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Paper Code : 1001CT103516015

ENGLISH

CLASSROOM CONTACT PROGRAMME


(Academic Session : 2016 - 2017)

JEE (Main + Advanced) : LEADER COURSE


PHASE-III to VII (SCORE-I)
Test Type : PART TEST Test Pattern : JEE-Advanced
TEST DATE : 05 - 03 - 2017
Time : 3 Hours PAPER – 1 Maximum Marks : 234

READ THE INSTRUCTIONS CAREFULLY


GENERAL :

1. This sealed booklet is your Question Paper. Do not break the seal till you are told
to do so.
2. Use the Optical Response sheet (ORS) provided separately for answering the questions.

DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR


3. Blank spaces are provided within this booklet for rough work.
4. Write your name, form number and sign in the space provided on the back cover of this
booklet.
5. After breaking the seal of the booklet, verify that the booklet contains 32 pages and that
all the 20 questions in each subject and along with the options are legible. If not, contact
the invigilator for replacement of the booklet.
6. You are allowed to take away the Question Paper at the end of the examination.

OPTICAL RESPONSE SHEET :


7. The ORS will be collected by the invigilator at the end of the examination.

8. Do not tamper with or mutilate the ORS. Do not use the ORS for rough work.
9. Write your name, form number and sign with pen in the space provided for this purpose on
the ORS. Do not write any of these details anywhere else on the ORS. Darken the
appropriate bubble under each digit of your form number.
DARKENING THE BUBBLES ON THE ORS :
10. Use a BLACK BALL POINT PEN to darken the bubbles on the ORS.

11. Darken the bubble COMPLETELY.

12. The correct way of darkening a bubble is as :

13. The ORS is machine-gradable. Ensure that the bubbles are darkened in the correct
way.
14. Darken the bubbles ONLY IF you are sure of the answer. There is NO WAY to erase
or "un-darken" a darkened bubble.
15. Take g = 10 m/s2 unless otherwise stated.
Please see the last page of this booklet for rest of the instructions
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1

SOME USEFUL CONSTANTS


Atomic No. H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58,
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,

 Boltzmann constant k = 1.38 × 10–23 JK–1


1
 Coulomb's law constant = 9 ×10 9
4 0
 Universal gravitational constant G = 6.67259 × 10–11 N–m2 kg–2
 Speed of light in vacuum c = 3 × 108 ms–1
 Stefan–Boltzmann constant  = 5.67 × 10–8 Wm–2 –K–4
 Wien's displacement law constant b = 2.89 × 10–3 m–K
 Permeability of vacuum µ0 = 4 × 10–7 NA–2
1
 Permittivity of vacuum 0 =
0 c2
 Planck constant h = 6.63 × 10–34 J–s
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HAVE CONTROL  HAVE PATIENCE  HAVE CONFIDENCE  100% SUCCESS

PHYSICS
BEWARE OF NEGATIVE MARKING
PART-1 : PHYSICS
SECTION–I(i) : (Maximum Marks : 32)
 This section contains EIGHT questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of
these four option(s) is (are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the
ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is (are)
darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases.
1. A circular conducting loop of radius r0 and having resistance per unit length  as shown in
the figure is placed in a magnetic field B which is constant in space and time. The ends of the
loop are crossed and pulled in opposite directions with a velocity v such that the loop always
remains circular and the radius of the loop goes on decreasing, then

(A) Radius of the loop changes with r as r = r0 – vt/


(B) EMF induced in the loop as a function of time is e = 2Bv[r0 – vt/]
Bv
(C) Current induced in the loop is I =
2

Bv
(D) Current induced in the loop is I =

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2. Current in R3 in the shown circuit :-
PHYSICS

E L

R3
R1
C R2

(A) just after closing the switch is zero (B) long after closing the switch is zero

E E
(C) just after closing the switch is (D) long after closing the switch is
R3 R3
3. A vessel of uniform cross-section open at the top with an orifice at its bottom contains oil
(relative density 0.8) on top of water. It is immersed vertically in a large open tank of same
oil as shown in figure. In which of following configuration will liquid level remain same.
(Water does not come out or oil does not enter vessel) :- (Take : area of orifice = 1 mm2 and
area of vessel as 100 cm2)

oil 5m

oil oil
Water 10m

Oil 5m Oil 12m Oil 8m Oil 12.5m


15m 15m 15m 15m
(A) Oil (B) Oil (C) Oil (D) Oil
Oil Water 8m Oil Oil Oil
Water 2.4m Water 4m Water 2m

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4. A series RLC circuit is activated by a frequency () variable ac source of voltage VS volt as
shown in the circuit. VRL and VC are the potential drops across RL and C respectively. Select

PHYSICS
the incorrect statement(s) :-
VS
~
C
R L

(A) At low frequency limit, both VRL and VC are proportional to 


1
(B) At high frequency limit, VRL approaches VS but VC is proportional to
2
1
(C) At high frequency limit, both VRL and VC are proportional to
2
(D) At low frequency limit, VRL is proportional to , whereas VC approaches VS
5. A long straight cylindrical shell has inner radius Ri and outer radius R0. It carries current i,
uniformly distributed over its cross section. A wire is to be placed parallel to the cylinder
axis, in the hollow region (r < Ri ).
(A) The magnetic field is zero everywhere in the hollow region. We conclude that the wire is
on the cylinder axis and carries current i in the same direction as the current in the shell
(B) The magnetic field is zero everywhere outside the shell (r > R0). We conclude that the
wire is on the cylinder axis and carries current i in the direction opposite to that of the
current in the shell.
(C) The magnetic field is zero everywhere in the hollow region. We conclude that the wire
may be anywhere in the hollow region but must be carrying current i in the same direction
as the current in the shell
(D) The magnetic field is zero everywhere in the hollow region. We conclude that the wire
does not carry any current
6. A soap film is formed on a vertical equilateral triangular frame ABC. Side BC can move
vertically always remaining horizontal. If m is the mass of rod BC, and T is surface tension of
soap film. Mark the correct statement(s) :-

mg
(A) The length of BC in equilibrium is
2T
mg
(B) The length of BC in equilibrium is
T
3m
(C) The time period of small oscillations about the equilibrium position is 
T
m
(D) The time period of small oscillations about the equilibrium position is 
3T
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7. The arrow OA in the PV diagram shown in figure represents a reversible adiabatic expansion
PHYSICS

of an ideal gas. The same sample of gas, starting from the same state O, now undergoes a
process to the same final volume. Select the appropriate combination of process and final
state.
P O

B
A
C
V
(A) Process : isothermal ; final state : B (B) Process : free expansion ; final state : B
(C) Process : isothermal ; final state : C (D) Process : free expansion ; final state : C
8. If you were to blow smoke into the space between the barrier of standard YDSE and the
viewing screen of figure, the smoke would show
P
r1
y
S1
r2
 
d Q
O

S2 

L
Viewing screen

(A) No evidence of interference between the barrier and the screen


(B) Evidence of interference everywhere between the barrier and the screen.
(C) Maxima are localised and located on hyperboloids.
(D) Maxima are non-localised and located on hyperbolic planes.
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SECTION–I(ii) : (Maximum Marks : 18)

PHYSICS
 This section contains THREE paragraphs.
 Based on each paragraph, there are TWO questions.
 Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four options
is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases.
Paragraph for Questions 9 and 10
The optical properties of a medium are governed by its relative permittivity (r) and relative
permeability (µr). For conventional materials like water or glass, which are usually optically
transparent, both of their r and r are positive, and refraction phenomenon meeting Snell’s
law occurs when light from air strikes obliquely on the surface of such kind of substances. In
1964, a Russia scientist V. Veselago rigorously proved that a material with simultaneously
negative r and r would exhibit many amazing and even unbelievable optical properties. In
early 21st century, such unusual optical materials were successfully demonstrated in some
laboratories. Nowadays study on such unusual optical materials has become a frontier scientific
research field. Through solving several problems in what follows, you can gain some basic
understanding of the fundamental optical properties of such unusual materials. It should
be noticed that a material with simultaneously negative  r and r possesses the
following important property. When a light wave propagates forward inside such a
medium for a distance , the phase of the light wave will decrease, rather than increase
an amount of r r k as what happens in a conventional medium with simultaneously
positive r and r . Here, positive root is always taken when we apply the square-root
calculation, while k is the wave vector of the light. In the questions listed below, we
assume that both the relative permittivity and permeability of air are equal to 1.
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9. A light beam strikes from air on the surface of such an unusual material with relative
PHYSICS

permittivity r < 0 & relative permeability µr < 0. If 'd' denotes the length, then :

B
1 1
air A C
medium
E
D r

d BC
(A) d CD  d AE  (B) d CD  d BC   r  r d AE
r r

(C) sin  r  r  r sin 1 (D) d CD  d AE  r  r d BC

10. Choose the CORRECT option :-

(A) (B)
µr < 0 µr < 0
r < 0 r < 0

(C) (D)
µr < 0 µr < 0
r < 0 r < 0

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Paragraph for Questions 11 and 12

PHYSICS
Let us do the Young's double slit experiment with electron rather than light waves. We make
an electron gun which consists of a tungsten wire heated by an electric current and surrounded
by a metal box with a hole in it. If the wire is at negative potential w.r.t. the box, electron
emitted by the wire (thermionic emission) will be accelerated towards the walls and same
will pass through the hole. All the electrons coming out of this gun will have the same energy,
qV. In front of gun there is a wall with two slits in it as shown. Beyond the wall there is
another plate which acts as a screen. The no. of electrons arriving at the screen/area/time can
be measured. When the graph of this is plotted with y coordinate on the screen, we obtain the
graph as seen in YDSE experiment. This can be explained using de broglie's hypothesis which
states that electrons also behave like waves.
y
detector
1
d
2
ELECTRON
GUN D
WALL Screen
(b)
(a)
11. Which of following would increase fringe width, assuming that  << d ?
(A) Increase temperature of wire (B) Decrease D
(C) Increase d (D) Decrease voltage V
12. Suppose we go on increasing the voltage from a very low value.Beyond a certain voltage, we
obtain 3 maxima on the screen. What is the voltage?

h2 5h2 9h2 7h 2
(A) (B) (C) (D)
2mqd 2 2mqd 2 2mqd 2 2mqd 2
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Paragraph for Questions 13 and 14
PHYSICS

The first nuclear reaction ever observed was by ernest Rutherford in 1919. It was triggered
14
by -particles incident on an isotope of nitrogen 7N . He observed a proton was emitted

along with another element x. Let us assume that 14 nucleus was initially stationary. For
7N

this reaction to occur, -particle must touch the nitrogen nucleus. The distance between
their centres at this moment is d. For this problem, we will neglect the effect of outer electrons
14
in 7N . Symbols have their usual meanings.

13. Value of d is
(A) R0(21/3 + 71/3) (B) R0(22/3 + 72/3) (C) R0(22/3 + 142/3) (D) R0(22/3 + 141/3)
14. The minimum initial kinetic energy of -particle so that reaction can occur is :-

18ke2 14ke2 18ke2 14ke2


(A) (B) (C) (D)
R0 (22 / 3  14 2 / 3 ) R0 (22 / 3  141 / 3 ) R0 (22 / 3  141 / 3 ) R0 (22 / 3  72 / 3 )

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SECTION–II : (Maximum Marks : 8)

PHYSICS
 This section contains ONE question.
 Question contains two columns, Column-I and Column-II.
 Column-I has four entries (A), (B), (C) and (D)
 Column-II has five entries (P), (Q), (R), (S) and (T)
 Match the entries in Column-I with the entries in column-II.
 One or more entries in Column-I may match with one or more entries in Column-II.
 The ORS contains a 4 × 5 matrix whose layout will be similar to the one shown below :
(A) (P) (Q) (R) (S) (T)

(B) (P) (Q) (R) (S) (T)

(C) (P) (Q) (R) (S) (T)

(D) (P) (Q) (R) (S) (T)


 For each entry in column-I, darken the bubbles of all the matching entries. For example,
if entry (A) in Column-I matches with entries (Q), (R) and (T), then darken these three
bubbles in the ORS. Similarly, for entries (B), (C) and (D).
 For each question, marks will be awarded in one of the following categories :
For each entry in Column-I
Full Marks : +2 If only the bubble(s) corresponding to all the correct match(es) is (are)
darkened
Zero Marks : 0 In none of the bubbles is darkened
Negative Marks : –1 In all other cases
1. Column-I shows certain system at t = 0. Column-II shows its behavior there after. Neglect
dissipative forces in all cases.
Column-I Column-II
(A) System experiences net torque (P) A charged bead is constrained to move along
intially about C. a non conducting ring in gravity free space. A
dipole is fixed at the centre of ring. Charge is
released from perpendicular bisector of dipole
at t = 0. System is bead.

 C +Q
p
charged
bead

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(B) Angular velocity about C first (Q) A spherical ball made of wood is released
PHYSICS

increases then decreases inside water from rest in the configuration


shown at t = 0. Point C is geometric centre of
ball. System is ball.

C.M. of
ball, nonuniform
mass distribution
C

(C) System executes periodic motion (R) Disc hangs with an elastic wire of constant
torsional stiffness. Uniform magnetic field is
suddenly switched on at t = 0.
System is disc.


B

uniformly
C charged disc

(D) Acceleration of centre of mass (S) A current carrying coil is placed in a uniform
of system is zero initially. magnetic field parallel to the plane of coil at
t = 0, coil lies in a gravity free space.
System is coil.

B
C

(T) A boy on a swing of small angular amplitude.


When swing gets to mean position (t = 0) boy
instantaneously stands up.
System is swing & boy.

Space for Rough Work

SECTION–III : Integer Value Correct Type


No question will be asked in section III

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SECTION–IV : (Maximum Marks : 20)

PHYSICS
 This section contains FIVE questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both
inclusive.
 For each question, darken the bubble corresponding to the correct integer in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 In all other cases.
1. A point like sound source emits sound in all direction uniformly. An observer who is at a
distance of 50 m from the source detects sound of intensity 10–8 watt/m2. If the bulk modulus
of air is 1.6 × 105 N/m2 and velocity of sound is 340 m/s. Find pressure amplitude at the position
of observer. If your answer is x × 10–3 N/m2 fill value of [x] (nearest integer)
2. One mole of an ideal monoatomic gas is taken from state A to state B through a polytropic
3 1/ 2
process in which gas obeys law P = T . It is found that its temperature increases by 100 K
2
in this process. Now it is taken from state B to C through another process for which internal
1 1/ 2
energy is related to volume as U = V , where volume at B is 100 m3 and at C it is 1600 m3.
2
Find the total work performed by the gas (in Joule). Both the processes have propotionality
x  45
constant unity with necessary dimensions. If your answer is x fill value of .
60
[Take : R = 8.3 J/mol-K]
3. A lizard of mass 4g is warming it self in the bright sunlight. It's surface area is 4.2 cm2, but its
body casts a shadow of area 1.4 cm2 on a piece of paper held perpendicular to sun rays. The
intensity of sun rays at earth is 1000 W/m2. Assume that specific heat capacity of lizard is
same as that of water and its body behaves like a black body, also neglect the radiation from
the lizard's body. How long (in minutes) must lizard lie in sun in order to raise it's temperature
n
by 5°C. Specific heat capacity of water is 4200 J/kgºC. If your answer is n fill value .
5
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4. The reaction 73 Li 11 H  74 Be 10 n is endothermic. Assuming that Li nuclei is free and at rest.
PHYSICS

What is the minimum kinetic energy (in keV) of incident proton so that this reaction
N
occurs ? Take Q value of this reaction as –1645 keV. If your answer is N fill value .
235
5. When the voltage applied to an X-ray tube increased from V1 = 15.5 KV to V2 = 31 KV, the
wavelength interval between the K line and the short wavelength cut-off of the continuous
X-ray spectrum increases by a factor of 1.3. Find the atomic number of the element of the
N
target. If your answer is N fill value of . (Take : hc = 1240 eV nm and R = 1 × 107 /m)
13
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PART-2 : CHEMISTRY

CHEMISTRY
SECTION–I(i) : (Maximum Marks : 32)
 This section contains EIGHT questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of
these four option(s) is (are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the
ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is (are)
darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases.
1. Which of the following are correct regarding associated colloids :
(A) They behave as normal electrolytes at low concentrations, but at higher concentrations exhibit
colloidal behaviour
(B) The formation of micelles takes below a particular temperature known as kraft
temperature (Tk)
(C) Associated colloids have both lyophobic and lyophillic parts
(D) For soaps, the CMC is 10–4 to 10–3 mol L–1
2. Which of the following is/are correct regarding the given graph's for an ideal gas.

Temp. is For the same


same for both gas gas at two
different temp.
dN dN
Ndu M2 Ndu T2
M1 T1
u u

(A) M2 > M1 (B) M1 > M2 (C) T2 > T1 (D) T1 > T2


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3. Select the CORRECT order :-


CHEMISTRY

(A) Thermal stability : LiF > NaF > KF > RbF > CsF
(B) Bond Angle : BF3 < BCl3 < BBr3 < BI3
(C) Rate of hydrolysis : SiF4 > SiCl4 > SiBr4 > SiI4
(D) Acidic nature : Mn2O7 > MnO2 > MnO
4. Select the CORRECT statement :-
(A) The removal of impurity of Ag from the commercial lead is known as desilverization of lead
(B) Nickel is purified by Van-Arkel method
(C) For the isolation of metal from cinnabar no reducing agent is required
(D) Tin stone consists of wolframite as non magnetic impurity
5. Which of the following complex ion(s) is/are not optically active :-
(A) [Co(H2O)4(en)]3+ (B) [Sc(H2O)3(NH3)3]3+
(C) [Ti(en)2(NH3)2]4+ (D) [Co(gly)3]
6. If (Q) contains anomeric carbon at 2nd position then select correct option(s) ?
C12H22O11 + H2O P + Q
(Sucrose)
(A) In sucrose, P & Q held together by -glucosidic linkage
(B) Equimolar mixture of P & Q obtained in above reaction is known as invert sugar
(C) Both P & Q on passing through Tollen's reagent followed by acidification gives gluconic acid
(D) Sucrose is dextrorotatory but equimolar mixture of P & Q is laevorotatory
7. Tranquilizer obtained (P) is :

CH2–CHO
(i) N2H4
P
(ii) H2, Ni

(A) Iproniazid (B) Phenelzine (C) Meprobamate (D) Equanil


8. Which of the following amino acids moves towards cathod on elelctrophoresis at pH = 7 ?
(A) Leucine (B) Lysine (C) Arginine (D) Histidine
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SECTION–I(ii) : (Maximum Marks : 18)

CHEMISTRY
 This section contains THREE paragraphs.
 Based on each paragraph, there are TWO questions.
 Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four options
is correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases.
Paragraph for Questions 9 and 10
The standard emf of the cell
Pt(s) | H2(g) | HBr(aq)| AgBr(s) | Ag(s)
was measured over a range of temperature, and the data were fitted to the following polynomial
(F = 96500 C mol–1)
2
T  T 
Eº (volt)  0.07  5  10   298   3.5  106   298 
4

K  K 
9. The standard Gibbs energy of reaction for 1 mole electron at 298 K is :

(A) –6.755 kJ / mol (B) –5 kJ / mol (C) –13.51 kJ / mol (D) +6.755 kJ / mol

10. The standard entropy of reaction for 1 mole electron at 298 K is :

(A) –48.25 JK–1mol–1 (B) –96.5 JK–1mol–1 (C) +48.25 JK–1mol–1 (D) +96.5 JK–1mol–1
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Paragraph for Questions 11 and 12


CHEMISTRY

Due to presence of -acid lignads synergic bonding takes place in coordination compounds.

11. Which of the following complex synergic bonding does not take place :-

(A) [Fe(-C5H5)2] (B) [Fe(H2O)5NO]2+ (C) [Ni(PF3)(CO)3] (D) None of these

12. The CORRECT order of metal-carbon bond order is :-

(A) [Mn(CO)6]+ > [Cr(CO)6] > [V(CO)6]– (B) [Cr(CO)6] > [Mn(CO)6] + > [V(CO)6]–

(C) [V(CO)6]– > [Mn(CO)6] + > [Cr(CO)6] (D) [V(CO)6]– > [Cr(CO)6] > [Mn(CO)6] +

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Paragraph for Questions 13 and 14

CHEMISTRY
C4H4O4 represent dicarboxylic acid with degree of unsaturation is 3. It can show G.I. and its
gemoetrical isomer are P & Q. P forms anhydride (R) on heating.
13. Major product of following reaction is :
Bayer's reagent
Q
(A) Meso (B) Pair of diastereomer
(C) Pair of enantiomers (D) Pair of G.I.

14. Correct statement about major product (S) is :

Anhydrous
+R S
AlCl3

(A) It is acetophenone (B) It can show Tautomerism


(C) It can consume only 1 mole of RMgX (D) Its degree of unsaturation is 7
Space for Rough Work

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Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
SECTION–II : (Maximum Marks : 8)
CHEMISTRY

 This section contains ONE question.


 Question contains two columns, Column-I and Column-II.
 Column-I has four entries (A), (B), (C) and (D)
 Column-II has five entries (P), (Q), (R), (S) and (T)
 Match the entries in Column-I with the entries in column-II.
 One or more entries in Column-I may match with one or more entries in Column-II.
 The ORS contains a 4 × 5 matrix whose layout will be similar to the one shown below :
(A) (P) (Q) (R) (S) (T)

(B) (P) (Q) (R) (S) (T)

(C) (P) (Q) (R) (S) (T)

(D) (P) (Q) (R) (S) (T)

 For each entry in column-I, darken the bubbles of all the matching entries. For example,

if entry (A) in Column-I matches with entries (Q), (R) and (T), then darken these three
bubbles in the ORS. Similarly, for entries (B), (C) and (D).
 For each question, marks will be awarded in one of the following categories :
For each entry in Column-I
Full Marks : +2 If only the bubble(s) corresponding to all the correct match(es) is (are)
darkened
Zero Marks : 0 In none of the bubbles is darkened

Negative Marks : –1 In all other cases


1. Column-I Column-II
(A) Rock salt type crystal (P) Cation is present in tetrahedral void

(B) Antifluorite type crystal (Q) Cation is present in octahedral void


(C) Zinc blende type crystal (R) Coordination number of cation and anion are same

(D) Corundum type crystal (S) Coordination number of anion is 8

(T) Coordination number of anion is 4


Space for Rough Work

SECTION–III : Integer Value Correct Type


No question will be asked in section III

E-20/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1

SECTION–IV : (Maximum Marks : 20)

CHEMISTRY
 This section contains FIVE questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both

inclusive.

 For each question, darken the bubble corresponding to the correct integer in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble corresponding to the correct answer is darkened.

Zero Marks : 0 In all other cases.

1. If 0.025 M NaCl is mixed with 0.1 M Na2SO4 in 2 : 3 volume ratio at 273 K , then find the

osmotic pressure of resulting solution in atomosphere upto nearest integer :

2. Find out the total number of stereoisomer of [Zn(gly)2] :-

3. The moles of NaOH required for complete reaction with one mole hydrolysis product of SF4 :-

Space for Rough Work

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Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
CHEMISTRY

4. How many of following compounds are less reactive than benzene for sulphonation by

conc. H2SO4 :
OH CH3 NO2 Cl

O
+
COOPh NMe3 NH–C–CH3 D
D D

D D
D
5. If P = number of compounds which gives (+ve) dye azo test on treatment with NaNO2, HCl
followed by -napthol
Q = number of compounds which gives (+ve) isocynide test
Then find value of (P + Q) ?

CH2–NH2 NH–CH3 NH2


NH2
NH

NH2 NH2
O
N

N NH2

H CH3

Space for Rough Work

E-22/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
PART-3 : MATHEMATICS

MATHEMATICS
SECTION–I(i) : (Maximum Marks : 32)
 This section contains EIGHT questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is (are) correct.
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is (are)
darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases.
1. A circle (x – 3)2 + (y – 6)2 = r2 touches parabola y2 = 4x at P(a,b). If the slope of common tangent
at P is m, then (where b,r > 0) -

r2
(A) r = 5 (B)  10 (C) (a + b)m = 4 (D) a b  8
m
2. A hyperbola intersects an ellipse x2 + 9y2 = 9 orthogonally. The eccentricity of the hyperbola is
reciprocal of that of ellipse. If the axes of the hyperbola are along coordinate axes, then-
 8 
(A) vertices of hyperbola are   ,0 
 3 
1 1
(B) y coordinate of point of intersection of ellipse and hyperbola is either or 
3 3
2
(C) latus rectum of hyperbola is
3
4
(D) latus rectum of hyperbola is
3
3. Let  are real numbers for which the system of linear equations
2x + y + z = 0
x + y + 2z = 1
2x + y – 3z = –2
never posses unique solution then point P() lies on a conic whose-
 1 
(A) center is   ,0  (B) eccentricity is less than 3
 2 
(C) one vertex is origin (D) (–1,0) lies on it
16 72
4. Let A = {z1; z1 = 1, z1  C}, B = {z2 ; z2 = 1, z2  C} and P = {z1z2; z1  A, z2  B} are three sets
of complex roots of unity (where C denotes set of complex numbers), then
(A) n(A  B) = 8 (B) n(A  B) = 4 (C) n(P) = 144 (D) n(P) = 72
Space for Rough Work

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5. Let A is a four order diagonal matrix whose entries are complex numbers such that A4 = I4. If
MATHEMATICS

trace of A is zero then (here I4 is four order unit matrix)


(A) There will be 24 distinct matrices A
(B) There will be 36 distinct matrices A
(C) Determinant value of all such matrices is 1
(D) Determinant value of all such matrices is –1

1 1 1
6. Let matrix B  0 1 1 and A is 3 ordered square matrix such that AB = BA. If all entries of
0 0 1
matrix A are whole numbers whose sum is 6, then-
(A) If there are exactly 3 zero's in matrix A, then det(A) = 1
(B) If traceA = 6, then det(A) = 8
(C) A is always an invertible matrix
(D) there are 4 such matrices A.
   
7. Let A  aiˆ  bjˆ  ckˆ be a unit vector and B is another vector in R3 such that A  B  1 ,
 1   
3
 
C  2iˆ  2jˆ  kˆ and A  B .C  1 , then which of the following statement(s) is (are) correct ?
 
 
(A) If A lies in plane x + y + z = 10, then there are exactly 2 choices for A .
 
(B) If A lies in plane x + y + z = 10, then there are exactly 4 choices for A .

(C) If a,b,c  I, then there is no such vector A .

(D) If a,b,c  I, then there are infinitely many choices for A .
8. Let there are n planes in R3 such that any three have exactly one point in common and no four
of them have a point in common. If ƒ(n) represent the number of parts in which these n planes
will divide the space, then-

(A) ƒ(3) = 8 (B) ƒ(4) = 15 (C) ƒ(4) = 12 (D) ƒ(10) = 176

Space for Rough Work

E-24/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
SECTION–I(ii) : (Maximum Marks : 18)

MATHEMATICS
 This section contains THREE paragraphs.
 Based on each paragraph, there are TWO questions.
 Each question has FOUR options (A), (B), (C) and (D) ONLY ONE of these four options is
correct.
 For each question, darken the bubble corresponding to the correct option in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +3 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –1 In all other cases.
Paragraph for Questions 9 and 10
x 2 y2
Let S(x1,0) for x1 > 0 is foci of the ellipse E :   1 . Suppose a parabola whose vertex is
9 4

V x1 
5,0 touches the ellipse at points A and B in I and IV quadrant respectively. Axis of parabola

is x-axis.
On the basis of above information, answer the following questions :
9. Equation of normal to the ellipse E at A is-
(A) 9x 2  3y  5 2  0 (B) 9x 2  3y  5 2  0

(C) 9x 2  3y  5 2 (D) 9x 2  3y  5
10. Tangent to the ellipse E at A and B meet at C, then area of ABC is-

32 2 16 2
(A) 32 2 (B) (C) 12 2 (D)
3 3
Space for Rough Work

1001CT103516015 E-25/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
Paragraph for Questions 11 and 12
MATHEMATICS

Let L1 : 4x – 3y + 13 = 0, L2 : 4x – 3y = 37, L3 : 3x + 4y = 34 are three lines in xy plane and


L4:(1 + )x + (1 – )y = 24 is a variable line. P(a,b) is centre of circle which touches lines L1,L2
and L3.

On the basis of above information, answer the following questions :

11. Maximum value of a + b is-

(A) 13 (B) 15 (C) 17 (D) greater than 17

12. If L1,L2,L3 and L4 form a quadrilateral, then the value of  for which slope of line L4 takes least
positive integral value is-

4 7 5
(A) (B) 2 (C) (D)
3 5 4

Space for Rough Work

E-26/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
Paragraph for Questions 13 and 14

MATHEMATICS
A train consists of n carriages and there are P passengers. Each one of the P passengers randomly
selects the carriage in which he will ride.
On the basis of above information, answer the following questions :
13. If n = 4 and p = 6, then the probability that there will be at least one passenger in each carriage
is-
6
195 1564 C4 4!4 2 5
C3 4!
(A) (B) (C) (D)
512 4096 46 46

n P n P n P n 1  n  P n


14.  1    2    3  ......   1    n is equal to (where    n Cr ) -
1  2 3 n  r
(A) (–1)n–1n!, if P < n (B) 0, if P = n (C) n!, if P = n (D) (–1)n–1n!, if P = n

Space for Rough Work

1001CT103516015 E-27/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
SECTION–II : (Maximum Marks : 8)
MATHEMATICS

 This section contains ONE question.


 Question contains two columns, Column-I and Column-II.
 Column-I has four entries (A), (B), (C) and (D)
 Column-II has five entries (P), (Q), (R), (S) and (T)
 Match the entries in Column-I with the entries in column-II.
 One or more entries in Column-I may match with one or more entries in Column-II.
 The ORS contains a 4 × 5 matrix whose layout will be similar to the one shown below :
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
 For each entry in column-I, darken the bubbles of all the matching entries. For example,
if entry (A) in Column-I matches with entries (Q), (R) and (T), then darken these three bubbles
in the ORS. Similarly, for entries (B), (C) and (D).
 For each question, marks will be awarded in one of the following categories :
For each entry in Column-I
Full Marks : +2 If only the bubble(s) corresponding to all the correct match(es) is (are)
darkened
Zero Marks : 0 In none of the bubbles is darkened
Negative Marks : –1 In all other cases
1. Column-I Column-II
(A) In a triangle ABC sinA,sinB,sinC are in A.P, then (P) Latus rectum of

B
sin
2 x2 y2
is less than or equal to ellipse  1
A C 16 4
sin sin
2 2
(B) In ABC if 2 + b2 + c2 = 2bc + a2, then value of x (Q) eccentricity of
which satisfy x2 – 5(sinA + cosA)x + 25sinAcosA = 0 hyperbola
2

is equal to
x  2  
y2
1
2 16

131
(C) In ABC if a = 7, b = 3, c  and median AD (R) Radius of director
2

x 2 y2
meets circumcircle at E, then AE is greater than circle of  1
36 13
(D) The point of contact of an inscribed circle of a right (S) Minimum value of
angle triangle divides the hypoteneous in two parts of |z1 – z2| where
lengths 4 and 7, then area of triangle is divisible by |z1| = 2 and
|z2 – 9|= 3
(T) Half of maximum
value of |z1 – z2|
where |z1|= 2 and
|z2 – 9| = 3

E-28/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
SECTION–III : Integer Value Correct Type

MATHEMATICS
No question will be asked in section III
SECTION–IV : (Maximum Marks : 20)
 This section contains FIVE questions.
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive.
 For each question, darken the bubble corresponding to the correct integer in the ORS.
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble corresponding to the correct answer is darkened.
Zero Marks : 0 In all other cases.
1. Let (x + 3)2 (x + 4)3 (x + 5)4 = (x + 1)9 + a 1(x + 1)8 + a 2(x + 1)7+..... + a 9, then a 2 – 365 is
equal to
2. A plane P intersects 4 lines L1,L2,L3 and L4 (given below) at A,B,C,D
x 3 y 3 z3 x 3 y 3 z
L1 :   ,L2 :  
2 1 2 2 1 2

x y 3 z x y 3 z 3
L3 :   ,L4 :   , then the
2 1 2 2 1 2
minimum area of quadrilateral ABCD is

3. Coefficient of x17 in the expansion of (1 + x5 + x7)20 is , then is equal to
380
Space for Rough Work

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Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
MATHEMATICS

4. Number of ways in which two distinct natural numbers can be selected out of first 100 natural
 N 
numbers so that sum of their cubes is multiple of 8 is N, then   is equal to
 200 
(where [.] denotes greatest integer function)
5. A die is rolled four times. If the probability that product of first 3 outcomes is equal to fourth
 1 
outcome is p, then   is equal to (where [.] denotes greatest integer function)
 p 

Space for Rough Work

E-30/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
Space for Rough Work

1001CT103516015 E-31/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
QUESTION PAPER FORMAT AND MARKING SCHEME :
16. The question paper has three parts : Physics, Chemistry and Mathematics.
17. Each part has three sections as detailed in the following table.
Que. No. Category-wise Marks for Each Question Maximum
Section Type of Full Partial Zero Negative Marks of the
Que. Marks Marks Marks Marks section
+4 0 –1
One or more If only the bubble(s) If none In all
I(i) correct corresponding of the other
option(s) 8 to all the correct — bubbles is cases 32
option(s) is(are) darkened
darkened
Paragraph +3 0 –1
Based If only the bubble If none In all
I(ii) (Single 6 corresponding to — of the other 18
correct the correct option bubbles is cases
option) is darkened darkened
+8 +2 0 –1
II Matrix If only the bubble(s) For darkeninga bubble If none In all
Match Type 1 corresponding to corresponding to each of the other 8
all the correct correct match is bubbles is cases
match(es) is(are) darkened darkened
darkened
+4 0
Single digit If only the bubble In all
IV Integer 5 corresponding — other — 20
(0-9) to correct answer cases
is darkened

NAME OF THE CANDIDATE ................................................................................................

FORM NO. .............................................

I have read all the instructions I have verified the identity, name and Form
and shall abide by them. number of the candidate, and that question
paper and ORS codes are the same.

____________________________ ____________________________
Signature of the Candidate Signature of the invigilator

Corporate Office :  CAREER INSTITUTE, “SANKALP”, CP-6, Indra Vihar, Kota (Rajasthan)-324005
+91-744-5156100 info@allen.ac.in www.allen.ac.in
E-32/32 Your Target is to secure Good Rank in JEE 2017 1001CT103516015
Paper Code : 1001CT103516015

CLASSROOM CONTACT PROGRAMME


HINDI

(Academic Session : 2016 - 2017)

JEE (Main + Advanced) : LEADER COURSE


PHASE-III to VII (SCORE-I)
Test Type : PART TEST Test Pattern : JEE-Advanced
TEST DATE : 05 - 03 - 2017
Time : 3 Hours PAPER – 1 Maximum Marks : 234



1. 
2. 
(ORS) 

3. 
4. 
5. 
32 
20 





6. 



7. 
8. 

9. 



:

10. 


11.  


12. 

:

13. 
14. 

15. g = 10 m/s2 

           
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1

SOME USEFUL CONSTANTS


Atomic No. H = 1, B = 5, C = 6, N = 7, O = 8, F = 9, Al = 13, P = 15, S = 16,
Cl = 17, Br = 35, Xe = 54, Ce = 58,
Atomic masses : H = 1, Li = 7, B = 11, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24,
Al = 27, P = 31, S = 32, Cl = 35.5, Ca=40, Fe = 56, Br = 80, I = 127,
Xe = 131, Ba=137, Ce = 140,
 Boltzmann constant k = 1.38 × 10–23 JK–1
1
 Coulomb's law constant = 9 ×10 9
4 0
 Universal gravitational constant G = 6.67259 × 10–11 N–m2 kg–2
 Speed of light in vacuum c = 3 × 108 ms–1
 Stefan–Boltzmann constant  = 5.67 × 10–8 Wm–2 –K–4
 Wien's displacement law constant b = 2.89 × 10–3 m–K
 Permeability of vacuum µ0 = 4 × 10–7 NA–2
1
 Permittivity of vacuum 0 =
0 c2
 Planck constant h = 6.63 × 10–34 J–s



H-2/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
HAVE CONTROL  HAVE PATIENCE  HAVE CONFIDENCE  100% SUCCESS

PHYSICS
BEWARE OF NEGATIVE MARKING

-1 :  
–I(i) : ( : 32)
   
 
   
  (A), (B), (C)  (D)  
      
               
       
 


   
  : +4            
  : 0         
  : –1    
1. r0 

B 
v 



(A) r 
r = r0 – vt/
(B) 
e = 2Bv[r0 – vt/] 
Bv
(C) 
I= 
2
Bv
(D)
I= 



1001CT103516015 H-3/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1

2. 
R3 
PHYSICS

E L

R3
R1
C R2

(A)
(B) 
E
(C) 
R  3

E
(D) 
R  3

3. 
0.8 


(
 )

= 1 mm2 
100 cm2 

oil 5m

oil oil
Water 10m

Oil 5m Oil 12m Oil 8m Oil 12.5m


15m 15m 15m 15m
(A) Oil (B) Oil (C) Oil (D) Oil
Oil Water 8m Oil Oil Oil
Water 2.4m Water 4m Water 2m



H-4/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
4. 
() VS 
ac 
RLC 
VRL 
VC 
RL C 

PHYSICS
VS
~
C
R L

(A) 
VRL VC 
 
1
(B) 
VRL, VS 
VC, 2 

1
(C) 
VRL VC 

2
(D) 
VRL,  
VC, VS 
5. 
Ri 
R0 
i 
(r < Ri )  

(A) 
i 
(B) 
(r > R0) 

i 
(C) 

i 
(D) 
6. 
ABC 
BC 

m BC 
T 


mg
(A) BC  
2T
mg
(B) BC  
T
3m
(C) 
 
T
m
(D) 
 
3T


1001CT103516015 H-5/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1

7. 
PV 
OA 
O 
PHYSICS



P O

B
A
C
V

(A)  :  ; 


:B (B)  : 
; 
:B
(C)  :  ; 
:C (D)  : 
; 
:C
8. YDSE 
(Barrier) 

P
r1
y
S1
r2
 
d Q
O

S2 

L
Viewing screen

(A) 
(B) 

(C) 
(D) 



H-6/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
–I(ii) : ( : 18)

PHYSICS
   
  
    
   
  

   (A), (B), (C) 
(D)  
   
               
        


   
 : +3           
 : 0         
  : –1    
9 10   
 (r) 
(µr) 
 r  r


1964 
V. Veselago 
r 
r 
21



 r r 
 
r  r
 r  r k 
 k  

1 



1001CT103516015 H-7/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
9. 
r < 0 
µr < 0 
PHYSICS


'd' 

B
1 1
air A C
medium
E
D r

d BC
(A) d CD  d AE  (B) d CD  d BC   r  r d AE
r r

(C) sin  r  r  r sin 1 (D) d CD  d AE  r  r d BC

10. 

(A) (B)
µr < 0 µr < 0
r < 0 r < 0

(C) (D)
µr < 0 µr < 0
r < 0 r < 0



H-8/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1

11 12   

PHYSICS



qV 



y 

YDSE 

y
detector
1
d
2
ELECTRON
GUN D
WALL Screen
(b)
(a)
11. 
 << d 
?
(A)  (B) D 
(C) d  (D) 
V 

12. 

h2 5h2 9h2 7h 2
(A) (B) (C) (D)
2mqd 2 2mqd 2 2mqd 2 2mqd 2



1001CT103516015 H-9/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
13 14   
PHYSICS


1919 
7 N 
14

-
x 
14
7N


-


d 
7 N 
14


13. d 

(A) R0(21/3 + 71/3) (B) R0(22/3 + 72/3) (C) R0(22/3 + 142/3) (D) R0(22/3 + 141/3)

14. -
18ke2 14ke2 18ke2 14ke2
(A) (B) (C) (D)
R0 (22 / 3  142 / 3 ) R0 (22 / 3  141 / 3 ) R0 (22 / 3  141 / 3 ) R0 (22 / 3  72 / 3 )



H-10/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
–II : (  : 8)

PHYSICS
   
  
    

-I 
 -II
  -I 
 
(A), (B), (C)  (D) 
  -II 
 
(P), (Q), (R), (S) (T) 
  -I   
-II     
  -I -II  
    4 
× 5 
  
: 
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)

  -I             
 -I  (A) 
(Q), (R) (T) 
   
(B), (C)  (D)   
   :
 -I     
 : +2           
 : 0        
  : –1    
1.  -I 
t = 0 
-II 

 -I  -II
(A)  C (P) 
 

t = 0 


 C +Q
p
charged
bead



1001CT103516015 H-11/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1

(B) C 
(Q) 
t = 0 
PHYSICS

 
C 

C.M. of
ball, nonuniform
mass distribution
C

(C)  (R) 


t = 0 




B

uniformly
C charged disc

(D) 
(S) 
 
t = 0 


B
C

(T) 
 t = 0 


C



–III : 
III 
H-12/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
–IV : (: 20)

PHYSICS
   
  
    
0 9      

 
 
             
       
 

   
 : +4           
 : 0    
1. 
50 m 

10–8 watt/m2 
1.6 × 105 N/m2 

340 m/s 
x × 10–3 N/m2 
[x]

3
2. 
A B 

P = T 
1/ 2
2
100 K

1
B  C  
B 
1/ 2
U= V
2
100 m3 C  1600 m3 
x  45
x 

60
[
: R = 8.3 J/mol-K]


1001CT103516015 H-13/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1

3. 4g 
4.2 cm2 
PHYSICS


1.4 cm2 
1000 W/m2 


5°C 
n

n


4200 J/kgºC 
5

4. 
7 1 7 1
3 Li 1 H  4 Be  0 n

Li 

(keV 
) 

N
Q –1645 keV 
N  
235
5.  X-
V1 = 15.5 KV  V2 = 31 KV 
K
X-
1.3 
N
N 
(hc = 1240 eV nm 
R = 1 × 107 /m )
13


H-14/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1


-2 :  

CHEMISTRY
–I(i) : ( : 32)
   
 
   
  
(A), (B), (C)  (D)  

      
               
       
 

   
 : +4            
 : 0         
  : –1    
1. 
(A) 

(B) 
(Tk) 
(C) 
(D) 
CMC  10–4  10–3 mol L–1 
2. 

Temp. is For the same


same for both gas gas at two
different temp.
dN dN
Ndu M2 Ndu T2
M1 T1
u u

(A) M2 > M1 (B) M1 > M2 (C) T2 > T1 (D) T1 > T2


3. :-
(A) 
: LiF > NaF > KF > RbF > CsF
(B) 
: BF3 < BCl3 < BBr3 < BI3
(C) : SiF4 > SiCl4 > SiBr4 > SiI4
(D) 
: Mn2O7 > MnO2 > MnO



1001CT103516015 H-15/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
4. 
:-
CHEMISTRY

(A) 
Ag 
(desilverization) 
(B) 
(C) 
(D) 
5. 
:-
(A) [Co(H2O)4(en)]3+ (B) [Sc(H2O)3(NH3)3]3+
(C) [Ti(en)2(NH3)2]4+ (D) [Co(gly)3]
6. (Q) 
2nd 
C12H22O11 + H2O P + Q

(A) 
P 
Q -
(B) 
P 
Q 
(C) P 
Q 
(D) 
P 
Q 
7. 
(Tranquilizer) (P) 

CH2–CHO
(i) N2H4
P
(ii) H2, Ni

(A)  (B)  (C)  (D) 


8. 
pH = 7 

(A)  (B)  (C)  (D) 




H-16/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
–I(ii) : ( : 18)

CHEMISTRY
   
  
   
 
   
   
   (A), (B), (C) 
(D)  
   
               
       
 

   
 : +3           
 : 0         
  : –1    
9 10   

Pt(s) | H2(g) | HBr(aq)| AgBr(s) | Ag(s)
emf 
(polynomial) 
(F = 96500 C mol–1)

2
T  T 
Eº (volt)  0.07  5  104   298   3.5  106   298 
K  K 

9. 298 K  1 


(A) –6.755 kJ / mol (B) –5 kJ / mol (C) –13.51 kJ / mol (D) +6.755 kJ / mol
10. 298 K  1 
(A) –48.25 JK–1mol–1 (B) –96.5 JK–1mol–1 (C) +48.25 JK–1mol–1 (D) +96.5 JK–1mol–1


1001CT103516015 H-17/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
11 12   
CHEMISTRY


-

11. 
:-

(A) [Fe(-C5H5)2] (B) [Fe(H2O)5NO]2+ (C) [Ni(PF3)(CO)3] (D) 

12. 
:-

(A) [Mn(CO)6]+ > [Cr(CO)6] > [V(CO)6]– (B) [Cr(CO)6] > [Mn(CO)6] + > [V(CO)6]–

(C) [V(CO)6]– > [Mn(CO)6] + > [Cr(CO)6] (D) [V(CO)6]– > [Cr(CO)6] > [Mn(CO)6] +



H-18/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
13 14   

CHEMISTRY
C4H4O4 , 
3 
G.I.

P 
Q 
P , 
(R) 
13. 

Q
(A)  (B) 
(C)  (D) G.I. 
14. 
(S) 

Anhydrous
+R S
AlCl3

(A)  (B) 


(C) 1 
RMgX 
(D) 
7 



1001CT103516015 H-19/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
–II : (  : 8)
CHEMISTRY

   


  
    

-I 
 -II
  -I 
 
(A), (B), (C)  (D) 
  -II 
 
(P), (Q), (R), (S) (T) 
  -I   
-II     
  -I -II  
    4 
× 5 
  
: 
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)

  -I             
 -I 
(A) 
(Q), (R) 
(T) 
   
(B), (C)  (D)    
   :
 -I     
 : +2           
 : 0        
  : –1    
1.  -I  -II
(A)  (P) 
(B) 
(Q) 
(C)  (R) 
(D)  (S) 8 
(T) 4 


–III : 
III 
H-20/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
–IV : (: 20)

CHEMISTRY
   
  
    
0 9      

 
 
             
       
 

   
 : +4           
 : 0    
1. 273 K  0.025 M NaCl 
0.1 M Na2SO4 
2 : 3 

2. [Zn(gly)2] 
:-

3. SF4 
NaOH 
:-



1001CT103516015 H-21/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1

4. 
H2SO4 
CHEMISTRY

OH CH3 NO2 Cl

O
+
COOPh NMe3 NH–C–CH3 D
D D

D D
D
5.  P = 
NaNO2, HCl
-
(+ve) 


Q= 
(+ve) 

(P + Q) 

CH2–NH2 NH–CH3 NH2
NH2
NH

NH2 NH2
O
N

N NH2

H CH3


H-22/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1


-3 : 

MATHEMATICS
–I(i) : ( : 32)
   
 
   
   (A), (B), (C) (D)  
      
               
       
 


   
  : +4            
  : 0         
  : –1    
1. (x – 3)2 + (y – 6)2 = r2  y2 = 4x 
P(a,b) P 
m 
(
b,r > 0)-
r2
(A) r = 5 (B)  10 (C) (a + b)m = 4 (D) a b  8
m
2. 
x2 + 9y2 = 9 

-
 8 
(A) 
  3 ,0  
 
1 1
(B) 
y
  
3 3
2
(C) 
3
4
(D) 
3
3. 
 
2x + y + z = 0
x + y + 2z = 1
2x + y – 3z = –2

P(), 
-
 1 
(A) 
  2 ,0   (B) 
3 
 
(C)  (D) (–1,0) 
4. 
A = {z1; z116 = 1, z1  C}, B = {z2 ; z272 = 1, z2  C} 
P = {z1z2; z1  A, z2  B} 
(
  C )
(A) n(A  B) = 8 (B) n(A  B) = 4 (C) n(P) = 144 (D) n(P) = 72



1001CT103516015 H-23/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1


A 
A4 = I4 
A 
MATHEMATICS

5.
(
 I4 
)
(A) 24 
A 

(B) 36 
A 
(C) 
1 

(D) 
–1 

1 1 1
6. 
B  0 1 1 
A, 
AB = BA 
A 
0 0 1
6 

-
(A) 
A 
3 
det(A) = 1
(B) traceA = 6 
det(A) = 8 
(C) 
A 
(D) 4 
A 
     1
7. 
R3 
A  aiˆ  bjˆ  ckˆ 
B 
AB 
 1 , C  2iˆ  2jˆ  kˆ 
3
  
A  B .C  1 
  ?
 
(A)  A ,  x + y + z = 10 
2
A 
 
(B)  A ,  x + y + z = 10 
4
A 

(C) a,b,c  I 
A 

(D) a,b,c  I 
A 
8. 
R3 
n 

n
ƒ(n)

-
(A) ƒ(3) = 8 (B) ƒ(4) = 15 (C) ƒ(4) = 12 (D) ƒ(10) = 176


H-24/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
–I(ii) : ( : 18)

MATHEMATICS
   
  
   
 
   
  

  (A), (B), (C) (D)  
   
               
       
 


   
  : +3           
  : 0         
  : –1    
9 10   
x 2 y2
x1 > 0 
S(x1,0), 
E:   1 
V x1 5,0  
9 4

I 
IV 
A B  
x- 
         
9. 
E 
A 
-

(A) 9x 2  3y  5 2  0 (B) 9x 2  3y  5 2  0

(C) 9x 2  3y  5 2 (D) 9x 2  3y  5

10. 
E
A 
B 
C 
ABC 

32 2 16 2
(A) 32 2 (B) (C) 12 2 (D)
3 3



1001CT103516015 H-25/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
11 12   
MATHEMATICS


L1  
: 4x – 3y + 13 = 0, L2 : 4x – 3y = 37, L3 : 3x + 4y = 34, xy
L4:(1 + )x + (1 – )y = 24 
P(a,b), 
L1,L2 L3 

         
11. a + b 

(A) 13 (B) 15 (C) 17 (D) 17 

12. L1,L2,L3 


L4 
 
L4 

-

4 7 5
(A) (B) 2 (C) (D)
3 5 4


H-26/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
13 14   

MATHEMATICS
n
(carriages) 
P 
P 

         
13. n = 4 
p = 6 
-

6
195 1564 C4 4!4 2 5
C3 4!
(A) (B) (C) (D)
512 4096 46 46

n P n P n P n 1  n  P  n n


14.  1    2    3  ......   1    n 
(
   Cr )
1  2 3 n  r

(A) (–1)n–1n!, P < n (B) 0, P = n

(C) n!,  P = n (D) (–1)n–1n!,  P = n



1001CT103516015 H-27/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1
–II : (  :
MATHEMATICS

8)
   
  
    

-I 
 -II
  -I 
 
(A), (B), (C)  (D) 
  -II 
 
(P), (Q), (R), (S) (T) 
  -I   
-II    
  -I  -II  
    4 
× 5 
  
: 
(A) (P) (Q) (R) (S) (T)
(B) (P) (Q) (R) (S) (T)
(C) (P) (Q) (R) (S) (T)
(D) (P) (Q) (R) (S) (T)
  -I             
 -I 
(A) 
(Q), (R) (T) 
(B), (C) 
    (D)   
   :
 -I     
  : +2            
  : 0        
  : –1    
1. -I -II
x2 y2
(A) 
ABC 
sinA,sinB,sinC      (P) 
 1
16 4
B
sin
2 ,.....        
A C
sin sin
2 2
(B) 
ABC  2 + b2 + c2 = 2bc + a2  
x (Q) 
2

  


x2 – 5(sinA + cosA)x + 25sinAcosA = 0
x  2  
y2
1
2 16
       
131 x 2 y2
(C) 
ABC 
a = 7, b = 3, c   
AD (R)  1  
2 36 13
 
E     AE, ..............       
(D)           (S) 
|z1 – z2| 
4 7           |z1| = 2  
  
..............    |z2 – 9|= 3 
(T) |z1 – z2|  


|z1|= 2 
|z2 – 9| = 3 
H-28/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1
–III : 

MATHEMATICS
III 
–IV : (: 20)
   
  
    
0 9      

 
 
             
       
 


   
  : +4           
  : 0    
1. 
(x + 3)2 (x + 4)3 (x + 5)4 = (x + 1)9 + a1(x + 1)8 + a2(x + 1)7+..... + a9 
a2 – 365 

2.  P, 
L1,L2,L3 
L4 (
) 
A,B,C,D  
x 3 y 3 z3 x 3 y 3 z
L1 :   ,L2 :  
2 1 2 2 1 2

x y 3 z x y 3 z 3
L3 :   ,L4 :   
ABCD 
2 1 2 2 1 2


3. (1 + x5 + x7)20
x17 
 
380


1001CT103516015 H-29/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1


100 
MATHEMATICS

4.

 N 

8 
N 
 200  
 
(
[.] 
)

5. 
 1 
p 
  
(
[.] 
)
 p 



H-30/32 1001CT103516015
Leader Course/Phase-III to VII/Score-I/05-03-2017/Paper-1


1001CT103516015 H-31/32
Target : JEE (Main + Advanced) 2017/05-03-2017/Paper-1

16. 
17. 
    
       
 
 +4 0 –1
I(i)    
 8  —  
32
  
 
 +3 0 –1
I(ii)    
6 — 18
   
   
+8 +2 0 –1
II     
1    
8
   
 
 +4 0
IV   
5 —
(0-9)   — 20
 

  


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 
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       



 


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H-32/32 Your Target is to secure Good Rank in JEE 2017 1001CT103516015

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