Q=...?

NH3
N1 NO
N3
REAKTOR H2O
T1=298ºK N2
T3= 1193ºK
O2
NH3
Konversi = 90% N2
Basis = 1 mol
T2= 1023ºK

Udara
N2 = 79%
O2 = 21%

4NH3 (g) + 5O2 (g) 4NO(g) + 6H2O(g)

Jika basis yang digunakan 1 mol, maka :

X= 90%
0,9=𝑟/(1 𝑚𝑜𝑙)
𝑟=0,9/𝑘𝑜𝑒𝑓=0,9/4=0,225 𝑚𝑜𝑙

Input – output + r(koef)=0

Sehingga :
Output = input + r(koef)
Maka output tiap senyawa yaitu
NH3 = 1 mol + 0,225(-4) = 0,1 mol
NO2 = 2,4 mol + 0,225(-5) = 1,275 mol
N2 = (79/21)×2,4 mol = 9,028 mol
NO = 0 mol + 0,225(4) = 0,9 mol
H2O = 0 mol + 0,225(6) = 1,35 mol

Q = N3- (N1 + N2)

sehingga :
 N
1
N1= 1 mol [ ∫1_298^298▒ 〖���� (𝑁𝐻3)+ ∆𝐻𝑓298(𝑁𝐻3) 〗 ]
= 1 [ 0 + (-10,92) ]
= -10,92 Kcal/grmol
N1 -10.92 Kcal -45689.28 Joule

N
2
T 1023 To 298

N2 = 2,4 [ ∫1_298^1023▒ 〖���� (𝑂2)+ ∆𝐻𝑓298(𝑂2) 〗 ] + 9,028 [ ∫1_298^1023▒ 〖���� (𝑁2)+

∆𝐻𝑓298(𝑁2) 〗 ]

∆Hf O2 0 Kcal/mol
∆Hf N2 0 Kcal/mol

CpdT
a b c d e CpdT(J/mol)
O2 2.99E+01 -1.14E-02 4.34E-05 -3.77E-08 1.01E-11 23316.427988949
N2 2.94E+01 -3.01E-03 5.45E-06 5.13E-09 4.25E-12 24118.1912866767

N2 273698.45811 Joule

N
3

T 1193 To 298

∆Hf NO 21.6 Kcal/mol 90374.4 J/mol

∆Hf H2O -57.8 Kcal/mol -241835.2 J/mol
∆Hf N2 0 Kcal/mol 0 J/mol
∆Hf O2 0 Kcal/mol 0 J/mol
∆Hf NH3 -10.92 Kcal/mol -45689.28 J/mol

a b c d e CpdT(J/mol)
NO 2.98E+01 9.76E-04 6.10E-06 -3.59E-09 5.85E-13 29156.642803187 107577.9
H2O 3.40E+01 -9.65E-03 3.30E-05 -2.04E-08 4.30E-12 34174.2263305004 -280342
N2 2.94E+01 -3.01E-03 5.45E-06 5.13E-09 4.25E-12 31985.6572026147 288766.5
O2 2.99E+01 -1.14E-02 4.34E-05 -3.77E-08 1.01E-11 29168.9403694246 37190.4
NH3 2.75E+01 2.56E-02 9.90E-06 -6.69E-09 0.00E+00 43850.15070562 -183.913
 153008.6

N2 = 0,9 [ ∫1_298^1193▒ 〖���� (𝑁𝑂)+ ∆𝐻𝑓298(𝑁𝑂) 〗 ] + 1,35

[ ∫1_298^1193▒ 〖���� (𝐻2𝑂)+ ∆𝐻𝑓298(𝐻2𝑂) 〗 ] + 9,028
[ ∫1_298^1193▒ 〖���� (𝑁2)+ ∆𝐻𝑓298(𝑁2) 〗 ] + 1,275 [ ∫1_298^1193▒ 〖���� (𝑂2)+
∆𝐻𝑓298(𝑂2) 〗 ] + 0,1 [ ∫1_298^1193▒ 〖���� (𝑁𝐻3)+ ∆𝐻𝑓298(𝑁𝐻3) 〗 ]

N3 153008.623336 Joule

Q -75000.554774 Joule
-75.000554774 Kj

Jadi, panas yang dibutuhkan pada reaktor

adalah -75000,6 Joule.
▒ 〖���� (𝑁2)+
� (𝑂2)+