Introduction to Separation
Process Engineering
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Examples of the Importance of Separations
Air Condenser
Water (100%) Air 99.5%
Water 0.5%
Distillate
Absorber Distillation Acetone 99.0%
column column Water 1.0%
Bottom product
Acetone 3.0%
Air 95.0%
Water 2.0%
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Water vapour
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C3H8
Mixing point
C3H6
Recycle
C3H8
C3H6
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In this course, we shall focus on the separation
processes in which two separated phases are in
contact and in equilibrium with each other
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1.1 Equilibrium
What is “equilibrium”?
What is(are) the difference(s) between
“equilibrium” and “steady state”?
yA yB
Tvapour Pvapour
Tliquid Pliquid
xA xB
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We have learned that, at equilibrium,
Tvapour = Tliquid
Pvapour = Pliquid
mivapour = miliquid
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When referring to the term “equilibrium”, it
means there are no changes in any properties
with time and there are no differences, also in
any properties, within the system
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1.2 Mass Transfer Basics
(
Rate = K ya yi* - yi ) (1.2)
or Rate = K a (x
x i
-x )
*
i
(1.3)
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where
K y = mass transfer coefficient in gas phase
K x = mass transfer coefficient in liquid phase
a = contacting area
x i or yi = concentration of species i at
any instant of time
x i* or yi* = concentration of species i at
equilibrium
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1.3 Pre-requisite Materials for Studying this
Course (AE 335 Separation Processes)
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1.4a Main textbook:
Wankat, P.C., Separation Process
Engineering, 2nd ed., Prentice Hall, 2007
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