Sri Chaitanya IIT Academy

SINGLES

Ans :1
2

Ans :1

Ans :2

Ans :4
7

Ans :4
8

Ans :3

Ans :B
Which of the following pairs have similar shape?
N ( CH 3 ) 3 , N ( SiH 3 ) 3 -2
1) 2) NF3 , BF3 *3) SO3 , CO3 4) CH 4 , XeF4
Which of the following molecule has zero dipolemoment?

*1) PBr3Cl2 2) PF3Br2

3) CH2Cl2 4) Hydroquinone
Which of the following molecules are planar?
F C = C = CF N H
(i) 2 2 (ii)N2F2 (iii) B3N3H6 (iv) 2 4 (v) I2Cl6
*1) ii, iii and v only 2) i,ii,iii and iv only
3) iii, iv and v 4) ii and iii only

In solid state PCl5 exist as an ionic solid. Hybridisation of phosphorous in cation

and anion are respectively
3 3 2 3 2 3 3 3 3 3
*1) sp , sp d 2) sp d , sp 3) sp , sp d 4) sp d , sp
0
The maximum number of 90 angles between bond pair-bond pair electrons is
 3 2
observed in sp d hybridization are
1) 4 2) 8 *3) 12 4) 10
Shape of ClF5 respectively
1) T-shape 2)Tetrahydral
3) Trigonal bipyramidal *4) square pyramidal
In which of the following pairs, the two species are not isostructural ?
+ 2- - 3-
1) PCl4 & SiCl 4 2) CO3 & NO3 3) AlF6 & SF6 *4) PF5 & BrF5
If the ionization enthalpy and electron gain enthalpy of an element are 275 and
-1
86 kcal mol respectively, then the electro negativity of the element on the
Pauling scale is:
*1) 2.8 2) 0.0 3) 4.0 4) 2.6
Which are the following pairs of species have identical shapes?
+ -
1) NO2 and NO2 2) PCl5 and BrF5
-
*3) XeF4 and ICl 4 4) TeCl 4 and XeO4
N2 and O2 are converted to monocations N+2 and O+2 respectively, which is
wrong statement:
+
1) In N2 , the N - N bond weakens
+
2) In O2 , the O - O bond order increases
+
3) In O2 , the paramagnetism decreases

+
*4) N2 becomes diamagnetic
Incorrect match in the following is
�
CCl3 Planar
1) CF3 - pyramidal 2)
N ( SiH 3 ) 3 - planar ( NH 2 ) 3 C � - pyramidal
3) *4)
+ - +
The hybridization of atomic orbitals of nitrogen in NO2 , NO3 and NH 4
respectively are
3 2 2 3 2 3 2 3
1) sp, sp and sp *2) sp, sp and sp 3) sp , sp and sp 4) sp , sp and sp
The correct order for bond angles is:
NO2+ > NO2 > NO2- + -
2) NO2 > NO2 > NO2
1)
 - + - +
3) NO2 > NO2 > N 02 4) NO2 > NO2 > NO2

Ans: 1 Cl
Cl

Cl Cl
Cl

The dipole moment of is 1.5 D. The dipole moment of is :

(A) 0 D *(B) 1.5 D (C) 2.86 D (D) 2.25 D
The type of hybridization shown by the central atom A in AB5 type of inter
halogen compounds is
3 3 2 3 3 3
1) sp d *2) sp d 3) sp d 4) sp
Which of the following about SF4 ,OSF4 and COF2 molecule is correct

1) Equatorial FSF bond angle in OSF4 will be less than in SF4 molecule

2) Hybridisation state of sulphur in

SF and OSF molecule will be different
4 4

*3) The bond angle FCO will be greater than 120 in molecule OCF2
0

4) The axial FSF bond angle in SF4 is 180

0

Linear structure is assumed by

+

II) CS 2 III) N O2 IV) Solid BeH 2

-
I) NCO
A) all four B) (II), (III) and (IV)
*C) (I), (II) and (III) D) (II) and (III)
2-
Which of the following is isostructural of Cr2O7 ?

2- 2- 2- 2-
*(A) S2O7 (B) S2O6 (C) S2O8 (D) S2O5
Incorrect order of covalent character among the following is
(a) LiF<LiCl<LiBr<LiI (b) NaCl<MgO<AlN<SiC
*(c) Mg3N2<MgO<MgF2 (d) CsCl<RbCl<KCl<LiCl
Ans :1 or 2 or 3

Ans :2

Ans :3

Ans :3
 Ans :1

Ans :C
- -
The xenon compounds that are iso structural with IBr2 and BrO3 , respectively
are

*1) Linear XeF2 and pyramidal XeO3 2) bent XeF2 and pyramidal XeO3

3) Bent XeF2 and planar XeO3 4) linear XeF2 and tetrahedral XeO3
Select the incorrect statement among the following:

1) NF3 is weaker base than NH 3 .

2) AlCl3 is largely covalent while AlF3 is largely ionic.

3) B2 H 6 2 NH 3 is ionic.
*4) NO has one unpaired electron in bonding molecular orbital.
If there was no interaction between S and P orbital before formation of
molecular orbitals, the type of bonds between ‘C’ atoms in C2 molecule would
be
1) 2p bonds *2) one s and one p bond
3) 2s bonds 4) 2s and one p bond
Increasing order of dipole moments is given by
1) CF4 < NH3 < NF3 < H2O 2) CF4 < NH3 < H2O < NF3
3) CF4 < NF3 < H2O < NH3 *4) CF4 < NF3 < NH3 < H2O
Which of the following set of species have planar structures?
- - - 2- - -
1) I 3 , CH 3 , ClO3 , SiF6 2) I 3 , ICl4 , Al2Cl6 , TeCl4
- -
3) SCl2 , N 2O5 , SF4 , XeOF4 *4) I 2Cl6 , XeF2 , BrF4 , XeF5

Multiples
Ans : AD
The presence of sp mixing in N 2 can be confirmed by

a) removal of one electron from s 2 p2 orbital

*

b) addition of one electron to p 2p orbital

*c) removal of two electrons from s 2 p2 orbital

*

d) addition of two electron to two p 2p orbitals

Which of the following is/are correct for the compound PhC≡N–O?

*A) It has a formal charge of +1 on nitrogen.

*B) It has a formal charge of -1 on oxygen.

C) It has a formal charge of +2 on nitrogen.

D) It has a formal charge of -2 on oxygen.

Ans :D
Which of the following pair of species (hypothetical) is/are having same bond
order and same magnetic moment.
+
*A) He–H and H2– *B) O2 and NO
 *C) He + and Li + *D) N2+ and N2–
2 2
Which of the following pair of species (hypothetical) is/are having same bond
order and same magnetic moment.
+
*A) He–H and H2– *B) O2 and NO

*C) He + and Li + *D) N2+ and N2–

2 2
In all the following molecules the central atom is having two bond pairs and
two lone pairs. The smallest bond angle is present in
OF2 H 2O SF2
B) C) D)
A) HOF

Ans : A and D

Ans :CD
The true statements regarding the properties of ionic compounds are:

*A) Ionic reactions in aqueous medium are fast and spontaneous.

*B) Ionic compounds do not exhibit stereoisomerism due to the non-directional

nature of the bond.

*C) Large cation, small anion and less charge on both of them is favorable for

ionic bond formation

D) Molten ionic compounds conduct electricity due to free movement of

electrons

INTEGER TYPE

Find the number of molecule(s) is/are having zero dipole moment and linear
shape from the following ClF3, CO2 HgCl2 ,XeF2, N2O, NOCl
Ans :3
Ans :2
Boron nitride which is isoelectronic and isostructural with graphite is made of

fused hexagonal rings made of boron and nitrogen atoms alternatively. The

number of p bonds in each hexagonal ring is

Ans :6
The number of tetrahedral bond angles (109° 28�
) in CH2F2 is

Ans :0
Find the number of molecule (s) which is/are planar and have net dipole moment
SF4 , PCl3F2 , PCl 2 F3 , XeF2 , BrF3
Ans :1

The number of molecules among the following having angular shape is

SO2, SOCl2, SnCl2, CO2, NO2, H2O, NH3, N2O, BeCl2

Ans :4
PARAGRAPH

VSEPR theory proposes that the stereochemistry of an atom in a molecule is

determined primarily by the repulsive interactions amongst all the electron
pairs in the valence shell.The shape of a molecule is determined by the
arrangement and the repulsion between all the electron pairs present in the
valence shell of the central atom. The magnitude of the repulsion between the
bonding pairs of electrons depends on the electro negativity difference
between the central atom and the other atoms bonded with it. When an atom
with filled valence shell and one or more lone pairs is bonded to an atom with
an incomplete valence shell, or a valence shell that can become incomplete by
electron shifts there is a tendency for the lone pairs to be partially transferred
from the filled to the unfilled shell.
Which of the following statement is wrong.
*A) Dimethyl ether is a weaker base than disilyl ether
B) Methyl isocyanate (CH3 – N = C = O) is bent, but silyl isocyanate
(SiH3 – N = C = O) is linear (neglecting hydrogens)
C) In trisilyl amine (SiH3)3N all N – Si bond lengths are identical but shorter than
the expected N – Si bond length
D) NMe3 and N(SiMe3)3 are not isostructural
Trialkyl amine and trialkyl phosphine forms corresponding amine oxides and
phosphine oxides respectively. Regarding N – O and P – O bonds in these
compounds the wrong statement is
A) P – O bond is stronger than N – O bond
*B) P – O bond is more polar than N – O bond
C) P – O bond has double bond character while N – O bond is not
D) Phosphine oxides have less dipole moment than amine oxides

MATCHING

Match the Column – I with Column-II

COLUMN - I COLUMN – II
 NH4Cl Covalent bond

HNC Ionic bond

H2O2 Hydrogen bond

Liquid

CuSO4 .5H2O Co-ordinate bond

Ans :A-PQS,B- PS,C-PR D- PQRS

Ans :C