Fisicoquímica IV
Integrantes:
Química
Grupo: 1501 C
Lab: L4-413
Equipo: 4
0.0592 𝑎𝑜𝑥
𝐸 = 𝐸° − 𝑙𝑜𝑔
𝑍 𝑎𝑟𝑒𝑑
Procedimiento Experimental:
Resultados Experimentales:
Análisis de Resultados:
CELDA O
REACCIÓN DE LA CELDA
POTENCIAL POTENCIAL Ecal Eexp
CADENA ÁNODO CÁTODO (mV)
(mV)
𝑃𝑏 2+ + 2𝐼 − ↔ 𝑃𝑏𝐼2
C -0.1444 -0.1662 -21.8 167
𝑃𝑏 2+ + 𝑆𝑂42− ↔ 𝑃𝑏𝑆𝑂4
D -0.1661 -0.1450 21.1 180.9
𝑃𝑏 2+ + 𝑍𝑛0 ↔ 𝑍𝑛2+ + 𝑃𝑏 0
F -0.1662 -0.8031 -636.9 636
𝑃𝑏 2+ + 𝐶𝑢0 ↔ 𝐶𝑢2+ + 𝑃𝑏 0
G -0.1662 0.7688 935 898
Calculos:
Celda A
Anodo: Catodo:
1 1
𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4 𝐼 = ( ) [(0.1𝑀)(2)2 + (0.1𝑀)(−2)2 ] = 0.4
2 2
Anodo: Cátodo:
1 1
𝐼 = ( ) [(0.01𝑀)(2)2 + (0.01𝑀)(−2)2 ] = 0.04 𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4
2 2
Celda C:
Anodo: Cátodo:
1 1
𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−1)2 ] = 2.5𝑉 𝐼 = ( ) [(0.1𝑀)(2)2 + (0.2𝑀)(−1)2 ] = 0.3
2 2
Celda D:
Anodo: Cátodo:
1 1
𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4𝑉 𝐼 = ( ) [(1𝑀)(2)2 + (2𝑀)(−1)2 ] = 3
2 2
Celda E:
1 1
𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4𝑉 𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4
2 2
Celda F:
Anodo: Cátodo:
1 1
𝐼 = ( ) [(0.1𝑀)(2)2 + (0.2𝑀)(−1)2 ] = 0.3𝑉 𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4𝑉
2 2
Anodo: Cátodo:
1 1
𝐼 = ( ) [(0.1𝑀)(2)2 + (0.2𝑀)(−1)2 ] = 0.3𝑉 𝐼 = ( ) [(0.5𝑀)(1)2 + (0.5𝑀)(−1)2 ] = 0.5𝑉
2 2
Celda H
Anodo: Cátodo:
1 1
𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−1)2 ] = 2.5𝑉 𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4
2 2
Celda I:
Anodo: Cátodo:
1 1
𝐼 = ( ) [(0.1𝑀)(2)2 + (0.2𝑀)(−1)2 ] = 0.3𝑉 𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4𝑉
2 2
−|(2)(−1)|(0.509 𝑚)√0.3𝑉 −|(2)(−2)|(0.509 𝑚)√4𝑉
𝛾−+ = = 0.4362 𝛾−+ = = 0.0439
1+√0.3𝑉 1+√4𝑉
Celda J:
Anodo: Cátodo:
1 1
𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4𝑉 𝐼 = ( ) [(0.5𝑀)(1)2 + (0.5𝑀)(−1)2 ] = 0.5𝑉
2 2
Batería 1
Anodo: Cátodo:
1 1
𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4𝑉 𝐼 = ( ) [(0.5𝑀)(1)2 + (0.5𝑀)(−1)2 ] = 0.5𝑉
2 2
1 1
𝐼 = ( ) [(0.1𝑀)(2)2 + (0.2𝑀)(−1)2 ] = 0.3𝑉 𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4𝑉
2 2
𝐸𝑡𝑜𝑡𝑎𝑙 = 𝐸1 + 𝐸2
Batería 2
Anodo: Cátodo:
1 1
𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4𝑉 𝐼 = ( ) [(0.5𝑀)(1)2 + (0.5𝑀)(−1)2 ] = 0.5𝑉
2 2
Cátodo: Anodo:
1 1
𝐼 = ( ) [(0.1𝑀)(2)2 + (0.2𝑀)(−1)2 ] = 0.3𝑉 𝐼 = ( ) [(1𝑀)(2)2 + (1𝑀)(−2)2 ] = 4𝑉
2 2
𝐸𝑡𝑜𝑡𝑎𝑙 = 𝐸1 + 𝐸2
Conclusiones:
Bibliografía: