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DEEPWATER GAS

What’s the problem?


by
Dr Julie E P Morgan
Granherne Pty Ltd

Perth
26th April 2007
Delivering
Consulting Excellence
Flow Assurance

How to get from A to B cost effectively?

A Reservoir
Asphaltenes
Pressure

Hydrates

Waxes

B
Product
Temperature
Delivering
Consulting Excellence
Where in the World is
Deepwater?

West of Shetland Norway

North Africa
Gulf of Mexico

West Africa SE Asia


Brazil

Delivering
Consulting Excellence
Deepwater Development
Issues
ÙReservoir uncertainty

ÙDeepwater installation

ÙRiser design / installation

ÙInspection, Maintenance and Repair (IMR)

ÙOperability / availability

ÙFlow Assurance
Delivering
Consulting Excellence
Deepwater Features
ÙDeeper water column (higher hydrostatic pressure)

ÙLower seabed ambient temperatures

ÙFluid Properties - hydrocarbons from different


geological sources to those in shallow water

ÙReservoir Complexity - shallow reservoir, HPHT,


compartmentalised, …

ÙComplex thermo-hydraulic fluid behaviour

Delivering
Consulting Excellence
GoM Water Temperature Profile

Delivering
Consulting Excellence
NWS versus GoM Water
Temperature

Delivering
Consulting Excellence
Hydrates

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What are Hydrates?
Ù Ice like crystals formed from water and light hydrocarbons (~85
mol% water, ~15 mol% hydrocarbon), which when
agglomerated can block the flow path
Ù Contain as much as 180 volumes (STP) of gas per volume of
hydrate
Ù Can form at >18°C (>65°F) when the pressure is >170 bar
(>2500psi)
Ù Can form in wellbore, flowline, valves and meter discharges
Ù Have been found in wet gases, condensates & black oils
Ù Structure sI
• Usually formed by smaller molecules like methane, ethane, and
carbon dioxide
Ù Structure sII
• Formed by larger molecules such as propane and isobutane
Ù Structure H
• Formed by large molecules such as methylcyclo-hexane, only in
the presence of a smaller molecule
Ù Most often encountered on restart
Delivering
Ù Safety issues associated with depressurisation for blockage
Consulting Excellence
Hydrates
Ù Manage problem - Prevent hydrate formation
(which requires water, light hydrocarbons, low
temperatures and high pressures):
• Thermodynamic solutions:
− Remove water
− Maintain high temperature
− Decrease pressure below hydrate dissociation pressure
− Inject thermodynamic hydrate inhibitor, e.g. MeOH, MEG,
salt!
• Non-thermodynamic solutions:
– Inject low dosage hydrate inhibitor

Delivering
Consulting Excellence
Hydrates
Ù Manage problem - Blockage remediation:
• Depressurisation below hydrate dissociation pressure:
– Single sided
– Double sided
• Thermal methods:
– Raise temperature above hydrate dissociation
temperature
– Hot Flushing - not effective on total blockages
– Exothermic Reaction - drastic action, difficult to deploy
and control in remote lines
• Chemical dissolvers:
– Alcohols e.g. MeOH
– Glycols e.g. MEG
• Mechanical methods
– Coiled tubing
– Pigs, if flow path open
Delivering
Consulting Excellence
Typical NWS Hydrate Curves

HYDRATES

NO HYDRATES

Delivering
Consulting Excellence
Typical NWS Hydrate Curves

HYDRATES

NO HYDRATES

Delivering
Consulting Excellence
Typical NWS Hydrate Curves

HYDRATES

NO HYDRATES

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Consulting Excellence
Multi-component Fluid
7000
Multiple Component Phase Diagram

6000 CRITICAL
POINT CRICONDENBAR

BUBBLE
5000 POINT DEW POINT CURVE
CURVE

VAPOR FRACTION = 100 MOLE %


Pressure (psia)

4000
LIQUID 99
MOLE %
QUALITY
LINES 95
3000 MOLE %
90 CRICONDENTHERM
80 MOLE %
MOLE %

2000

1000
VAPOR

0
-100 0 100 200 300 400 500 600 700 800 900 1000
Courtesy: DeepStar Temperature (F)

Delivering
Consulting Excellence
Retrograde Gas
5000
PRESSURE PATH
IN RESERVOIR
1 RETROGRADE GAS

DEW POINT CURVE


4000 CRITICAL 2
POINT

3000
Pressure (psia)

60
50 40
30
20
10 % LIQUID

2000

SEPARATOR
1000

0
0 100 200 300 400 500 600
Courtesy: DeepStar Temperature (F)
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Consulting Excellence
Wet Gas
3000
PRESSURE PATH
WET GAS IN RESERVOIR
1

2500

DEW POINT CURVE


2000
CRITICAL
Pressure (psia)

POINT

1500
20 % LIQUID
10
5 1
1000 2

SEPARATOR

500

0
-50 0 50 100 150 200 250
Courtesy: DeepStar Temperature (F)

Delivering
Consulting Excellence
Dry Gas
3000
PRESSURE PATH
IN RESERVOIR
DRY GAS
1

2500

2000
Pressure (psia)

1500
DEW POINT CURVE

CRITICAL
POINT
1000
2

SEPARATOR
10 5 1% LIQUID
500

0
-100 -50 0 50 100 150 200
Courtesy: DeepStar Temperature (F)
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Consulting Excellence
Fluid D

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Fluid E

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Fluid Liquid “Features”
Ù Hydrocarbon liquid content
• CGR (condensate to gas ratio)
– Typical range is from 3 to 100 stb/MMscf
Ù Water content
• Saturated water (water of condensation)
– Ranges from 1.5 to 5 stb/MMscf initially up to 25 stb/MMscf late
in life
• Formation water
– Range ??????
– Upper limit constrained by some processing capacity e.g. MEG
regeneration to say 5,000 bwpd, maybe more?
Ù Total liquid content
• Ranges from 5 to 105 stb/MMscf early life up to 130
stb/MMscf late in life

Delivering
Consulting Excellence
Associated FA Challenges
Ù Production chemistry related:
• Wax
• Asphaltenes
• Scale
• Corrosion
• Chemical compatibility
Ù Other:
• Sand production
• Erosion
• Hydraulic performance / liquid management

Delivering
Consulting Excellence
Hydraulic Performance
ÙInfluenced by:
• System operating conditions (pressure &
temperature)
• Multiphase flow (hydrocarbons, water &
chemicals)
• Pipeline topography
ÙChallenges:
• Slugging (hydrodynamic, terrain, riser)
• Liquid surges as a result of rate changes e.g.
start-up, ramp-up (dynamic pigging), pigging

Delivering
Consulting Excellence
Generic Development

Ù Development details:
• 20 km subsea tieback:
– 4 wells at a single drill centre
• Production rates:
– Early life: 1,000 MMscfd
– End of plateau: 600 MMscfd
• Required arrival pressures:
– Early life: 120 bara
– End of plateau: 25 bara
• Liquids content:
– CGR: 5 bbl/MMscf
– Saturated water: 2 bbl/MMscf

Delivering
Consulting Excellence
Generic Development
20 km 25oC

100 m shallow
20oC
10 km

100 m 20oC

1,000 m scarp

4o C

1,000 m

deep

4o C

Delivering
Consulting Excellence
Hydraulic Performance

Delivering
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Thermal Performance

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Consulting Excellence
Liquid Content – Total Hold-up

Delivering
Consulting Excellence
Liquid Management

Shallow Deep Scarp

Slugging Not predicted <500 MMscfd <500 MMscfd

Location Not predicted Along whole Only in scarp


pipeline section

Mean Slug - 74 to 110 74 to 110


Volume (m3)
Liquid by 121@1,000 MMscfd 123@1,000 MMscfd 111@1,000 MMscfd
sphere (m3) 179@500 MMscfd 1,083@500 MMscfd 594@500 MMscfd
3,610@100 MMscfd 2,524@100 MMscfd 2,841@100 MMscfd

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Liquids in Deep Case

1,000 MMscfd 500 MMscfd 100 MMscfd

Liquid Hold-up 213 1,474 3,850


(m3)
Equivalent 730 5,052 13,192
length (m)

Static Head (m) 36.5 252.6 659.6

Static Head 3.1 21.7 56.7


(bara)

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Thanks for your
attention

Any questions?

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