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AIR POLLUTION MONITOR

AP-360CE Series

CO O3
NOX
SO2
HC

Type approved by European agencies and US.EPA


These ambient air pollution monitors are surprisingly
compact and easy to maintain for such sensitive,
precise and reliable instruments.

FEATURES
INDEX
Model Name and Application age values, three different timeset-
Automatic calibration ※ tings can be specified.
APMA-360CE 4
CO in ambient air Troublesome calibration procedures
have been reduced to the push of a
Storing data in memory ※
function key. At the Auto-Interval
APSA-360ACE 5 Calibration (AIC) menu you can set the Four different values may be stored in
SO2 in ambient air memory: three simple averages and
start time, the start range, and the
interval for the automatic calibration. the integrated value.
APNA-360CE The system clock and calendar then For example:
6 assure that your calibration instruc-
NO, NO2 and NOx in ambient air Average value #1 (3 min)
tions are executed precisely. To make → 1,000 data sets
things even easier, remote auto-cal- Average value #2 (30 min)
APHA-360CE ibration can also be done from your → 1,000 data sets
7
CH4, NMHC and THC in ambient air own computer, via the monitor's RS- Average value #3 (3 h)
232C serial port (optional). → 100 data sets
Integrated value (1 h)
APOA-360CE 8 → 1,000 data sets
O3 in ambient air Auto-range function

An auto-range function that automati- Readout toggles to mg/m3 ※


cally switches to the range best suited
to the object gas concentration for both A touch of a button on the front panel
momentary and average values is is all that is needed to toggle the
included as a standard feature. As an readout from ppm or ppb to mg/m 3.
option, even when randomly set to any (Not available on Model APHA-360CE,
range (within 10 times the range ratio), where CH 4 values are displayed as
the auto-range function can still be ppm, NMHC and THC as ppmC.)
used. Switching over from auto-range
to manual-range is a simple task.
Pressure-compensation ※

Selective data output ※ Automatic compensation for ambient


pressure assures reliable data regard-
For each component measured, the less of the weather or the monitor's
system provides four types of data: location.
momentary values, integrated values,
moving averages, and simple aver- Easy-to-read 256 × 64 dot-matrix
ages. Any two of theses may be out- fluorescent readout display
put. Simultaneous output to any two
external devices (e.g., PC, printer). The Separate menus for measurement,
time-span for both average and inte- calibration, alarms, maintenance, and
grated values may be specified (i.e., other functions are easy to read on the
when the momentary value has not fluorescent readout display. Menu
been selected). With the simple aver- switching is a one-touch operation.

2
AP-360CE Series

FRONT PANEL
Readout display cursor keys
The alarms menu lets you see clearly
any malfunction or error, including
zero calibration errors, span calibra-
tion errors, and flow-volume errors.
The maintenance menu gives digital
readouts of valuable status informa-
tion, including detector temperature
and sample pressure.

Minimal influence from interference


components and ambient temperature
These monitors use Horiba's in-
novative detection technology and
sampling method for outstanding sen-
sitivity. The influence from interfer-
ence components is minimal and
results are very stable over long
periods of measurement. power switch function keys DEC key INC key

Input/output via RS-232C port ※ Measurement


(option)
The systems' RS-232C serial port can
be used to transmit measured values,
alarms, and other data to remote
equipment. It can also be used to
input changes to parameter settings
Calibration
and other data. A hard-copy printout of
measured values can be produced by
attaching a recorder to the RS-232C
port.

Alarms
At last ---- a small, compact system

A small, light-weight unit for each


component to be measured fits neatly
into a 19inch rack. This makes it easy
to up-grade your system for multi- Maintenance
component capabilities. This new
design offers great savings in valu-
able lab space.

3
APMA--360CE
Ambient
CO Monitor

U.S.EPA Designation number: RFCA-0895-106


Umweltbundesamt, Pilot Station Offenbach, Report No.22, March 1996

Features Principle Specifications


■ The cross flow modulation type, Cross flow modulation, inflared- Principle: Cross flow modulation,
infrared-absorption technology elimi- absorption technology (NDIR) non-dispersive infrared absorption
Conventional technology uses an opti- technology (NDIR)
nates the need for troublesome optical
cal chopper to obtain modulation sig- Application: CO in ambient air
adjustments. For the user, this means
Range:
very stable and sensitive (5 ppm F.S.) nals. Instead of this, the APMA-360CE
Standard ranges: 0-10/20/50/100 ppm;
measurements. uses a solenoid valve modulation.
0-5/10/20/50 ppm; auto range ∼ manual
Fixed amounts of the sample gas and
range selectable; can be operated by
■ The APMA-360CE uses an AS- the reference gas are injected alter- remote switching.
type interference-compensating detec- nately into the measurement cell. With Optional (measurable) ranges: 4 ranges
tor, and a flowing reference gas. The the cross flow-modulation method, if selectable from 0-100 ppm, within 10
reference gas is generated by purging the same gas is used for both the times range ratio; auto range ∼ manual
sample through an oxidation process, sample gas and the reference gas (e. range selectable; can be operated by
where an oxidizing catalyst burns the g., zero gas could be used for both), no remote switching.
CO to CO2. These features eliminate modulation signal will be generated. Lower detectable limit: 0.02 ppm (3 sigma)
the interference effect of other ele- This has the great advantage that, in Repeatability: ± 1.0 % of F.S.
principle, when analyzing minute Linearity: ± 1.0 % of F.S.
ments, resulting in extremely high accu-
amounts of gas there is no generation Zero drift:
rate measurements.
<LDL/day at lowest range
of zero-drift. An additional advantage
<0.2ppm/ week at lowest range
■ The APMA-360CE does not use is that the elimination of rotary sectors
Span drift:
components, such as reflecting mirrors, precludes the need for optical adjust-
<LDL/day at lowest range
that attract foreign matter. This means ment. These features assure greatly ± 1.0% F.S./week
the optical bench stays clean assuring improved stability over long periods of Response time (T90):
you of stable results over long periods measurement. A further improvement Within 50 sec at lowest range
of time. is that in the front chamber of the Sample gas flow rate: Approx. 1.5L/min
detector, the measurable components, Indication: Measured value, range,
including interference components, alarm, maintenance screen
are detected; in the rear chamber, Alarms: During AIC, zero calibration
interference components only are error, span calibration error, temperature
detected. By means of subtraction error in catalyzer, etc.
processing, the actual signal obtained On-screen messages are available in
four languages: English, German,
is one that has only very little interfer-
French, and Japanese.
ence influence.
Input/output:
・ 0-1V/0-10V/4-20 mA, to be specified
(2 systems: either (1) momentary value
and integrated or (2) moving average
calibration
zero gas
value)
inlet ・ Contact input/output
calibration
span gas ・ RS-232C
inlet flow sensor
Ambient temperature: 5-40 ℃
Power: 100/110/115/120/220/230/240
pressure
sensor
VAC, 50/60 Hz (to be specified)
Dimensions: 430(W)× 550(D)× 221(H)mm
filter
analyzer
Mass: Approx. 20 kg,
sample
exhaust
inlet
H2O flow sensor buffer pump
buffer buffer tank
catalyzer tank

filter

4
APSA--360ACE
Ambient
SO2 Monitor

U.S.EPA Designation number: EQSA-0197-114


TÜV Rheinland, Cologne, Report No. 936/805008/SO2, 29.02.1996

Features Principle Specifications


■ The APSA-360ACE uses an UV fluorescence Principle: UV fluorescence (UVF)
innovative detector and a new optical The UV fluorescence method operates on Application: SO2 in ambient air
the principle that when the SO2 molecules Range:
system for low background, high
contained in the sample gas are excited Standard ranges: 0-0.05/0.1/0.2/0.5 ppm;
sensitivity (0.05 ppm F.S.:), and greatly
auto range ∼ manual range selectable; can
improved stability. by ultraviolet radiation they emit a charac-
be operated by remote switching.
teristic fluorescence in the range of 220-
Optional (measurable) ranges: 4 ranges
■ Fluorescent chamber design 240 nm. This fluorescence is measured
selectable from 0-10 ppm, within 10 times
gives measurements with minimum and the SO2 concentration is obtained range ratio; auto range ∼ manual range
influence from moisture. from changes in the intensity of the fluo- selectable; can be operated by remote
rescence. The reactive mechanism is switching.
■ The unit has built-in aromatic- (1) SO2+hν1 → SO2* (3) SO2* → SO+(O) Lower detectable limit: 0.5 ppb (3 sigma)
hydrocarbon cutter with a selective (2) SO2* → SO2+hν2 (4) SO2*+M → SO2+M Repeatability: ± 1.0 % of F.S.
transmission membrane. This reduces Here, (1) shows the excited state of the SO2 Linearity: ± 1.0 % of F.S.
the influence of interference compo- molecules that have absorbed the amount Zero drift:
nents. Coupled with Horiba's unique of energy hν1 by ultraviolet radiation. (2) <LDL/day at lowest range
shows the amount of energy, hν2 emitted <LDL/week at lowest range
flow-path, it also makes it possible to
by the excited molecules as they return to Span drift:
extend the working life of the cutter and
<LDL/day at lowest range
to take measurements free from influ- the ground state. (3) shows the decompo-
<LDL/week at lowest range
ence from variations of sample flow. sition by the light emitted from the excited
Response time (T90):
molecules. (4) shows the quenching, i.e.,
Within 120 sec at lowest range
■ In comparison with the FPD method, the energy lost by the excited molecules Sample gas flow rate: Approx. 0.8L/min
the APSA-360ACE design is (1) highly colliding with other molecules. The APSA- Indication: Measured value, range,
selective for SO2, (2) requires no supple- 360ACE uses an Xe lamp as the light alarm, maintenance screen
mental gas, and (3) gives linear output. source, and the fluorescent chamber Alarms: During AIC, zero calibration
design mini-mizes scattered light. The error, span calibration error, temperature
■ Compensation for the lamp's lumi- optical system has been carefully error in catalyzer, light intensity error, etc.
nous energy guarantees prolonged designed with low background, making it On-screen messages are available in
span stability. possible to take measurements with a four languages: English, German,
highly stable zero-point. In addition, a ref- French, and Japanese.
erence detector monitors any fluctuation Input/output:
■ The sample inlet has a Teflon filter
・ 0-1 V/0-10 V/4-20 mA, to be specified
built-in. in the intensity of the light source. This
(2 systems: either (1) momentary value and
allows the unit to calibrate itself automati-
integrated or (2) moving average value)
■ The unit comes with a built-in a cally for sensitivity, resulting in greater
・ Contact input/output
span-gas dilution unit. span stability. ・ RS-232C
Ambient temperature: 5-40 ℃
Power: 100/110/115/120/220/230/240
pressure sensor VAC, 50/60 Hz (to be specified)
Dimensions: 430(W)× 550(D)× 221(H)mm
Mass: Approx. 25 kg,
analyzer buffer
filter cutter tank
sample inlet exhanst

flow sensor pump


calibration
gas inlet

filter catalyzer

5
APNA--360CE
Ambient
NOx Monitor

U.S.EPA Designation number: RFNA-0196-111


Umweltbundesamt, Pilot Station Offenbach, Report No.24, March 1996

Features Principle Specifications


■ The APNA-360CE uses a combi- Cross flow modulation type, reduced Principle: Cross flow modulation type,
nation of (1) the dual cross flow modu- pressure chemiluminescence (CLD) reduced pressure chemiluminescence (CLD)
The chemiluminescence method uses Application: NO2, NO and NOx in ambient air
lation type chemiluminescence principle
the reaction of NO with O3 Range:
and (2) the referencial calculation
Standard ranges: 0-0.1/0.2/0.5/1.0 ppm;
method. This gives it the advantages of NO + O3 → NO2* + O2
auto range ∼ manual range selectable;
the single-detector method plus the NO2* → NO2 + hν
can be operated by remote switching.
ability to do continuous measurements A portion of the NO2 generated as the
Optional (measurable) ranges: 4 ranges
of NOx, NO, and NO2. The design result of this reaction becomes NO 2*. selectable from 0-10 ppm, within 10
gives great stability and extremely high As these excited molecules return to times range ratio; auto range ∼ manual
sensitivity (F.S. 0.1 ppm) the ground state, chemiluminescence is range selectable; can be operated by
generated in the range of 600 nm 3,000 remote switching.
■ Standard equipment includes a nm. The light intensity is in proportion Lower detectable limit: 0.5 ppb (3 sigma)
drier unit with an automatic recycle to the concentration of NO molecules Repeatabiliy: ± 1.0 % of F.S.
function to provide dry ambient air as and by measuring it we obtain the NO Linearity: ± 1.0 % of F.S.
the ozone source. This makes longrun concentration of the sample. A deoxida- Zero drift:
tion converter changes the NO2 to NO, <LDL/day at lowest range
continuous measurements possible.
which is measured. In other words, the ± 1.0ppb/week at lowest range
Span drift:
■ The detector uses a semiconduc- NO2 concentration can be obtained by
<LDL/day at lowest range
tor sensor for compactness and long the difference between (1) the NOx
± 1.5 % of F.S./week
working life. concentration measured when the sam-
Response time (T90):
ple gas is directed through a converter Within 90 sec at lowest range
■ All the necessary features are built and (2) the NO concentration measured Sample gas flow rate: Approx. 0.8L/min
right into a single rack-sized unit, when the gas is not run through the Indication: Measured value, range, alarm,
including a reference-gas generator, an converter. maintenance screen
ozone-source drier unit, an ozone Alarms: During AIC, zero calibration error,
decomposer, and a sampling pump. No span calibration error, temperature error in
supplemental gas is required. converter, etc.
On-screen messages are available in four
languages: English, German, French, and
Japanese.
Input/output:
・ 0-1 V/0-10 V/4-20 mA, to be specified
(2 systems: either (1) momentary value and
integrated or (2) moving average value)
・ Contact input/output
・ RS-232C
ozonator Ambient temperature: 5-40 ℃
filter filter unit
Power: 100/110/115/120/220/230/240
dryer VAC, 50/60 Hz (to be specified)
filter filter
filter pump Dimensions: 430(W)× 550(D)× 221(H)mm
Permeation
dryer Mass: Approx. 26 kg,
drier
calibration gas inlet
buffer
tank
sample inlet
pressure
filter converter sensor
unit deozonizer
exhanst
buffer
Permeation filter flow tank pump
drier analyzer
sensor

6
APHA--360CE
Ambient
THC Monitor

Umweltbundesamt, Pilot Station Offenbach, Report No.25 , March 1996

Features Principle Specifications


■ The APHA-360CE uses a combi- Flame ionization detection method Principle: Flame ionization detection (FID)
nation of (1) the flame ionization detec- (FID) with selective combustion with selective combustion
The flame ionization detection method Application: THC, NMHC, and CH4 in
tion method (2) and selective-combus-
(FID) --- used in combination with the ambient air
tion. This gives it the advantages of the
Range:
single-detector method plus the ability selective-combustion system --- uti-
Standard ranges: 0-5/10/25/50 ppmC;
to do continuous, zero-drift free mea- lizes the ionization that occurs as the
auto range ∼ manual range selectable;
surements of THC, NMHC, and CH 4. result of the high-temperature energy
can be operated by remote switching.
The design gives great stability and from combustion at the tip of the Optinal (measurable) ranges: 4 ranges
high sensitivity (F.S. 5 ppm) burner jet when organic carbon com- selectable from 0-100 ppmC, within 10
pounds are introduced into the hydro- times range ratio; auto range ∼ manual
■ The APHA-360CE has a rela- gen flame. The hydrogen flame is range selectable; can be operated by
tive-sensitivity correction function for located between two electrodes. remote switching.
CH4 and NMHC. When an electrical voltage is applied Lower detectable limit: 0.022 ppmC (3 sigma)
across these electrodes a minute ion Repeatabiliy: ± 1.0 % of F.S.
■ A catalytic unit for generating current proportional to the hydrocar- Linearity: ± 1.0 % of F.S.
bon concentration is produced. This Zero drift:
reference gas and auxiliary combus-
current is monitored by a low leakage <LDL/day at lowest range
tion air is standard equipment in the
± 0.05 ppmC/week at lowest range
APHA-360CE. amplifier, giving a voltage readout for
Span drift:
THC. To measure CH4 the sample gas
<LDL/day at lowest range
■ All the necessary features are is passed through the selective cata-
± 0.5 % F.S./week
built right into a single rack-sized lytic combustion unit (the NMHC cut- Response time (T90):
instrument, including a catalytic unit ter), which oxidizes NMHC without Within 60 sec at lowest range
for selective combustion (i.e., an oxidizing CH4. This is shown as A Sample gas flow rate: Approx. 0.5L/min
NMHC cutter); a cataytic unit for below. B represents the THC concen- Indication: Measured value, range, alarm,
generating reference gas and auxiliary tration measured without passing the maintenance screen
combustion air; and a sampling pump. gas through the NMHC cutter. Thus B Alarms: During AIC, zero calibration error,
The only supplemental gas required is - A will give the concentration of span calibration error, temperature error
H2. NMHC. The final concentration value in zero gas purifier, ignition failure error,
is calculated using a relative-sensi- etc.
tivity correction coefficient, k, as shown On-screen messages are available in four
languages: English, German, French,
below.
and Japanese.
CH4 Concentration A
Input/output:
NMHC Concentration k (B - A)
・ 0-1 V/0-10 V/4-20 mA, to be specified
THC Concentration A + k (B - A) (2 systems: either (1) momentary value and
integrated or (2) moving average value)
filter ・ Contact input/output
fuel (H2) inlet
calibration ・ RS-232C
zero gas inlet
calibration
Ambient temperature: 5-40 ℃
flow sensor
span gas inlet flow sensor buffer tank
Power: 100/110/115/120/220/230/240
sample inlet
filter dummy
filter VAC, 50/60 Hz (to be specified)
exhanst
pump Dimensions: 430(W)× 550(D)× 221(H)mm
non-methan cutter filter

bufer
Mass: Approx. 33 kg,
zero gas analyzer
purifier
tank
pressure
Notes: ppmC is shown as symbol, not as
sensor unit.
filter filter

drier
filter filter

drier pressure
sensor

7
APOA--360CE
Ambient
O3 Monitor

U.S.EPA Designation number: EQOA-0196-112


Tüv Rheinland, Cologne, Report No. 936/805008/O3, 29.02.1996

Features Principle Specifications


■ The APOA-360CE uses the Ultra-violet-absorption method Principle: Ultra-violet-absorption method (NDUV)
cross flow modulation type, ultra-vio- (NDUV) Application: O3 in ambient air
The ultra-violet-absorption method Range:
let-absorption method in conjunction
works on the principle that ozone Standard ranges: 0-0.1/0.2/0.5/1.0 ppm;
with the comparative calculation
auto range ∼ manual range selectable;
method. This permits continuous mea- absorbs ultra-violet rays in the area of
can be operated by remote switching.
surement with great stability and high 254 nm. Measurements are taken from
Optional (measurable) ranges: 4 ranges
sensitivity (F.S. 0.1 ppm) continuous, alternate injections of the
selectable from 0-10 ppm, within 10 times
sample gas and the reference gas into range ratio; auto range ∼ manual range
■ Horiba's innovative heated de- the measurement cell, controlled by a selectable; can be operated by remote
ozonizer provides reference gas by long-life solenoid valve. The cross switching.
decomposing the O3 found in the sam- flow modulation method is character- Lower detectable limit: 0.5 ppb (3 sigma)
ple gas. This has the advantages of (1) istically zero drift-free. All fluctuations Repeatability: ± 1.0 % of F.S.
reducing the influence from interfer- in the mercury-vapor light source and in Linearity: ± 1.0 % of F.S.
ence, (2) making the monitor insensi- the detector are automatically com- Zero drift:
tive to great changes in moisture con- pensated for by a comparative cal- <LDL/day at lowest range
culation circuit. This means that, in <LDL/week at lowest range
tent, and (3) prolonging the working life
principle, the APOA-360CE makes it Span drift:
of the monitor.
<LDL/day at lowest range
possible to carry out zero-span drift-
<LDL/week at lowest range
■ All gas connections are either free, continuous measurements. In
Response time (T90):
Teflon or glass. addition, HORIBA'S unique de-ozonizer
Within 75 sec at lowest range
for the comparison gas line is unaf- Sample gas flow rate: Approx. 0.8L/min
fected by interference elements or Indication: Measured value, range, alarm,
moisture retention, prolonged, stable maintenance screen
measurement is possible. Alarms: During AIC, zero calibration error,
span calibration error, temperature error
in ozone separator, light intensity error,
etc.
On-screen messages are available in four
languages: English, German, French,
and Japanese.
Input/output:
・ 0-1V/0-10V/4-20 mA, to be specified
(2 systems: either (1) momentary value and
integrated or (2) moving average value)
・ Contact input/output
・ RS-232C
Ambient temperature: 5-40 ℃
Power: 100/110/115/120/220/230/240
VAC, 50/60 Hz (to be specified)
Dimensions: 430(W)× 550(D)× 221(H)mm
pressure sensor
Mass: Approx. 20 kg,
analyzer buffer
flow sensor tank
sample inlet exhanst
deozonizer
pump

calibration gas inlet

8
H2S/NH3 Measurement
H2S Measurement
Combined use of the H2S converter unit and the APSA-
360ACE SO2 Monitor makes H2S measurement possible.
The H2S converter unit contains two types of catalyst: SOx
scrubber and H2S converter. SOx is removed by the SOx
scrubber, and then the H2S that has passed through is con-
verted into SO 2 by the H 2S converter. This SO 2 is then
measured by the APSA-360ACE SO2 Moniter for display as
H2S concentration.

NH3 Measurement
Combined use of the NH3 converter unit and the APNA-
360CE NOx Monitor makes NH 3 measurement possible.
The NH 3 converter unit contains two types of catalyst
tubes: one which converts NH3 into NOx, and one which
allows the NOx in the ambient air to pass through directly.
The difference in NOx value between the two is measured
by the APNA-360CE NOx Monitor for display as NH3 con-
centration.

Standard Gas Generator


The SGGU Standard Gas Generator eliminates the prob-
lems of instability of bottled span gases containing low
concentrations of SO2 or NOx. The zero gas is also gen-
erated using ambient air. Reliable span gas of SO2 or NOx
at an extremely low concentration is generated by an
innovative flow rate ratio mixing technique which dilutes a
known standard gas of a sufficiently high concentration
with zero gas produced within the unit. The OPGU, which
generates pure hydrogen (H2), is also available to provide
a safe supply of fuel for the APHA-360CE (THC).

9
Standard 19-inch Packages
Each HORIBA AP-360CE Series Monitor is packaged in a light metal enclosure with sliding chassis suitable for
either a table-top set-up in a research laboratory or mounting on a standard 19-inch rack for permanent installation.
All the controls and serviceable components are accessible from the front for easy maintenance while the
plumbing and cable connections are neatly arranged at the back.
APMA-360CE/APSA-360ACE/APNA-360CE/APHA-360CE/APOA-360CE Unit: mm

482
465
430

221

70
146

POWER

21
41.9 238.1 212.7

550

10
11
Horiba continues contributing
to the preservation of the global
environment through analysis
and measuring technology.

Please read the operation manual before using this product to assure safe and proper handling of the product.

● The contents of this catalog are subject to change without prior notice, and without any subsequent liability to this company.
● The color of the actual products may differ from the color pictured in this catalog due to printing limitations.
● It is strictly forbidden to copy the content of this catalog in part or in full.

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