Introduction1 The main aim of this research is to correlate a relation that can
relate the different variables of heat transfer and pressure drop
Carbon dioxide is an old refrigerant, and the history of its use characteristics of any flow undergoing condensation or evaporation.
dates back to the end of the 19th century. The unusual properties of This relation will enhance the calculations of heat flux from pipes
carbon dioxide give heat transfer and two-phase flow characteristics with inside phase change flow. Thus, design of heat exchangers,
that are very different from those of conventional refrigerants. condensers and evaporators will be more reliable and more
Examples of such differences are a much higher pressure, resulting predictable.
high vapor density, a very low surface tension, and a low liquid Carbon dioxide is an old refrigerant. It was used in the
viscosity as reported by Kim et al. (2004). experimental part of this work. Dimensional analysis results were
One of the major challenges for CO2 refrigeration systems is the compared to the experimental results.
improvement of the performance of heat exchangers. Park and
Hrnjak (2005; 2007), and Abu-Dhem (2006) performed works on
CO2 using macro scale tube heat exchangers. Nomenclature
Experimental investigation of the convective boiling heat ASD = Average Standard Deviation
transfer in the super critical region of CO2 flowing through Ai = micropipe internal surface area, m2
micropipes was studied by Liao and Zhao (2002), Choi et al. (2007) CO2 = carbon dioxide
and X-Jiang et al. (2004). Cp, m = mean specific heat, J/ (kg K)
Thome and Ribatski (2005) listed previous experimental studies DAS = Data Acquisition System
of CO2 flow in macro- and micro- channels undergoing boiling or Di = micropipe internal diameter, m
simple two phase flow. Eu = Euler number
Jokar et al. (2006) used the dimensional analysis technique to fl = friction factor for liquid state
correlate a formula for heat transfer coefficient and Nusselt number fg = friction factor for gas state
during evaporation and condensation processes of refrigerant R- F = some function
134a in mini channel plate heat exchangers. g(ρl -ρg) = Buoyancy force per unit volume, kg/ (m2 s2)
Alshqirate (2008) studied the condensation and evaporation of Ga = Galileo number
CO2 inside micropipes experimentally and by using dimensional hfg = latent heat of vaporization, J/ kg
analysis. hi = convection internal heat transfer coefficient, W/ (m2 K)
The basic objective in dimensional analysis is to reduce the Ja = Jacob number
number of variables involved in a correlation by introducing Km = mean thermal conductivity, W/(m K)
independent dimensionless groups of variables (dimensionless Ltotal = overall test section length, m
parameters). The method for selecting dimensionless groups is using L = length of the condensation region, m
the Buckingham π theorem and the method of indices which is Lg = length of the cooling (gas) region, m
commonly known in the texts of fluid mechanics, as presented by Ll = length of the subcooling (liquid) region, m
Chapra (1998) and Oosthuizen and Naylor (1999). N = number of data points
Nu = average Nusselt number
Paper received 2 November 2010. Paper accepted 21 October 2011. Nu exp. = experimental average Nusselt number
Technical Editor: José Parise
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Alshqirate et al.
Nu corr. = correlated (predicted) average Nusselt number Experimental Set-up and Experimental Results
Pb = barometric pressure, kPa The schematic diagram of the test apparatus used in this study
Pga = Gauge pressure, kPa and its main components are shown in Fig. 1. The experimental set-
Pin = test section inlet pressure, kPa up consists basically of:
Pin ,cond = micropipe condenser inlet pressure, kPa 1- The pressurized CO2 (g) cylinder as a main source of
Pout = test section outlet pressure, kPa carbon dioxide gas.
Pr = Prandtl number 2- High pressure regulating valve with built-in gas cylinder
R2 = coefficient of determination (curve fitting) pressure gauges.
Re D = Reynolds number 3- Chest freezer used as environment to cool, condense and
T sat, in = condenser inlet saturation temperature, ºC sub cool the carbon dioxide gas flowing inside the
T sat, out = condenser outlet saturation temperature, ºC micropipe condenser test section by natural convection.
T si = measured surface temperature, ºC 4- The micropipe condenser.
T surf = calculated surface temperature, ºC 5- High pressure cutoff and isolating valves.
Vm = mean velocity, m/ s2 6- Pressure gauges.
Vg = velocity of the gas, m/ s2 7- Sight glasses.
Vl = velocity of the liquid, m/ s2 8- The micropipe evaporator.
We = Weber number 9- Data Acquisition System (DAS).
W = uncertainty 10- Volume flow meter for measuring the mass flow rate of
Greek Symbols the gas.
∆Pcond = pressure drop during condensation, kPa K-type thermocouples were used in order to measure the outside
∆Ptotal = overall pressure drop, kPa wall surface temperature of the micropipe condensers and
∆Pg = the pressure drop across the vapor region, kPa evaporators during condensation and evaporation processes, the
∆Pl = the pressure drop across the liquid region, kPa chest freezer inside air temperature and the ambient temperature.
∆T = difference between saturation temperature and test Thirty two temperature readings, distributed along each
section surface temperature, ºC condenser and each evaporator, were sensed by K-type
∆ Tlm = logarithmic mean temperature difference, ºC thermocouples connected to a module of (32 channels), which is in
∆Tout = difference between outlet saturation temperature turn plugged into a data acquisition system of model SCXI-1000,
and calculated surface temperature, ºC manufactured by National Instruments Company.
∆Tin = difference between inlet saturation temperature and The well-known LAB VIEW software was used for processing
calculated surface temperature, ºC the signals from the thermocouples and for changing it to
∆Xj = distance along the condenser between two temperature readings on the screen of a connected personal
subsequent thermocouples, m computer. For each experimental test run, the variations of the
m CO2 = mass flow rate of carbon dioxide, kg/s temperature with time were monitored. The temperature readings
Q CO2 = total heat transfer rate rejected from carbon dioxide were monitored until the steady state conditions were achieved.
gas, W The pressure was recorded in three positions at steady state
µm = mean dynamic viscosity, Pa s conditions; they were: before condensation, after condensation and
µg = gas dynamic viscosity, Pa s after evaporation. Volumetric rate of flow in m3s-1 was read at the
µl = liquid dynamic viscosity, Pa s end outlet flow by a gas flow meter calibrated for CO2 (g).
ρm = mean density, kg/ m3 Experiments were conducted for different pipe diameters, at
ρg = gas density, kg/ m3 different pressures, and at settings of different rate of flows. More
ρl = liquid density, kg/ m3 than 2500 readings were collected.
σ = surface tension, N/ m
V = volume flow rate, l /min 2 5
6 10
Subscripts Chest Freezer
3 7
j = thermocouple number
l = liquid Data Acquisition 9
Printer Computer System DAS
lm = logarithmic
m = mean
Figure 1. Schematic diagram of the test apparatus.
out = outlet
sat = saturation
total = overall The experimental convective heat transfer coefficient was
Superscripts calculated (These data are always used to calculate the constants of
the empirical equation as will be shown).
a,b,c,d,e, = power constants
The experimental conditions that were used in this study are
f,h,i,j,k, = power constants
listed in Table 1.
l,m,n,p,q = power constants
Table 1. Experimental conditions. dioxide across the condenser (two phase region) (∆Pcond) in kPa
Three micropipe Three micropipe results from:
Test sections
condensers evaporators
Condensation inside ∆Pcond = ∆Ptotal – (∆Pg + ∆Pl) (1)
Evaporation in still
Process a chest freezer of
room temperature air where:
–28oC
Working fluid CO2 (g) CO2 (l)
∆Pl = ( fl ρl Vl 2 Ll) / (2Di) (2)
Micropipe internal
0.6, 1.0, 1.6 0.6, 1.0, 1.6
diameter, Di , mm ∆Pg = ( fg ρg Vg2 Lg) / (2Di) (3)
Test section total
29.72 16
length, m fg , f l are friction factors for the vapor and the liquid states of
Test section inlet 3350, 3600, 4000, 3600, 4000, 4500, CO2, respectively.
pressure, kPa 4500 4800 Lg, Ll are the length of the cooling (vapor state) and the sub
Saturation -1.5, 1.23, 5.30, 1.23, 5.30, 9.98, cooling (liquid state) regions from the test section in meters,
temperature, oC 9.98 12.60 respectively. These lengths can be found by considering Fig. 2. This
Volume flow rate, figure represents temperature values for all positions along the pipe.
1, 2, 3, 4 1, 2, 3, 4
l / min Each test produces such a curve.
Condensation process
25 Device:Micropipe internal diameter
Three micropipe test sections of different internal diameters 20
0.6mm
Process: Condensation
were used for the condensation process with 29.72 m total length for 15 Test section inlet pressure: 3600 kPa
each test section. The test tube was installed inside a chest freezer as
a cooling environment. Flow of CO2 (g) inside the tube was carried 10
Temperature (oC)
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Alshqirate et al.
from the hot environment in evaporation process. Radial heat flux mentioned the use of dimensional analysis of at least 10 variables
will be the same either through internal forced convection with CO2 and 5 dimensions.
(g), or external natural convection with surrounding air. All these In this research, the results for convection heat transfer
processes were performed under steady state conditions. The two coefficient and pressure drop during condensation processes, and
figures in Appendix A illustrate the two processes (condensation convection heat transfer coefficient during evaporation processes
and evaporation) and show the limits of the tube regions, especially were presented, plotted and discussed.
the phase change region.
The rate of heat transfer from carbon dioxide to the inner surface Dimensional analysis of convection heat transfer coefficient
of the condenser is:
. during condensation
Q CO2
= hi Ai ∆ Tlm (5) The convection internal heat transfer coefficient (hi) of any gas
during condensation process in micropipes is expected to depend on
the following dimensional variables: the difference between the
where hi is the convective internal heat transfer coefficient. mean saturation temperature during condensation process and the
The logarithmic mean temperature difference calculation is: test section surface temperature; the buoyancy force arising from the
liquid-vapor density difference; the latent heat of vaporization; the
∆Tlm = (∆Tout – ∆Tin) / ln (∆Tout / ∆Tin) (6) mean surface tension; the micropipe internal diameter; the length of
the micropipe condenser; the mean velocity; the pressure drop
∆Tout = Tsat, out - Tsurf (7) across the condenser; the mean value of the density; the mean
specific heat; and the mean thermal conductivity and the mean
∆Tin = Tsat, in - Tsurf (8) dynamic viscosity as presented by Incropera and Dewitt (2002).
The mean values of the properties were defined by liquid and
where Tsat,out and Tsat,in are the condenser outlet and inlet saturation gas properties,
temperatures at the outlet and inlet condenser pressures,
respectively. Tsurf is the calculated outer surface temperature of the
ρl + ρ g µl + µ g
(i.e., ρm = , µm = , etc.).
condenser in oC. 2 2
Jiang et al. (2004) calculated the outer surface temperature
(Tsurf) required for logarithmic mean temperature difference using Liquid and gas properties were obtained from CO2 tables
the following relation: published by (IIR).
It is assumed, therefore, that:
∑T si ∗ ∆X J
Tsurf = , j= 1, L (9) F [hi, ∆T, g(ρl - ρg), hfg, Di, L, Vm, ∆Pcond, ρm, Cp, m, Km, µm] = 0
L (12)
∆Pcond
π1 = = dimensionless pressure drop,
Empirical correlation of convection heat transfer coefficient Pin,cond
during condensation
The empirical correlation equation for the convection internal Vm ρ m1 / 2 µm L
π2 = 1 / 2 , π3 = , π4 = (20)
heat transfer coefficient during the condensation processes inside Pin ,cond P1/ 2
ρ m1 / 2 Di
in , cond Di
micropipe condensers out of the dimensionless group of the average
Nusselt number can be obtained as follows:
The groups' π2 and π3 are new numbers, once multiplied with
each other a new non-dimensional group is found:
L
Nu = function (ReD, Pr, Ga, Ja, , Eu) (15)
Di Vm ρ m1 / 2 µm
π = π2 * π3 = 1/ 2 * =
A general formula for heat transfer coefficient during Pin ,cond P 1/ 2
ρ m1 / 2 Di
in ,cond
condensation can be put in the form:
µ mV m Vm ρ m Vm2 ρ m µm
∗ = ∗
L Pin ,cond Di Vm ρ m Pin ,cond ρ m DiVm
Nu =C (ReD)a (Pr)b (Ga)c (Ja)d ( )e (Eu)f (16)
Di 1 1
= ∗ (21)
Eu Re D
where C, a, b, c, d, e, and f are constants.
Solving for carbon dioxide data generated by the experimental
work using the Multiple Linear Regression Method will give the Empirical correlation of pressure drop during condensation
following correlation: The dimensionless pressure drop can be obtained as follows:
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Alshqirate et al.
temperature during the evaporation process and the test section wall Results and Analysis
surface temperature, the buoyancy force arising from the liquid-
vapor density difference during phase change, the latent heat of The convection heat transfer coefficient during condensation
vaporization; the mean surface tension; the micropipe internal The experimentally determined values of the average Nusselt
diameter; the length of the micropipe evaporator; the mean velocity;
the evaporation test section inlet pressure (the saturation pressure); number ( Nu exp ) were compared with the predicted values of the
the mean value of the density; the mean specific heat; the mean
average Nusselt number ( Nu corr.) obtained from Eq. (17). The
thermal conductivity and the mean dynamic viscosity.
It is assumed, therefore, that: comparison is shown in Fig. 3. A reasonable degree of agreement is
exhibited.
F [hi, ∆T, g(ρl - ρg), hfg, σm, Di, L, Vm, Pin, ρm, Cp, m, Km, µm]= 0 For curve fitting it is clear that the Coefficient of Determination
(25) (R2) = 0.985, which indicates that 98.5 percent of the original
uncertainty has been explained by the linear model.
where F is a function. This equation consists of 13 variables with The accuracy refers to how closely a computed value agrees
five basic primary dimensions needed to express the variables. with the measured value. So the inaccuracy (also called bias) of
Based on the above, the number of the dimensionless variables measured and calculated values can be calculated as follows:
resulted for this problem was eight.
____ ____
The results of dimensional analysis are in the following form:
100 N Nu exp . − Nu corr.
F (π1, π2, π3, π4, π5, π6, π7, π8) = 0 (26)
Bias error (%) = ∑ ( ____
N 1
) (31)
Nu exp .
where:
where N is the number of data points.
hi Di V m Di ρ m C P ,m µ m The Bias error = 0.462%.
π1 = = Nu , π2 = = ReD, π3 = = Pr, While the Average Standard Deviation (ASD):
km µm km
g ( ρ l − ρ g ) Di3 ρ m ∆TC pm ___
100 N Nu exp . − Nu corr .
___
π4 =
µ m2
= Ga, π5 =
h fg
= Ja, ASD (%) = ∑ ( ___
N 1
) = 4.62% (32)
Nu exp .
ρ mVm2 Di L Pin
π6 = = We, π7 = , π8 = = Eu
σm Di V m2 ρ m
(27)
L
Nu = function (ReD, Pr, Ga, Ja, We, , Eu) (28)
Di
This equation can be put in the following form:
Figure 3. Comparison of the experimental and predicted values of the
Nusselt number of Carbon Dioxide during condensation.
L
Nu = C (Re,D)j (Pr)k (Ga)l (Ja)m (We)n ( )p (Eu)q (29)
Di The pressure drop during condensation
The experimentally determined values of the pressure drop
where C, j, k, l, m, n, p and q are constants.
Solving for carbon dioxide data generated by the experimental ∆Pcond
work using the Multiple Linear Regression Method will give the exp were compared with the predicted values of the
following correlation:
Pin ,cond
∆Pcond
pressure drop obtained from the resulted correlation of
Nu = 34.92 * [(ReD)-0.31 (Pr)-0.39 (Ga) 0.11 (Ja)-0.71 (We) 0.81 corr
Pin ,cond
L Eq. (13). The comparison is displayed in Fig. 4. A reasonable degree
( ) -0.82 (Eu) 0.2] (30)
Di of agreement is exhibited.
in ,cond
While the Average Standard Deviation (ASD): of the barometer ( W P ) is ±0.25 mbar; and the uncertainty of the
b
J. of the Braz. Soc. of Mech. Sci. & Eng. Copyright 2012 by ABCM January-March 2012, Vol. XXXIV, No. 1 / 95
Alshqirate et al.
The relationship between the pressure drop of carbon dioxide Finally, the value of the uncertainty of the pressure drop is equal to:
during condensation and the measured parameters can be obtained
as follows: W∆Pcond = ± 1.0 kPa
Conclusions Kim, M., Pettersen, J. and Bullard, C.W., 2004, "Fundamental process
and system design issues in CO2 vapor compression systems", Progress in
The following conclusions resulted from this work: Energy and Combustion Science, Vol. 30, pp. 119-174.
1- For the condensation process, two empirical correlations were Liao, S.M. and Zhao, T.S., 2002, "An experimental investigation of
developed for the carbon dioxide pressure drop and convective heat convection heat transfer to supercritical carbon dioxide in miniature tubes",
International Journal of Heat and Mass Transfer, Vol. 45, pp. 5025-5034.
transfer coefficient. These correlations were proved to be highly Oosthuizen, P.H. and Naylor, D., 1999, "An introduction to convective
accurate for pressure drops with the bias error = 5.25% and ASD = heat transfer analysis", McGraw-Hill, Singapore.
17.94%, while for convective heat transfer coefficients, with bias Park, C.Y. and Hrnjak, P.S., 2007, "CO2 and R410A flow boiling heat
error = 0.4% and ASD = 4.62%. transfer, pressure drop, and flow pattern at low temperatures in a horizontal
2- For the evaporation process, an empirical correlation was smooth tube", International Journal of Refrigeration, Vol. 30, pp. 166-178.
developed for the carbon dioxide convective heat transfer
coefficient. This correlation was proved to be highly accurate for Appendix A
convective heat transfer coefficients with bias error = 3.8% and
ASD = 4.14%.
3- All resulted correlations obtained in this work are listed in
Table 2.
4- The study covered flow of Reynolds number (ReD) ranging
between 2000 and 15000.
References
Abu-Dhem, F.M., 2006, "Modeling Simulation and Experimental Study
of the Heat Transfer Characteristic of Subcritical Carbon Dioxide during
Condensation and Evaporation Processes in Refrigeration Systems", Ph.D
Thesis, University of Jordan, Amman, Jordan.
Alshqirate, A.S., 2008, "Characteristic Study of Carbon Dioxide (CO2)
During Condensation and Evaporation inside Micropipes when used as
Refrigerant", Ph.D Thesis, University of Jordan, Amman, Jordan.
Chapra, S.C. and Canale, R.P., 1998, "Numerical Methods for
Engineers", 3ed edition, McGraw-Hill, Singapore.
Choi, K., Pamitran, A.S. and Oh, J.T., 2007, "Two-phase flow heat
transfer of CO2 vaporization in smooth horizontal mini channels",
International Journal of Refrigeration, Vol. 30, pp. 767-777.
Incropera, F.P. and Dewitt, D.P., 2002, "Fundamentals of heat and mass
transfer", 5th edition, John Wiley and Sons.
Jiang, P.-X., Xu, Y., Lv, J., Shi, R., He, S. and Jackson, J.D., 2004,
"Experimental investigation of convection heat transfer of CO2 at super-
critical pressures in vertical mini-tubes and in porous media", Applied
Thermal Engineering, Vol. 24, pp. 1255-1270.
Jokar, A., Hosni, M.H. and Eckels, S.J., 2006, "Dimensional analysis on
the evaporation and condensation of refrigerant R-134a in minichannel plate
heat exchangers", Applied Thermal Engineering, Vol. 26, pp. 2287-2300.