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® Code

P31-17
0
ADVANCED PATTERN PART TEST-1(APT-1)
TARGET : JEE (MAIN+ADVANCED) 2018
REVISION PLAN-2 COURSE : VIJETA (JP), VISHWAAS (JF), VIJAY (JR)
Date : 17-04-2018 Time: 3 Hours Maximum Marks : 171
Please read the instructions carefully. You are allotted 5 minutes specifically for this purpose.
GENERAL %
1. The sealed booklet is your Question Paper. Do not break the seal till you are instructed to do so.
2. The question paper CODE is printed on the right hand top corner of this sheet and the right hand top corner of the back cover of
this booklet.
3. Use the Optical Response Sheet (ORS) provided separately for answering the question.
4. Blank spaces are provided within this booklet for rough work.
5. Write your Name and Roll Number in the space provided on the below cover.
6. After the open booklet, verify that the booklet contains all the 54 questions along with the options are legible.

QUESTION PAPER FORMAT AND MARKING SCHEME :


7. The question paper has three parts : Mathematics, Physics and Chemistry. Each part has three sections.
8. Each section as detailed in the following table :
Category-wise Marks for Each Question Maximum
Number of
Section Question Type Marks of the
Questions Negative
Full Marks Partial Marks Zero Marks Section
Marks
+3
0 –1
Comprehension If only the bubbles
1 8 – if not In all other 24
(SCQ) corresponding to the correct
attempted cases
answer is darkened
+3
0 –1
If only the bubbles
2 Single digit Integer (0-9) 7 – if not In all other 21
corresponding to the correct
attempted cases
answer is darkened
+1
+4 0
For darkening a bubble –2
Matching Type If only the bubble(s) If none of
3 3 corresponding to each correct In all other 12
(MCQ) corresponding to all the correct the bubbles
option, provided NO incorrect cases
option(s) is(are) darkened is darkened
option is darkened

OPTICAL RESPONSE SHEET :


9. Darken the appropriate bubbles on the original by applying sufficient pressure.
10. The original is machine-gradable and will be collected by the invigilator at the end of the examination.
11. Do not tamper with or mutilate the ORS.
12. Write your name, roll number and the name of the examination centre and sign with pen in the space provided for this purpose on
the original. Do not write any of these details anywhere else. Darken the appropriate bubble under each digit of your roll
number.

DARKENING THE BUBBLES ON THE ORS :


13. Use a BLACK BALL POINT to darken the bubbles in the upper sheet.
14. Darken the bubble COMPLETELY.
15. Darken the bubble ONLY if you are sure of the answer.
16. The correct way of darkening a bubble is as shown here :
17. There is NO way to erase or "un-darkened bubble.
18. The marking scheme given at the beginning of each section gives details of how darkened and not darkened bubbles are
evaluated.

NAME OF THE CANDIDATE : ………………………………………………………………..………………………

ROLL NO. : ………………………..………………………

I have read all the instructions I have verified the identity, name and roll number
and shall abide by them of the candidate.

------------------------- -------------------------
Signature of the Candidate Signature of the Invigilator

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MATHEMATICS
PART : I MATHEMATICS

MATHEMATICS
SECTION – 1 : (Maximum Marks : 24)
 This section contains FOUR paragraphs
 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is correct
 For each question, darken the bubble corresponding to the correct option in the ORS
 Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubble is darkened
–1 In all other cases

Paragraph for Question Nos. 1 to 2

Let n be a positive integer, such that (1 + x + x2)n = a0 + a1 x + a2 x2 + a3x3 +...... a2nx2n , then
Answer the following question:

1. The value of ar when (0 r  2 n) is


(A) a 2n – r (B) an – r (C) a2n (D) n. a2n – 1

2. The value of a0 + a1 + a2 + ..... an – 1 is

1 n 1 n an
(A) (3 ) (B) (3  an ) (C) (D) 3an
2 2 2

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MATHEMATICS
Paragraph for Question Nos. 3 to 4

MATHEMATICS
3 2
If the roots of the equation ax + bx – x + 1 = 0 are distinct real numbers in H.P. Then answer the

following:

3. The interval in which ‘a’ lies, is

(A) [1/27, )

(B) [–1/27, )

(C) (–1/27, )

(D) (1/27, )

4. The maximum value of 2b – 9a is

(A) –1

(B) 0

(C) 1

(D) None of these

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MATHEMATICS
Paragraph for Question Nos. 5 to 6

MATHEMATICS
xy 2xy
For any two positive number x & y, we have A.M.  G.M.  H.M. i.e.  xy  equality
2 xy

holds only if x = y
Now based upon the above information answer the following

16 36
5. The minimum value of + , with respect to the condition x + y = 10 is
x y

(A) 10
(B) 14
(C) 16
(D) 18

4 9
6. Minimum value of + with respect to the condition x2y3 = 3456, is
x y

(A) 5
(B) 2
(C) 10
5
(D)
2

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MATHEMATICS
Paragraph for Question Nos. 7 to 8

MATHEMATICS
The roots of the quadratic equation (having real coefficients, a is non zero) ax 2  bx  c  0 are

,  . Quadratic equation is also satisfied by  2 and 2 where   . Then answer the following:

7. For a given value of a, the number of distinct equations satisfying given conditions will be

(A) 2

(B) 3

(C) 4

(D) more than 4

8. Satisfying given conditions, the value of  3  3 can not be equal to

(A) –1, – 2

(B) 0, 1

(C) 1, 2

(D) 0, 2

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MATHEMATICS

SECTION – 2 : (Maximum Marks : 21)

MATHEMATICS
 This section contains SEVEN questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+3 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases

2  4   4
9. If  2  4  2  4  16  where  2 ,  4 are all real. Then 2 
4 5

2
10. ( a  0) If  be one of the roots of the quadratic equation x –x + 4a = 0 and  be one of the roots

of the equation x2 –x +3a = 0 such that  :  = 2 : 3. Then 4      

11. Let f(n) = nC0 nC1 + nC1 nC2 + .........+ nCn – 1 nCn. If 4f(n + 1)= 15 f(n), then sum of all the possible
values of ‘n’ is

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MATHEMATICS

MATHEMATICS
12. If coefficient of xn –1 in the expansion of (1 + 2x + 3x2 +….+ nxn –1)2 be n + aCb then a + b =

13. Let ,  be the roots of quadratic equation x2 + px + q = 0 and ,  be the roots of the quadratic
1 1 1 1 5
equation x2 – px + (q – 2) = 0.     and  = 24, if q1, q2 are two possible values
    6

p  q1  q2
of q, then is equal to
3

100
 1  N  2 
14. Let N be the number of distinct terms in the expansion of  x3  1  3  , then  =
 x   50 
([.] represents the greatest integer function)

2n
i  Hi  Hi 1 
15. If H1, H2, H3, …….H2n+1 are in H.P, for n = 36 then sum of digits of value of   1  H  H
i i 1
 is
i1

equal to

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MATHEMATICS

SECTION – 3 : (Maximum Marks : 12)

MATHEMATICS
 This section contains THREE questions of matching type.
 This section contains ONE table having 3 columns and 4 rows
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is(are) correct
 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
 For each question, marks will be awarded in one of the following categories :
Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)
darkened.
Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided
NO incorrect option is darkened.
Zero Marks : 0 If none of the bubbles is darkened.
Negative Marks : –2 In all other cases.
 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three
will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and
(B) will result in –2 marks, as a wrong option is also darkened.

Answer Q.16, Q.17, Q.18 by appropriately matching the information given in the three
columns of following table.

Entries in Column- contains rth term of a sequence.

Entries in Column- represents sum of first n terms.

Entries in Column- denotes sum to infinite terms of the sequence.

(Note that  in trigonometric expressions are such that these expressions are well defined)

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MATHEMATICS

Column- Column- Column-

MATHEMATICS
4r   
() 4 (i) tan – tan  n  (P) 2
r 4 2 
r2 tan((n  1)) – tan 
() r (ii) (Q) 1
2 .r(r  1) sin 
     n2  n  1
() tan  r  .sec  r –1  (iii) (R) does not exists
2  2  n2  n  2
1 (n  1)2n – 1
(V) (iv) (S) tan 
cos(r). cos((r  1)) (n  1).2n

16. Identify the correct combination

(A) () (iv) (P) (B) () (III) (R) (C) () (iv) (Q) (D) () (i) (Q)

17. Identify the correct combination

(A) () (iii) (Q) (B) () (iv) (P) (C) (V) (i) (R) (D) (V) (i) (S)

18. Identify the correct combination

(A) () (iv) (R) (B) () (ii) (S) (C) () (i) (S) (D) (V) (ii) (S)

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PHYSICS
PART - II : PHYSICS

PHYSICS
SECTION – 1 : (Maximum Marks : 24)

 This section contains FOUR paragraphs

 Based on each paragraph, there will be TWO questions.

 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is

correct

 For each question, darken the bubble corresponding to the correct option in the ORS

 Marking scheme :

+3 If only the bubble corresponding to the correct option is darkened

0 If none of the bubble is darkened

–1 In all other cases

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PHYSICS
Paragraph for Question Nos. 19 to 20

PHYSICS
An isotropic point source of light of power P is kept in front of a screen which has a circular hole of
radius R as shown in figure -1. Power crossing the circular hole is P1. Now a transparent cylinder
which does not absorb any light of a refractive index  2 ) is introduced between the source
and screen and kept as shown in figure -2. Consider the following two cases.
Case-1 : Source is kept on the axis of the cylinder, just outside the cylinder.
Case-2 : Source is kept on the axis of the cylinder, just inside the cylinder.
In case-1 power crossing the circular hole is P2 and in case-2 it is P3.

A A
s R R 2R
2R

d  3R d  3R B

Figure -1 Figure -2

Answer the following two questions :

19. Value of P2 is :
2P1 P1 2P1 P1
(A) (B) (C) (D)
2 3 2 3 2 3 2 3

20. Value of P3 is :
2 2  2 2  2 2  2 2 
(A) P1  (B) P1  (C) P1  (D) P1 
 2  3   2  3   2  3   2  3 
       

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PHYSICS
Paragraph for Question Nos. 21 to 22

PHYSICS
An Infinite large uniform charged non-conducting sheet having surface charge density  is placed

in an external uniform electric field E . Figure shows electric field lines near the sheet. Magnitude
of electric field in left side of sheet is 4N/C and electric field in right side of the sheet is at angle
tan–1(2) from sheet.

21. What is magnitude of uniform external electric field ?

(A) 4 N/C (B) 5 N/C (C) 2 2 N/C (D) 4 2 N/C

 
22. If EL is electric field in region left side of the sheet and ER is electric field in region right side of the

sheet then which of the following is correct statement :


        2   2
(A) | EL  ER | = (B) | EL  ER | = (C) | EL  ER | = (D) | EL  ER | =
2 0 0 0 2 0

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PHYSICS
Paragraph for Question Nos. 23 to 24

PHYSICS
The Hohmann Transfer Orbit maneuver is used by spaceships to transfer from one circular orbit
around a planet to another, by temporarily entering an intermediate elliptical orbit. The spaceship
starts on a small circular orbit of radius r around a planet of mass M. At point A in the diagram
below, it fires its propellers to put itself onto an intermediate elliptical orbit. At point B, it fires its
propellers again, and ends on the larger circular orbit of radius 2r. You may assume that the
propellers are so powerful that the changes in velocity occur instantaneously at each point.
Between point A and B space ship experience only gravitational force from planet.
B

2r
A

23. Find VA (the amount by which the velocity needs to be changed at point A) needed to achieve
this travel path.
GM  2  GM  4  GM  4  2GM  4 
(A)   1 (B)   1 (C)   1 (D)   1
r  3  r  3  r  3  r  3 
   

24. Time period of a satellite in inner orbit is 2 days then what is find taken by space ship to go from
A to B.
3/2 3/2 3/2
4 3 2
(A) (2)3/2 days (B)   days (C)   days (D)   days
3 2 3

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PHYSICS
Paragraph for Question Nos. 25 to 26

PHYSICS
There are two non-conducting spheres having uniform volume charge densities  and –. Both

spheres have equal radius R. The spheres are now laid down such that they overlap as shown in

the figure.

 

25. The electric field E in the overlapped region is

 
(A) non uniform (B) zero (C) d (D) R
3 0 3 0

26. The potential difference V between the centers of the two spheres for d = R is :

 2  2 2 2
(A) d (B) d (C) zero (D) d
3 0 0 0

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PHYSICS
SECTION – 2 : (Maximum Marks : 21)

PHYSICS
 This section contains SEVEN questions

 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive

 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+3 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases

27. The figure here shows a glass ball of refractive index 1.5 having inner radius 7 cm and outer radius
14 cm. The ball has a small mark at point A on its inner surface. This mark is being observerd by
an eye as shown. How nearer/farther (than it really is) will the mark appear to the eye (Answer
should be in cm)

Eye
A

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PHYSICS
28. A converging lens (focal length f) is broken in two equal pieces and placed at 60 cm as shown

PHYSICS
along with the object. It is found that real images are formed at the same place and ratio of image
 1
heights is 9 : 1, if the value of f is  22   cm then value of x is :
 x

29. Twelve infinite long wire of uniform linear charge density () are passing along the twelve edges of
  
a cube. If electric flux through any face of cube is   . Then value of n is :
 n0 

30. A thin spherical soap bubble has surface tension S. It's surface is uniformly charged with charge
Q, it's volume is V. It is found that when Q2 = 16n0SV, the excess pressure inside the bubble
becomes zero. Find n.

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PHYSICS
31. A tube of length 30 cm has its inner lateral surface which is completely absorbing. Two lenses of

PHYSICS
focal lengths 10 cm and 20 cm are fixed at the ends of the tube. For same beam, intensities of
spots on screen are I1 and I2 for arrangement (1) and arrangement (2) respectively. Find the value
I2
of
2I1
.

10 cm 20 cm 20 cm 10 cm
Beam

Beam
Tube Tube

Screen Screen
Arrangement (1) Arrangement (2)

32. A tunnel is dug inside the earth across one of its diameters . Radius of earth is R and its mass is
2GM
M. A particle is projected inside the tunnel with velocity from one of its ends then
R
nGM
maximum velocity attained by the particle in the subsequent motion is (assuming tunnel to
R
be frictionless). Find n.

33. Consider a spherical planet rotating about its axis. The velocity of a point at equator is v. The
angular velocity of this planet is such that it makes apparent value of ‘g’ at the equator half of value
of ‘g’ at the pole. The escape speed for a polar particle on the planet expressed as multiple of v is
given by v. Find .

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PHYSICS
SECTION – 3 : (Maximum Marks : 12)

PHYSICS
 This section contains THREE questions of matching type.

 This section contains ONE table having 3 columns and 4 rows

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these

four option(s) is(are) correct

 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

 For each question, marks will be awarded in one of the following categories :

Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)

darkened.

Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided

NO incorrect option is darkened.

Zero Marks : 0 If none of the bubbles is darkened.

Negative Marks : –2 In all other cases.

 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three

will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and

(B) will result in –2 marks, as a wrong option is also darkened.

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PHYSICS
Column–1 shows a system for which two numbers x and y are defined, column–2 shows value of x
and column–3 shows the value of y. Answer Q.34. Q.35 and Q.36 by appropriately matching

PHYSICS
the information given in the three columns of the following table.
Column -1 Column -2 Column -3
Converging mirror
Plane mirror

(I) (i) 1 (P) 2


A 10cm O 20cm
10cm P

Converging lens
Object is kept at position A, lying at the principal axis of
lens as well mirror. Final images of the object is formed
at object itself. Focal length of converging mirror = x cm
Focal length of converging lens = y cm

(II) (ii) 2 (Q) 6




O
Hemispherical shell, having surface charge density
 (may be constant or variable) Electric field at O

(if  = 0 = constant) = 0 Electric field at O
x 0
0
(if  = 0 cos) =
y 0
(III) 2a
(iii) 4 (R) 8
m m
Two identical point masses, kept at Separation 2a,
2 a 3
and then released. Time after they collide =
Space for Rough
xGm Work
Velocity of approach of particles when Separation
yGm
between them is a =
a

(IV) (iv) 5 (S) 20


P

Uniform charged long cylinder, charge density ,


having long cylindrical cavity inside its. Electric field at
xR 2R
the axis of long cylinder = Electric field at the axis of cavity =
40 y 0
34. Which of the following is/are correctly matched :
(A) (I) (iv) (S) (B) (I) (iv) (R) (C) (I) (iii) (S) (D) (III) (ii) (P)

35. Which of the following is/are correctly matched :


(A) (I) (iv) (P) (B) (I) (iii) (Q) (C) (II) (iii) (Q) (D) (IV) (i) (S)

36. Which of the following is/are correctly matched :


(A) (IV) (i) (R) (B) (IV) (iii) (R) (C) (III) (ii) (S) (D) (I) (iii) (S)

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CHEMISTRY
PART : III CHEMISTRY

CHEMISTRY
Atomic masses : [H = 1, D = 2, Li = 7, C = 12, N = 14, O = 16, F = 19, Na = 23, Mg = 24, Al = 27, Si = 28,
P = 31, S = 32, Cl = 35.5, K = 39, Ca = 40, Cr = 52, Mn = 55, Fe = 56, Cu = 63.5, Zn = 65, As = 75,
Br = 80, Ag = 108, I = 127, Ba = 137, Hg = 200, Pb = 207]

SECTION – 1 : (Maximum Marks : 24)

 This section contains FOUR paragraphs


 Based on each paragraph, there will be TWO questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option is
correct
 For each question, darken the bubble corresponding to the correct option in the ORS
 Marking scheme :
+3 If only the bubble corresponding to the correct option is darkened
0 If none of the bubble is darkened
–1 In all other cases

Paragraph for Question Nos. 37 to 38

Fluorocarbon polymers (CF2)n can be made by fluorinating polyethylene according to the reaction :

(CH2 )n  CoF3 
(CF2 )n  HF  CoF2

The CoF3 can be regenerated by the reaction CoF2  F2  CoF3 .

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CHEMISTRY
37. If the HF can be recovered and electrolyzed to H2 & F2 and this F2 is also used for regenerating
CoF3. What is the net consumption of F2 for per Kg production of fluorocarbon? Assume in the first

CHEMISTRY
reaction reactants are present in the stoichiometric proportion.
(A) 1520 g (B) 760 g (C) 800 g (D) None of these

38. In the above question how many moles of CoF2 will form from 5 mole of CoF3?
(A) 4 (B) 5 (C) 6 (D) None of these

Paragraph for Question Nos. 39 to 40

Simple acid base titration reaction is : Acid + Base  Salt + Water

At equivalent point : Eq. of acid = Eq. of base


For Redox titration at equivalent point : Eq. of oxidizing agent = Eq. of reducing agent.

39. 10 g oxalate sample was dissolved in 300 mL of solution. This solution required 250 mL of

M
KMnO4 , in acidic medium for complete oxidation. The percentage of oxalate ion in the
10
sample is :
(A) 57.8% (B) 55% (C) 45% (D) none of these

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CHEMISTRY
40. Certain moles of CO2 are dissolved in excess of NaOH. The resulting solution is divided into two
equal parts. One part needs 30 mL of 2.5 N HCl and other part needs 40 mL of 2.5 N HCl using

CHEMISTRY
phenolphthalein and methyl orange indicator respectively. The moles of CO2 dissolved is –
(A) 50 mol (B) 5 × 10–2 mol (C) 5× 10–3 mol (D) None of these

Paragraph for Question Nos. 41 to 42

One mole of NH4HS(s) was allowed to decompose in 1L container at 200°C. It decomposes

reversibly to NH3(g) and H2S(g). NH3(g) further undergoes decomposition to form N2 and H2.

Finally when, equilibrium was set up, the ratio between the number of moles of NH3 and H2 was

found to be 3.

NH4HS(s) NH3(g) + H2S(g) KC = 8.91 × 10–2 M2

2NH3(g) N2(g) + 3H2(g) KC = 3 × 10–4 M2

41. What is the mole fraction of H2 gas in the equilibrium in the gas phase ?

1 3 1
(A) (B) (C) (D) 4
4 4 8

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CHEMISTRY
42. Assuming the volume due to solid NH4HS is negligible. What will be the density of the gaseous

mixture in the above equilibrium system?

CHEMISTRY
(A) 16.83 g/L (B) 16.83 g/mL (C) 18.41 g/L (D) 14.83 g/L

Paragraph for Question Nos. 43 to 44

Consider the following cell


+
Pt(s) | H2(g) (1 bar) | H (aq) (1M) || C6H5NH2HCl(aq) (10–2 M) | H2(g) (1 bar) | Pt(s)

 2.303 RT 
Ecell = –0.24V Given :  0.06 V 
 F 

43. What is the pH of cathodic chamber?

(A) 3 (B) 4 (C) 2 (D) None of these

44. What is the hydrolysis constant of C6H5NH2HCl ?

(A) 10–2 (B) 10–8 (C) 10–6 (D) None of these

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CHEMISTRY

SECTION – 2 : (Maximum Marks : 21)

CHEMISTRY
 This section contains SEVEN questions
 The answer to each question is a SINGLE DIGIT INTEGER ranging from 0 to 9, both inclusive
 For each question, darken the bubble corresponding to the correct integer in the ORS
 Marking scheme :
+3 If the bubble corresponding to the answer is darkened
0 If none of the bubbles is darkened
–1 In all other cases

45. How many of the following statement(s) is/are correct?

1. The more positive E° is, the greater is the tendency for the substance to be reduced.

2. The cell potential depends upon concentration of reactant & product, temperature and

stoichiometric coefficients of reaction.

3. Conductance is an additive property.

4. The SI unit of equivalent conductivity is S cm2 eq–1

5. Conductivity increases with increase in concentration.

6. In electrolytic cell cathode is of positive polarity.

7. Debye – Huckel – Onsagar equation is not valid for weak electrolyte.

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CHEMISTRY
46. Find the normality of 1 M FeC2O4 against acidic KMnO4.

CHEMISTRY
47. EMF of the following cell is 0.634 volt at 298 K.

Pt(s) | H2 (1 bar) | H+ (aq) || KCl (1N) | Hg2Cl2(s) | Hg().

Calculate pH of the anode compartment.

2.303 RT
Given E0Cl |Hg Cl = 0.28 V and = 0.059 V
2 |Hg
2
F

48. What volume (in L) of 6 M NaOH would be required to react with the SO2 produced from 1000 Kg

of coal containing 0.072% by mass of pyrites impurity according to the given reaction?

[Given : FeS2  O 2  SO2  FeO ], [SO2  NaOH  Na2 SO3  H2O]

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CHEMISTRY
49. One mole of an impure sample of CO containing 40% CO2 by mole as impurity was passed over

CHEMISTRY
excess solid 2O5 at 25ºC. At equilibrium the number of moles of CO remaining unreacted is 0.5.

Find out the KP value of the following equilibrium :

  2O5(s) + 5CO(g) 2(s) + 5CO2(g)

50. 80 gm of NaOH is added to 1 L of 2M NiCl2 solution. Calculate the pH of final solution. Ksp of

Ni(OH)2 is 10– 16. Assume volume remains unchanged.

51. Consider the following reaction :

xKMnO 4  yH2SO 4  zH2O 2  aMnSO 4  bO 2  cK 2SO 4  dH2 O

What is the sum of y & z in the balanced reaction with simplest integer coefficient.

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CHEMISTRY

SECTION – 3 : (Maximum Marks : 12)

CHEMISTRY
 This section contains THREE questions of matching type.

 This section contains ONE table having 3 columns and 4 rows

 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these

four option(s) is(are) correct

 For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS

 For each question, marks will be awarded in one of the following categories :

Full Marks : +4 If only the bubble(s) corresponding to all the correct option(s) is(are)

darkened.

Partial Marks : +1 For darkening a bubble corresponding to each correct option, provided

NO incorrect option is darkened.

Zero Marks : 0 If none of the bubbles is darkened.

Negative Marks : –2 In all other cases.

 For example, if (A), (C) and (D) are all the correct options for a question, darkening all these three

will result in +4 marks ; darkening only (A) and (D) will result in +2 marks and darkening (A) and

(B) will result in –2 marks, as a wrong option is also darkened.

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CHEMISTRY
Given are titration and conductometric graphs for HA v/s BOH.

Column I Column II Column III

CHEMISTRY
10
At equivalent point pH
At equivalent point
(1) (a) pH 4 (p) depends upon
pH > 7
concentration of species

Vbase

10

At equivalent point 7 At equivalent point


(2) (b) pH (q)
pH < 7 solution contain only salt

Vbase
Conductance

(3) At equivalent point Phenolphthalein indicator


(c) (r)
pH = 7 can be used

Vbase Work
Space for Rough
Conductance

At half
equivalent Point Methyl orange indicator
(4) (d) (s)
pH = ionization can be used
constant
Vbase

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CHEMISTRY
52. For titration of weak acid with strong base correct set is/are :

(A) (1) (b) (p) (B) (4) (d) (q)

CHEMISTRY
(C) (1) (b) (r) (D) (2) (a) (q)

53. For titration of strong acid with strong base correct set is/are :

(A) (3) (a) (q) (B) (2) (a) (r)

(C) (3) (c) (r) (D) (3) (c) (p)

54. For titration of weak base with strong acid correct set is/are :

(A) (2) (d) (s) (B) (4) (d) (q)

(C) (3) (a) (q) (D) (2) (c) (s)

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