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# C3 2.

4
Homework sheet
Name: Class:

## More titrations [Higher]

Aim
To gain further practice in solving titration problems.

## Atomic weights H=1 Li = 7 O = 16

Na = 23 S = 32 Co = 58.9 Cu = 63.5

Fairly straightforward
1 What volume of 0.2 M ammonia solution, NH 4OH, would be neutralised by 25 cm3 of 0.3 M nitric
acid, HNO3?
2 25 cm3 of sulfuric acid, H2SO4, neutralised 18.4 cm3 of 0.4 M potassium hydroxide, KOH. What
was the concentration of the acid?
3 What volume of 0.1 M hydrochloric acid, HCl, would neutralise 17.5 cm 3 of 0.2 M barium
hydroxide, Ba(OH)2?
4 25 cm3 of phosphoric acid, H3PO4, neutralised 42.6 cm3 of 0.2 M sodium hydroxide, NaOH. What
was the concentration of the acid?
5 What volume of 0.4 M ethanoic acid, CH3CO2H, would neutralise 17.6 cm3 of 0.3 M sodium
hydroxide?

Challenge
6 4.0 g of sodium hydroxide, NaOH, is dissolved in water and the solution diluted to 1 dm 3. What
volume of this solution would neutralise 25 cm 3 of 0.1 M sulphuric acid, H2SO4?
7 2.0 g of pure undiluted H2SO4 is cautiously added to water and the solution diluted to 500 cm 3.
What volume of 0.1 M potassium hydroxide, KOH, would exactly neutralise 25 cm 3 of the acid
solution?
8 What mass of copper oxide, CuO, would dissolve in 200 cm3 of 2.0 M sulfuric acid? What mass of
copper sulphate crystals, CuSO4.5H2O could then be obtained by letting the solution crystallise?
9 1.67 g of an alkali, formula QOH, was dissolved in water and the solution diluted to 500 cm 3.
25 cm3 of this solution exactly neutralised 35 cm3 of 0.1 M HCl. If you know that Q is an element
in Group 1 of the periodic table, identify Q.
10 Tm is a transition metal that forms an oxide of formula TmO. 10.7 g of TmO dissolved in 200 cm3
of 1.0 M sulfuric acid, forming a pink solution and neutralising some but not all of the acid. The
remaining acid was titrated with 1.0 M sodium hydroxide when 114.4 cm 3 was required for
complete neutralisation. Use this information to identify the transition metal Tm.