Akhil Bharatiya Sr. Sec.
Write the structure and monomers of the
School, Kaithal
XII Chemistry M.M.70
Carry 1 mark each
1. A solid has a cubic structure in which
X atoms are located at the corners of
the cube, Y atoms are at the cube
centre and O atoms are at the edges
centres. What is the formula of the
compound?
2. 0.5 M aqueous solution of NaCl show
higher value of osmotic pressure than
0.5 M glucose solution at the same
temperature. Why?
3. Give one example each of positively
and negatively charged sol.
4. Explain the role of collectors in froth
floatation process.
5. What is zeigler-Natta catalyst?
6. What is emulsion? Give example.
Carry 2 marks each
7. Urea forms an ideal solution in water.
Determine the vapour pressure of an
aqueous solution containing 10% by mass
of urea (NH2CONH2) AT 400C.( vapour of
water is 55.3 mm of Hg)
8. Differentiate thermoplastic and
thermosetting polymers.
9. Calculate the equilibrium constant for a
reaction, Ni (s) + Cu+2 (aq) Cu(s)+
Ni+2 . given the values of E0Ni2+/Ni and
E0cu2+/Cu as -0.25 and +0.34 v respectively.
(antilog 20= 1x1020)
10. Explain any two factors affecting the rate
of reaction.
11. What is adsorption? Write any two
features that distinguish physiosorption
from chemisorptions.
Carry 3 marks each
12. Explain the term Brownian movement and
peptization.
13. Describe the principle involved in each of
the followings: (a) zone refining (b)
electrolytic refining of metals (c) froath
floatation method
14. Name any two ores of zinc. Describe the
extraction of zinc from one of these ores.
15.
followings polymers: (a) Perlon (b)
Bakelite (c) Buna-S
16. 0.5 g of KCl was dissolved in 100g of
water and the solution originally at 200c
froze at -0.240c. calculate the percentage
of dissociation of the salt. Kf for water is
1.86 K kg mol-1.
17. The rate of the chemical doubles for an
increase of 10K in absolute temperature
from 298K. Calculate Ea.( log2=0.3010,
R=8.314J K-1mol-1)
18. The electrical resistance of a column of
0.05M caustic soda solution of diameter
1cm and length 50 cm is 5.55x103 ohm.
Calculate its resistivity, conductivity and
molar conductivity.
19. Potassium crystallises in a body centre
cubic lattice.what is the approximate
number of unit cells in 4.0g of potassium?
Atomic mass of potassium= 39.
20. What is semiconductor? Describe the two
main types of semiconductor and contrast
their conduction mechanism.
21. Explain : (a) Biodegradable polymers (b)
Electrophoresis (c) fuel cells
Carry 4 marks
22. Seeing the growing cases of diabetes
and depression among young children,
Mr. Lugani, the principal of one
reputed school organized a seminar in
which he invited parents and
principals. They all resolved this issue
by strictly banning junk food in
schools and introducing healthy
snacks and drinks like soup, lassi,
milk, etc. in school canteens. They
also decided to make compulsory half
an hour of daily physical activities for
the students in the morning assembly.
After six months, Mr. Lugani
conducted the health survey in most of
the schools and discovered a
tremendous improvement in the health
of the students.After reading the above
passage, answer the following
questions : (i) What are the values (at
least two) displayed by Mr. Lugani?
(ii) As a student, how can you spread
awareness about this issue? (iii) What
are antidepressant drugs? Give an
 example. (iv)Name the sweetening
agent used in the preparation of sweets
for a diabetic patient.
Carry 5 marks each
23. (a) An element having atomic mass 60
has FCC unit cells. The edge length of the
unit cell is 400pm. Find out density of the
element. (b) Vapour pressure of
water at 20ºC is 17.5 mm Hg.
Calculate the vapour pressure of water
at 20ºC when 15 g of glucose (Molar
mass = 180 g mol–1) is dissolved in
150 g of water.
24. (a) For a reaction A + B → P the rate
is given by Rate = k [A]2 [B] (i) How
is the rate of reaction affected if the
concentration of A is doubled? (ii)
What is the overall order of reaction if
B is present in large excess?
(b) A first order reaction takes 23.1
minutes for 50% completion.
Calculate the time required for 75%
completion of this reaction. (Given :
log 2 = 0.301, log 3 = 0.4771, log 4 =
0.6021)
25. (a) Define conductivity and molar
conductivity for the solution of an
electrolyte. Discuss their variation
with concentration.
(b) If a current of 0.5 amp flows
through a metallic wire for two hours,
then how many electrons flow through
the wire.
26. (a) How are sulphur sol and collodion
prepared?
(b) Name a type of battery used in
hearing aids. And explain it.