DeltaG,

Especies Cu O S kcal/mol
1 Cu 1,000 0.000 0.000 0.000
2 CuO 1,000 1,000 0.000 -16,376
3 Cu2O 2,000 1,000 0.000 -23,310
4 CuO*CuSO4 2,000 5,000 1,000 -115,167
5 CuS 1,000 0.000 1,000 -11,192
6 Cu2S 2,000 0.000 1,000 -24,532
7 CuSO4 1,000 4,000 1,000 -97,408
X= O2(g) 0.000 2,000 0.000 0.000
Y= SO2(g) 0.000 2,000 1,000 -69,513

REACTIONS at T = 973.000
1 1.000 Cu + 0.500 O2(g) -> CuO
2 2.000 Cu + 0.500 O2(g) -> Cu2O
3 2.000 Cu + 1.500 O2(g) + 1.000 SO2(g) -> CuO*CuSO4
4 1.000 Cu + 1.000 SO2(g) -> 1.000 O2(g) + CuS
5 2.000 Cu + 1.000 SO2(g) -> 1.000 O2(g) + Cu2S
6 1.000 Cu + 1.000 O2(g) + 1.000 SO2(g) -> CuSO4
7 2.000 CuO -> 0.500 O2(g) + Cu2O
8 2.000 CuO + 0.500 O2(g) + 1.000 SO2(g) -> CuO*CuSO4
9 1.000 CuO + 1.000 SO2(g) -> 1.500 O2(g) + CuS
10 2.000 CuO + 1.000 SO2(g) -> 2.000 O2(g) + Cu2S
11 1.000 CuO + 0.500 O2(g) + 1.000 SO2(g) -> CuSO4
12 1.000 Cu2O + 1.000 O2(g) + 1.000 SO2(g) -> CuO*CuSO4
13 0.500 Cu2O + 1.000 SO2(g) -> 1.250 O2(g) + CuS
14 1.000 Cu2O + 1.000 SO2(g) -> 1.500 O2(g) + Cu2S
15 0.500 Cu2O + 0.750 O2(g) + 1.000 SO2(g) -> CuSO4
16 0.500 CuO*CuSO4 + 0.500 SO2(g) -> 1.750 O2(g) + CuS
17 1.000 CuO*CuSO4 -> 2.500 O2(g) + Cu2S
18 0.500 CuO*CuSO4 + 0.250 O2(g) + 0.500 SO2(g) -> CuSO4
19 2.000 CuS + 1.000 O2(g) -> 1.000 SO2(g) + Cu2S
20 1.000 CuS + 2.000 O2(g) -> CuSO4
21 0.500 Cu2S + 1.500 O2(g) + 0.500 SO2(g) -> CuSO4

COORDINATES OF TRIPLE POINTS

Phases Present Log pO2(g)
1 Cu - Cu2O - Cu2S -10470
2 CuO - Cu2O - CuO*CuSO4 -4241
3 Cu2O - CuO*CuSO4 - CuSO4 -5484
4 Cu2O - Cu2S - CuSO4 -8438
5 CuS - Cu2S - CuSO4 -9682
 LINES BETWEEN TRIPLE POINTS AND AXIS
Log pO2(g) Log pSO2(g) Log pO2(g)
1 Cu2O - Cu2S -10470 -0.368 -8438
2 Cu2O - CuO*CuSO4 -4241 -0.777 -5484
3 Cu2O - CuSO4 -5484 0.465 -8438
4 Cu2S - CuSO4 -8438 2681 -9682
5 Cu-Cu2O -10470 -4000 -10470
6 Cu-Cu2S -12000 -1898 -10470
7 CuO-Cu2O -4241 -4000 -4241
8 CuO-CuO*CuSO4 2204 -4000 -4241
9 CuO*CuSO4-CuSO4 3447 -4000 -5484
10 CuS-Cu2S -12000 4094 -9682
11 CuS-CuSO4 -9682 16000 -9682
 G / cal
-16376000
-23309900
CuO*CuSO4 -45654300
58320400
44981100
-27895200
9442100
> CuO*CuSO4 -12902300
74696400
77733100
-11519200
-> CuO*CuSO4 -22344400
69975350
68291000
-> CuSO4 -16240250
0 O2(g) + CuS 81147550
90635400
SO2(g) -> CuSO4 -5068050
-71659700
-86215600
-> CuSO4 -50385750

Log pSO2(g)
-0.368
-0.777
0.465
2681
6413
Log pSO2(g)
2681
0.465
2681
6413
-0.368
-0.368
-0.777
-0.777
0.465
6413
6413
 DeltaG,
Especies Cu O S kcal/mol
1 Cu 1,000 0.000 0.000 0.000
2 CuO 1,000 1,000 0.000 -16,376
3 Cu2O 2,000 1,000 0.000 -23,310
4 CuO*CuSO4 2,000 5,000 1,000 -115,167
5 CuS 1,000 0.000 1,000 -11,192
6 Cu2S 2,000 0.000 1,000 -24,532
7 CuSO4 1,000 4,000 1,000 -97,408
X= O2(g) 0.000 2,000 0.000 0.000
Y= SO2(g) 0.000 2,000 1,000 -69,513