1. Calculate ̂ and ̂ of methan (1) and n-butane (2) vapour mixture at 2.76x106 Pa, and 310.93K
and y1 = 0.8942 assumint the pure components and the gas mixture to follow virial equation of
state, . The following data are given:
2. Show that fr a binary gas mixture following the virial equation of state
, where
3. Show that the activity coefficient for components 1 and 2 in a binary gas mixture following virial
equation of state, are given by
4. A gas phase mixture of nitrogen(1) and n-butane (2) at 460K and 40 bar contains 49.74 mol %
nitrogen and 50.26 mol% n-butane. Calculate the fugacity coefficient of nitrogen and n-butane in
the mixture assuming pure components and the mixture follows;