JP MT3 P2

®
P21-17
PAPER-2 Academic Session: 2017-18 C OD E - 0
MAJOR TEST-3 (MT-3)
DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

(JEE ADVANCED PATTERN)
Target : JEE (Main+Advanced) 2018
Date: 07-01-2018 | Duration : 3 Hours | Max. Marks: 240
COURSE : VIJETA (02JP)
Please read the last page of this booklet for the instructions.
(Ñi;k funsZ'kksa ds fy;s bl iqfLrdk ds vfUre i`"B dks i<+sA )
Resonance Eduventures Ltd.
CORPORATE OFFICE : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | Toll Free : 1800 258 5555
Reg. Office : J-2, Jawahar Nagar, Main Road, Kota (Raj.)-324005 | Ph. No.: +91-744-3192222 | FAX No. : +91-022-39167222
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN: U80302RJ2007PLC024029
MATHEMATICS
PART : I MATHEMATICS
MATHEMATICS
SECTION – 1 : (Maximum Marks : 16)
 This section contains FOUR questions
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.
1. If inside a big circle exactly n(n  3) small circles, each of radius r, can be drawn in such a way that
each small circle touches the big circle and also touches both its adjacent small circles, then the
radius of big circle is f(n) then
(A) f(6) = 3r (B) f(4) = ( 2  1) r

2
  
 2   sin 2n  cos n 
(C) f( n) = r  1  cosec  (D) f (n) = r
 n sin

n
Space for Rough Work
Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)-324005
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in
P202JPMT3070118C0-1
Toll Free : 1800 258 5555 | CIN: U80302RJ2007PLC024029
MATHEMATICS
2. For the smallest positive values of x and y, the equation 2(sinx + siny) – 2cos(x – y) = 3 has a
MATHEMATICS
solution then which of the following is/are true
x y x y 1
(A) sin =1 (B) cos 
2 2 2
(C) number of ordered pairs (x, y) is 2 (D) number of ordered pairs (x, y) is 3
Let A = [–2, 4) and B = {x|x – ax – 4  0} It is given that B  A and complete set consisting all
2
3.
possible corresponding values of real a for this to be true is S = [, ) then identify correct
option(s)
(A) No. of integers in set S are 3 (B) No. of integers in set S are 2.
(C) [0.5, 1.5] is a subset of S. (D) [1.5, 2.5] is a subset of S
4. If P is a point on hyperbola, then

(A) The locus of the ex-centre of the circle described opposite to P for PSS' (S and S are
focii) is tangent at vertex
(B) The locus of the ex-centre of the circle described opposite to S ' for PSS' (S and S are
focii) is a hyperbola.
(C) The locus of the ex-centre of the circle described opposite to P for PSS' (S and S’ are
focii) is hyperbola.
(D) The locus of the ex-centre of the circle described opposite to S ' for PSS' (S and S are
focii)is tangent at vertex
P202JPMT3070118C0-2
MATHEMATICS
MATHEMATICS
 This section contains THREE paragraphs
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct 
 For each question, darken the bubble corresponding to the correct option in the ORS
 Marking scheme :
+4 If only the bubble corresponding to the correct option is darkened
0 If none of the bubbles is darkened
–2 In all other cases
Paragraph for Question Nos. 5 to 6
Internal bisectors of ABC meet the circumcircle at point D, E, F and R is circumradius of ABC .
5. The length of side EF is

A A
(A) 2R cos   (B) 2R sin  
2 2
A B C
(C) R cos   (D) 2R cos   cos  
2 2 2
6. Area of DEF is
A B C A B C
(A) 2R2 cos2   cos2   cos2   (B) 2R2 sin   sin   sin  
2 2 2 2 2 2
A B C A B C
(C) 2R2 sin2   sin2   sin2   (D) 2R2 cos   cos   cos  
2 2 2 2 2 2
P202JPMT3070118C0-3
MATHEMATICS
MATHEMATICS
Consider the equation x
4
 2ax3  x 2  2ax  1  0 , where a  R . Also the range of function
1
f(x) = x is (, 2]  [2, ) .
x
7. If the equation has at least two distinct positive real roots then set of all possible values of a is
 1 5   3
(A)  ,   (B)  ,  (C)  ,   (D) none of these
4 4 4
8. If exactly two roots are positive and two roots are negative then the number of integer values of a is
(A) 2 (B) 1 (C) 0 (D) 3
Two variable chords AB and BC of a circle x 2  y 2  a 2 are such that AB = BC = a, M and N are
the midpoints of AB and BC, respectively such that the line joining MN intersects the circle at P
and Q, where P is closer to AB and O is centre of circle.
9. The angle between the tangents at A and C is

 2  5
(A) (B) (C) (D)
2 3 3 6
10. The locus of the point of intersection of tangents at A and C is

(A) x2  y 2  a2 (B) x 2  y 2  2a 2 (C) x 2  y 2  4a 2 (D) x 2  y 2  8a 2
P202JPMT3070118C0-4
MATHEMATICS
MATHEMATICS
 This section contains FOURTEEN questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 There are 14 Questions & you have attempt any 10 Questions. If a student attempts more
than 10 questions, then only first 10 questions which he has attempted will be checked.
 For each question, darken the bubble corresponding to the correct integer in the ORS
+4 If the bubble corresponding to the answer is darkened
0 In all other cases
11. Number of permutations of 1, 2, 3, 4, 5, 6, 7, 8 and 9 taken all at a time such that the digit 1
appearing somewhere to the left of 2, 3 appearing to the left of 4 and 5 somewhere to the left of 6
is k.7!, then the value of k is
Assume that A = {(x, y) : 3x + 4y = 12} and B = {(x, y) : y = mx + c}. If A  B   for all m  R,

2 2
12.
then number of integral values of c, is
13. Consider the locus of centre of the circle which touches the circle x 2  y 2  4 and the line x = 4.
The distance of the vertex of the locus from the origin is
P202JPMT3070118C0-5
MATHEMATICS
2 2
x y
14. The value of a for which extremities of the latus rectum of the ellipse  2  1 , (a > b) having
MATHEMATICS
2
a b
positive ordinates lie on the parabola x 2  2( y  2) is
15. In a plane there are two families of lines: y = x + r and y = –x + r, where r  {0, 1, 2, 3, 4}, then the
number of squares of diagonal of length 2 formed by these lines are ?
16. The line 3x + 2y = 24 meets the y-axis at A and x-axis at B. The perpendicular bisector of AB
meets the line through (0, –1) and parallel to the x-axis at C. If the area of Triangle ABC is P, then
P
the value of is
13
17. Let x 2  y 2  xy  1  a( x  y )  x, y  R , then the number of possible integer(s) in the range

of a is
P202JPMT3070118C0-6
MATHEMATICS
If p is even prime number and q is minimum value of sin x + sinx + 1, and if  is the only positive root
2
18.
MATHEMATICS
–1)p + (p – 1 – 
2018 2 2018 2018 2 2017
of ((2017) –1)x + (p – (2017) )x = 1 then the value of ( ) pq + 4q is
equal to
3 4 5 6
19. Let S be the sum of the series 3
 4  6  7  ............... , then the value of S 1 is?
2 2 .3 2 .3 2 .5
20. The number of positive integral ordered pairs of (a, b) such that 6, a. b are in harmonic
progression is
21. If p is a prime number such that 16p + 1 is a cube of a positive integer m and E is exponent of m in
p! then number of solution of |x| + |x + 1| + |x – 1| = E – 15 is
P202JPMT3070118C0-7
MATHEMATICS
22. If N is the number of ways in which 3 distinct number can be selected from the set
MATHEMATICS
2 3 10 N
{3, 3 , 3 ,.......3 } such that they form a G.P. Then the value of is?
5
The number of positive integers satisfying x  log10 (2  1)  x log10 5  log10 6 is?

x
23.
9
24. In a triangle ABC, sinA.sinB + sinB.sinC + sinC.sinA = and BC = 2 units , then the value of
4
3 (where  is the area of triangle) is?
P202JPMT3070118C0-8
PHYSICS
PART - II : PHYSICS
PHYSICS

darkened.
25 . A rectangular bar is uniformly loaded axially with force per unit area  as shown. Shown is a
section AA in the bar. Choose the correct option(s)


A

(A) Normal stress for the section is  (independent of )

(B) Shear stress for the section is maximum for  = 45° and is equal to
2
(C) Normal stress for the section is  sin 
2
(D) Shear stress for the section is minimum for  = 90° and is equal to zero
® Corporate Office : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.)- 324005
P202JPMT3070118C0-9
PHYSICS
26. 4 g of He gas is taken in a cyclic process as shown on the P-T diagram. The minimum temperature
PHYSICS
is 300 K and the maximum is 600 K. The pressures of the points are, PA = 1 × 105 N/m2,
PB = PD = 2 × 105 N/m2.Choose the correct option(s).
(A) The workdone in the process BC is W 1 and in the process DA is W 2 then W 1 = W 2
(B) Heat supplied to the gas in the process C  D is 600 R n2
(C) Net workdone by the gas in the cycle is +ve

(D) The workdone in the process BC is W 1 and in the process DA is W 2 then W 1 < W 2
27. When a capillary tube is dipped in a liquid, the liquid rises to a height h in the tube. The free liquid
surface inside the tube is hemispherical in shape. The tube is now pushed down so that the height
of the tube outside the liquid is less than h. choose the correct option(s)
(A) The liquid will come out of the tube like in a small fountain.
(B) The liquid will come out of the tube slowly.
(C) The liquid will fill the tube but not come out of its upper end.
(D) The free liquid surface inside the tube will not be hemispherical.
P202JPMT3070118C0-10
PHYSICS
28. Two coherent point sound sources S1 and S2 are placed as shown in the figure. Both are emitting
PHYSICS
sound of frequency 165 Hz. S1 is ahead of S2 in phase by -radian. (Speed of sound is 330 m/s)
(A) Total number of maxima on the line AB is 6.
(B) If power of sources are same and equal to 7200  watt. Resultant intensity at point B is
( 50  18 )2 watt/m .
2
(C) Total number of maxima on the line BC is 2.
(D) Initial path difference between the waves produced by S1 and S2 is 1 meter
P202JPMT3070118C0-11
PHYSICS
PHYSICS
Many species of (animals mostly insects and spiders) are capable of walking on the surface of
water. Compared to the displacement required to float only a very small part of the water walking
animal’s body is below the ambient water surface level. The animal’s weight is mostly carried by
surface tension while buoyancy is negligible.
The water is deformed by animal’s weight and makes contact with its feet along a combined
perimeter length L (Total length in contact with surface). Here we define a parameter ‘Bond
number’ B0. Bond number is the ratio of weight and surface tension force. If B0 is less than 1 then
the animal floats, if it is more than 1 then it drowns.
29. An insect with mass 10 mg and total length of the contact perimeter 1.3 mm can just walk on the
liquid surface. The surface tension of liquid is :
(A) 0.058 N/m (B) 0.026 N/m (C) 0.076 N/m (D) 0.112 N/m
30. Mass of insect A is 15 mg and total contact perimeter is 2.5 mm. Mass of insect B is 6 mg and total
contact perimeter is 0.6 mm. The surface tension of a liquid is 7.5 × 10–2 N/m. Both insect are on
surface of the liquid. Choose the correct option.
(A) insect A will float and insect B will drown (B) insect B will float and insect A will drown
(C) insect A and B both will drown (D) insect A and B both will float
P202JPMT3070118C0-12
PHYSICS
PHYSICS
One mole of an ideal monatomic gas undergoes a linear process from A to B, in which its pressure
P and its volume V change as shown in figure
31. The absolute temperature T versus volume V for the given process can be represented by :
(A) (B) (C) (D)
32. Choose the correct option(s) :

P0 V0
(A) The maximum temperature of the gas during this process is
4 R
3P0 V0
(B) The maximum temperature of the gas during this process is
4R
(C) As the volume of the gas is increased, then the volume after which if the volume of gas is
V
further increased the given process switches from endothermic to exothermic is 0
8
(D) As the volume of the gas is increased, then the volume after which if the volume of gas is
3V0
further increased the given process switches from endothermic to exothermic is
8
P202JPMT3070118C0-13
PHYSICS
PHYSICS
A block of mass m is attached to an unstretched ideal spring of force constant k and held at rest.
m
A bullet of mass m/2 is vertically fired to it with speed u = 4 3 g as shown. The moment bullet
k
strikes the block it is released and it is seen that bullet comes out of the lock at speed u/2. Due to
this block starts oscillating.
33. The amplitude of oscillation of block is :

mg mg 3mg 2mg
(A) (B) (C) (D)
2k k 2k k
34. The maximum speed of block during oscillation is :

g k k 3g k k
(A) (B) g (C) (D) 2 g
2 m m 2 m m
P202JPMT3070118C0-14
PHYSICS
PHYSICS
35. A straight line source of sound of length L = 10m, emitts a pulse of sound that travels radially
outward from the source. What is the power (in mW) intercepted by an acoustic cylindrical detector
2
of surface area 1.2 cm , located at a perpendicular distance 7m from the source. The waves reach
perpendicularly at the surface of the detector. The total power emitted by the source in the form
of sound is 2.2 × 10 W. (Use  = 22/7)
4
36. Subsonic aircraft flying in circular path of radius R in vertical plane with constant speed V. Speed
of sound in medium is Vw. (assume the medium to be at rest.) Detector which can detect position
of plane as well as frequency of sound emitted by plane lie below the centre of circular path at
distance 2R from the centre. Whenever detector detects maximum frequency, its also detects that
V 11
plane is nearest to detector. In this condition  . Here  is an integer. Find .
VW (11 – 1) 3
P202JPMT3070118C0-15
PHYSICS
37. An object of mass 'M' kg hangs in equilibrium from a string with a total length of L = 16 m and
PHYSICS
linear density of  = 0.01 kg/m, as shown in figure. The string is wrapped around two light small
frictionless pulleys that are separated by distance d = 6 m. When the string between the pulleys
vibrates to form the standing wave pattern with three loops on it, the frequency of vibration is
2
25 Hz. Find the value of M/2. (Take g = 10 m/s )
d=6m
5m 5m
M kg
38. A uniform solid hemisphere of mass m and radius R is attached to the roof with a chord of torsional
constant C and performing torsional SHM. Then the time period (in seconds) of SHM is
2
(Take m = 15 kg, R = m, C = 6 Nm/rad.)


P202JPMT3070118C0-16
PHYSICS
39. Two ideal monoatomic and diatomic gases are mixed with one another to form an ideal gas
PHYSICS
11
mixture. The equation of the adiabatic process of the mixture is PV = constant, where  = .
7
If n1 and n2 are the number of moles of the mono atomic and diatomic gases in the mixture
n1
respectively, find the ratio .
n2
40. Some water at 0ºC is placed in a large insulated vessel. The water vapour formed is pumped out
7
continuously. The fraction of water that will ultimately freeze is . If the latent heat of vaporization
8
is ‘x’ times the latent heat of fusion. Find out value of ‘x’.
41. A non–viscous ideal fluid is flowing vertically downwards in a pipe. The area of cross-section at
section 'A' is double that at section 'B'. Vertical distance between section A and section B is h and
h
the height of water column in tube (2) is more than that in tube (1) by distance. Find the
2
velocity(m/s) of the fluid at section A if h = 2.7 m.
P202JPMT3070118C0-17
PHYSICS
42. In the figure shown AB, AC and PQ are thin, smooth, rigid wires. AB and AC are joined at A and
PHYSICS
fixed in vertical plane. BAC = 2 = 90°and line AD is angle bisector of angle BAC. A liquid of
surface tension T = 0.025 N/m forms a thin film in the triangle formed by intersection of the wires
AB, AC and PQ. In the figure shown the uniform wire PQ of mass 1 gm is horizontal and in
equilibrium under the action of surface tension and gravitational force. Find the time period of SHM

of PQ in vertical plane for small displacement from its mean position, in the form s and fill value
X
of X.
43. A uniform disc of radius R = 2m lies in the x-y plane, with its centre at origin. its moment of inertia
about z-axis is equal to its moment of inertia about line y = x + c. If the value of c (in meters) is
n
± . Find the value of 'n'.
2
44. Two identical particles of same mass, having velocities opposite to each other, equal in magnitude,
collide head on. During collision 50% of kinetic energy is lost. If Coefficient of restitution is
n
(where n and m are integers) find the value of 'm + n'.
m
P202JPMT3070118C0-18
PHYSICS
2
45. A wire frame is in the shape of a parabola y = 5x . It is being rotated about y-axis with an angular
PHYSICS
velocity . A small bead of mass (m = 1 kg) is at point P and is in equilibrium with respect to the

. (g = 10 m/s ) where  is in rad/sec.
2
frame. Find the value of
2
Y

P(1, 5)
X
46. A particle is moved along the different paths OAC, OBC & ODC as shown in the fig. Path ODC is a

parabola, y = 4 x2. If the work done by a force F = x y ˆi  x 2 y ˆj on the particle along the path
OAC and path OBC are "m" and "n" respectively , then the value of m/n is:
y
B C (1,4)
O x
A
P202JPMT3070118C0-19
PHYSICS
47. A balloon is ascending at the constant rate of 9.8 m/sec at a height of 98 m above the ground a
PHYSICS
packet is dropped. If time taken by the packet to reach the ground is 1  3 sec. Find .  
2
(Use g = 9.8 m/s )
48. A block of mass 2 kg is given a push for a moment horizontally and then the block starts sliding
over a horizontal plane. The graph shows the velocity-time graph of the motion. The co-efficient of
sliding friction between the plane and the block is µ , then the value of 10µ is:
P202JPMT3070118C0-20
CHEMISTRY
PART III : CHEMISTRY
CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

darkened.
P202JPMT3070118C0-21
Toll Free : 1800 258 5555 |CIN: U80302RJ2007PLC024029
CHEMISTRY
49. The van der Waal's equation for a real gas may be rearranged to give :
 RT  2 a ab
Vm3   b  Vm + Vm  0
CHEMISTRY

 P  p p
Where Vm is molar volume of the gas. Select the correct statement (s) amongs the following.
(A) At temperature greater than Tc, there are three values of Vm , one real and two imaginary.
(B) At temperature Tc, the three real values of Vm are identical.
(C) At temperature less than Tc there are three real values of Vm.
(D) At any temperature there are three value of Vm, one real and two imaginary.
50. For chromium element, how many electrons can have n +  + | m | =4, with clockwise spin in ground
state?
(A) 2 (B) 3 (C) 4 (D) 6
51. Which of the following pair of structures is/are a pair of resonating structures ?
+ – +
(A) H – C NH ; H – C = NH (B) CH2 = C O ; CH2 – C  O
  
(C) CH2  C  C  CH2 ; CH2  C  C  CH2 (D) CH2  CH  NH3 ; CH2  CH  NH3
52. In which of the following reaction(s), the mention product is/are correct :
(A) CH3  CH2  Cl  KNO 2  CH3  CH2  O  N  O  KCl
(B) CH3  CH2  Cl  AgNO 2  CH3  CH2  NO 2  AgCl
(C) CH3 – CH – CH3 + aq. KOH CH3 – CH = CH2 + KCl
Cl
Br
dry acetone
(D) + Na
P202JPMT3070118C0-22
CHEMISTRY
CHEMISTRY


  Acidic strength means the tendency of an acid to give H3O+ or H+ ions in water.
 So greater the tendency to give H+, more will be the acidic strength of the substance.
  Basic strength means the tendency of a base to give OH– ions in water.
So greater the tendency to give OH– ions, more will be basic strength of the substance.
 The concentration of H+ ions is written in a simplified form introduced by Sorenson known
1
as pH scale. pH = – log [H+] or pH = log pH = – log [H3O+]
[H ]
P202JPMT3070118C0-23
CHEMISTRY
53. A 100 mL solution of oxalic acid requires 200 mL of NaOH for complete neutralisation. Find the pH
when 120 mL of NaOH is added. (Given k a1  104 and k a2  10 7 ) (log2 = 0.30)
CHEMISTRY
(A) 4.4 (B) 5.4 (C) 6.4 (D) None of these
54. pH of which of the following solution is affected by dilution ?
(A) 0.01 M NaHC2O4
(B) buffer of 0.01 M CH3COONa and 0.01 M CH3COOH
(C) 0.01 M CH3COONa
(D) 0.01 M CH3COONH4
An ideal gas whose adiabatic exponent is equal to , is expanded reversibly according to the law
P = aV, where a is a constant. The initial volume of the gas is equal to V0. As a result of expansion,
the volume increases 4 times.
P202JPMT3070118C0-24
CHEMISTRY
55. What is the magnitude of work performed by the gas ?
CHEMISTRY
15aV02 aV02 15aV02
(A) (B) (C) (D) None of these
 1  1 2
56. What is the molar heat capacity of the gas in the process ?
R(   1) aV02 R(   1)
(A) (B) (C) (D) None of these
2(   1)  1 2(   1)
H2/Ni O3 + Zn
x y Acetaldehyde
H2O and butanone
57. How many positional alkenes of y (including its structure) are possible?
(A) 5 (B) 2 (C) 3 (D) 4
58. How many structural monochloro products of x are possible?
(A) 2 (B) 3 (C) 4 (D) 5
P202JPMT3070118C0-25
CHEMISTRY
CHEMISTRY
59. The maximum number of emission lines for atomic hydrogen you would expect to see with naked
eyes if only electronic levels involved are those shown in figure is :
n=7
n=6
n=5
n=4
n=3
n=2
n=1
P202JPMT3070118C0-26
CHEMISTRY
60. A solution of specific gravity 1.6 contains 67.5 % solute by weight. What will be the % by weight of
CHEMISTRY
solute in the resulting solution if the original solution is diluted to density 1200 Kg/m3 ? Assume
volume conservation to be valid. Give your answer after dividing by 10.
61. Boric acid B(OH)3 is used as a mild antiseptic. What is the pH of a 0.0025 M aqueous solution of
boric acid ? The hydrogen ion arises principally from the reaction (log2 = 0.30, log 5 = 0.70) :
– + –10
B(OH)3 (aq) + H2O() B(OH)4 (aq) + H (aq), K = 4.0 × 10 .
62. If 48 g Mg is dissolved in excess of concentrated H2SO4 in an open beaker. Temperature of
reaction
is 27ºC at atmospheric pressure. Calculate magnitude of work done (in KJ) by evolution of H2 gas
25
(R = J/K mol).
3
63. An electron beam can undergo diffraction by crystal. Through what potential (in volt) should a
beam of electron be accelerated so that its de Broglie wavelength becomes equal to 500 pm.
P202JPMT3070118C0-27
CHEMISTRY
64. At 25ºC 560 g of deuterium oxide D2O(d = 1.1 g/mL) and 504 g of H2O (d = 0.997 g/mL) are mixed.
The volumes are additive. Fifty percent of H2O reacts to form HDO at equilibrium. The value of Kc
CHEMISTRY
at 25ºC for the reaction H2O() + D2O() 2HDO() is :
65. How many of the following statement(s) is/are correct according to IUPAC conventions?
1. Standard molar entropy of elements is taken zero.
2. Standard enthalpy of formation of substance is always negative.
3. Standard enthalpy of Neutralisation of acid and base is always negative.
4. Standard enthalpy of ionisation of weak electrolyte is always positive.
5. Standard electron gain enthalpy is always negative.
6. Enthalpy of combustion of Al (s) is equal to enthalpy of formation of Al2O3(s).
7. Enthalpy of combustion of graphite is equal to enthalpy of formation of gaseous CO2.
+2 –
66. How many following compounds can give positive Fehling's test (Cu /OH ).
(1) CH3 – C – H (2) Ph – C – CH3 (3) Ph – C – H (4) H – C – O – H

O O O O
COOH
O
(5) CH3 – CH2 – OH (6) H– C – – NH2 (7) CH3 – C  CH (8)
P202JPMT3070118C0-28
CHEMISTRY
NH2
+
CHEMISTRY
N
67.
N
N O +
O
H
(4) (5)
(1) (2) (3)
O H O
N
+
N B
O
H H H
(6) (7) (8) (9)
X = number of compounds which are aromatic.
Y = number of compounds which are non aromatic.
Z = number of compounds which are anti aromatic.
Report your answer is |X + Z – Y| = ?
P202JPMT3070118C0-29
CHEMISTRY
68. Identify number of reaction(s) that can give phenol as major product ?
Cl
CHEMISTRY
OH
1. NaOH
COONa Sodalime
2. HCl
(a) (b) high temp
 pressure
+ –
SO3H NN Cl
1. NaOH/ Heat
(c) 2. H+ (d) H2O
+ –
NN Cl NH2
H3PO2 CHCl3 + KOH

(e) (f) 
H3C CH3
CH NO2
1. O2 / hv Sn / HCl
(g) 2. H3O+ (h)
P202JPMT3070118C0-30
CHEMISTRY
69. How many of the following compounds do not contain unpaired electrons.
CHEMISTRY
KO2, NO2, SO2, BaO2, ClO2, O2, NO, N2O, O3, CO.
70. How many of following can give a brown colored gas on heating.
NaNO3, KNO3 , LiNO3, Mg(NO3)2 , Ca(NO3)3, CsNO3, RbNO3, Sr(NO3)2, CaCO3, Na2CO3
71. Sum of number of P-P bonds in SO2, CO2 and P4O10 are :
72. Trimolite is an amphibole silicate having formula. Ca2Mgn(Si4O11)2(OH)2. What is the value of n?
P202JPMT3070118C0-31
P21-17 PAPER-2
MAJOR TEST-3 (MT-3) (JEE ADVANCED PATTERN)
DATE : 07-01-2018 | COURSE : VIJETA (02JP) C OD E - 0
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %
1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the back cover of
this booklet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the question.
4. Blank spaces are provided within this booklet for rough work.
5. Write your Name and Roll Number in the space provided on the below cover.
DO NOT BREAK THE SEALS WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

6. After the open booklet, verify that the booklet contains all the 72 questions along with the options are legible.
QUESTION PAPER FORMAT AND MARKING SCHEME :

7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has three sections.
8. Each section as detailed in the following table :
Category-wise Marks for Each Question Maximum

Number of
Section Question Type Marks of the
Questions Negative
Full Marks Partial Marks Zero Marks Section
Marks
+4 +1
0
If only the bubble(s) For darkening a bubble –2
One or More If none of
1 4 corresponding to all corresponding to each correct In all other 16
Correct Option(s) the bubbles
the correct option(s) option, provided NO incorrect cases
is darkened
is(are) darkened option is darkened
+4
0
Comprehension If only the bubble –2
If none of
2 (Single Correct 6 corresponding to the – In all other 24
the bubbles
Option) correct option is cases
is darkened
darkened
+4
If only the bubbles 0
Single digit Integer
3 14 corresponding to the – if not – 40
(0-9)
correct answer is attempted
darkened
For Section-3 : There are 14 Questions & you have attempt any 10 Questions. If a student attempts more than
10 questions, then only first 10 questions which he has attempted will be checked.
OPTICAL RESPONSE SHEET :
9. Darken the appropriate bubbles on the original by applying sufficient pressure.
10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.
11. Do not tamper with or mutilate the ORS.
12. Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this purpose on
the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each digit of your roll
number.
DARKENING THE BUBBLES ON THE ORS :
13. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
14. Darken the bubble COMPLETELY.
15. Darken the bubble ONLY if you are sure of the answer.
16. The correct way of darkening a bubble is as shown here :
17. There is NO way to erase or "un-darkened bubble.
18. The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles are
evaluated.
NAME OF THE CANDIDATE : ………………………………………………………………..………………………

ROLL NO. : ………………………..………………………
I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.
------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator
Resonance Eduventures Ltd.

CORPORATE OFFICE : CG Tower, A-46 & 52, IPIA, Near City Mall, Jhalawar Road, Kota (Raj.) - 324005
Ph.No. : +91-744-3012222, 6635555 | Toll Free : 1800 258 5555
Reg. Office : J-2, Jawahar Nagar, Main Road, Kota (Raj.) 324005 | Ph. No.: +91-744-3192222 | FAX No. : +91-022-39167222
Website : www.resonance.ac.in | E-mail : contact@resonance.ac.in | CIN: U80302RJ2007PLC024029

JP MT3 P2

Diunggah oleh

Informasi Dokumen

Hak Cipta

Format Tersedia

Bagikan dokumen Ini

Bagikan atau Tanam Dokumen

Opsi Berbagi

Apakah menurut Anda dokumen ini bermanfaat?

Apakah konten ini tidak pantas?

Hak Cipta:

Format Tersedia

JP MT3 P2

Diunggah oleh

Hak Cipta:

Format Tersedia

®

MAJOR TEST-3 (MT-3)

DO NOT BREAK THE SEAL WITHOUT BEING INSTRUCTED TO DO SO BY THE INVIGILATOR

COURSE : VIJETA (02JP)

(A) f(6) = 3r (B) f(4) = ( 2  1) r

4. If P is a point on hyperbola, then

Space for Rough Work

SECTION – 2 : (Maximum Marks : 24)

Paragraph for Question Nos. 5 to 6

5. The length of side EF is

Space for Rough Work

Paragraph for Question Nos. 9 to 10

9. The angle between the tangents at A and C is

10. The locus of the point of intersection of tangents at A and C is

Space for Rough Work

SECTION – 3 : (Maximum Marks : 40)

Assume that A = {(x, y) : 3x + 4y = 12} and B = {(x, y) : y = mx + c}. If A  B   for all m  R,

Space for Rough Work

17. Let x 2  y 2  xy  1  a( x  y )  x, y  R , then the number of possible integer(s) in the range

Space for Rough Work

p! then number of solution of |x| + |x + 1| + |x – 1| = E – 15 is

Space for Rough Work

The number of positive integers satisfying x  log10 (2  1)  x log10 5  log10 6 is?

3 (where  is the area of triangle) is?

Space for Rough Work

 This section contains FOUR questions

Space for Rough Work

Space for Rough Work

(A) The workdone in the process BC is W 1 and in the process DA is W 2 then W 1 = W 2

(B) Heat supplied to the gas in the process C  D is 600 R n2

(C) Net workdone by the gas in the cycle is +ve

Space for Rough Work

(A) Total number of maxima on the line AB is 6.

(C) Total number of maxima on the line BC is 2.

Space for Rough Work

Space for Rough Work

SECTION – 2 : (Maximum Marks : 24)

Paragraph for Question Nos. 29 to 30

Space for Rough Work

(A) (B) (C) (D)

32. Choose the correct option(s) :

Space for Rough Work

33. The amplitude of oscillation of block is :

34. The maximum speed of block during oscillation is :

Space for Rough Work

SECTION – 3 : (Maximum Marks : 40)

Space for Rough Work

Space for Rough Work

Space for Rough Work

Space for Rough Work

Space for Rough Work

Space for Rough Work

Space for Rough Work

Space for Rough Work

Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION – 1 : (Maximum Marks : 16)

 This section contains FOUR questions

Space for Rough Work

Space for Rough Work

SECTION – 2 : (Maximum Marks : 24)

Paragraph for Question Nos. 53 to 54

 The concentration of H+ ions is written in a simplified form introduced by Sorenson known

Space for Rough Work

when 120 mL of NaOH is added. (Given k a1  104 and k a2  10 7 ) (log2 = 0.30)