Calculate the standard heat of reaction for the conversion of cyclohexane

to benzene :

If the reactor for the conversion operates at 70% conversion of C6H12,

what is the heat removed from or added to the reactor if (a) the exit
gases leave at 25C and (b) the exit gases leave at 300C and the entering
materials consist of C6H12 together with one-half mole of N2 per mole
of C6H12, both at 25C?

1. Degree of Freedom 2. Mass Balance

5 unknown variables (n1, n2, n3, n4, Q) Basis : 10 mol

(-4 mass balance)
(-1 energy balance)

0 degrees of freedom

mol bereaksi =

Reaksi :

mula-mula
reaksi
sisa
ohexane

Reactor

s Balance

Product :

= 3 mol
= 7 mol
= 21 mol
= 15 mol

mol bereaksi = 7

Feed :
= 10 mol
= 15 mol
10
7 7 21
3 7 21
BM :
= 84 = -123.14 kJ/mol
= 78 = 82.93 kJ/mol
= 2 = 0 kJ/mol
= 28 = 0 kJ/mol
(from App. C.4 Chemical Engineering Thermodynamics Sixth Edition by Smith Van Ne

3. Energy Balance

252 gr
546 gr
42 gr
(inert) 420 gr

1260 gr Condition :

840 gr
420 gr

1260 gr

Step 1 :

1811.91 kJ

Step 2 :
 = 136069.1

= 230869.91

= 167206.88

= 121783.97

655929.9 kJ

Step 3 :

657742
 Cp a bT cT2 dT3
94.14 0.4962 -0.000319 8.063E-08
74.06 0.3295 -0.000252 7.757E-08
28.84 0.0000765 0.000003288 -8.698E-10
29 0.002199 0.000005723 -2.871E-09
s Sixth Edition by Smith Van Ness) (from App.G.1 Basic Principles And Calculation In Chemical Enginering Eight Edition By Himmel

Tin Tout
25 300
kJ

kJ

kJ

kJ

kJ
nering Eight Edition By Himmelblau)