O

‖‖
H2C─O─C─R1 H2C─OH R1─COOH
O

H2C─O─C─R2 + 3HOH H─C─OH + R2─COOH

O

H2C─O─C─R3 H2C─OH R3─COOH

Lemak Gliserol Asam lemak

Reaksi Hidrolisa

H H H H H H H H
| | | | energi | | | |
R1 ─ C ─ C = C ─ C ─ R 2 R1 ─ C ─ C = C ─ C – R 2 + H ●
●
| | Panas + sinar |
H H Radikal bebas H

Asam lemak tidak jenuh H H H H Hidrogen

| | | | yang
R1 ─ C ─ C = C ─ C – R 2 labil + O2
| |
O ─ O• H

H H H H Peroksida aktif
| | | |
R1 – C ─ C = C ─ C ─ R 2 +
| |
H H

H H H H H H H H
| | | | | | | |
R1 ─ C ─ C = C ─ C – R 2 + R1 ─ C ─ C = C ─ C ─ R 2
●
| |
O – OH H

Hidroperoksida Radikal bebas

Gambar 2. Reaksi Oksidasi Minyak(Winarno, 2008)
Reaksi oksidasi‖