World – ©2000 KCI Publishing BV


Practical aspects for production welding and control of duplex stainless steel pressure and process plants
DA2_032
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Steel grade AS SAF 2507 Welding consumable 2507/P100


Wall thickness 10mm
Root gap 1–2mm
Root face 2mm
Welding position 1G
Interpass temp. 125ºC
PWHT None

Pass & Consum. Heat input Properties achieved (To contract requirements)
process diam. (mm) (kJ/mm)
Phase balance Pass
Root SMA 3.25 1.0–1.2 Bends (R&F) 180º 4t Pass
Cold SMA 3.25 0.8–1.0 G48A @ 35ºC Pass
Fill SMA 4.0 0.7–1.2 CVN: weld metal >56 J@ –30ºC
Cap SMA 4.0 0.8–1.2 CVN: weld metal J@ –30ºC
(10×7.5mm CVNs)
Table 2. Welding procedure qualification data for SMA welded AS SAF 2507 superduplex stainless steel.

former which may limit the corrosion perfor- dent on national and local practices. Propri-
mance of the welded component. Fluxing etary gas mixtures have also been
processes should only be used for root developed for the duplex grades.
runs where there is adequate access to the Argon/low-nitrogen proprietary gas mix-
root pass either for deslagging or for cut- tures are available for welding particularly
out and seal welding. the duplex grades. These gases may be
Submerged arc welding is a very efficient appropriate as shielding gas for welds that
process for filling and capping. However, have a high corrosion requirement.
the efficiency is reduced dramatically in, for The purge gas serves two purposes: to pre-
example, thick-walled pipe welding if the vent loss of nitrogen from the weld zone
welding must be stopped after each rota- during welding and to prevent root pass
tion for interpass temperature require- oxidation. The purge gas is used to displace
ments. Methods for effectively cooling the air from behind the joint. In most cases ade-
pipe must be implemented, taking care to quate oxidation protection is achieved if the
avoid the obvious issues of contamination, purging mixture contains < ~0.5% oxygen.
health and safety etc. Allowance must be If no nitrogen is present in this gas mixture,
made for deslagging. the nitrogen partial pressure in the weld
Flux cored arc welding (FCAW) is utilized for zone will be higher than in the purge gas
welding 22Cr and 23 Cr duplex grades. It is and there may be loss of nitrogen from the
a fast economic process suitable for joints weld metal particularly. A low level of nitro-
that do not have high demands for corro- gen should be retained in the purge gas to
sion or toughness. Heat input control of prevent this loss. Proprietary gas mixture
mechanized FCAW is obviously straightfor- containing 2–3% nitrogen can be used, in
ward but, when using the process manually, which case the purge gas must be ‘free of
the welder has no reference points to gauge oxygen’ before starting to weld. Alterna-
heat input in the same sense as run-out tively the oxygen content of the argon purge
length control is available in MMA (SMAW). gas can be controlled to contain ~0.5%
FCAW can be used for the two duplex retained oxygen, and therefore ~2% nitro-
grades that are most tolerant to heat input. gen.
Many contracts require that the welding
4.4 Gases oxidation is removed from penetration and
Argon and argon/helium gases are both capping beads. This should certainly be
used for shielding and purge gases depen- regarded as the norm. It is not possible to

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Duplex America 2000 Conference
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absolutely relate the color of the oxide inter- relates to actual production. Notch tough-
ference film to the performance of the joint ness and microstructural phase balance are
but any oxide on the root pass that is darker numerical data that may be sensitive to
than ‘light straw’ should be removed. It is changes in welding practice. The sub-
also advisable to investigate why a higher merged arc welding data in table 3 shows
level of oxidation has occurred. these data to be reasonably consistent
It is not possible to be dogmatic about across a number of welds, over a period of
which gases should be used as every fabri- 4 months and for a range of applied thick-
cator and country has its own practices. nesses. The maximum hardness and tensile
Notwithstanding the comments above, the strength are also consistent; no accelerated
gases should be clean, dry and inert. The corrosion testing failures were experienced
only exception to this is the possible inclu- in these or any other of the production test
sion of a low level of oxidizing species for pieces.
the gas shielded wire processes. Table 4 shows the data for a rather difficult
There is a strong positive argument for production weld, a compensating plate to
using the same gas as both shield and shell weld. This production weld was
purge gas. However, each fabricator’s welded as a prolongation to the strake, not
shop’s facilities and practices must be as a stand-alone test piece. The production
respected. weld is covered by two PQRs as shown. All
the properties achieved in production
reflect the qualification welds.
5 Procedures
It is very important that the required levels 6 Specifications
of properties are achieved in qualification
and that those levels are sustained in pro- It is extremely important to every one that
duction. realistic specifications are used. They must
The outline results of welding procedure be technically accurate and relevant and,
qualification are shown in tables 1 and 2. importantly, they must be accurately
Both of these procedures reflect the basis applied.
of sound procedure design, show the inevi- There are several difficult areas still being
table ranges in parameters that are used debated, not least of which is the signifi-
and result in properties that are achieved to cance of different product and fabrication
meet contract requirements. tests. For example, most specifications
Production test plate data, tables 3 and 4, state that the phase balance shall be within
demonstrate how the qualification data limits and no deleterious phases shall be

Prodn test plate I/D PQR 901542 902906 809205


PQR no. PQR 616 616 616 616
Thickness mm 16 30 30 14
UTS (X weld) MPa 785 762 775 720
CVN J W/M @ –50ºC >58 >57 >42 >61
J F/L @ –50ºC >79 >64 >78 >104
Ferrite %
Weld (Av) 42
Weld cap 49 49 48
Weld root 46 48 49
HAZ root 52 51 48
HAZ hardness Hv10 (max.) 279 272 274 283
G48A @ 22ºC Pass Pass Pass Pass
Table 3. Summary of AS 2205 production welding (SAW) data obtain for contract requirements.

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Practical aspects for production welding and control of duplex stainless steel pressure and process plants
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Prodn test plate I/D PQR PQR 809331


PQR no. PQR 615 PQR 634 615 & 634
Thickness mm 16 50 20–50 compensator plate
UTS (X weld) MPa 808 734 728
CVN J W/M @ –30ºC >48 >60 >58
F/L @ –30ºC >70 >36 >52
Ferrite %
Weld (Av) 42
Weld cap 41 47
Weld root 60 49
HAZ hardness Hv10 (max.) 274 279 276
G48A @ 22ºC Pass Pass Pass
Table 4. Summary of AS 2205 production welding (SMAW) data obtain for contract requirements.

detected during microstructural evaluation. duction test plate is to ensure that the
However, the significance of low levels of procedure is achieving the properties
intermetallic is, in general terms, almost obtained in qualification. Testing regimes
certainly doubtful. Additionally, the signifi- should be kept in this context. It is rarely
cance is related to application. It is notice- necessary to complete the same level of
able that, in recent years, industry is moving testing on a production test plate as has
from accepting low levels of intermetallic on been completed on a qualification plate.
concession to actually allowing low levels in Common sense and engineering judgement
application and project specifications. should be used to consider what a particu-
Given this situation, the question arises lar test is measuring, why it is being mea-
regarding how to accurately quantify low sured and how does it relate to other tests
levels of intermetallic content; it is very dif- that may be completed for this quality con-
ficult and expensive. trol operation. It does seem unnecessary to
Specifications must be applied accurately. duplicate all the qualification tests on the
ASTM A923 is a case in point. This standard production test plates if, of course, the
was written as a wrought product accep- results are satisfactory.
tance specification and as such it is very
valuable. However, it does get applied erro-
neously to fabrication acceptance. The 7 Education
requirements and implications of product
and fabrication ‘qualification’ should not be The education and awareness of the work-
confused. This specification is good for the force, at all levels, is very important.
intended purpose, product specification: The whole of the shop floor must be made
do not abuse it. aware that whilst the principles of 300
Accelerated corrosion testing of parent series welding are relevant (crater filling
material or welds is only as relevant to stain- techniques, tack weld condition etc.), the
less steel as notch toughness testing is to detail of duplex must be applied and proce-
carbon manganese steels (or stainless dures must be followed. The welders must
steels). It is no more, no less a QC test. be allowed time and facilities to ‘convert’
ASTM G48A and CVN testing are, at best, from welding 316 to welding duplex grades.
broad brush indicators of service perfor- They must practice the almost certainly
mance. They must not be over-specified or, unfamiliar technique of stringer bead weld-
indeed, over-interpreted. ing and continuous filler addition. Con-
There must be a distinction between quali- trolled heat input must become second
fication plates and production test plates. nature for duplex as it is for many high-
There is no doubt that qualification plates grade C-Mn steels.
should be thoroughly examined and char- The company’s management must be
acterized. However, the purpose of the pro- aware that the material be welded is rather

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more sophisticated than, say, 304 and that Attention to detail is carried through to
it requires greater attention to detail. practical application by good production
Everyone must know stainless steel confi- control and supportive process monitoring.
dently and think duplex absolutely. Specification of technical parameters is
obviously appropriate but the specifications
should not be over-prescriptive or mis-
8 Conclusions applied.
One of the keys to successful duplex fabri-
Stainless steel good practice is the basis for cation is education, at all levels of the com-
welding duplex grades. However, different pany. It is important that the shop floor
emphases must placed on various aspects understand the practical issues of duplex
for Duplex Stainless Steel Good Practice. fabrication, maybe also having a level of
Welding procedure design and control is appreciation of the technical background.
central to successful fabrication and appli- However, the CEO or President must also
cation. Experience and confidence is very understand that a sophisticated material is
important. Heat input, interpass tempera- being fabricated and greater attention to
ture and balanced welding techniques are detail is necessary. There is no substitute
three of the factors to which detailed atten- for experience in the successful supply of
tion must be paid. fabricated duplex process plant.

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Practical aspects for production welding and control of duplex stainless steel pressure and process plants
DA2_032
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