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NASA-GLENN CHEMICAL EQUILIBRIUM PROGRAM CEA2, MAY 21, 2004

BY BONNIE MCBRIDE AND SANFORD GORDON
REFS: NASA RP-1311, PART I, 1994 AND NASA RP-1311, PART II, 1996

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problem case=assignmnet
tp t,c=300,350,400,450,500,550,600,650,700,750,800,850,900, p,bar=1.5,
react
fuel=CH4 moles=10
oxid=O2 moles=4.5
oxid=H2O moles=60
name=N2 moles=25.5
only
CH4 CO CO2 O2 H2 N2 H2O
end

OPTIONS: TP=T HP=F SP=F TV=F UV=F SV=F DETN=F SHOCK=F REFL=F INCD=F
RKT=F FROZ=F EQL=F IONS=F SIUNIT=T DEBUGF=F SHKDBG=F DETDBG=F TRNSPT=F

T,K = 573.1500 623.1500 673.1500 723.1500 773.1500 823.1500 873.1500

T,K = 923.1500 973.1500 1023.1500 1073.1500 1123.1500 1173.1500

TRACE= 0.00E+00 S/R= 0.000000E+00 H/R= 0.000000E+00 U/R= 0.000000E+00

P,BAR = 1.500000

REACTANT MOLES (ENERGY/R),K TEMP,K DENSITY

EXPLODED FORMULA
F: CH4 10.000000 0.000000E+00 0.00 0.0000
C 1.00000 H 4.00000
O: O2 4.500000 0.000000E+00 0.00 0.0000
O 2.00000
O: H2O 60.000000 0.000000E+00 0.00 0.0000
H 2.00000 O 1.00000
N: N2 25.500000 0.000000E+00 0.00 0.0000
N 2.00000

SPECIES BEING CONSIDERED IN THIS SYSTEM

(CONDENSED PHASE MAY HAVE NAME LISTED SEVERAL TIMES)
LAST thermo.inp UPDATE: 9/09/04

g 8/99 CH4 tpis79 *CO g 9/99 *CO2

tpis78 *H2 g 8/89 H2O tpis78 *N2
tpis89 *O2

O/F = 1.400273

EFFECTIVE FUEL EFFECTIVE OXIDANT MIXTURE

ENTHALPY h(2)/R h(1)/R h0/R
(KG-MOL)(K)/KG 0.00000000E+00 0.00000000E+00 0.00000000E+00

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KG-FORM.WT./KG bi(2) bi(1) b0i

C 0.11431625E-01 0.00000000E+00 0.47626357E-02
H 0.45726499E-01 0.97966269E-01 0.76202171E-01
O 0.00000000E+00 0.56330605E-01 0.32862186E-01
N 0.58301286E-01 0.00000000E+00 0.24289442E-01

POINT ITN T C H O N

1 11 573.150 -2.459 -9.680 -54.885 -12.317

2 4 623.150 -2.557 -9.430 -51.529 -12.399

3 4 673.150 -2.655 -9.249 -48.655 -12.483

4 4 723.150 -2.804 -9.128 -46.158 -12.570

5 4 773.150 -3.076 -9.061 -43.940 -12.656

6 4 823.150 -3.569 -9.049 -41.907 -12.738

7 4 873.150 -4.307 -9.086 -39.999 -12.812

8 4 923.150 -5.146 -9.149 -38.235 -12.882

THERMODYNAMIC EQUILIBRIUM PROPERTIES AT ASSIGNED

TEMPERATURE AND PRESSURE

CASE = assignmnet

REACTANT MOLES ENERGY TEMP

KJ/KG-MOL K
FUEL CH4 10.0000000 0.000 0.000
OXIDANT O2 4.5000000 0.000 0.000
OXIDANT H2O 60.0000000 0.000 0.000
NAME N2 25.5000000 0.000 0.000

O/F= 1.40027 %FUEL= 41.661932 R,EQ.RATIO= 1.449275 PHI,EQ.RATIO= 4.444444

THERMODYNAMIC PROPERTIES

P, BAR 1.5000 1.5000 1.5000 1.5000 1.5000 1.5000 1.5000 1.5000

T, K 573.15 623.15 673.15 723.15 773.15 823.15 873.15 923.15
RHO, KG/CU M 6.5030-1 5.8920-1 5.3391-1 4.8401-1 4.4028-1 4.0447-1 3.7720-1 3.5563-1
H, KJ/KG -7609.60 -7456.50 -7269.93 -7052.02 -6816.99 -6600.15 -6436.65 -6312.19
U, KJ/KG -7840.27 -7711.08 -7550.88 -7361.93 -7157.69 -6971.01 -6834.32 -6733.97
G, KJ/KG -13591.8 -14120.0 -14661.7 -15218.5 -15791.0 -16378.5 -16977.6 -17584.8
S, KJ/(KG)(K) 10.4375 10.6932 10.9808 11.2929 11.6071 11.8791 12.0723 12.2110

M, (1/n) 20.660 20.352 19.921 19.401 18.868 18.455 18.256 18.198

(dLV/dLP)t -1.00730 -1.01307 -1.01999 -1.02612 -1.02742 -1.01912 -1.00736 -1.00199
(dLV/dLT)p 1.1361 1.2274 1.3270 1.4057 1.4086 1.2750 1.1021 1.0266

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Cp, KJ/(KG)(K) 2.7481 3.3910 4.0663 4.6070 4.6736 3.8509 2.7644 2.3101
GAMMAs 1.2221 1.2025 1.1915 1.1872 1.1900 1.2064 1.2388 1.2602
SON VEL,M/SEC 530.9 553.3 578.6 606.6 636.7 668.9 701.9 729.1

MOLE FRACTIONS

CH4 0.06823 0.05976 0.04792 0.03361 0.01896 0.00758 0.00211 0.00052

*CO 0.00004 0.00018 0.00069 0.00213 0.00525 0.00993 0.01461 0.01852
*CO2 0.03013 0.03699 0.04627 0.05666 0.06566 0.07038 0.07022 0.06763
*H2 0.03207 0.06127 0.10174 0.14986 0.19749 0.23221 0.24647 0.24809
H2O 0.61863 0.59464 0.56144 0.52212 0.48349 0.45577 0.44487 0.44423
*N2 0.25091 0.24717 0.24194 0.23562 0.22915 0.22413 0.22171 0.22101

* THERMODYNAMIC PROPERTIES FITTED TO 20000.K

PRODUCTS WHICH WERE CONSIDERED BUT WHOSE MOLE FRACTIONS

WERE LESS THAN 5.000000E-06 FOR ALL ASSIGNED CONDITIONS

*O2

POINT ITN T C H O N

1 3 973.150 -5.967 -9.217 -36.633 -12.948

2 3 1023.150 -6.738 -9.285 -35.186 -13.013

3 3 1073.150 -7.455 -9.352 -33.874 -13.076

4 3 1123.150 -8.123 -9.417 -32.681 -13.138

5 3 1173.150 -8.746 -9.481 -31.592 -13.198

THERMODYNAMIC EQUILIBRIUM PROPERTIES AT ASSIGNED

TEMPERATURE AND PRESSURE

CASE = assignmnet

REACTANT MOLES ENERGY TEMP

KJ/KG-MOL K
FUEL CH4 10.0000000 0.000 0.000
OXIDANT O2 4.5000000 0.000 0.000
OXIDANT H2O 60.0000000 0.000 0.000
NAME N2 25.5000000 0.000 0.000

O/F= 1.40027 %FUEL= 41.661932 R,EQ.RATIO= 1.449275 PHI,EQ.RATIO= 4.444444

THERMODYNAMIC PROPERTIES

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P, BAR 1.5000 1.5000 1.5000 1.5000 1.5000

T, K 973.15 1023.15 1073.15 1123.15 1173.15
RHO, KG/CU M 3.3710-1 3.2057-1 3.0562-1 2.9201-1 2.7956-1
H, KJ/KG -6199.95 -6090.07 -5980.23 -5869.91 -5758.98
U, KJ/KG -6644.92 -6558.00 -6471.05 -6383.60 -6295.54
G, KJ/KG -18198.4 -18817.6 -19442.2 -20072.0 -20706.6
S, KJ/(KG)(K) 12.3295 12.4396 12.5444 12.6449 12.7415

M, (1/n) 18.184 18.180 18.179 18.179 18.179

(dLV/dLP)t -1.00052 -1.00015 -1.00005 -1.00002 -1.00001
(dLV/dLT)p 1.0068 1.0019 1.0006 1.0002 1.0001
Cp, KJ/(KG)(K) 2.2071 2.1941 2.2009 2.2124 2.2249
GAMMAs 1.2649 1.2643 1.2626 1.2607 1.2588
SON VEL,M/SEC 750.2 769.2 787.2 804.7 821.8

MOLE FRACTIONS

CH4 0.00013 0.00004 0.00001 0.00000 0.00000

*CO 0.02203 0.02534 0.02847 0.03140 0.03414
*CO2 0.06444 0.06121 0.05810 0.05517 0.05244
*H2 0.24591 0.24293 0.23989 0.23698 0.23425
H2O 0.44665 0.44969 0.45274 0.45566 0.45839
*N2 0.22084 0.22080 0.22078 0.22078 0.22078

* THERMODYNAMIC PROPERTIES FITTED TO 20000.K

PRODUCTS WHICH WERE CONSIDERED BUT WHOSE MOLE FRACTIONS

WERE LESS THAN 5.000000E-06 FOR ALL ASSIGNED CONDITIONS

*O2