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Date : 06th July 2016 Sub : Chemistry CH – 2 MM:20 Batch : 11TH GSEB|SEM - I

PAPER –A
1. Which of the following is the relation between momentum and the wave length of moving
particle according to de Broglie’s principle ?
(a) Inversely proportional (b) Proportional
(c) Square root (d) No relation
2. The ratio of de Broglie wavelengths of particles A and B if the mass of B is four times than A and
the velocity of A is eight times than B is
(a) 1: 2 (b) 2: 1 (c) 2 : 3 (d) 6 : 9
3. The velocity of de Broglie wave is given by
mc 2 mc 2 hv
(a) (b) (c) (d) n
v h mc
4. What is the de Broglie wavelength of a pitched base ball with mass of 120 g and a speed of 44.7
m/s ?
(a) 1 .24  10-34 m (b) 2. 68  10-28m (c) 1.75  10-28m (d) 1.67  10-34m
5. The uncertainties in the velocities of two particles A and B are 0.05 and 0.02m/s respectively.
The mass of B is five times to that of mass A .What is the ratio of uncertainties in their positions ?
(a) 2 (b) 0.25 (c) 4 (d) 1
6. The de Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10 metres per
second is approximately
(a) 10-25 metres (b) 10-33metres (c) 10-31metres (d) 10-16 metres
7. The uncertainty in position of an electron & helium atom is same. If the uncertainty in
momentum for the electron is 32105 , then the uncertainty in momentum of helium atom will
be:
(a) 32  105 (b) 16  105 (c) 8  105 (d) None
8. What is the ratio of the de-Broglie wave length for electrons accelerates through 200 volts and 50
volts:
(a) 1 : 2 (b) 2 : 1 (c) 3 : 10 (d) 10 : 3
9. The uncertainty in the position of an electron (mass 9.1 10 -28 GM) moving with a velocity of 3
10 cm sec , uncertainty in velocity is 0.011% will be :
4 -1

(a) 1.92 cm (b) 7.68 cm (c) 0.175 cm (d) 3.84 cm


°
10. A particle X moving with a certain velocity has – a debgroglie wavelength of 1 If particle Y has
A
a mass of 25 % that of X and velocity 75% that of X.Debroglie wavelength of Y will be :
° ° ° °
(a)3 (b) 5.33 (c) 6.88 (d) 48
A A A A
11. Heisenberg uncertainty principle is not valid for
(a) moving electron (b) Motor car (c) stationary particles (d) B and C both
12. Calculate the wavelength (in nanometer) associated with a proton moving at 1.0  103 ms-1
(a) 0.40 nm (b) 14.0 nm (c) 2.5 nm (d) 0.32 nm
13. A body of mass x kg is moving with velocity of 100 ms . Its de Broglie wavelength is 6.62  10-35
-1

m-1 hence, x is ……… [h = 6.62  10-34 Js]


(a) 0.25 kg (b) 0.15 kg (c) 0.2 kg (d) 0.1 kg

2nd Floor, Rajcastle, Near Kalpataru, Ellora Park, Baroda – 390007 Ph: +91-265-3053166 1
Date : 06th July 2016 Sub : Chemistry CH – 2 MM:20 Batch : 11TH GSEB|SEM - I

14. The energy per quantum associated with light of wavelength 5890 A is :
(a) 3.37  10-12 erg (b) 4.7  10-12 erg (c) 3.37  10-10 (d) 4.7  10-10 erg
15. The de-broglie wavelength associated with a ball of mass 1 kg having kinetic energy 0.5 J is :
(a) 6.626  10-34 m (b) 13.20  10-34 m (c) 10.38  10-21 m (d) 6.626  10-34 A
16. The position of electron is located at 1 A with microscope. What will be the uncertainty in the
velocity of electron ?
(a) 5.8  105 ms-1 (b) 4.5  108 ms-1 (c) 9.1  107 ms-1 (d) 6.2  108 ms-1
17. A microscope using suitable photons is employed to locate an electron in an atom within a
distance of 0.1 A. What is uncertainty involved in the measurement of its velocity ?
(a) 6.79  106 ms-1 (b) 5.79  105ms-1 (c) 5.79  102ms-1 (d) 5.79  10ms-1
18. If an electro and a proton possess same de-Broglie ‘s wavelength and velocity of electron V m s-1,
then the velocity of proton will be approximately…
V 1836
(a) m s-1 (b) 1836 V m s-1 (c) m s-1 (d) V m s-1
1836 V
19. Which of the following will have the maximum de-Broglie’s wavelength of the particle having
equal velocity ?
(a) H-atom (b) C-atom (c) proton (d) Electron
20. If the uncertainty in the position of an electron is zero, then the uncertainty in its momentum
would be …….
h h
(a) > (b) < (c) infinite (d) zero
4 4

PAPER – B
1. The position of electron is located at 1 A with microscope. What will be the uncertainty in the
velocity of electron ?
(a) 5.8  105 ms-1 (b) 4.5  108 ms-1 (c) 9.1  107 ms-1 (d) 6.2  108 ms-1
2. A microscope using suitable photons is employed to locate an electron in an atom within a
distance of 0.1 A. What is uncertainty involved in the measurement of its velocity ?
(a) 6.79  106 ms-1 (b) 5.79  105ms-1 (c) 5.79  102ms-1 (d) 5.79  10ms-1
3. If an electro and a proton possess same de-Broglie ‘s wavelength and velocity of electron V m s-1,
then the velocity of proton will be approximately…
V 1836
(a) m s-1 (b) 1836 V m s-1 (c) m s-1 (d) V m s-1
1836 V
4. Which of the following will have the maximum de-Broglie’s wavelength of the particle having
equal velocity ?
(a) H-atom (b) C-atom (c) proton (d) Electron
5. If the uncertainty in the position of an electron is zero, then the uncertainty in its momentum
would be …….
h h
(a) > (b) < (c) infinite (d) zero
4 4
2nd Floor, Rajcastle, Near Kalpataru, Ellora Park, Baroda – 390007 Ph: +91-265-3053166 2
Date : 06th July 2016 Sub : Chemistry CH – 2 MM:20 Batch : 11TH GSEB|SEM - I

6. Heisenberg uncertainty principle is not valid for


(a) moving electron (b) Motor car (c) stationary particles (d) B and C both
7. Calculate the wavelength (in nanometer) associated with a proton moving at 1.0  103 ms-1
(a) 0.40 nm (b) 14.0 nm (c) 2.5 nm (d) 0.32 nm
8. A body of mass x kg is moving with velocity of 100 ms-1. Its de Broglie wavelength is 6.62  10-35
m-1 hence, x is ……… [h = 6.62  10-34 Js]
(a) 0.25 kg (b) 0.15 kg (c) 0.2 kg (d) 0.1 kg
9. The energy per quantum associated with light of wavelength 5890 A is :
(a) 3.37  10-12 erg (b) 4.7  10-12 erg (c) 3.37  10-10 (d) 4.7  10-10 erg
10. The de-broglie wavelength associated with a ball of mass 1 kg having kinetic energy 0.5 J is :
(a) 6.626  10-34 m (b) 13.20  10-34 m (c) 10.38  10-21 m (d) 6.626  10-34 A
11. The de Broglie wavelength of a tennis ball of mass 60 g moving with a velocity of 10 metres per
second is approximately
(a) 10-25 metres (b) 10-33metres (c) 10-31metres (d) 10-16 metres
12. The uncertainty in position of an electron & helium atom is same. If the uncertainty in
momentum for the electron is 32105 , then the uncertainty in momentum of helium atom will
be:
(a) 32  105 (b) 16  105 (c) 8  105 (d) None
13. What is the ratio of the de-Broglie wave length for electrons accelerates through 200 volts and 50
volts:
(a) 1 : 2 (b) 2 : 1 (c) 3 : 10 (d) 10 : 3
14. The uncertainty in the position of an electron (mass 9.1 10 -28 GM) moving with a velocity of
3 104 cm sec-1 , uncertainty in velocity is 0.011% will be :
(a) 1.92 cm (b) 7.68 cm (c) 0.175 cm (d) 3.84 cm
°
15. A particle X moving with a certain velocity has – a debgroglie wavelength of 1 If particle Y has
A
a mass of 25 % that of X and velocity 75% that of X.Debroglie wavelength of Y will be :
° ° ° °
(a)3 (b) 5.33 (c) 6.88 (d) 48
A A A A
16. Which of the following is the realation between momentum and the wave length of moving particle
according to de Broglie’s principle ?
(a) Inversely proportional (b) Proportional
(c) Square root (d) No relation
17. The ratio of de Broglie wavelengths of particles A and B if the mass of B is four times than A and
the velocity of A is eight times than B is
(a) 1: 2 (b) 2: 1 (c) 2 : 3 (d) 6 : 9
18. The velocity of de Broglie wave is given by
mc 2 mc 2 hv
(a) (b) (c) (d) n
v h mc
19. What is the de Broglie wavelength of a pitched base ball with mass of 120 g and a speed of 44.7
m/s ?
(a) 1 .24  10-34 m (b) 2. 68  10-28m (c) 1.75  10-28m (d) 1.67  10-34m

2nd Floor, Rajcastle, Near Kalpataru, Ellora Park, Baroda – 390007 Ph: +91-265-3053166 3
Date : 06th July 2016 Sub : Chemistry CH – 2 MM:20 Batch : 11TH GSEB|SEM - I

20. The uncertainties in the velocities of two particles A and B are 0.05 and 0.02m/s respectively. The
mass of B is five times to that of mass A .What is the ratio of uncertainties in their positions ?
(a) 2 (b) 0.25 (c) 4 (d) 1

SET-A ANSWER KEY


QUE 1 2 3 4 5 6 7 8 9 10

ANS A A A A B A A C B

QUE 11 12 13 14 15 16 17 18 19 20

ANS D A D C A A B A D C

SET-B ANSWER KEY


QUE 1 2 3 4 5 6 7 8 9 10

ANS A B A D C D A D C A

QUE 11 12 13 14 15 16 17 18 19 20

ANS B A A C B A A A A

2nd Floor, Rajcastle, Near Kalpataru, Ellora Park, Baroda – 390007 Ph: +91-265-3053166 4

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