P0

LEMBAR PERHITUNGAN REAGEN

1. Menghitung kebutuhan NaOH

𝑔𝑟𝑎𝑚 1000
N= 𝑥 𝑥 𝑣𝑎𝑙𝑒𝑛𝑠𝑖 𝑥 𝑘𝑎𝑑𝑎𝑟 𝑁𝑎𝑂𝐻
𝐵𝑀 𝑚𝑙
𝑔𝑟𝑎𝑚 1000
0,4 = 𝑥 𝑥 1 𝑥 0,98
40 300
gram = 4,89 gram
2. Perhitungan densitas
 Kalibrasi Picnometer
Massa picnometer kosong = 22,691 gr
Volume picnometer = 25 ml
 Densitas HCL
m picno kosong = 22,691 gr
m picno + HCL = 53,243 ml
v picno = 25ml
53,243−22,691
𝜌= = 1,222 gr/ml
25
 Densitas Asam Asetat
m picno kosong = 22,691 gr
m picno + asam asetat = 50,403ml
v picno = 25ml
50,403−22,691
𝜌= = 1,108 gr/ml
25
 Densitas Metanol
m picno kosong = 22,691 gr
m picno + metanol = 43,791ml
v picno = 25ml
43,791−22,691
𝜌= = 0,844 gr/ml
25
Menghitung kebutuhan katalis HCL 0,25N :
𝑁 𝑥 𝐵𝑀HCL x 𝑉𝑏𝑎𝑠𝑖𝑠
𝑉=
𝜌 𝑥 𝑘𝑎𝑑𝑎𝑟 𝐻𝐶𝐿 𝑥 𝑣𝑎𝑙 𝑥 1000
0,25 𝑥 36,5 x 250
𝑉=
1,222 𝑥 0,25𝑥 1𝑥 1000
V = 7,467 ml
Menghitung kebutuhan methanol dan asam asetat (HCL 0,25N) :
V methanol + V asam asetat = 250 ml – V HCL
V asam asetat = (250 – 7,467) – V methanol
V asam asetat + V methanol = 242,533 ml
Variabel 1 :
mol asam asetat : mol methanol = 1 : 2,08
 P0

𝑚𝑜𝑙 𝑎𝑠𝑎𝑚 𝑎𝑠𝑒𝑡𝑎𝑡 1

=
𝑚𝑜𝑙 𝑚𝑒𝑡𝑎𝑛𝑜𝑙 2,08
𝑉. 𝜌. %
𝐵𝑀 𝑎𝑠𝑎𝑚 𝑎𝑠𝑒𝑡𝑎𝑡 = 1
𝑉. 𝜌. % 2,08
𝐵𝑀 𝑚𝑒𝑡𝑎𝑛𝑜𝑙
𝑉asam asetat𝑥1,108𝑥 0,98
60 1
=
𝑉𝑚𝑒𝑡𝑎𝑛𝑜𝑙 𝑥 0,844𝑥 0.98 2,08
33
V asam asetat = 0,69249 V methanol
V asam asetat + V methanol + V katalis = 250ml
V asam asetat + V methanol + 7,467 = 242,54ml
1,69249 V methanol = 242,54ml
V methanol = 143,303 ml
V asam asetat = 250–7,467–143,303
= 99,229 ml