DIQI
Gpo: 2IM41
Tabla de datos experimentales
Temperatura pH.
°C
19 2.44
29 2.34
39 2.20
49 2.03
59 1.8
69 1.71
79 1.6
89 1.24
Ka1 =
¿
¿
¿
H2=10-2.34=0.00457 0.00457 ¿2
Ka2 =
¿
¿
¿
H3=10-2.20=0.00631 0.00631 ¿
2
Ka3 =
¿
¿
¿
H4=10-2.03=0.00933 0.009332
Ka4 = =0.000961
0.1−0.00933
H5=10-1.80=0.01580 0.01580
2
Ka5 = =0.002985
0.1−0.01580
H6=10-1.71=0.01940 0.019402
Ka6 = =0.004723
0.1−0.01940
H7=10-1.60=0.02510 0.02512
Ka7 = =0.008426
0.1−0.0251
H8=10-1.24=0.05754 0.057542
Ka8 = =0.07797
0.1−0.05754
°
Para obtener ∆ H R , se utiliza la ecuación de Vant Hof
°
1 −∆ H R
Donde y=InKa , x= , m=
T R
Determinacion de (x,y)
y=InKa 1
x=
T
y 4 =¿ ( 0.000961 )=−6.9479 1
x 4= =¿ 0.003104
322.15 K
Temperatura vs Ka
400
350 362.15
300
250
200 Valores Y
Temperatura
150
100
50
0
0 0.01 0.02 0.03 0.04 0.05 0.06 0.07 0.08 0.09
Constante de equiulibrio Ka
1/T vs In k
0
-1 0 0 0 0 0 0 0 0 0
-2
-3
-4 f(x) = - 9121.87x + 21.75
x=1/T -5 R² = 0.92
-6
-7
-8
-9
-10
In k
y=-9133.3x+21.748
Sustituyendo
1 −∆ H °R
y=InKa , x= , m=
T R
−∆ H °R
m= = -9133.3
R
J J
−∆ H °R =m∗R=−9133.3∗8.314 =75934.256
mol k mol k
∆ H °R
∆ S0 = =¿ ∆ G=−InKRT
T
75934.256 J /molK J
∆ S1=
292.15 K
=259.915 J /mol
(
∆ G1=−¿ ( 0.00137 ) 8.314
molK )
( 292.15 K ) =216103 J /molK
75934.256 J /molK J
∆ S2=
302.15 K
=251.313 J /mol
(
∆ G2=−¿ ( 0.000219 ) 8.314
molK )
( 302.15 K )
¿ 21168.6 J/molK
75934.256 J /molK J
∆ S3=
312.15 K
=243.262 J /mol
(
∆ G3=−¿ ( 0.000425 ) 8.314
molK )
( 312.15 K )=20148.3 J /molK
75934.256 J /molK J
∆ S4 =
322.15 K
=235.711 J /mol
(
∆ G4 =−¿ ( 0.000961 ) 8.314
molK )
( 322.15 K )
¿ 18609 J/molK
75934.256 J /molK J
∆ S5=
332.15 K
=228.514 J /mol
(
∆ G5=−¿ ( 0.002985 ) 8.314
molK )
( 332.15 K )=16055.8 J /molk
J J
∆ S6 =
75934.256
molK
=221.933 J /mol
(
∆ G6=−¿ ( 0.004723 ) 8.314
molK )
(342.15 K ) =¿
342.15 K
15234.1 J/molK
75934.256 J /molK J
∆ S7 =
352.15 K
=215.631 J /mol
(
∆ G7=−¿ ( 0.008426 ) 8.314
molK )
(352.15 K ) =13984 J /molK
75934.256 J /molK J
∆ S8 =
362.15 K
=209.676 J /mol
(
∆ G8=−¿ ( 0.07787 ) 8.314
molK )
( 362.15 K ) =6704.63 J /molK