MATERIAL AND EN

STRIPPER INLET
sp heat KJ/K
Components Kg/hr K mole/hr mole fraction x mol0C,Cp
Ammonia 70350 4138.24 0.51 98.00
CO2 29200 663.64 0.08 56.00
Urea 73560 1226.00 0.15 121.32
Water 38500 2138.89 0.26 74.00
Biuret 240 2.33 0.0003 183.80
Total 211850 8169.09 1.00 533.12

HEAT INPUT 142529462.3

Prem Baboo

Sr. Manager(Prod)

National Fertilizers Ltd. ,India

HEAT INPU

STRIPPER INLET + STEAM LA

210869746
IAL AND ENERGY BALANCE OF STRIPP
STRIPPER OUTLET VAPOUR
Components Kg/hr Wt % mole %

Ammonia 34116 68.80% 0.04

CO2 14360 28.96% 0.01
Water 400 0.81% 0.0004
Inerts 713 1.44% 0.0005
Total 49589 100.00% 0.05

VAPOUR
STEAM

Σ x.cp

49.64
4.55
18.21
STRIPPER
19.38
0.05
91.83

KJ/HR

HEAT INPUT = HEAT OUTPUT

RIPPER INLET + STEAM LATENT HEAT = STRIPPER OUTLET(Liquid) + STRIPPER

Sensible + Latent)

210869746 KJ/HR 210869746

 OF STRIPPER M/S SAIPEM
R OUTLET VAPOUR
Mol Kg
Sp. Heat,Cp Σ x.cp Mλ
Fraction,x Mol/Hr
0.85 106.76 2006.82 90.96 46704804 So, heat carried by outlet stream =
0.14 59.96 326.36 8.31 8242640
0.01 79.80 22.22 0.75 744000 Sensible Heat of vapour
0.01 34.00 25.46 0.37
1.00 246.52 2355.41 100.02 55691444 Latent Heat of
Vapour
Total

STRIPPER OUTLET LIQUID

Mol
Kg/hr Wt % mole %
Components Fraction,x Sp. Heat,Cp
LIQUID Ammonia 38234 23.46 1.3800108 0.38212394 80.24
CO2 12840 7.88 0.1790581 0.04958106 55.88
Urea 73532 45.12 0.7519809 0.20822293 140
Water 38100 23.38 1.2987757 0.35962999 77.5
Biuret 268 0.16 0.0015965 0.00044208 185
Total 162974 100 3.611422 1

So, heat carried by outlet stream = m.Cp. DT =

Heat supplied to the Stripper 24.5 ata steam at 224 0C
Flow Rate 38.39 T/H
Latent Heat 1780 KJ/Kg

HEAT OUTPUT
TLET(Liquid) + STRIPPER VAPOUR (i.e
Sensible + Latent)

210869746
ed by outlet stream = m.Cp. DT

45940162.5091 KJ/Hr

55691444 KJ/Hr

101631606.5 KJ/Hr

Kg Mol/Hr Σ x.cp

2249.06 30.66
291.82 2.77
1225.53 29.15
2116.67 27.87
2.60 0.08
5885.68 90.54

109238139.374 KJ/Hr

68340283.51 KJ/Hr
 MATERIAL AND ENERGY BALANCE OF UREA REACOR

INLET REACTOR OUTLET

Components Kg/hr KJ /Hr Components Kg/hr K mole/hr

Ammonia 42214 30647153 Ammonia 70350 4138.24

REACTOR
CO2 52962 11907182 CO2 29200 663.64
1900C
Carbamate Urea 73560 1226.00
Pr.-160 ata.
Ammonia 76836 55782552 Water 38500 2138.89
CO2 18829 4233230 Biuret 240 2.33
Water 21009 10111106 Total 211850 8169.09
Total 211850 112681223
HEAT INPUT Heat carried by outlet stream

Heat input + ΔHR - Heat output = rate of accumulatio

ΔHR =

Amount of urea formed during the reaction =

ΔHR =

126618100
Rate of Acculumation
Prem Baboo
Sr. Manager(Prod) This Heat
59.39
National Fertilizers Ltd.,India Equivalent to
A REACOR

REACTOR OUTLET
sp heat KJ/K
mole fraction x Σ x.cp
mol0C,Cp
0.51 106.76 54.08
0.08 58.96 4.79
0.15 121.32 18.21
0.26 75.37 19.73
0.0003 183.80 0.05
1.00 546.21 96.87

m .Cp. dT 150347123 KJ/Hr

put = rate of accumulation

134000 KJ/K mol of Urea formed.

ing the reaction = 1226.00 Kmol/hr

164284000 Kj/hr

KJ/Hr

Ton of 5.0 ata steam per Hour

 CO2 DATA
Property Value Unit
Medium : carbon dioxide

state of aggregation : overcritical fluid

Pressure : 160 [ bar ]

Temperature : 115 [ Celsius ]
Density : 329.074 [ kg / m ] 3

Specific Enthalpy : 481.074 [ kJ / kg ]

Specific Entropy : 1.80426 [ kJ / kg K ]

Specific isobar heat capacity :

1.95546 [ kJ / kg K ]
cp

Specific isochor heat capacity :

0.886488 [ kJ / kg K ]

cv
Isobar coefficient of thermal 8.61674 [ 10-3 (1 / K) ]
expansion :

Heat conductance 43.5846 [ 10-3 (W / m * K) ]

Dynamic viscosity : 28.5946 [ 10-6 (Pa s) ]

Kinematic viscosity : 0.0868941332 [ 10 m / s]
-6 2

Thermal diffusivity : 0.72957 [ 10 m / s]

-7 2

Prandtl-Number : 1.27992
Coefficient of compressibility Z : 0.67966
speed of sound : 289.588 [ m / s ]
CO2 DATA
Property Value Unit
Medium : carbon dioxide

state of aggregation : overcritical fluid

Pressure : 160 [ bar ]

Temperature : 190 [ Celsius ]
Density : 213.436 [ kg / m ] 3

Specific Enthalpy : 597.252 [ kJ / kg ]

Specific Entropy : 2.0816 [ kJ / kg K ]

Specific isobar heat capacity :

1.34 [ kJ / kg K ]
cp

Specific isochor heat

42.3522 capacity : 0.861744 [ kJ / kg K ]

cv
Isobar coefficient of thermal 3.91012 [ 10-3 (1 / K) ]
expansion :
[ 10-3 (W / m * K)
Heat conductance 39.4164 ]
Dynamic viscosity : 26.6152 [ 10-6 (Pa s) ]
Kinematic viscosity : 0.1246987387 [ 10 m / s]
-6 2

Thermal diffusivity : 1.419076 [ 10 m / s]

-7 2

Prandtl-Number : 0.9048
Coefficient of compressibility 0.86304
Z:
speed of sound : 326.092 [m/
Property Value Unit
Medium : carbon dioxide

state of aggregation : overcritical fluid

Pressure : 146 [ bar ]

Temperature : 205 [ Celsius ]
Density : 182.158 [ kg / m ] 3

Specific Enthalpy : 621.941 [ kJ / kg ]

Specific Entropy : 2.149304 [ kJ / kg K ]

Specific isobar heat

capacity : 1.270732 [ kJ / kg K ]
cp

Specific isochor heat

capacity : 0.8601096 [ kJ / kg K ]

cv
Isobar coefficient of 3.414294 [ 10-3 (1 / K) ]
thermal expansion :

Heat conductance 38.7589 [ 10-3 (W / m * K) ]

Dynamic viscosity : 26.1809 [ 10-6 (Pa s) ]

Kinematic viscosity : 0.1437263255 [ 10 m / s]
-6 2

Thermal diffusivity : 1.711498 [ 10 m / s]

-7 2

Prandtl-Number : 0.8586072
Coefficient of 0.8907314
compressibility Z :
speed of sound : 330.9056 [m/s]
 AMMONIA DATA
Property Value Unit

Medium : ammonia

state of aggregation : fluid

Pressure : 160 [ bar ]
Temperature : 115 [ Celsius ]
Density : 453.55 [ kg / m ] 3

787.85
Specific Enthalpy : [ kJ / kg ]
2.6986
Specific Entropy : [ kJ / kg K ]

Specific isobar heat capacity : 6.3135

cp [ kJ / kg K ]

2.744
Specific isochor heat capacity :
cv [ kJ / kg K ]

6.055
Isobar coefficient of thermal
expansion : [ 10-3 (1 / K) ]
303.75
Heat conductance [ 10-3 (W / m * K) ]
62.69
Dynamic viscosity : [ 10-6 (Pa s) ]
0.1382207033
Kinematic viscosity : [ 10 m / s]
-6 2

1.0645
Thermal diffusivity : [ 10 m / s]
-7 2

1.3
Prandtl-Number :

0.186
Coefficient of compressibility Z :
764.7
speed of sound : [m/s]
IA DATA
Property Value Unit Property

Medium : ammonia Medium :

state of
state of aggregation : gas aggregation :
Pressure : 160 [ bar ] Pressure :
Temperature : 190 [ Celsius ] Temperature :
Density : 116.6 [ kg / m ] 3
Density :
1565 Specific
Specific Enthalpy : [ kJ / kg ] Enthalpy :
4.5257 Specific Entropy
Specific Entropy : [ kJ / kg K ] :
Specific isobar heat Specific isobar
capacity : 6.28 heat capacity :
cp [ kJ / kg K ] 106.76 cp

Specific isochor heat 2.6355 Specific isochor

capacity : heat capacity :
cv [ kJ / kg K ] cv

Isobar
10.085 coefficient of
Isobar coefficient of thermal thermal
expansion : [ 10-3 (1 / K) ] expansion :
87.115 Heat
Heat conductance [ 10-3 (W / m * K) ] conductance
20.46 Dynamic
Dynamic viscosity : [ 10-6 (Pa s) ] viscosity :
0.1754716981 Kinematic
Kinematic viscosity : [ 10 m / s]
-6 2
viscosity :
1.2355 Thermal
Thermal diffusivity : [ 10 m / s]
-7 2
diffusivity :
1.47 Prandtl-
Prandtl-Number : Number :
Coefficient of
Coefficient of 0.6115 compressibility
compressibility Z : Z:

speed of sound : 431.75 [ m / s ] speed of sound :

 Value Unit

ammonia

gas
146 [ bar ]
205 [ Celsius ]
89.561 [ kg / m ] 3

1681.44 [ kJ / kg ]

4.803566 [ kJ / kg K ]

4.72752 [ kJ / kg K ]

2.4771 [ kJ / kg K ]

6.5412 [ 10-3 (1 / K) ]

78.9042 [ 10-3 (W / m * K) ]

19.5182 [ 10-6 (Pa s) ]

0.2179319 [ 10 m / s]
-6 2

1.9076 [ 10 m / s]
-7 2

1.168

0.70174

460.722 [ m / s ]
roductLatent Heat of Evaporation *)(kJ/kg)(Btu/lb)

cetic acid 402

Acetone 518

Alcohol 896

Alcohol, ethyl (ethanol) 846

Alcohol, methyl (methanol
alcohol, wood alcohol, wood
naphtha or wood spirits) 1100

Alcohol, propyl 779

Ammonia 1369
Aniline 450
Benzene 390

Bromine 193
Carbon bisulphide

Carbon dioxide 574

Carbon disulfide 351

Carbon tetrachloride 194

Chlorine 293
Chloroform 247

Decane 263

Dodecane 256
Ether 377
Ethylene glycol 800
Freon refrigerant R-11 180
Freon refrigerant R-11 165
Freon refrigerant R-11 232
Glycerine 974
Helium 21
Heptane 318
Hexane 365
Hydrogen 461
Iodine 164
Kerosene 251
Mercury 295
Methyl chloride 406
Nitrogen 199
Octane 298
Oxygen 214
 Propane 428
Propylene 342
Propylene glycol 914
Sulphur 1510
Sulfur dioxide
Toluene 351
Turpentine 293
173
223

385

364

473

335
589
193
168

83
160

247

151

83

106

113

110
162
344
77
71
100
419
9
137
157
198
71
108
127

86
128
92
184
147
393
650
164
151
126
 Latent
Latent Heat Melting Boiling
Heat
Vaporizati
Fusion Point Point
Substance on

kJ/kg °C kJ/kg °C

Alcohol, ethyl 108 −114 855 78.3

Ammonia 332.17 −77.74 1369 −33.34
Carbon dioxide 184 −78 574 −57
Helium 21 −268.93

Hydrogen(2) 58 −259 455 −253

Lead[9] 23 327.5 871 1750

Nitrogen 25.7 −210 200 −196

Oxygen 13.9 −219 213 −183

Refrigerant R134a −101 215.9 −26.6

Refrigerant R152a −116 326.5 -25

Toluene 72.1 −93 351 110.6

Turpentine 293

Water 334 0 2260 100

 roperty Value Unit

Medium : Air

Pressure : 146 [ bar ]

Temperature : 190 [ Celsius ]

Density : 103.94064 [ kg / m ] 3

Specific Enthalpy : 458.1016 [ kJ / kg ]

Specific Entropy : 5.849712 [ kJ / kg K ]
Specific isobar heat capacity
:
30.575104 cp 1.091968 [ kJ / kg K ]
Isobar coefficient of thermal
expansion : 2.243352 [ 10-3 (1 / K) ]
[ 10-3 (W / m *
Heat conductance 41.93616 K) ]

Dynamic viscosity : 27.38976 [ 10-6 (Pa s) ]

Kinematic viscosity : 0.2635134823 [ 10 m / s]

-6 2

Thermal diffusivity : 3.746 [ 10 m / s]

-7 2

Prandtl-Number : 0.7134056
Coefficient of
compressibility Z : 1.057976