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QUANTUM MECHANICS SOLUTIONS
GATE- 2010
Q1. Which of the following is an allowed wavefunction for a particle in a bound state? N is
a constant and α, β > 0.
e r
(a) N (b) N 1 e r
r3
(c) Ne x e x (d) 0non - zero constant if r R
2
y2 z2
if r R
Ans: (c)
Q2. A particle of mass m is confined in the potential
1
V x 2 m x
2 2
for x 0
for x 0
Let the wavefunction of the particle be given by
1 2
x 0 1 ,
5 5
where 0 and 1 are the eigenfunctions of the ground state and the first excited state
(a)
2 s s 1 m 2
(b) 2 s s 1 2m 2
2
(c) s s 1 m 2
2
(d) 2 m 2
Ans: (a)
1 1
sm S S sm sm S 2 S 2 S S S S sm
2
Solution: sm S z2 sm
2 2
1
sm S S S S sm
2
2
2
s s 1 m 2
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Q4. A particle of mass m is confined in an infinite potential well:
V x 0 if 0 x L,
otherwise.
2x
It is subjected to a perturbing potential V p x Vo sin
L V x
within the well. Let E(a) and E(2) be corrections to the ground
state energy in the first and second order in V0, respectively. V p x
0 L
Which of the following are true?
(a) E(a) = 0; E(2) < 0 (b) E(a) >
0; E(2) = 0
(c) E(a) = 0; E(2) depends on the sign of V0 (d) E(a) < 0; E(2) < 0
Ans: (a)
2
2
L
2x m VP 1
Solution: E V0 sin
1
1 dx 0 ; E12 E1 E m so E12 ve .
L0 L m 1 E1 Em
GATE- 2011
Q5. The quantum mechanical operator for the momentum of a particle moving in one
dimension is given by
d d 2 d 2
(a) i (b) i (c) i (d)
dx dx t 2m dx 2
Ans: (b)
Q6. An electron with energy E is incident from left on a potential barrier, given by
V ( x) = 0 for x < 0 V x
= V0 for x > 0
V0
as shown in the figure. For E < V0, the space part of the
E
wavefunction for x > 0 is of the form
(a) eax (b) e-ax (c) eiax x
0
(d)e-iax
Ans: (b)
Solution: E V0 , so there is decaying wave function.
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Q7. If Lx, Ly and Lz are respectively the x, y and z components of angular momentum operator
L. The commutator [Lx Ly, Lz] is equal to
(a) i L2x L2y (b) 2iLz (c) i L2x L2y (d) 0
Ans: (c)
Solution: Lx L y , Lz = Lx Ly Lz Lx , Lz Ly = iL2x L2y
1
from the nucleus, located at the origin. The expectation value is
r2
8 4 4 2
(a) (b) (c) (d)
a2 a2 a2 a2
Ans: (d)
2
1 1 1 2 2ar 2
3 2
Solution: r e dr sin d d 2
r2 4a 0 r 0 0
a
V x 0 if 0 x a
otherwise
2 nx
are given by n x sin , where n = 1, 2, 3,….
a a
The particle is subjected to a perturbation
x a
V ' x Vo cos for 0 x
a 2
=0 otherwise
Q10. The shift in the ground state energy due to the perturbation, in the first order perturbation
theory,
2Vo Vo Vo 2Vo
(a) (b) (c) (d)
3 3 3 3
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Ans: (a)
a/2
3 x
sin
x x
a/2 a/2
2 2 2V0
Solution: E11 1 V x 1dx V0 a
*
sin 2 V0 cos dx
a a a a 3
0 0 3
a 0
Q13. For the value of α determined in Q30, the expectation value of energy of the oscillator in
the state ψ2 is
(a) ħω (b) 3 ħω/2 (c) 3 ħω (d) 9 ħω/2
Ans: (b)
3 5
2 H 2
Solution: 2 0 1 2 put 1 , H 2 2 2 3
2 2 3 2
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GATE- 2012
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Q16. A particle is constrained to move in a truncated harmonic potential well (x > 0) as shown
in the figure. Which one of the following statements is CORRECT?
(a) The parity of the first excited state is even
(b) The parity of the ground state is even Vx
1
(c) the ground state energy is
2
7
(d) The first excited state energy is
2
Ans: (d) x
3 7
Solution: There is only odd parity. Ground state is and first excited
2 2
Q17. Consider a system in the unperturbed state described by the Hamiltonian, H0 1 0 .
0 1
2 0 1 0 2 0
H one will get H , H .
0 0 0 1 0 0
So E 1 2 and 1 0 .
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Q18. The ground state wavefunction for the hydrogen atom is given by
3/ 2
1 1
100 e r / a0 , where a 0 is the Bohr radius. The plot of the radial probability
4 a 0
density, P(r) for the hydrogen atom in the ground state is
(a) (b)
P(r) P(r)
r/a 0 r/a 0
(c) (d)
P(r) P(r)
r/a 0 r/a 0
Ans: (d)
3/ 2
1 1
Solution: The ground state is given by 100 e r / a0
4 a0
Radial probability function
Pr
1 1 2 2 r / a0
Pr r =
2 2
r e
4 a0 r / a0
Common Data for Questions 19–20
The wavefunction of particle moving in free space is given by, e ikx 2e ikx
Q19. The energy of the particle is
5 2 k 2 3 2 k 2 2k 2 2k 2
(a) (b) (c) (d)
2m 4m 2m m
Ans: (c)
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2 2 2
Solution: H E , H ik ik e ikx 2 ik ik e ikx
2m x 2
2m
2 k 2 ikx 2 k 2
H (e 2e 2ikx )
2m 2m
Q20. The probability current density for the real part of the wavefunction is
k k
(a) 1 (b) (c) (d) 0
m 2m
Ans: (d)
Solution: The real part of the wave function real cos kx 2 cos kx
Current density for real part of wave function = 0
GATE- 2013
Q21. Which one of the following commutation relations is NOT CORRECT? Here, symbols
have their usual meanings.
(a) L2 , L z 0
(b) L x , L y iL z
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Q23. A spin-half particle is in a linear superposition 0.8 0.6 of its spin-up and spin-
down states. If and are the eigenstates if z then what is the expectation value
up to one decimal place, of the operator 10 z 5 x ? Here, symbols have their usual
meanings. _______________
Ans: 76
1 0 .8
Solution: .8 .6 .8 .6
0 1 .6
1 0 0 1 10 5
Operator A 10 z 5 x 10 5 A
0 1 1 0 5 10
10 5 .8
A A .8 .6 = 88 12 76
5 10 .6
Q24. Consider the wave function Ae i k r r0 / r , where A is the normalization constant.
For r 2r0 , the magnitude of probability current density up to two decimal places, in
units of A 2 k / m is. _____________
Ans:
2 2
2 k 2 r k 2 r k 2 k
Solution: J A 0 J A 0 J A
m r m 2r0 m 4m
1 1 1
we add a small perturbation given by 1 1 1 where is small quantity.
1 1 1
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Q25. The ground state eigenvector of the unperturbed Hamiltonian is
(a) 1 / 2 ,1 2 ,0
(b) 1 / 2 ,1 / 2 ,0
(c) 0,0,1 (d) 1,0,0
Ans: (c)
5 2 0 1 1 1
H 0 2 5 0 , H P 1 1 1
0 0 2 1 1 1
Eigen value of H 0 is E1 2, E2 3, E3 7 and the Eigen vector corresponds
1 1 1 1 1
1 1 1
E2 2 H P 2 1 1 0. 1 1 1. 1 = 0 0 1 1 0
2 1 1 1 2 0 2 0
1 1 1 1 1
1 1 1
E3 3 H P 3 1 1 0 . 1 1 1 . 1 = . 2 2 0. 1
2 1 1 1 2 0 2 0
1
E 3 4 2
2
E1 2 1 , E 2 3 0 , E3 7 2 .
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GATE- 2014
Q27. The recoil momentum of an atom is p A when it emits an infrared photon of wavelength
1500 nm , and it is p B when it emits a photon of visible wavelength 500 nm . The ratio
pA
is
pB
potential which one of the following with x1 and x2 denoting the position of the two
electrons correctly represents the space part of the ground state wave function of the
system?
1 1
(a) 1 x1 2 x1 1 x2 2 x2 (b) 1 x1 2 x2 1 x2 2 x1
2 2
1 1
(c) 1 x1 2 x1 1 x2 2 x2 (d 1 x1 2 x 2 1 x 2 2 x1 )
2 2
Ans: (d)
Solution: From the given information only possible spin configuration is symmetric in nature so
space part will anti symmetric
1
1 x1 2 x 2 1 x 2 2 x1
2
Q29. If L is the orbital angular momentum and S is the spin angular momentum, then L.S
does not commute with
(a) S z (b) L2 (c) S 2
(d) L S 2
Ans: (d)
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Q30. An electron in the ground state of the hydrogen atom has the wave function
r
1
r e a0
a 03
z r cos is
n n 1! )
(Hint: 0
e ar r n dr
a n 1
a n 1
a 02 3a 02
(a) (b) a 02 (c) (d) 2a02
2 2
Ans: (d)
V x, y
1
2
m 2 x 2 y 2 , x , y
8 3 4
200 310 321
21 7 21
where n, l , m in nl m denote the principal. Orbit and magnetic quantum numbers,
respectively. If L is the angular momentum operator, the average value of L2 is
_______ 2
Ans: 2
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Solution: If L will measure on state the measurement is 0 2 , 2 2 and 6 2 with probability
2
8 3 4 3 4
, and so L2 2 2 6 2 = 2 2
21 7 21 7 21
1
Q33. 1and 2 are two orthogonal states of a spin system. It is given that
2
1 1 2 0
1 ,
3 0 3 1
1 0
where and represent the spin-up and spin-down states, respectively. When the
0 1
system is in the state 2 its probability to be in the spin-up state is _______
2
Ans:
3
1 1 2 0 2 1 1 0
Solution: If is 1 , then 2 ,
3 0 3 1 3 0 3 1
2
so probability that 2 is in up state is
3
Q34. A particle is confined to a one dimensional potential box, with the potential
V x 0, 0xa
, otherwise
If particle is subjected to a perturbation within the box. W x . Where is small
constant, the first order correction to the ground state energy is
(a) 0 (b) a / 4 (c) a / 2 (d) a
Ans: (c)
Solution: First order energy correction is W x the average value position in ground state
a
is x so ans is a / 2
2
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Q35. A one dimensional harmonic oscillator is in the superposition of number state n given
by
1 3
2 3
2 2
The average energy of the oscillator in the given state is______ .
Ans: 3.25
1 5 3 7
. .
Solution: Average energy will 4 2 4 2 3.25
1 3
4 4
Q36. If L and L are the angular momentum ladder operators then the expectation value of
Ans: 2
Solution: L L L L 2( L2 L2z ) 2(l.(l 1) m 2 ) 2 = 2 2
GATE- 2015
1
Q37. An operator for a spin particle is given by  B ,where
2
B
B xˆ yˆ , denotes Pauli matrices and is a constant. The eigenvalues of  are
2
B
(a) (b) B (c) 0, B (d) 0, B
2
Ans.: (b)
B
Solution: Aˆ , B xˆ yˆ
2
Aˆ x Bx y By z Bz Aˆ x Bx y By
0 1 B 0 i B ˆ B 0 1 i
Aˆ A
1 0 2 i 0 2 2 1 i 0
B 1 i
A I 0 0 B
2 1 i
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1
Q38. The Pauli matrices for three spin particles are 1 , 2 and 3 , respectively. The
2
dimension of the Hilbert space required to define an operator Oˆ 1 2 3 is_______
Ans.: 8
Solution: 2 3 has dimension of 4 and 1. 2 3 has dimension of 2 4 8
Q39. Let L and p be the angular and linear momentum operators, respectively, for a a particle.
The commutator L x , p y gives
(a) i pz (b) 0 (c) i px (d) i pz
Ans.: (d)
Solution: Lx , p y ypz zp y , p y ypz , p y zp y , p y y, p y pz
p y , p y 0 and z , p y 0
Lx , p y ipz y, p y i
3
Q40. Consider a system of eight non-interacting, identical quantum particles of spin in a
2
one dimensional box of length L . The minimum excitation energy of the system, in units
2 2
of is ________
2mL2
Ans.: 5
3 3
Solution: spin degeneracy 2S 1 2 1 4
2 2
22 4 2 2 20 2 2
Eground 4 4
2mL2 2mL2 2mL2
st 22 22 22 2 2
I
Eexcited 4 3 4 1 9 25
2mL2 2mL2 2mL2 2mL2
st 22 22 2 2
Now minimum excitation energy E Eexcited
I
Eground 25 20 5
2mL2 2mL2 2mL2
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Q41. A particle is confined in a box of length L as shown below.
V0
L/2
If the potential V0 is treated as a perturbation, including the first order correction, the
ground state energy is
2 2 2 2 V0
(a) E V0 (b) E
2mL2 2mL2 2
2 2 V0 2 2 V0
(c) E (d) E
2mL2 4 2mL2 2
Ans.: (d)
L
2
x L
x
Solution: E01 V0 sin 2 dx 0 sin 2 dx
0
L L L
2
L L
V0 2
2 x V0 2 x L 2
E01
2 0
1 cos
L
dx
2 x sin L 2 x
0
V0 2 2 V0
E01 E
2 2mL2 2
Q42. Let the Hamiltonian for two spin-½ particles of equal masses m , momenta p1 and p2
and positions r1 and r2 be H
1 2
2m
p1
1 2 1
2m
p 2 m 2 r12 r22 k 1 2 , where 1
2
and 2 denote the corresponding Pauli matrices, 0.1eV and k 0.2 eV . If the
ground state has net spin zero, then the energy (in eV ) is ___________
Ans.: -0.3
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1 2 1 2 1
Solution: H p1 p2 m 2 r12 r22 k 1. 2
2m 2m 2
2 2
1 2 12 22 2 1. 2 2 1. 2 12 22
2 1. 2 0 3I 3I 6 I 1. 2 3
3
Now energy E 2 k 3 3 0.1 0.2 3 0.3 eV
2
Q43. Suppose a linear harmonic oscillator of frequency and mass m is in the state
1 i
0 e 2
1 at t 0 where 0 and 1 are the ground and the first
2
excited states, respectively. The value of x in the units of at t 0 is _____
m
Ans. : 0
1
Solution: 0 e i 1
2 2
x
2m
a a x
2m
a a
1 i 2 1 i
a e 0 and a
0 2 e 2
2
2 2
1 1 i 2 1 1 i 2
x e e 1 1
2m 2 2
0 0
2 2
x 0 0
2m
GATE-2016
Q44. Which of the following operators is Hermitian?
d d2 d2 d3
(a) (b) (c) i (d)
dx dx 2 dx 2 dx 3
Ans.: (b)
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So value of n 2
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Q48. If s1 and s2 are the spin operators of the two electrons of a He atom, the value of
s1 .s 2 for the ground state is
3 3 1 2
(a) 2 (b) 2 (c) 0 (d)
2 4 4
Ans.: (b)
1 1 s s 1 2 s1 s1 1 2 s 2 s 2 1 2
Solution: s s1 s2 s1 , s1 , s 0,1 , s1 .s 2
2 2 2
3 3
22 2 2
4 4 3 2
For s 1, s1.s2
2 4
3 3
02 2 2
4 4 3 2
s 0, s1.s2
2 4
Q49. A two-dimensional square rigid box of side L contains six non-interacting electrons at
T 0 K . The mass of the electron is m . The ground state energy of the system of
2 2
electrons, in units of is _________.
2mL2
Ans.: 24
Solution: 2
1 2
12 2 2
4
2 2
12 2 2
24 2 2
2mL2 2mL2 2mL2
Q50. x , y and z are the Pauli matrices. The expression 2 x y y x is equal to
Q51. If x and p are the x components of the position and the momentum operators of a
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2 2
2
2
Solution: x , p p x , p x p p 2ipx 2ixp 2i xp px
Q52. Let l , m be the simultaneous eigenstates of L2 and L z . Here L is the angular
1, 0 ( Lx iLy ) 1, 1 is
Solution: 1, 0 ( Lx iLy 1, 1 1, 0 L 1, 1 2 1, 0 1, 0 2
Q53. For the parity operator P , which of the following statements is NOT true?
(a) P† P (b) P 2 P (c) P 2 I (d) P † P 1
Ans.: (b)
Q54. The state of a system is given by
1 2 2 3 3
Where 1 , 2 and 3 form an orthonormal set. The probability of finding the system
in the state 2 is ________. (Give your answer upto two decimal places)
22 4 4 2
Ans probability that in state 2 0.28
2 2
1 2 32
1 4 9 14 7
Q55. A particle of mass m and energy E , moving in the positive x
V0
direction, is incident on a step potential at x 0 , as indicated in the
E
figure. The height of the potential is V0 , where V0 E . At x x0 ,
1
where x0 0 , the probability of finding the electron is times the
e x0 x x0
2mV0 E
probability of finding it at x 0 . If , the value of x0 is
2
2 1 1 1
(a) (b) (c) (d)
2 4
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Ans.: (c)
1 1
Solution: e 2 x0 e 1 e 2 x0 x0
e 2
GATE-2017
Q56. The Compton wavelength of a proton is…………….. fm. (up to two decimal places).
Ans. : 3 108
Solution: m p 1.67 1027 kg , h 6.626 1034 Js, e 1.602 1019 C , c 3 108 ms 1
p2 1 2
Q57. A one dimensional simple harmonic oscillator with Hamiltonian H 0 kx is
2m 2
subjected to a small perturbation, H1 x x 3 x 4 . The first order correction to the
ground state energy is dependent on
(a) only (b) and
(c) and (d) only
Ans. : (d)
Solution: H1 x x 3 x 4 E1g x x3 x 4
x 0, x3 0, x 4 0
Q58. For the Hamiltonian H a0 I b . where a0 R, b is a real vector, I is the 2 2
identity matrix, and are the Pauli matrices, the ground state energy is
(a) b (b) 2a0 b (c) a0 b (d) a0
Ans. : (c)
1 0 0 1 0 i 1 0 a0 bz bx iby
Solution: a0 I b . a0 bx by bz
0 1 1 0 i 0 0 1 bx iby a0 bz
a0 bz bx iby
H a0 I b .
bx iby a0 bz
Head office Branch office
fiziks, H.No. 23, G.F, Jia Sarai, Anand Institute of Mathematics,
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Institute for NET/JRF, GATE, IIT‐JAM, JEST, TIFR and GRE in PHYSICAL SCIENCES
a0 bz bx iby
For eigen value 0
b x ib y a0 b z
a0 bz a0 bz bx2 by2 0
1 a0 b , 1 a0 b
Q59. The degeneracy of the third energy level of a 3-dimensional isotropic quantum harmonic
oscillator is
(a) 6 (b) 12 (c) 8 (d) 10
Ans. : (a)
Solution: First energy level is n 0
Second energy level is n 1
Third energy level is n 2
Q61. Consider a one-dimensional potential well of width 3nm . Using the uncertainty principle
x p , an estimate of the minimum depth of the well such that it has at least one
2
e 1.602 1019 C )
(a) 1 eV (b) 1meV (c) 1eV (d) 1MeV
Ans. : (b)
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2
p
Solution: E , p p
2m 2x 2a
so E
2
h
2 6.6 10 34 2
.0011019 J 1 meV
31 18
8ma 2
32 ma
2 2
32 10 9.3110 9 10
x e
2 x2
Q62. The integral dx is equal to……….. (up to two decimal places).
0
Ans. : 0.44
x
2
Solution: The given integral is 2
e x dx
0
dt
Let x 2 t then 2 xdx dt dx
2 t
Thus the given integral can be written as
3
dt 1 1 1
t e e t t1/ 2 dt e t t 2 dt
t
0 2 t 20 20
1 3 1 1 1
2 2 2 2 2 4
Hence the value of the integral up to two decimal places is 0.44 .
Q63. Which one of the following operators is Hermitian?
(a) i
p x x
2
x 2 px
(b) i
p x x
2
x 2 px
2 2
(c) ei px a (d) e i px a
Ans. : (a)
Solution: A i
p x x
2
x 2 px
, A i
†
p x x p i p x x p
x
2 † 2
x
†
x
2 2
x
2 2 2
Head office Branch office
fiziks, H.No. 23, G.F, Jia Sarai, Anand Institute of Mathematics,
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