INDEX
CHAPTER 2` 4
FUNDAMENTAL ELEMENTS
1. RESISTOR
2. CAPACITOR
3. INDUCTOR
CHAPTER 3 12
THE MISSING ELEMENT: MEMRISTOR
1. THE 4TH NEW FUNDAMENTAL ELEMENT
2. NEED OF MEMRISTOR
CHAPTER 4 15
1
MEMRISTOR
CHAPTER 8 25
POTENTIAL APPLICATION
1. NANO-SCALE NATURE
2. REPLACEMENT OF FLASH MEMORY
3. REPLACEMENT OF D-RAM
4. BRAIN LIKE SYSTEMS
CHAPTER 9 27
COST
CHAPTER 10 28
NEW HORIZONS
1. MEMCAPACITOR
2. MEMINDUCTOR
CHAPTER 11 30
CONCLUSION
REFERENCES 31
2
MEMRISTOR
CHAPTER - 1
INTRODUCTION
Generally when most people think about electronics, they may initially think of
products such -as cell phones, radios, laptop computers, etc. others, having some engineering
background, may think of resistors, capacitors, etc. which are the basic components necessary
for electronics to function. Such basic components are fairly limited in number and each having
their own characteristic function.
Memristor theory was formulated and named by Leon Chua in a 1971 paper. Chua
strongly believed that a fourth device existed to provide conceptual symmetry with the resistor,
inductor, and capacitor. This symmetry follows from the description of basic passive circuit
elements as defined by a relation between two of the four fundamental circuit variables. A
device linking charge and flux (themselves defined as time integrals of current and voltage),
which would be the Memristor, was still hypothetical at the time. However, it would not be
until thirty-seven years later, on April 30, 2008, that a team at HP Labs led by the scientist R.
Stanley Williams would announce the discovery of a switching Memristor. Based on a thin
film of titanium dioxide, it has been presented as an approximately ideal device.
The reason that the Memristor is radically different from the other fundamental circuit
elements is that, unlike them, it carries a memory of its past. When you turn off the voltage to
the circuit, the Memristor still remembers how much was applied before and for how long.
That's an effect that can't be duplicated by any circuit combination of resistors, capacitors, and
inductors, which is why the Memristor qualifies as a fundamental circuit element.
The arrangement of these few fundamental circuit components form the basis of almost
all of the electronic devices we use in our everyday life. Thus the discovery of a brand new
fundamental circuit element is something not to be taken lightly and has the potential to open
the door to a brand new type of electronics. HP already has plans to implement Memristors in
a new type of non-volatile memory which could eventually replace flash and other memory
systems.
3
MEMRISTOR
CHAPTER - 2
FUNDAMENTAL ELEMENTS
1. RESISTOR
A resistor is a two- terminal electronic component that produces a voltage across its
terminals that is proportional to the electric current through it in accordance with
Ohm's law which states
―Voltage (V) across a resistor is proportional to the current (I) through it where the
constant of proportionality is the resistance (R)‖.
V = IR
Electronic symbol
(Europe) (US)
Resistors are elements of electrical networks and electronic circuits and are ubiquitous
in most electronic equipment. Practical resistors can be made of various compounds
and films, as well as resistance wire (wire made of a high-resistivity alloy, such as
nickel/chrome).
The primary characteristics of a resistor are the resistance, the tolerance, maximum
working voltage and the power rating. Other characteristics include temperature
coefficient, noise, and inductance. Less well-known is critical resistance, the value
below which power dissipation limits the maximum permitted current flow, and above
which the limit is applied voltage. Critical resistance depends upon the materials
constituting the resistor as well as its physical dimensions; it's determined by design.
4
MEMRISTOR
Resistors can be integrated into hybrid and printed circuits, as well as integrated
circuits. Size, and position of leads (or terminals) are relevant to equipment designers;
resistors must be physically large enough not to overheat when dissipating their power.
5
MEMRISTOR
6
MEMRISTOR
2. CAPACITOR
Capacitors are widely used in electronic circuits to block the flow of direct current while
allowing alternating current to pass, to filter out interference, to smooth the output of
power supplies, and for many other purposes. They are used in resonant circuits in radio
frequency equipment to select particular frequencies from a signal with many frequencies.
ELECTRONIC SYMBOL
CURRENT-VOLTAGE RELATION
The current i (t ) through a component in an electric circuit is defined as the rate of change
of the charge q (t ) that has passed through it. Physical charges cannot pass through the
dielectric layer of a capacitor, but rather build up in equal and opposite quantities on the
7
MEMRISTOR
electrodes: as each electron accumulates on the negative plate, one leaves the positive plate.
Thus the accumulated charge on the electrodes is equal to the integral of the current, as well
as being proportional to the voltage (as discussed above). As with any antierivative, a
constant of integration is added to represent the initial voltage v (t0).
This is the integral form of the capacitor equation,
Taking the derivative of this, and multiplying by C, yields the derivative form,
The dual of the capacitor is the inductor, which stores energy in the magnetic field rather
than the electric field. Its current-voltage relation is obtained by exchanging current and
voltage in the capacitor equations and replacing C with the inductance L.
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MEMRISTOR
3. INDUCTOR
In general, the relationship between the time-varying voltage v(t) across an inductor
with inductance L and the time-varying current i(t) passing through it is described by
9
MEMRISTOR
Inductors are used extensively in analog circuits and signal processing. Inductors in
conjunction with capacitors and other components form tuned circuits which can emphasize or
filter out specific signal frequencies. Applications range from the use of large inductors in
power supplies, which in conjunction with filter capacitors remove residual hums known
as the Mains hum or other fluctuations from the direct current output, to the small
inductance of the ferrite bead or torus installed around a cable to prevent radio frequency
interference from being transmitted down the wire. Smaller inductor/capacitor
combinations provide tuned circuits used in radio reception and broadcasting.
Two (or more) inductors which have coupled magnetic flux form a transformer, which is a
fundamental component of every electric utility power grid. The efficiency of a
transformer may decrease as the frequency increases due to eddy currents in the core
material and skin effect on the windings. Size of the core can be decreased at higher
frequencies and, for this reason, aircraft use 400 hertz alternating current rather than the
usual 50 or 60 hertz, allowing a great saving in weight from the use of smaller transformers.
An inductor is used as the energy storage device in some switched-mode power supplies.
The inductor is energized for a specific fraction of the regulator's switching frequency, and
de-energized for the remainder of the cycle. This energy transfer ratio determines the input-
voltage to output-voltage ratio. This XL is used in complement with an active semiconductor
device to maintain very accurate voltage control.
Inductors are also employed in electrical transmission systems, where they are used to depress
voltages from lightning strikes and to limit switching currents and fault current. In this field,
they are more commonly referred to as reactors.
Larger value inductors may be simulated by use of gyrator circuits.
10
MEMRISTOR
Fig: An inductor with two 47mH windings, as may be found in a power supply
11
MEMRISTOR
CHAPTER - 3
THE MISSING LINK: MEMRISTOR
There are six different mathematical relations connecting pairs of four fundamental
circuit variables viz. current I, voltage v, charge q, and magnetic flux Φ.
One of these relation (the charge is time integral of current) is determined from the
definition of two of the variables and another (the flux is the time integral of the
electromotive force or voltage) is determined from faraday’s law of induction. Thus
there should be four basic circuit elements described by the remaining relation between
the variables.
RESISTORS (v=RI)
Current
Voltage
(v) (i)
(v=dΦ/dt)
CAPACITORS (i=dq/dt) INDUCTORS
(q=Cv) Φ=Li
?
Charge Flux
(q) ? (Φ)
The relation between the charge and the flux was unknown, and so the device which
describes it. This led to the discovery of the fourth fundamental element which describes
the above missing relation between Charge and Flux.
12
MEMRISTOR
Memristor is one of four basic electrical circuit components, joining the resistor, capacitor,
and inductor. The Memristor, short for ―memory resistor‖ was first theorized by student Leon
Chua in the early 1970s. He developed mathematical equations to represent the Memristor,
which Chua believed would balance the functions of the other three types of circuit elements.
Since, there is no proof of any practical device which shows memristance, according to
Chua’s paper
In the beginning of 2006, the group of researchers headed by R.Stanley Williams at HP labs,
developed a simple model of binary switch based on the coupled movement of both charge
dopants and electrons in the semiconductor and saw that the defining equations for this switch
were identical to Chua’s mathematical definitions of memristor and they were able to write
down a defining equation for memristance of this device in terms of its physical and geometric
properties
MEMRISTOR
13
MEMRISTOR
2. NEED OF MEMRISTOR
The known three fundamental circuit elements as resistor, capacitor and inductor relates four
fundamental circuit variables as electric current, voltage, charge and magnetic flux. In that we
were missing one element to relate charge to magnetic flux. That is where the need for the
fourth fundamental element comes in. This element has been named as MEMRISTOR.
14
MEMRISTOR
CHAPTER - 4
MEMRISTOR: THEORY AND PROPERTIES
Electronic Symbol
Chua defined the element as a resistor whose resistance level was based on the amount of
Charge that had passed through the Memristor
MEMRISTANCE
o Memristance is a property of an electronic component to retain its resistance
level even after power had been shut down or lets it remember (or recall) the
last resistance it had before being shut off.
Chua’s. Theory
o Each Memristor is characterized by its memristance function describing the
charge-dependent rate of change of flux with charge.
As we know from, Faraday's law of induction that magnetic flux is simply the time
integral of voltage, and charge is the time integral of current, we may write the more
convenient
15
MEMRISTOR
This equation reveals that memristance defines a linear relationship
betweencurrent and voltage, as long as charge does not vary. Of
course,
Nonzero current implies instantaneously varying charge. Alternating
current, however, may reveal the linear dependence in circuit operation
by inducing a measurable voltage without net charge movement—as
long as the maximum change in q does not cause much change in M.
CURRENT VS. VOLTAGE CHARACTERISTICS
o This new circuit element shares many of the properties of resistors and shares
the same unit of measurement (ohms). However, in contrast to ordinary
resistors, in which the resistance is permanently fixed, memristance may be
programmed or switched to different resistance states based on the history of
the voltage applied to the memristance material. This phenomena can be
understood graphically in terms of the relationship between the current flowing
through a Memristor and the voltage
Applied across the Memristor.
o In ordinary resistors there is a linear relationship between current and voltage
so that a graph comparing current and voltage results in a straight line. However,
for Memristors a similar graph is a little more complicated. It illustrates the
current vs. voltage behavior of memristance.
16
MEMRISTOR
o In contrast to the straight line expected from most resistors the behavior of a Memristor
appear closer to that found in hysteresis curves associated with magnetic materials. As
observed above that two straight line segments are formed within the curve. These two
straight line curves may be interpreted as two distinct resistance states with the remainder
of the curve as transition regions between these two states.
1. HYSTERESIS MODEL
Hysteresis model illustrates an idealized resistance behavior demonstrated in accordance with above
current-voltage characteristic wherein the linear regions correspond to a relatively high resistance (RH)
and low resistance (RL) and the transition regions are represented by straight lines.
Fig: Idealized hysteresis model of resistance vs. voltage for memristance switch.
Thus for voltages within a threshold region (-VL2<V<VL1 in Fig. 4) either a high or low resistance
exists for the Memristor. For a voltage above threshold V L1 the resistance switches from a high to a
low level and for a voltage of opposite polarity above threshold V L2 the resistance switches back to a
high resistance.
17
MEMRISTOR
Stanley found an interesting feature of memristor that it can Re-program itself according to its
previous state for a given output.
This feature is revolution in the programming field of modern era. To verify their statement,
they have done a experiment which was related to programming of memristors. The
specifications of their experiment, which proved the fact about re-programming, is described
by an example.
18
MEMRISTOR
In this figure, “A” shows equivalent circuit schematic of the hybrid programmable logic
array. The dashed lines define the nanocrossbar boundary, the black dots are the
programmed memristors, VA through VD are the 4 digital voltage inputs and VOUT is the
output voltage. V1 and V2 are the transistor power supply voltage inputs. A single
nanowire has a resistance of ≈33 kΩ, and 4 connected in series provides a ≈130-kΩ on-
chip load resistor for a transistor.
Figure “B” illustrates the map of the conductance of the memristors in the crossbar. The
straight lines represent the continuous nanowires, and their colors correspond to those of the
circuit in A. The broken nanowires are the missing black lines in the array. The squares
display the logarithm of the current through each memristor at a 0.5-V bias.
The above figure is the equivalent circuit for testing the compound logic operation. This
circuit computes AB+CD from 4 digital voltage inputs, VA to VD, representing the 4 input
values A to D, respectively. The operations AB and CD are performed on 2 different rows in
the crossbar, and the results are output to inverting transistors, which then restore the signal
amplitudes and send voltages corresponding to NOT (AB) and NOT (CD), or equivalently A
NAND B and C NAND D and denoted using Boolean algebra as AB and CD, respectively,
back onto the same column of the crossbar. There, the operation AB X CD is performed and
the result is sent to another inverting transistor, which outputs the result AB X CD = AB +
CD = AB + CD, following from De Morgan’s Law, as an output voltage level on VOUT. The
signal path is emphasized by the thick colored lines red–blue– green from the inputs to the
output. In red, 2 programmed-ON memristors are linked to a transistor gate to perform as a
NAND logic gate with the inputs VA and VB in one operation or VC and VD in the other. In
blue, the outputs from the first 2 logic gates are then connected to the second stage NAND
gate formed from 2 other programmed-ON memristors and 1 transistor. The green line
shows the output voltage. This experiment began with the configuration of the array. The
conductivity of all of the crossbar nanowires was measured by making external connections
with a probe station to the contact pads at the ends of the fan out wires connected to each
nanowire, and those that were not broken or otherwise defective are shown as straight black
or colored lines. Each required programmed-ON memristor was configured by externally
applying a voltage pulse of +4.5 V across its contacting nanowires, whereas all other
memristors in the row and column of the target junction were held at 4.5/2 = 2.25 V, a
voltage well below the effective threshold such that those junctions were not accidentally
programmed ON.
19
MEMRISTOR
CHAPTER - 5
DELAY IN DISCOVERY OF MEMRISTOR
Memristor, was not been seen before because the effect depends on atomic-scale movements,
it only popped up on the Nan scale of William’s devices. Information can be written into the
material as the resistance state of the memristor in a few nanoseconds using few Pico joules of
energy-― as good as anything needs to be‖.
20
MEMRISTOR
The Diagram with a simplified equivalent circuit. V, voltmeter; A, ammeter.
Applied voltage and resulting current as a function of time t for a typical
memristor.
The equation given below describes the memristance of any device as a function of charge:
Where
M(q) = Memristance of a device as a function of charge
Roff = High resistance state
Ron = Low resistance state
µv = Mobility of charge
q(t) = Charge flowing through device at any time t
D = Thickness of semiconductor film sandwiched between two metal contacts
For any material, this term is 1,000,000 times larger in absolute values at nanometer scale then is
at micrometer scale because of factor 1/D2 and memristance is correspondingly more significant.
So it
Was not possible to get the feel of memristance at millimeter scale that is why it took 30
years to
Discover this nanoscale component.
21
MEMRISTOR
CHAPTER - 6
WORKING OF MEMRISTOR
Semiconductors are doped to make them either p-type or n-type. For example, if silicon is
doped with arsenic, it become n-type. However, when we apply an electric field to piece of
n-type silicon, the ionized arsenics atoms sitting inside the silicon lattice will not move. We
do not want them to move, in any case. Pure titanium dioxide (TiO2), which is also a
semiconductor, has high resistance, just as in the case of intrinsic silicon, and it can also be
doped to make it conducting. If an oxygen atom, which is negatively charged, is removed
from its substantial site in TiO2, a positively charged oxygen vacancy is created (V0+) is
created, which act as a donor of electrons. These positively charged oxygen vacancies (V0+)
can be in the direction of current applying electric field. Taking advantage of this ionic
transport, a sandwich of thin conducting and non-conducting layers of TiO2 was used to
release memristor
Consider, we have two thin layers of TiO2, one highly conducting layer with lots of oxygen
vacancies(V0+ ) and the other layer undoped, which is highly resistive. Suppose that good
ohmic contact are formed using platinum electrodes on either side of sandwich of TiO2. The
electronics barrier between the undoped TiO2 and the metal looks broader. The situation remains the
same, even when a negative potential I applied to electrode A, because the positively charged oxygen
vacancies (V0+) are attracted towards electrode A and the length of undoped region increases. Under
22
MEMRISTOR
these conditions the electronics barrier at the undoped TiO2 and the metal is still too wide and it
will be difficult for the electrons to cross over the barrier.
However, when a positive potential is applied at electrode A the positively charged oxygen
vacancies are repelled and moved into the undoped TiO2. This ionic movement towards electrode
B reduces the length of undoped region. When more positively charged oxygen
vacancies(V0+) reach the TiO2 metal interface, the potential barrier for the electrons become
very narrow, as shown, making tunneling through the barrier a real possibility. This leads to a
large current flow, making the device turn ON. In this case, the positively charged oxygen
vacancies (V0+) are present across the length of device. When the polarity of the applied
voltage is reversed, the oxygen vacancies can be pushed back into their original place on the
doped side, restoring the broader electronic barrier at TiO2 metal interface. This forces the
device to turn OFF due to an increase in the resistance of the device and reduce possibility for
carrier tunneling.
The specialty of Memristor is not just that it can be turned OFF or ON, but, that it can
actually remember the previous state. This is because when the applied bias is removed,
the positively charged Ti ions (which are actually the oxygen deficient sites) do not move
anymore, making the boundary between the doped and undoped layers TiO2 immobile.
When we next apply a bias (positive or negative) to the device, it starts from where it was
left. Unlike in the case of typical semiconductors, such as silicon in which only mobile
carrier moves, in the case of memristor both the ionic and the electron movement, into the
undoped TiO2 and out of undoped TiO2 are responsible for the hysteresis in its cuurent-
coltage characteristic.
23
MEMRISTOR
CHAPTER - 7
ANALOGOUS SYSTEM
In William switches, the upper resistor was made of pure semiconductor, and the lower of
the oxygen-deficient material metal. Applying a voltage to the device pushes charged
bubbles up from the metal, radically reducing the semiconductor’s resistance and making
it into a full-blown conductor. A voltage applied in the other direction starts the merry-go-
round revolving the other way: the bubbles drain back into the lower layer, and the upper
layer reverts to a high resistance, semiconducting state.
The crucial thing is that, every time when the voltage is switched off, the merry-go-round
stops and the resistance is frozen. When the voltage is switched on again, the system
―remembers‖ where it was, waking up in the same resistance state.
The analogous system of memory resistor or ―memristor‖ is perfectly explained, assuming
that memristor behaves like a pipe whose diameter varies according to the amount and
direction of
current passing through it.
24
MEMRISTOR
CHAPTER - 8
POTENTIAL APPLICATIONS
1. NANO-SCALE NATURE
The main objective in the electronic chip design is to move computing beyond the
physical and fiscal limits of conventional silicon chips. For decades, increases in chip
performance have come about largely by putting more and more transistors on a circuit. Higher
densities, however, increase the problems of heat generation and defects and affect the basic
physics of the devices.
Memristor, was not been seen before because the effect depends on atomic-scale
movements, it only popped up on the nanoscale of William’s devices. Information can be
written into the material as the resistance state of the memristor in a few nanoseconds using
few Pico joules of energy-― as good as anything needs to be‖. And once written memory
stays written even when the power is shut.
25
MEMRISTOR
Computers using conventional D-RAM lack the ability to retain information once they are
turned off. When power is restored to a D-RAM-based computer, a slow, energy-consuming
"boot-up" process is necessary to retrieve data stored on a magnetic disk required to run the
system. the reason computers have to be rebooted every time they are turned on is that their
logic circuits are incapable of holding their bits after the power is shut off. But because a
Memristor can remember voltages, a Memristor-driven computer would arguably never need
a reboot. ―You could leave all your Word files and spreadsheets open, turn off your computer,
and go get a cup of coffee or go on vacation for two weeks
4. BRAIN-LIKE SYSTEMS
As for the human brain-like characteristics, Memristor technology could one day lead
to computer systems that can remember and associate patterns in a way similar to how people
do.
This could be used to substantially improve facial recognition technology or to provide
more complex biometric recognition systems that could more effectively restrict access to
personal information. These same pattern-matching capabilities could enable appliances that
learn from experience and computers that can make decisions.
It is observed that the complex electrical response of synapses to the ebb and flow of
potassium and sodium ions across the membrane of each cell which allows the synapses to
alter their response according to the frequency and strength of the signals. It looked
maddeningly similar to the response a memristor would produce.
26
MEMRISTOR
CHAPTER - 9
COST
Hewlett-Packard surprised the electronics industry in 2008 by building the first working
memristor – a fundamentally new kind of electronic circuit that can store multiple levels of
data in a single cell. Since then, HP has touted memristors as a revolutionary alternative to
transistors that is poised to transform computing, and the $77 billion memory chip market,
with chips that are fast, durable and energy efficient, and retain data when powered off.
Knowm Inc., a small Santa Fe, N.M., company have brought the industry’s first
memristor chips to market.
Knowm’s chips, priced at $220 each, are clearly intended for experimentation, not
actual production.
CEO Alex Nugent, who co-founded Knowm after working for Los Alamos National
Laboratory, concedes that these initial memristor chips are expensive and far from ready for
commercial use. But they’re a starting point for researchers to learn about the technology.
27
MEMRISTOR
CHAPTER - 10
NEW HORIZONS
After the discovery of memristor the authors have taken a new step towards the new
devices with properties like memristor.
In 2009, Ventra, Pershin, and Chua extended the concept of the memristor to
memcapacitor and meminductor, which are defined by the charge–voltage relation and the
current–flux relation, respectively. These memory devices are common at the nanoscale,
where the dynamical characteristics of ions and electrons are likely to depend on the
histories of the systems that exhibit their memorability. These nanoscale devices can store
information without a power source, and their combination in circuits is likely to find new
applications in non-volatile memory, and to simulate learning, adaptive, and spontaneous
behaviors. Therefore, the nanoscale memory device is becoming a new hot spot in
research.
In 2009, a piecewise model of the memcapacitor was presented. In fact, it has long been
found that a nanoscale capacitor possesses a memory effect, and shows a capacitance–
voltage or charge–voltage hysteresis characteristic, the examples include Ge nanocrystal
embedded Hf-aluminate high- k gate dielectric metal oxide semiconductor structure
containing nanocrystals deposited by ion-beam-assisted electron beam deposition. Since
then some systems with the memcapacitance property have been found, including
vanadium dioxide metamaterials, ionic memcapacitive effects in nanopores, the analog
memory capacitor based on field configurable ion-doped polymers, and the solid-state
memcapacitive system with negative and diverging capacitance.
28
MEMRISTOR
1. MEMCAPACITOR
2. MEMINDUCTOR
The memcapacitor meminductor are the memdevices in which the capacitance and
inductance respectively depends on the state and history of the system.
They show pinched hysteresis loop in the constitutive variables that define them:-
The difference between the Memristor and both these devices is that they store energy
whereas memristor cannot.
MEMCAPACITOR MEMINDUCTOR
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MEMRISTOR
CHAPTER - 11
CONCLUSION
30
MEMRISTOR
REFERENCES
1. WWW.GOOGLE.COM
2. WWW.WIKIPEDIA.COM
3. WWW.HOWSTUFFWORKS.COM
5. HTTP://WWW.MEMRISTOR.ORG/
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